CN103321065A - High-temperature leveling agent, and preparation method and application thereof - Google Patents
High-temperature leveling agent, and preparation method and application thereof Download PDFInfo
- Publication number
- CN103321065A CN103321065A CN2013102257311A CN201310225731A CN103321065A CN 103321065 A CN103321065 A CN 103321065A CN 2013102257311 A CN2013102257311 A CN 2013102257311A CN 201310225731 A CN201310225731 A CN 201310225731A CN 103321065 A CN103321065 A CN 103321065A
- Authority
- CN
- China
- Prior art keywords
- block copolymer
- parts
- silicone oil
- high temperature
- levelling agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Silicon Polymers (AREA)
Abstract
The invention relates to a high-temperature leveling agent, and a preparation method and an application thereof. The high-temperature leveling agent is prepared from 0.1-1% of a polyester-polyether-silicon oil block copolymer, 9-10% of polyethylene glycol monostearate, and balance of water. The polyester-polyether-silicon oil block copolymer is prepared from the raw materials of, by weight: 120-160 parts of polyethylene glycol, 18-30 parts of glycol, 15-25 parts of dihydroxy polyether, 20-28 parts of dimethyl terephthalate, 10-30 parts of an amino-terminated double-head sealant organosilicon, 5-10 parts of 3-piperazine propyl dimethoxysilane, and 0.2-2 parts of metal acetate. With the high-temperature leveling agent provided by the invention, dyeing quality of polyester fiber or fabric thereof can be improved, and the dyed polyester fiber or fabric thereof is provided with excellent fluffy and soft property, good antistatic performance, and good hydrophilic property. The dyed polyester or fiber thereof can be provided with excellent comfortableness with no other finishing.
Description
Technical field
The present invention relates to the fabric finishing agent technical field, particularly a kind of high temperature levelling agent and preparation method thereof.
Background technology
As everyone knows, the fluffy flexibility of polyester fiber, moisture absorbing and sweat releasing property, antistatic property, soil release performance can be all poor.Poor, the easy pickup of the taking of the textiles therefore, processed with polyester fiber, easily play the characteristics of static.This will cause to the health of human body certain harm undoubtedly.In order to overcome the existing deficiency of polyester fiber and, for the satisfying the market requirement more and more higher for textiles, must to be arranged polyester fiber, to improving its performance.
Known again, in the dyeing course of silvalin, line or fabric, for impelling even dyeing, do not produce the faults such as vitta, color spot and often need to add levelling agent.But existing levelling agent only has even dyeing effect, and does not have other finishing effect.For polyester fiber or its fabric, this just need to be after dyeing completes, then carries out, such as anti-arrangements such as antistatic, fluffy softnesses, so, making production technology more complicated, and cost is higher.
Summary of the invention
Technical problem to be solved by this invention is to overcome the deficiencies in the prior art, and a kind of high temperature levelling agent with fluffy soft finish effect is provided.
The present invention also will provide a kind of Preparation method and use of high temperature levelling agent simultaneously.
For solving the problems of the technologies described above, a kind of technical scheme that the present invention takes is:
A kind of high temperature levelling agent, the polyester polyether silicone oil block copolymer 0.1%～1% that it is 8000～20000 by number-average molecular weight, polyethylene glycol mono stearate 9%～10% and surplus are that water forms, in weight portion, the composition of raw materials of described polyester polyether silicone oil block copolymer is: 120～160 parts of polyethylene glycol, 18～30 parts of ethylene glycol, 15～25 parts of polyether diols, 20～28 parts of dimethyl terephthalate (DMT)s, hold 10～30 parts of amino double-seal head agent organosilicons, 5～10 parts of 3-gamma-piperazinepropyl methyldimethoxysilanes and as 0.2～2 part of the acetic acid slaine of catalyst.
Preferably, the number-average molecular weight of described polyester polyether silicone oil block copolymer is 10000～15000.
Preferably, the preparation method of described polyester polyether silicone oil block copolymer is: by proportioning, in reactor, drop into described raw material, be warming up to 140 ℃～180 ℃, insulation reaction 120～180 minutes, then continue to be warming up to 220 ℃～240 ℃, insulation reaction 50～70 minutes, finally make material vacuum-0.08～-240 ℃～300 ℃ of 0.1MPa and temperature under reaction, generate described polyester polyether silicone oil block copolymer, be cooled to 190～220 ℃ after blowing, obtain.
