CN103270008A - 离聚物和离子传导性组合物 - Google Patents

离聚物和离子传导性组合物 Download PDF

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Publication number
CN103270008A
CN103270008A CN2011800614506A CN201180061450A CN103270008A CN 103270008 A CN103270008 A CN 103270008A CN 2011800614506 A CN2011800614506 A CN 2011800614506A CN 201180061450 A CN201180061450 A CN 201180061450A CN 103270008 A CN103270008 A CN 103270008A
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ionomer
polymer
pdd
pfsve
ionomers
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Chinese (zh)
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R.L.佩里
M.G.勒罗夫斯
R.C.惠兰
R.M.阿滕
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/182—Monomers containing fluorine not covered by the groups C08F214/20 - C08F214/28
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C08F216/1466—Monomers containing sulfur
    • C08F216/1475—Monomers containing sulfur and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
    • C08L23/0876—Salts thereof, i.e. ionomers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
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    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1044—Mixtures of polymers, of which at least one is ionically conductive
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C08F216/1408—Monomers containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/54—Electrolytes
    • H01G11/58—Liquid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
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    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13—Energy storage using capacitors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Fuel Cell (AREA)
CN2011800614506A 2010-12-20 2011-12-20 离聚物和离子传导性组合物 Pending CN103270008A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201061425088P 2010-12-20 2010-12-20
US61/425088 2010-12-20
PCT/US2011/066273 WO2012088166A1 (en) 2010-12-20 2011-12-20 Ionomers and ionically conductive compositions

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CN103270008A true CN103270008A (zh) 2013-08-28

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US (1) US20130245219A1 (https=)
JP (1) JP2014500392A (https=)
CN (1) CN103270008A (https=)
WO (1) WO2012088166A1 (https=)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104220467A (zh) * 2012-04-16 2014-12-17 旭硝子株式会社 电解质材料、液状组合物及固体高分子型燃料电池用膜电极接合体
CN107785590A (zh) * 2016-08-25 2018-03-09 中国科学院宁波材料技术与工程研究所 一种高倍率性能空气电极材料及其应用
CN107922531A (zh) * 2015-08-21 2018-04-17 旭硝子株式会社 含氟聚合物的制造方法
CN108878898A (zh) * 2017-05-12 2018-11-23 通用汽车环球科技运作有限责任公司 具有分离的电解质分布的燃料电池及其制造方法
CN116364991A (zh) * 2023-05-31 2023-06-30 安徽明天新能源科技有限公司 一种催化层涂覆膜及其制备方法
CN118684808A (zh) * 2024-08-22 2024-09-24 江苏科润膜材料有限公司 一种以过氧化苯甲酰为引发剂的高透氧性离聚物合成方法及其产物，薄膜和应用

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JP6225468B2 (ja) * 2013-04-25 2017-11-08 株式会社豊田中央研究所 燃料電池用電極
WO2015182676A1 (ja) 2014-05-28 2015-12-03 ダイキン工業株式会社 高酸素透過性アイオノマー
US9463450B1 (en) 2015-03-25 2016-10-11 Compact Membrane Systems, Inc. Polymeric acid catalysis
JP6633992B2 (ja) * 2016-09-09 2020-01-22 株式会社豊田中央研究所 シクロアルキルパーフルオロジオキソールモノマ、低密度アイオノマ、及び固体高分子型燃料電池
EP3681948A4 (en) 2017-09-14 2021-07-14 3M Innovative Properties Company FLUORINATED COPOLYMER WITH SULFONYL SIDE GROUPS AS WELL AS COMPOSITIONS AND ARTICLES THEREFORE
JP7355039B2 (ja) * 2018-12-07 2023-10-03 Ａｇｃ株式会社 ペルフルオロポリマー、液状組成物、固体高分子電解質膜、膜電極接合体および固体高分子形水電解装置
CN113228356B (zh) * 2018-12-21 2025-03-25 3M创新有限公司 减少催化剂中毒的含氟聚合物离聚物及由其制得的制品
WO2020183306A1 (en) 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
US11905350B2 (en) 2019-09-09 2024-02-20 Compact Membrane Systems, Inc. Gas permeable fluoropolymers and ionomers
JP7685484B2 (ja) 2019-12-12 2025-05-29 ジョンソン マッセイ ハイドロジェン テクノロジーズ リミテッド 電極触媒インク
CN114901710B (zh) 2019-12-20 2024-01-30 3M创新有限公司 氟化共聚物以及包括其的组合物和制品
EP4133542A1 (en) 2020-04-09 2023-02-15 3M Innovative Properties Company Composite including fluorinated polymer and salt nanoparticles and articles including the same
JP7504542B2 (ja) 2020-11-12 2024-06-24 株式会社豊田中央研究所 多孔質酸化物半導体粒子
JP7284776B2 (ja) 2021-03-30 2023-05-31 株式会社豊田中央研究所 メソポーラスカーボン、並びに、燃料電池用電極触媒及び触媒層
US20250239638A1 (en) 2021-10-07 2025-07-24 3M Innovative Properties Company Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same
JP7735208B2 (ja) 2022-03-17 2025-09-08 株式会社豊田中央研究所 メソポーラスカーボン、並びに、燃料電池用電極触媒及び触媒層

