CN103282101B - 海水排烟脱硫系统及发电系统 - Google Patents
海水排烟脱硫系统及发电系统 Download PDFInfo
- Publication number
- CN103282101B CN103282101B CN201180061109.0A CN201180061109A CN103282101B CN 103282101 B CN103282101 B CN 103282101B CN 201180061109 A CN201180061109 A CN 201180061109A CN 103282101 B CN103282101 B CN 103282101B
- Authority
- CN
- China
- Prior art keywords
- seawater
- gas desulfurization
- flue
- absorption tower
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000013535 sea water Substances 0.000 title claims abstract description 305
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 170
- 230000023556 desulfurization Effects 0.000 title claims abstract description 160
- 239000007789 gas Substances 0.000 claims abstract description 90
- 238000010521 absorption reaction Methods 0.000 claims abstract description 83
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 69
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 60
- 239000003546 flue gas Substances 0.000 claims abstract description 60
- 238000010790 dilution Methods 0.000 claims abstract description 47
- 239000012895 dilution Substances 0.000 claims abstract description 47
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 239000002912 waste gas Substances 0.000 claims description 77
- 239000005864 Sulphur Substances 0.000 claims description 67
- 239000000203 mixture Substances 0.000 claims description 48
- 238000007254 oxidation reaction Methods 0.000 claims description 34
- 230000003647 oxidation Effects 0.000 claims description 33
- 238000010926 purge Methods 0.000 claims description 16
- 230000005611 electricity Effects 0.000 claims description 15
- 239000007921 spray Substances 0.000 claims description 15
- 238000007599 discharging Methods 0.000 claims description 12
- 239000000428 dust Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000002817 coal dust Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 abstract description 5
- 238000007865 diluting Methods 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- 238000011084 recovery Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 9
- 230000003009 desulfurizing effect Effects 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 5
- 230000033228 biological regulation Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000005276 aerator Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 239000010742 number 1 fuel oil Substances 0.000 description 1
- -1 ocean temperature Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/74—Treatment of water, waste water, or sewage by oxidation with air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K9/00—Plants characterised by condensers arranged or modified to co-operate with the engines
- F01K9/003—Plants characterised by condensers arranged or modified to co-operate with the engines condenser cooling circuits
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/04—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/10—Inorganic absorbents
- B01D2252/103—Water
- B01D2252/1035—Sea water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/40—Sorption with wet devices, e.g. scrubbers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2900/00—Special arrangements for conducting or purifying combustion fumes; Treatment of fumes or ashes
- F23J2900/15041—Means for absorbing SOx using seawater
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Thermal Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Chimneys And Flues (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011042962A JP5773687B2 (ja) | 2011-02-28 | 2011-02-28 | 海水排煙脱硫システムおよび発電システム |
JP2011-042962 | 2011-02-28 | ||
PCT/JP2011/069148 WO2012117586A1 (ja) | 2011-02-28 | 2011-08-25 | 海水排煙脱硫システムおよび発電システム |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103282101A CN103282101A (zh) | 2013-09-04 |
CN103282101B true CN103282101B (zh) | 2015-06-03 |
Family
ID=46757540
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201180061109.0A Expired - Fee Related CN103282101B (zh) | 2011-02-28 | 2011-08-25 | 海水排烟脱硫系统及发电系统 |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP5773687B2 (th) |
CN (1) | CN103282101B (th) |
CL (1) | CL2013001879A1 (th) |
TW (1) | TWI482657B (th) |
WO (1) | WO2012117586A1 (th) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5892265B2 (ja) * | 2012-12-19 | 2016-03-23 | 富士電機株式会社 | 排ガス浄化装置 |
WO2014119513A1 (ja) * | 2013-01-29 | 2014-08-07 | 富士電機株式会社 | スクラバの海水量制御装置、スクラバの海水量制御方法、アルカリ量制御装置及びアルカリ量制御方法 |