Preferably, the polyethylene glycol of described polyethylene glycol mono stearate is PEG200 or PEG600.
The present invention also provides the preparation method of above-mentioned high temperature levelling agent, and it comprises the steps:
(1) prepare polyester polyether silicone oil block copolymer: by proportioning, in reactor, drop into described raw material, be warming up to 140 ℃～180 ℃, insulation reaction 120～180 minutes, then continue to be warming up to 220 ℃～240 ℃, insulation reaction 50～70 minutes, finally make material vacuum-0.08～-240 ℃～300 ℃ of 0.1MPa and temperature under reaction, generate described polyester polyether silicone oil block copolymer, blowing after being cooled to 190～220 ℃, obtain polyester polyether silicone oil block copolymer;
(2), polyester polyether silicone oil block copolymer, polyethylene glycol mono stearate and water are mixed in proportion, obtain described high temperature levelling agent.
According to the present invention, all commercially available acquisitions of raw material components.Wherein: the preferred number-average molecular weight of polyethylene glycol is 1000～4000, PEG2000 for example, PEG4000.Polyether diols claims again the propylene glycol polyethers, and its number-average molecular weight is generally between 1000～4000; Hold the organosilicon that amino double-seal head agent organosilicon is amino end socket, there is following structural formula:
The possible structural formula of the polyester polyether silicone oil block copolymer that the present invention obtains is as follows:
In above formula, R
1, R
2, R
3be H or methyl independently, and R
1, R
2, R
3when different, be H or methyl.
In addition, the invention still further relates to the application of above-mentioned high temperature levelling agent in polyester fiber or dacron fabric dyeing.
Due to the enforcement of above technical scheme, the present invention compared with prior art has following advantage:
Use high temperature levelling agent provided by the invention can not only improve the dyeing quality of polyester fiber or its fabric, make dyeing after fabric color more all even aquatic foods and, but also making polyester fiber or its fabric after dyeing obtain excellent fluffy softness, good antistatic property and hydrophilicity, the polyester fiber after making to dye or fabric are without after other, just arranging and can obtain excellent comfortableness.In addition, the cost of material of high temperature levelling agent of the present invention and manufacturing cost are lower.
The specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described in detail, but the invention is not restricted to following examples.
Embodiment 1
A kind of high temperature levelling agent, it prepares as follows:
(1), take polyethylene glycol (PEG4000) 800 grams, ethylene glycol 150 grams, polyether diols 125 grams, dimethyl terephthalate (DMT) 140 grams, hold amino double-seal head agent organosilicon 150 grams, 3-gamma-piperazinepropyl methyldimethoxysilane 50g, magnesium acetate 10 grams;
(2), to dropping into above-mentioned material in reactor, be warming up to 140 ℃ and keep 180 minutes, continue to be warming up to 220 ℃ and keep 60 minutes.Then in vacuum, be-0.08MPa, temperature is to carry out polymerization under 240 ℃, generates polyester polyether silicone oil block copolymer, be cooled to 190 ℃ after blowing, obtain polyester polyether silicone oil block copolymer;
(3), step (2) gained polyester polyether silicone oil block copolymer, polyethylene glycol (200) monostearate and water are mixed according to weight ratio 0.1:9.9:90, obtain high temperature levelling agent.
Embodiment 2
A kind of high temperature levelling agent, it prepares as follows:
(1), take polyethylene glycol (PEG2000) 900 grams, ethylene glycol 140 grams, polyether diols 140 grams, dimethyl terephthalate (DMT) 165 grams, hold amino double-seal head agent organosilicon 180 grams, 3-gamma-piperazinepropyl methyldimethoxysilane 60g, zinc acetate 6 grams;
(2), to dropping into above-mentioned material in reactor, be warming up to 150 ℃ and keep 180 minutes, continue to be warming up to 230 ℃ and keep 60 minutes.Then carry out polymerization, in vacuum be-0.08MPa, temperature is to carry out polymerization under 260 ℃, generates polyester polyether silicone oil block copolymer, be cooled to 200 ℃ after blowing, obtain polyester polyether silicone oil block copolymer;
(3), step (2) gained polyester polyether silicone oil block copolymer, polyethylene glycol (200) monostearate and water are mixed according to weight ratio 0.2:9.8:90, obtain high temperature levelling agent.