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US20020142207A1 (en) * 2000-12-26 2002-10-03 Asahi Glass Company Limited Solid polymer electrolyte material, liquid composition, solid polymer fuel cell and fluoropolymer
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EP0073087A1 (en) * 1981-08-20 1983-03-02 E.I. Du Pont De Nemours And Company Amorphous copolymers of perfluoro-2,2-dimethyl-1,3-dioxole
EP1026152A1 (en) * 1997-03-31 2000-08-09 Daikin Industries, Limited Process for producing perfluorovinyl ethersulfonic acid derivatives and copolymer of the same
CN1310190A (zh) * 2000-02-15 2001-08-29 旭硝子株式会社 嵌段聚合物及其制备方法和该聚合物电解质燃料电池
US20020142207A1 (en) * 2000-12-26 2002-10-03 Asahi Glass Company Limited Solid polymer electrolyte material, liquid composition, solid polymer fuel cell and fluoropolymer
CN1739216A (zh) * 2003-01-20 2006-02-22 旭硝子株式会社 固体高分子型燃料电池用电解质材料的制造方法及固体高分子型燃料电池用膜电极接合体
WO2008013601A1 (en) * 2006-06-01 2008-01-31 E.I. Du Pont De Nemours And Company Membrane electrode assemblies prepared from fluoropolymer dispersions
US20080275147A1 (en) * 2007-01-18 2008-11-06 Asahi Glass Company, Limited Electrolyte material

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104220467A (zh) * 2012-04-16 2014-12-17 旭硝子株式会社 电解质材料、液状组合物及固体高分子型燃料电池用膜电极接合体
CN107922531A (zh) * 2015-08-21 2018-04-17 旭硝子株式会社 含氟聚合物的制造方法
CN107922531B (zh) * 2015-08-21 2020-02-21 Ａｇｃ株式会社 含氟聚合物的制造方法
CN107785590A (zh) * 2016-08-25 2018-03-09 中国科学院宁波材料技术与工程研究所 一种高倍率性能空气电极材料及其应用
CN108878898A (zh) * 2017-05-12 2018-11-23 通用汽车环球科技运作有限责任公司 具有分离的电解质分布的燃料电池及其制造方法
CN108878898B (zh) * 2017-05-12 2021-05-18 通用汽车环球科技运作有限责任公司 具有分离的电解质分布的燃料电池及其制造方法
CN116364991A (zh) * 2023-05-31 2023-06-30 安徽明天新能源科技有限公司 一种催化层涂覆膜及其制备方法
CN116364991B (zh) * 2023-05-31 2023-08-18 安徽明天新能源科技有限公司 一种催化层涂覆膜及其制备方法
CN118684808A (zh) * 2024-08-22 2024-09-24 江苏科润膜材料有限公司 一种以过氧化苯甲酰为引发剂的高透氧性离聚物合成方法及其产物，薄膜和应用

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WO2012088166A1 (en) 2012-06-28
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