CN103328437B - 加成-断裂剂 - Google Patents

加成-断裂剂 Download PDF

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Publication number
CN103328437B
CN103328437B CN201280006055.2A CN201280006055A CN103328437B CN 103328437 B CN103328437 B CN 103328437B CN 201280006055 A CN201280006055 A CN 201280006055A CN 103328437 B CN103328437 B CN 103328437B
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China
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group
meth
addition
acrylate
afm
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CN201280006055.2A
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English (en)
Chinese (zh)
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CN103328437A (zh
Inventor
G·D·乔利
L·R·克里普斯基
A·R·福尔诺夫
S·尤尔特
B·N·加达姆
A·S·阿布尔雅曼
M·A·克罗普
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Shuwanuo Intellectual Property Co
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/205—Compounds containing groups, e.g. carbamates
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/16—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
    • C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/593—Dicarboxylic acid esters having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
CN201280006055.2A 2011-02-15 2012-02-01 加成-断裂剂 Active CN103328437B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161442980P 2011-02-15 2011-02-15
US61/442,980 2011-02-15
US13/169,306 US20120208965A1 (en) 2011-02-15 2011-06-27 Addition-fragmentation agents
US13/169,306 2011-06-27
PCT/US2012/023475 WO2012112304A1 (en) 2011-02-15 2012-02-01 Addition-fragmentation agents

Publications (2)

Publication Number Publication Date
CN103328437A CN103328437A (zh) 2013-09-25
CN103328437B true CN103328437B (zh) 2016-05-04

Family

ID=46637380

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280006055.2A Active CN103328437B (zh) 2011-02-15 2012-02-01 加成-断裂剂

Country Status (6)

Country Link
US (2) US20120208965A1 (https=)
EP (2) EP2675783B1 (https=)
JP (1) JP5925218B2 (https=)
KR (1) KR101940161B1 (https=)
CN (1) CN103328437B (https=)
WO (1) WO2012112304A1 (https=)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10370322B2 (en) 2011-02-15 2019-08-06 3M Innovative Properties Company Addition-fragmentation agents
WO2012112350A2 (en) 2011-02-15 2012-08-23 3M Innovative Properties Company Dental compositions comprising ethylenically unsaturated addition-fragmentation agent
US20120208965A1 (en) 2011-02-15 2012-08-16 3M Innovative Properties Company Addition-fragmentation agents
US9433563B2 (en) 2011-06-29 2016-09-06 Bradley D. Craig Dental compositions comprising a fatty mono(meth)acrylate
US9758597B2 (en) * 2011-08-05 2017-09-12 The Regents Of The University Of Colorado, A Body Corporate Reducing polymerization-induced shrinkage stress by reversible addition-fragmentation chain transfer
EP2747737B1 (en) 2011-08-23 2019-09-25 3M Innovative Properties Company Dental compositions comprising addition-fragmentation agents
JP6087355B2 (ja) * 2011-08-23 2017-03-01 スリーエム イノベイティブ プロパティズ カンパニー 付加開裂剤
EP2834313A1 (en) 2012-04-03 2015-02-11 3M Innovative Properties Company Crosslinkable composition comprising photobase generators
US9414996B2 (en) 2012-11-12 2016-08-16 3M Innovative Properties Company Dental compositions comprising addition-fragmentation agents
JP6403679B2 (ja) * 2012-11-12 2018-10-10 スリーエム イノベイティブ プロパティズ カンパニー 付加開裂剤
EP2931756B1 (en) * 2012-12-17 2018-08-08 3M Innovative Properties Company Addition-fragmentation oligomers
WO2014116461A1 (en) 2013-01-24 2014-07-31 3M Innovative Properties Company Photoinitiated oligomerization of methacrylate esters
JP6300899B2 (ja) * 2013-03-20 2018-03-28 スリーエム イノベイティブ プロパティズ カンパニー 高屈折率の付加−開裂剤
WO2014172138A1 (en) 2013-04-15 2014-10-23 3M Innovative Properties Company Dental composition containing high refractive index monomers
WO2015041863A1 (en) 2013-09-20 2015-03-26 3M Innovative Properties Company Trithiocarbonate-containing addition-fragmentation agents
CN105683257B (zh) * 2013-10-16 2018-02-13 3M创新有限公司 包含烯丙基二硫化物的加成‑断裂低聚物
JP6647206B2 (ja) 2014-02-18 2020-02-14 スリーエム イノベイティブ プロパティズ カンパニー 高屈折率基を有する付加開裂オリゴマー
WO2016069290A1 (en) 2014-10-31 2016-05-06 3M Innovative Properties Company Dental materials and methods
US10350297B2 (en) 2014-10-31 2019-07-16 3M Innovative Properties Company Dental materials and methods
US10479848B2 (en) 2015-02-20 2019-11-19 3M Innovative Properties Company Addition-fragmentation oligomers
WO2017136374A1 (en) 2016-02-05 2017-08-10 3M Innovative Properties Company Dental compositions comprising nanoparticles providing a refractive index differential between polymerizable resin and filler
JP6865898B2 (ja) 2017-12-21 2021-04-28 スリーエム イノベイティブ プロパティズ カンパニー シラン処理された表面を有する歯科用無機充填剤
JP7366134B2 (ja) * 2018-12-13 2023-10-20 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン （メタ）アクリレート官能化ワックスおよびそれと共に作製される硬化性組成物
CN111848529A (zh) * 2020-07-05 2020-10-30 李太杰 一种具有阻燃性的链转移剂及其制备方法
WO2022096973A1 (en) 2020-11-05 2022-05-12 3M Innovative Properties Company Imide addition-fragmentation agents
US12398301B2 (en) 2021-12-06 2025-08-26 3M Innovative Properties Company Adhesives comprising cyclic imide addition-fragmentation and adhesion agents
WO2023105315A1 (en) 2021-12-06 2023-06-15 3M Innovative Properties Company Dental compositions
WO2026078464A1 (en) 2024-10-08 2026-04-16 Solventum Intellectual Properties Company Multi-part medical composition and use thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060009574A1 (en) * 2001-01-26 2006-01-12 Aert Huub V Method of emulsion polymerization