Embodiment 3
A kind of high temperature levelling agent, it prepares as follows:
(1), take polyethylene glycol (PEG2000) 700 grams, ethylene glycol 125 grams, polyether diols 125 grams, dimethyl terephthalate (DMT) 130 grams, hold amino double-seal head agent organosilicon 150 grams, 3-gamma-piperazinepropyl methyldimethoxysilane 50 grams, calcium acetate 10 grams;
(2), in reactor, drop into above-mentioned material, being warming up to 170 ℃ keeps 180 minutes, continuing to be warming up to 220 ℃ keeps 60 minutes, then carry out polymerization, in vacuum, be-0.09MPa, temperature is to carry out polymerization under 250 ℃, generates polyester polyether silicone oil block copolymer, blowing after being cooled to 200 ℃, obtain polyester polyether silicone oil block copolymer;
(3), step (2) gained polyester polyether silicone oil block copolymer, polyethylene glycol (600) monostearate and water are mixed according to weight ratio 0.5:9.5:90, obtain high temperature levelling agent.
Embodiment 4
A kind of high temperature levelling agent, it prepares as follows:
(1), take polyethylene glycol (PEG2000) 800 grams, ethylene glycol 130 grams, polyether diols 110 grams, dimethyl terephthalate (DMT) 125 grams, hold amino double-seal head agent organosilicon 150 grams, 3-gamma-piperazinepropyl methyldimethoxysilane 40g, tin acetate 8 grams;
(2), to dropping into above-mentioned material in reactor, be warming up to 180 ℃ and keep 180 minutes, continue to be warming up to 230 ℃ and keep 60 minutes, then in vacuum, be-0.095MPa, temperature is to carry out polymerization under 240 ℃, generates polyester polyether silicone oil block copolymer, be cooled to 200 ℃ after blowing;
(3), step (2) gained polyester polyether silicone oil block copolymer, polyethylene glycol (600) monostearate and water are mixed according to weight ratio 0.3:9.7:90, obtain high temperature levelling agent.
Embodiment 5
A kind of high temperature levelling agent, it prepares as follows:
(1), take polyethylene glycol (PEG4000) 1000 grams, ethylene glycol 140 grams, polyethers 150 grams, dimethyl terephthalate (DMT) 170 grams, hold amino double-seal head agent organosilicon 180 grams, 3-gamma-piperazinepropyl methyldimethoxysilane 80g, tin acetate 6 grams;
(2), to dropping into above-mentioned material in reactor, be warming up to 150 ℃, keep 180 minutes, continue to be warming up to 230 ℃ and keep 60 minutes.In vacuum, be-0.08MPa, temperature is to carry out polymerization under 280 ℃, generates polyester polyether silicone oil block copolymer, be cooled to 200 ℃ after blowing;
(3), step (2) gained polyester polyether silicone oil block copolymer, polyethylene glycol (600) monostearate and water are mixed according to weight ratio 0.2:9.8:90, obtain high temperature levelling agent.
sign and the performance test of polyester polyether silicone oil block copolymer
1, to embodiment 1～5, prepared polyester polyether silicone oil block copolymer has carried out the test of molecular weight and physical property respectively, and result is referring to table 1.
Table 1
2, the result of use of the prepared high temperature levelling agent of test implementation example 1～5 to the PET polyester fiber
(1) colouring method: take the dyeing of high temperature-pressure dyeing machine and conventional PET polyester fiber to be dyeed and (under 40 ℃, add levelling agent a collection of PET polyester fiber, the auxiliary agents such as anti wrinkling agent, dyestuff, insulation 10min, speed with 2 ℃/min is warming up to 80 ℃, continuation is warming up to 130 ℃ with the speed of 1.5 ℃/min, insulation 30min, speed with 1.5 ℃/min is cooled to 60 ℃, discharge opeing), wherein, levelling agent is used respectively the prepared high temperature levelling agent of embodiment 1～5 and traditional levelling agent (leveling agent 1227 dodecyl benzyl dimethyl ammonium chloride).
(2) method of testing:
Fluffy flexibility feel: the professional person divides into groups to touch scoring, is divided into into five grades, wherein: 1-without feel; 2-slight fluffy softness; 3-some fluffy softnesses are arranged; 4-more fluffy softness; 5-super fluffy softness.