JP2014233702A (ja) * | 2013-06-04 | 2014-12-15 | 三菱重工業株式会社 | 海水脱硫装置及び海水脱硫システム |
JP6302191B2 (ja) * | 2013-09-02 | 2018-03-28 | 三菱日立パワーシステムズ株式会社 | 発電システム |
KR101740678B1 (ko) | 2014-07-18 | 2017-05-26 | 후지 덴키 가부시키가이샤 | 스크러버의 해수량 제어장치, 스크러버의 해수량 제어방법 및 알칼리량 제어장치 |
CN104162361A (zh) * | 2014-07-29 | 2014-11-26 | 江苏南极机械有限责任公司 | 一种利用海水吸收净化柴油机尾气中so2的装置及吸收方法 |
CN106029206A (zh) * | 2014-09-02 | 2016-10-12 | 富士电机株式会社 | 废气处理装置及废气处理装置的排水处理方法 |
JP6632452B2 (ja) * | 2016-03-31 | 2020-01-22 | 三菱日立パワーシステムズ株式会社 | 充填塔用の充填物及び海水脱硫装置 |
CN106076066A (zh) * | 2016-06-11 | 2016-11-09 | 彭斯干 | 海水式碳捕集封存方法及装置 |
EP3604116A4 (en) * | 2017-03-24 | 2021-01-20 | Mitsubishi Shipbuilding Co., Ltd. | MARINE DESULFURATION DEVICE DRAINAGE SYSTEM |
KR20190026978A (ko) * | 2017-03-28 | 2019-03-13 | 미츠비시 히타치 파워 시스템즈 가부시키가이샤 | 선박용 탈황 장치 및 선박 |
KR101918663B1 (ko) | 2018-04-18 | 2018-11-14 | 주식회사 지스코 | 발전시스템 |
CN113198294B (zh) * | 2021-05-21 | 2021-11-19 | 华能国际电力股份有限公司大连电厂 | 一种海水脱硫控制方法和设备 |
CN113740197A (zh) * | 2021-06-29 | 2021-12-03 | 西安热工研究院有限公司 | 一种烟气海水脱硫装置的除雾器性能评估系统及方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101557868A (zh) * | 2007-02-28 | 2009-10-14 | 三菱重工业株式会社 | 海水排烟脱硫系统 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11244646A (ja) * | 1998-03-05 | 1999-09-14 | Ishikawajima Harima Heavy Ind Co Ltd | 排煙脱硫装置の吸収剤スラリー流量制御方法及び装置 |
JP4381064B2 (ja) * | 2003-08-26 | 2009-12-09 | 三菱重工業株式会社 | 排ガス処理装置および処理方法 |
WO2009149603A1 (zh) * | 2008-06-13 | 2009-12-17 | Peng Sigan | 海船排烟脱硫方法及装置 |
JP5231957B2 (ja) * | 2008-11-27 | 2013-07-10 | バブコック日立株式会社 | 湿式脱硫装置 |
-
2011
- 2011-02-28 JP JP2011042962A patent/JP5773687B2/ja not_active Expired - Fee Related
- 2011-08-25 WO PCT/JP2011/069148 patent/WO2012117586A1/ja active Application Filing
- 2011-08-25 CN CN201180061109.0A patent/CN103282101B/zh not_active Expired - Fee Related
- 2011-11-28 TW TW100143573A patent/TWI482657B/zh not_active IP Right Cessation
-
2013
- 2013-06-25 CL CL2013001879A patent/CL2013001879A1/es unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101557868A (zh) * | 2007-02-28 | 2009-10-14 | 三菱重工业株式会社 | 海水排烟脱硫系统 |
Also Published As
Publication number | Publication date |
---|---|
JP5773687B2 (ja) | 2015-09-02 |
TWI482657B (zh) | 2015-05-01 |
JP2012179521A (ja) | 2012-09-20 |
CN103282101A (zh) | 2013-09-04 |
TW201238644A (en) | 2012-10-01 |
WO2012117586A1 (ja) | 2012-09-07 |
CL2013001879A1 (es) | 2013-11-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103282101B (zh) | 海水排烟脱硫系统及发电系统 | |
CN204073811U (zh) | 海水排烟脱硫系统及发电系统 | |
CN101063527B (zh) | 控制烟道气中水分浓度的方法 | |
JP2012179521A5 (th) | ||
CN102361825B (zh) | 氧化槽、海水处理装置及海水脱硫系统 | |
CN102387850B (zh) | 海水脱硫氧化处理装置、脱硫海水的处理方法及应用该方法的发电系统 | |
PL241095B1 (pl) | Sposób działania układu generatora pary | |
CN204107298U (zh) | 氧化槽、海水排烟脱硫系统及发电系统 | |
CN103657349A (zh) | 工艺气体的脱硫和冷却 | |
JP2012239958A (ja) | 湿式排煙脱硫装置と方法 | |
CN208025546U (zh) | 一种用于湿烟气除白的热虹吸换热器 | |
JP2013086054A (ja) | 海水利用の湿式石灰石−石膏法脱硫装置 | |
KR20160062707A (ko) | 습식 연도 가스 탈황 폐수로부터 가스 배출을 감소시키기 위한 시스템 및 방법 | |
WO2013118683A1 (ja) | 脱硫海水処理システム | |
JP5437151B2 (ja) | 排煙脱硫装置及びこれを備えた酸素燃焼装置と方法 | |
PL185093B1 (pl) | Sposób odsiarczania gazów i urządzenie odsiarczające | |
CN205381962U (zh) | 液硫脱气系统 | |
CN102343209B (zh) | 应用锅炉排污水的烟气海水脱硫系统 | |
WO2013057661A1 (en) | Oxygen preheating in oxyfuel combustion system | |
JP3251883B2 (ja) | 排ガス脱硫方法及びその装置 | |
CN105480951A (zh) | 液硫脱气系统及液流脱气方法 | |
RU2179281C2 (ru) | Способ работы и устройство теплоэнергетической установки с комплексной системой глубокой утилизации теплоты и снижения вредных выбросов в атмосферу | |
JP6934125B1 (ja) | アンモニア及び水素製造システム | |
JP2009095696A (ja) | 排ガス脱硫装置酸化塔のバイパス運転方法 | |
CN116199189A (zh) | 一种硫磺回收系统 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: MITSUBISHI HITACHI POWER SYSTEM LTD. Free format text: FORMER OWNER: MITSUBISHI JUKOGIO KK Effective date: 20150226 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20150226 Address after: Kanagawa County, Japan Applicant after: MITSUBISHI HEAVY INDUSTRIES, Ltd. Address before: Tokyo, Japan Applicant before: MITSUBISHI HEAVY INDUSTRIES, Ltd. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder |
Address after: Kanagawa Prefecture, Japan Patentee after: Mitsubishi Power Co.,Ltd. Address before: Kanagawa Prefecture, Japan Patentee before: MITSUBISHI HEAVY INDUSTRIES, Ltd. |
|
CP01 | Change in the name or title of a patent holder | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150603 |