Family Cites Families (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3496250A (en) 1967-02-21 1970-02-17 Borg Warner Blends of epoxy resins and acrylonitrile butadiene-styrene graft copolymers
US3719522A (en) * 1970-12-21 1973-03-06 Ford Motor Co Vinyl resin and acrylic rubber-urethane-acrylate paint and painting process
US3910992A (en) * 1972-09-28 1975-10-07 Goodrich Co B F Liquid vinylidene-terminated polymers
US4119640A (en) * 1975-07-10 1978-10-10 Union Carbide Corporation Polymerizable epoxide-modified compositions
JPS5374049A (en) * 1976-11-04 1978-07-01 Toray Industries Soft contact lens material
US4260701A (en) * 1980-05-12 1981-04-07 Lee Pharmaceuticals Formulation for self-curing artificial fingernails containing methoxyethyl methacrylate
US4547323A (en) 1984-03-21 1985-10-15 Scm Corporation Synthesis of 2,2-dimethyl-4-methyleneglutaric acid and derivatives
US4503169A (en) 1984-04-19 1985-03-05 Minnesota Mining And Manufacturing Company Radiopaque, low visual opacity dental composites containing non-vitreous microparticles
US4886861A (en) 1985-04-23 1989-12-12 E. I. Dupont De Nemours And Company Molecular weight control in free radical polymerizations
US4608423A (en) * 1985-06-20 1986-08-26 Scm Corporation Linear addition polyester copolymers
US5324879A (en) 1985-12-03 1994-06-28 Commonwealth Scientific And Industrial Research Organisation Oligomerization process
US4621131A (en) * 1986-02-06 1986-11-04 Scm Corporation Polyesters derived from 2,2-dimethyl-4-methyleneglutaric acid and coatings prepared therefrom
US4877838A (en) * 1988-01-25 1989-10-31 The Glidden Company High solids coatings with reactive epoxy ester diluent
EP0458296B1 (en) * 1990-05-24 1996-03-06 Nippon Paint Co., Ltd. Modified epoxy resins having acetylenically unsaturated functions
US5264530A (en) * 1992-05-01 1993-11-23 E. I. Du Pont De Nemours And Company Process of polymerization in an aqueous system
IL111484A (en) * 1993-11-03 2001-06-14 Commw Scient Ind Res Org Polymerization process using pendant chain transfer means to regulate the molecular weight, the polymers thus obtained and a number of new pesticide compounds
US5767211A (en) * 1996-05-02 1998-06-16 E. I. Du Pont De Nemours And Company Synthesis of multi-functional hyperbranched polymers by polymerization of di-or tri-vinyl monomers in the presence of a chain transfer catalyst
JPH101523A (ja) * 1996-06-14 1998-01-06 Japan Synthetic Rubber Co Ltd 放射線硬化性樹脂組成物
US6184339B1 (en) * 1996-11-14 2001-02-06 The United States Of America As Represented By The Secretary Of The Commerce High strength polymeric networks derived from (meth) acrylate resins with organofluorine content and process for preparing same
US6316519B1 (en) * 1997-02-19 2001-11-13 E. I. Du Pont De Nemours And Company Molecular weight controlled polymers by photopolymerization
US6030606A (en) 1998-06-22 2000-02-29 3M Innovative Properties Company Dental restoratives comprising Bis-EMA6
US6730156B1 (en) 1999-10-28 2004-05-04 3M Innovative Properties Company Clustered particle dental fillers
US20020072580A1 (en) * 2000-01-26 2002-06-13 Aert Huub Van Method of emulsion polymerization
DE10048258B4 (de) * 2000-09-29 2004-08-19 Byk-Chemie Gmbh Verlaufmittel für Oberflächenbeschichtungen
DE60013154T2 (de) * 2000-12-20 2005-09-08 Agfa-Gevaert Verfahren zur Emulsionspolymerisation