Washability, with reference to the AATCC-135 standard;
Hydrophily and capillary effect method: with reference to GB/T21655.1-2008.
The soil release performance energy, carry out with reference to the FZ/T10012-1998 standard.
Antistatic property, carry out with reference to the FZ/T01042-1996 standard.
The test of other index is carried out with reference to relevant criterion.
(3) test result of the rear PET polyester fiber of dyeing is referring to table 2.
Table 2
Above the present invention is described in detail; its purpose is to allow the personage who is familiar with this art can understand content of the present invention and be implemented; can not limit the scope of the invention with this; the equivalence that all Spirit Essences according to the present invention are done changes or modifies, and all should be encompassed in protection scope of the present invention.
Claims (6)
1. a high temperature levelling agent, it is characterized in that: the polyester polyether silicone oil block copolymer 0.1% ~ 1% that described high temperature levelling agent is 8000 ~ 20000 by number-average molecular weight, polyethylene glycol mono stearate 9% ~ 10% and surplus are that water forms, in weight portion, the composition of raw materials of described polyester polyether silicone oil block copolymer is: 120 ~ 160 parts of polyethylene glycol, 18 ~ 30 parts of ethylene glycol, 15 ~ 25 parts of polyether diols, 20 ~ 28 parts of dimethyl terephthalate (DMT)s, hold 10 ~ 30 parts of amino double-seal head agent organosilicons, 5 ~ 10 parts of 3-gamma-piperazinepropyl methyldimethoxysilanes and as 0.2 ~ 2 part of the acetic acid slaine of catalyst.
2. high temperature levelling agent according to claim 1, it is characterized in that: the number-average molecular weight of described polyester polyether silicone oil block copolymer is 10000 ~ 15000.
3. high temperature levelling agent according to claim 1, it is characterized in that: the preparation method of described polyester polyether silicone oil block copolymer is: by proportioning, in reactor, drop into described raw material, be warming up to 140 ℃ ~ 180 ℃, insulation reaction 120 ~ 180 minutes, then continue to be warming up to 220 ℃ ~ 240 ℃, insulation reaction 50 ~ 70 minutes, finally make material vacuum-0.08 ~-240 ℃ ~ 300 ℃ of 0.1MPa and temperature under reaction, generate described polyester polyether silicone oil block copolymer, blowing after being cooled to 190 ~ 220 ℃, obtain described high temperature levelling agent.
4. high temperature levelling agent according to claim 1, it is characterized in that: the polyethylene glycol in described polyethylene glycol mono stearate is PEG200 or PEG600.
5. the preparation method as the described high temperature levelling agent of any one claim in claim 1 to 4, it is characterized in that: described method comprises the steps:
(1) prepare polyester polyether silicone oil block copolymer: by proportioning, in reactor, drop into described raw material, be warming up to 140 ℃ ~ 180 ℃, insulation reaction 120 ~ 180 minutes, then continue to be warming up to 220 ℃ ~ 240 ℃, insulation reaction 50 ~ 70 minutes, finally make material vacuum-0.08 ~-240 ℃ ~ 300 ℃ of 0.1MPa and temperature under reaction, generate described polyester polyether silicone oil block copolymer, blowing after being cooled to 190 ~ 220 ℃, obtain polyester polyether silicone oil block copolymer;
(2), polyester polyether silicone oil block copolymer, polyethylene glycol mono stearate and water are mixed in proportion, obtain described high temperature levelling agent.
6. the application of the described high temperature levelling agent of any one claim in polyester fiber or dacron fabric dyeing in claim 1 to 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310225731.1A CN103321065B (en) | 2013-06-07 | 2013-06-07 | High-temperature leveling agent, and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310225731.1A CN103321065B (en) | 2013-06-07 | 2013-06-07 | High-temperature leveling agent, and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103321065A true CN103321065A (en) | 2013-09-25 |
| CN103321065B CN103321065B (en) | 2015-07-01 |
Family
ID=49190090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310225731.1A Active CN103321065B (en) | 2013-06-07 | 2013-06-07 | High-temperature leveling agent, and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103321065B (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103741518A (en) * | 2013-12-09 | 2014-04-23 | 常熟市梦迪安家饰用品有限公司 | High-temperature levelling agent |
| CN103911889A (en) * | 2013-12-13 | 2014-07-09 | 苏州芳然纺织有限公司 | Compound level dyeing assistant for textile, and preparation method thereof |
| CN103952911A (en) * | 2014-04-21 | 2014-07-30 | 张家港市德宝化工有限公司 | Dye-bath reduction clearing resistant multifunctional finishing agent for polyester fiber material and preparation method thereof |
| CN104389204A (en) * | 2014-12-11 | 2015-03-04 | 浙江安诺其助剂有限公司 | High-temperature leveling agent composition |
| CN104389205A (en) * | 2014-12-11 | 2015-03-04 | 上海安诺其集团股份有限公司 | Preparation method of high-temperature leveling agent composition |
| CN105274873A (en) * | 2015-11-20 | 2016-01-27 | 常熟市梦迪安家饰用品有限公司 | High temperature levelling agent for textile dyeing and finishing |
| CN105648797A (en) * | 2016-04-12 | 2016-06-08 | 湖州吉昌丝绸有限公司 | Environment-friendly and efficient biparental levelling agent |
| CN106637949A (en) * | 2016-11-01 | 2017-05-10 | 桐乡市濮院毛针织技术服务中心 | Crease-resistant agent for dyeing polyamide fibers |
| CN108914624A (en) * | 2018-06-20 | 2018-11-30 | 福建石狮晨光化纤染织有限公司 | A kind of dyeing of deep color polyester-cotton fabric |
| CN108930178A (en) * | 2018-06-20 | 2018-12-04 | 福建石狮晨光化纤染织有限公司 | A kind of fabric dyeing process of pre-treatment and one bath of dyeing |
| CN111118921A (en) * | 2020-02-27 | 2020-05-08 | 南通思聪家居有限公司 | Dyeing method of Arctic polar fleece fabric |
| CN111172781A (en) * | 2020-01-20 | 2020-05-19 | 宁波萌恒线业有限公司 | High-temperature leveling agent and preparation method thereof |
| CN112663360A (en) * | 2020-12-28 | 2021-04-16 | 浙江震东新材料有限公司 | Multifunctional dispersing leveling agent and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05106175A (en) * | 1991-10-15 | 1993-04-27 | Nikka Chem Co Ltd | Dyeing assistant for polyester fiber |
| CN101424046A (en) * | 2008-11-21 | 2009-05-06 | 张家港市德宝化工有限公司 | Polyester fiber modifying agent as well as preparation method and use thereof |
-
2013
- 2013-06-07 CN CN201310225731.1A patent/CN103321065B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05106175A (en) * | 1991-10-15 | 1993-04-27 | Nikka Chem Co Ltd | Dyeing assistant for polyester fiber |
| CN101424046A (en) * | 2008-11-21 | 2009-05-06 | 张家港市德宝化工有限公司 | Polyester fiber modifying agent as well as preparation method and use thereof |
Non-Patent Citations (1)
| Title |
|---|
| 陈荣圻: "低黄变和亲水性氨基聚硅氧烷的发展", 《印染助剂》 * |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103741518A (en) * | 2013-12-09 | 2014-04-23 | 常熟市梦迪安家饰用品有限公司 | High-temperature levelling agent |
| CN103911889A (en) * | 2013-12-13 | 2014-07-09 | 苏州芳然纺织有限公司 | Compound level dyeing assistant for textile, and preparation method thereof |
| CN103911889B (en) * | 2013-12-13 | 2016-06-22 | 泉州市新宏化工贸易有限公司 | A kind of weaving compound Levelling assistants and preparation method thereof |
| CN103952911A (en) * | 2014-04-21 | 2014-07-30 | 张家港市德宝化工有限公司 | Dye-bath reduction clearing resistant multifunctional finishing agent for polyester fiber material and preparation method thereof |
| CN104389204A (en) * | 2014-12-11 | 2015-03-04 | 浙江安诺其助剂有限公司 | High-temperature leveling agent composition |
| CN104389205A (en) * | 2014-12-11 | 2015-03-04 | 上海安诺其集团股份有限公司 | Preparation method of high-temperature leveling agent composition |