EP1457527B1 (en) * 2001-09-27 2013-03-27 Sekisui Chemical Co., Ltd. Curable composition, sealing material, and adhesive
ES2227384T3 (es) * 2001-12-21 2005-04-01 Dainippon Ink And Chemicals, Inc. Composiciones de resina curables y procedimiento para la preparacion de oligomeros que continen grupos acrilato y grupos metacilato sustituidos.
JP4070637B2 (ja) * 2003-03-05 2008-04-02 富士フイルム株式会社 重合性組成物、それに用いる化合物、それに用いた画像形成材料および感光性平版印刷版
US7090722B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Acid-reactive dental fillers, compositions, and methods
US7090721B2 (en) 2004-05-17 2006-08-15 3M Innovative Properties Company Use of nanoparticles to adjust refractive index of dental compositions
US7649029B2 (en) 2004-05-17 2010-01-19 3M Innovative Properties Company Dental compositions containing nanozirconia fillers
US7156911B2 (en) 2004-05-17 2007-01-02 3M Innovative Properties Company Dental compositions containing nanofillers and related methods
US7943680B2 (en) * 2005-02-10 2011-05-17 The Regents Of The University Of Colorado Stress relaxation in crosslinked polymers
JP5260505B2 (ja) 2006-06-09 2013-08-14 デンツプライ インターナショナル インコーポレーテッド 低応力流動性歯科用組成物
US20080076853A1 (en) 2006-06-09 2008-03-27 Xiaoming Jin Photopolymerizable and photocleavable resins and low shrink and low stress composite compositions
DK2038310T3 (da) * 2006-07-12 2010-09-27 Novartis Ag Aktinisk tværbindelige copolymerer til fremstilling af kontaktlinser
US8080623B2 (en) * 2006-10-20 2011-12-20 Zeon Corporation Polymerizable composition, crosslinkable resin, and manufacture methods and applications thereof
WO2008082881A1 (en) * 2006-12-28 2008-07-10 3M Innovative Properties Company (meth)acryloyl-containing materials, compositions, and methods
JP2011510002A (ja) 2008-01-15 2011-03-31 デンツプライ インターナショナル インコーポレーテッド 調節された重合応力のための機能性樹脂組成物
WO2011126647A2 (en) 2010-03-31 2011-10-13 3M Innovative Properties Company Polymerizable isocyanurate monomers and dental compositions
US20120208965A1 (en) 2011-02-15 2012-08-16 3M Innovative Properties Company Addition-fragmentation agents
WO2012112350A2 (en) * 2011-02-15 2012-08-23 3M Innovative Properties Company Dental compositions comprising ethylenically unsaturated addition-fragmentation agent
JP6087355B2 (ja) * 2011-08-23 2017-03-01 スリーエム イノベイティブ プロパティズ カンパニー 付加開裂剤

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060009574A1 (en) * 2001-01-26 2006-01-12 Aert Huub V Method of emulsion polymerization

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Chain Transfer Activity of ψ-Unsaturated Methyl Methacrylate Oligomers;Catherine L. Moad et al.;《Macromolecules》;19961231;第29卷(第24期);第7717-7726页 *
Synthesis and Copolymerization Behavior of Methacrylate Dimers;K. J. ABBEY et al.;《Journal of Polymer Science: Part A: Polymer Chemistry》;19931231;第31卷;第3417—3424 *

Also Published As

Publication number Publication date
EP2675783A1 (en) 2013-12-25
WO2012112304A1 (en) 2012-08-23
EP3502092A1 (en) 2019-06-26
US20120208965A1 (en) 2012-08-16
EP2675783B1 (en) 2020-04-22
JP2014513154A (ja) 2014-05-29
KR20140010396A (ko) 2014-01-24
US9403966B2 (en) 2016-08-02
CN103328437A (zh) 2013-09-25
EP3502092B1 (en) 2022-10-19
KR101940161B1 (ko) 2019-01-18
US20150203658A1 (en) 2015-07-23
JP5925218B2 (ja) 2016-05-25

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