| CN105274873A (en) * | 2015-11-20 | 2016-01-27 | 常熟市梦迪安家饰用品有限公司 | High temperature levelling agent for textile dyeing and finishing |
| CN105648797A (en) * | 2016-04-12 | 2016-06-08 | 湖州吉昌丝绸有限公司 | Environment-friendly and efficient biparental levelling agent |
| CN106637949A (en) * | 2016-11-01 | 2017-05-10 | 桐乡市濮院毛针织技术服务中心 | Crease-resistant agent for dyeing polyamide fibers |
| CN108914624A (en) * | 2018-06-20 | 2018-11-30 | 福建石狮晨光化纤染织有限公司 | A kind of dyeing of deep color polyester-cotton fabric |
| CN108930178A (en) * | 2018-06-20 | 2018-12-04 | 福建石狮晨光化纤染织有限公司 | A kind of fabric dyeing process of pre-treatment and one bath of dyeing |
| CN108930178B (en) * | 2018-06-20 | 2021-01-15 | 福建石狮晨光化纤染织有限公司 | Fabric dyeing process with one-bath pretreatment and dyeing |
| CN108914624B (en) * | 2018-06-20 | 2021-01-15 | 福建石狮晨光化纤染织有限公司 | Dyeing process of dark polyester-cotton fabric |
| CN111172781A (en) * | 2020-01-20 | 2020-05-19 | 宁波萌恒线业有限公司 | High-temperature leveling agent and preparation method thereof |
| CN111172781B (en) * | 2020-01-20 | 2022-12-06 | 宁波萌恒线业有限公司 | High-temperature leveling agent and preparation method thereof |
| CN111118921A (en) * | 2020-02-27 | 2020-05-08 | 南通思聪家居有限公司 | Dyeing method of Arctic polar fleece fabric |
| CN112663360A (en) * | 2020-12-28 | 2021-04-16 | 浙江震东新材料有限公司 | Multifunctional dispersing leveling agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103321065B (en) | 2015-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103321065B (en) | High-temperature leveling agent, and preparation method and application thereof | |
| CN103321054A (en) | Fluffy and soft finishing agent used for polyester fiber, and preparation method thereof | |
| CN103321055A (en) | In-bath crease-resisting agent used in polyester fiber fabric, and preparation method thereof | |
| CN101914206B (en) | Quaternized modified amino silicone oil softener and preparation and application thereof | |
| CN104086779A (en) | Super-soft/smooth block silicon oil and preparation method thereof | |
| CN101798760A (en) | Method for applying moisture control agent in fabric dyeing process | |
| CN103334320B (en) | High-temperature leveling agent for polyester fibers and preparation method thereof | |
| CN106674507B (en) | The preparation method of superpower washable Moisture management of polyester fabric agent | |
| CN101805994A (en) | Organosilicon emulsion used for hand feel finishing of wool and blended yarn thereof and preparation method and application thereof | |
| CN106592223A (en) | Water-proofing, oil-proofing and antifouling type easy-care finishing liquid of shirt and finishing method of water-proofing, oil-proofing and antifouling type easy-care finishing liquid | |
| CN102995472B (en) | Preparation method of textile color fixing agent | |
| CN106968046A (en) | A kind of cool feeling uvioresistant cotton knitted fabric | |
| CN103469577A (en) | Stiffening agent used for crease finishing of jean clothes | |
| CN103614934A (en) | Fabric color fixing agent | |
| CN106436329A (en) | Skin-care permanently-antibacterial DP finishing liquid for shirts and finishing method | |
| CN106592224A (en) | Wear-resisting ironing-free finishing liquid of shirt and finishing method of wear-resisting ironing-free finishing liquid | |
| CN106592225A (en) | Aromatherapy skin-protection type non-ironing finishing liquid for shirts and finishing method thereof | |
| CN103741518A (en) | High-temperature levelling agent | |
| CN106633049A (en) | Vat dye ozone-proof fastness improver as well as preparation method and application thereof | |
| CN203420072U (en) | Knitted fabric with water absorption cooling function | |
| CN103321050B (en) | In-bath crease-resisting agent used in polyester fiber, and preparation method thereof | |
| CN106758155A (en) | The fire-retardant vapor-permeable type noniron finish liquid and its method for sorting of a kind of shirt | |
| CN103321038A (en) | Decontamination finishing agent used for polyester fiber, and preparation method thereof | |
| CN106758200A (en) | The uvioresistant protection type noniron finish liquid and its method for sorting of a kind of shirt | |
| CN102993429A (en) | Preparation method for polyester fiber modifying agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |