CN103251517A - Applications of zinc glycyrrhetate, and zinc glycyrrhetate-containing composition - Google Patents
Applications of zinc glycyrrhetate, and zinc glycyrrhetate-containing composition Download PDFInfo
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- CN103251517A CN103251517A CN2012100371464A CN201210037146A CN103251517A CN 103251517 A CN103251517 A CN 103251517A CN 2012100371464 A CN2012100371464 A CN 2012100371464A CN 201210037146 A CN201210037146 A CN 201210037146A CN 103251517 A CN103251517 A CN 103251517A
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Abstract
The invention belongs to the field of daily chemical products, and discloses applications of zinc glycyrrhetate, and a zinc glycyrrhetate-containing composition, specifically applications of the zinc glycyrrhetate in shampoo and/or hair conditioner preparation. A shampoo composition comprises, by weight, 0.05-5.0% of zinc glycyrrhetate, preferably 0.3-2.0% of zinc glycyrrhetate. A hair conditioner composition comprises, by weight, 0.05-5.0% of zinc glycyrrhetate, preferably 0.3-1.5% of zinc glycyrrhetate. With the zinc glycyrrhetate-containing anti-inflammation and itching relieving composition, scalp inflammations can be effectively eliminated, dried hair caused by the common anti-dandruff shampoo can be effectively improved, and effects of hair moisturizing, dandruff reduction, dandruff removing, itching relieving, and hair quality improvement are achieved.
Description
Technical field
The invention belongs to household chemicals field, relate to the application of zinc glycyrrhetate and contain the compositions of zinc glycyrrhetate.
Background technology
Scalp is itched, and the flying or fluttering in profusion dandruff is a difficult point of puzzlement people daily life always.The source that it has been generally acknowledged that the dandruff mainly is that ovum shape bran skin pityrosporion ovale causes, anti-dandruff shampoo water on the market also is by adding some antibacterial such as Zinc Pyrithione, climbazole at present, two pyrithione, ketoconazole, sulfur, materials such as selenium sulfide reach the effect of removing scurf and relieving itching.But in use not only there is variable color in these antibacterial, and photosensitive, degreasing power is strong, causes problems such as hair is dry and astringent, and all can exist the use potential safety hazard to scalp generation zest more or less, as sulfur and selenium sulfide carcinogenic danger are just arranged.In recent years, have research and data to show, Zinc Pyrithione (ZPT) commonly used in the anti-dandruff shampoo water can produce harmful effect to anemia of pregnant woman and baby at phenolics.Life-time service contains the shampoo of Zinc Pyrithione composition, not only can damage the normal header chrotoplast, also can absorb by skin to cause baby's deformity, so the use of following Zinc Pyrithione may be restricted.
In fact, scalp is itched and the generation of dandruff, is not simple because fungus such as pityrosporon ovale or antibacterial cause, in most cases is due to some inflammation and environmental stimuli of scalp surface.Scalp and hair long term exposure are in the middle of air, standing the stimulation of extraneous different material and gas, the shampoo of life-time service is in cleaning hair and scalp, the different chemical substance composition of forming shampoo and hair conditioner also in various degree act on scalp and hair, cause scalp inflammation, cause scalp to be itched, the disorder of scalp tissue cellular metabolism, dandruff increases, so use antibacterial only can damage the metabolism of normal header chrotoplast merely, increases the weight of dandruff, hair is dry and astringent short-tempered, so need a kind of soft antiinflammatory, the pruritus of antiallergic is applied in shampoo and the hair conditioner, alleviates chemical constituent to the zest of scalp, make the normal metabolism of scalp tissue cellular-restoring, eliminate scalp inflammation, keep scalp and hair moisture, solve the dry and astringent crude phenomenon of hair.
Zinc is the necessary a kind of important trace element of human body, participates in nucleic acid, and the metabolism of protein and energy and oxidation-reduction process are conducive to the division of immunocyte, and breeding can promote epithelial tissue regeneration, and enhancing body's immunological function improves immunity.Zinc supplement preparation commonly used at present has zinc sulfate, zinc gluconate, and zinc stearate, zinc lactate, zinc glycyrrhetate etc., wherein machine acid zinc will be far below mineral acid zinc to the zest of human tissue cell and the intestines and stomach mucosa.
Zinc glycyrrhetate is glycyrrhizic acid or its soluble-salt and zinc ion complexation and a kind of organic acid zinc of forming, combines the effect of glycyrrhizic acid and zinc ion, and good antiinflammatory is arranged; antiallergic; antibiotic property, and can recover the normal activity of cell tissue, promote the regeneration of epithelial tissue cell.People such as the skilful show of Yangzhou University's medical college anti inflammatory immunity drug research chamber gold in 1989 have done abundant research to the antiinflammatory action of zinc glycyrrhetate, by discovering the mice auricle swelling of zinc glycyrrhetate to being caused by dimethylbenzene, rat paw edema due to the carrageenin, and phenomenon such as the microbial rat granulation tissue hyperplasia of cotton balls has the obvious suppression effect, illustrates that zinc glycyrrhetate has antiinflammatory action to acute and chronic inflammation.Show that through zoopery zinc glycyrrhetate toxicity is little, and is safe, be mainly used in children's's zinc supplement preparation clinically, treatment ulcer and sweeting agent.
Just the bioavailability of zinc glycyrrhetate has been carried out animal experiment study as far back as people such as Drug and Equipment Section in 1985.Studies show that: though zinc glycyrrhetate is an organic insoluble drug, the bioavailability of zinc glycyrrhetate is poor unlike zinc sulfate, and glycyrrhizic acid is combined with zinc, does not hinder the biological activity separately of glycyrrhizic acid and zinc, and the two is combined with good synergism.Zinc glycyrrhetate has overcome the zest of inorganic acid radical ion pair skin and mucous membrane tissue, the property of medicine is softer, with antiinflammatory, antibiotic with promote histiocyte to recover normal function to combine and glycyrrhizic acid Pear Power in personal care articles, antioxidation, antiallergic, preserve moisture, hair care reduces the effect that poliosis generates.
The present relevant report of in disclosed technical literature, also not using in shampoo and hair conditioner about zinc glycyrrhetate.
Summary of the invention
The objective of the invention is to the above-mentioned defective at prior art, the application of zinc glycyrrhetate is provided.
Another object of the present invention provides the compositions that contains zinc glycyrrhetate.
Purpose of the present invention can be achieved through the following technical solutions:
The application of zinc glycyrrhetate in preparation shampoo and/or hair conditioner.
The consumption of described zinc glycyrrhetate in shampoo is 0.05%～5.0%wt of shampoo system gross weight, and preferable amount is 0.3%～2.0%; The consumption of zinc glycyrrhetate in the hair conditioner system is 0.05%～5.0% of hair conditioner gross weight, preferred 0.3%～1.5%.
Zinc glycyrrhetate (C described in the present invention
42H
60O
16Zn), be a polyol, its structural formula is as follows:
Wherein, X, Y, Z are respectively one-OH, 2 1/2Zn
2+
The zinc glycyrrhetate poorly soluble, ionization degree is little, and slow release effect is remarkable, combines the physiologically active of glycyrrhizic acid and zinc, and very outstanding antiinflammatory is arranged, antiallergic, recovery organization cell homergy, the effect of promotion wound healing.
A kind of shampoo compositions comprises: (A) account for composition total weight 0.05%～5.0%, preferred 0.3%～2.0% zinc glycyrrhetate; (B) account for the surfactant of composition total weight 5.0%～50%; (C) account for the conditioner of composition total weight 0.1%～10%; (D) account for the rheology modifier of composition total weight 0.1%～20%; (E) account for pearling agent, essence, pH regulator agent, anti-dandruff dose, the antiseptic of composition total weight 0.01%～8%; (F) surplus is water.
Wherein, described surfactant is anion surfactant, non-ionic surface active agent, one or more in the amphoteric surfactant, be the first type surface activating agent with the anion surfactant preferably, non-ionic surface active agent and amphoteric surfactant are used; Described anion surfactant is selected from carboxylate, carboxylate salts, sulfuric acid, N-acylamino acid and salt thereof; the common use of in sulfonic acid and the salt thereof one or more; preferred fat alcohol ether sodium sulfate salt; the fatty alcohol ether ammonium sulfate, one or more in lauryl sulfate sodium salt or the lauryl sulfate ammonium salt.In the present invention with anion surfactant as the first type surface activating agent, play decontamination.For zest and the spumescence that cushions anion surfactant, adopt kinds of surface activating agents such as non-ionic surface active agent and amphoteric surfactant to be used, form a netted colloform texture that polymolecular is joined, discharge the anti-inflammation and sterilization agent better in scalp surface, finish the effect of sterilization, antiinflammatory, cleaning.
Described conditioner is one or more in cationic surfactant, cationic polymer, lubricant, wetting agent, hydrolytic collagen, hydrolyzed protein or other conditioners; Described cationic surfactant is selected from the cationic surfactant of quaternary ammonium salinization, one or more in preferred mountain Yu amido propyl pg dimonium chloride, the inferior oil base ammonium chloride of dihydroxypropyl PEG-5 or the inferior oleamide propyl group pg dimonium chloride phosphate ester; Described cationic polymer is selected from hydroxyethyl-cellulose, the guar hydroxypropyltrimonium chloride of quaternary ammonium salinization, in polyquaternary ammonium salt-4, quaternary ammonium salt-7, quaternary ammonium salt-10, quaternary ammonium salt-17, quaternary ammonium salt-18, quaternary ammonium salt-47 or the quaternary ammonium salt-39 one or more, one or more in preferred guar hydroxypropyltrimonium chloride or the polyquaternary ammonium salt-10; Described lubricant is selected from silicone oil, silicone grease, one or more in ethylene glycol fatty acid or the isopropyl fatty acid ester; Described other conditioners are selected from pantothenylol or N-oleoyl dihydrosphingosine.
Described rheology modifier is one or more in the water-soluble polymer of organic synthesis, organic semisynthetic water-soluble polymer or the natural water-soluble polymer, the water-soluble polymer of described organic synthesis preferably is usually used in the acrylic copolymer of the organic synthesis of shampoo system, further preferred Carbopol AQUA
TMSF-1, SuperGel
TMAC30, Aculyn 33, Aculyn 22 or its mixture, or carbomer series of products: Carbopol 980, Carbopol 981, Carbopol 940, Carbopol 941, Ultrez 10, Ultrez 20, Ultrez 21, SuperGel
TMCE, SuperGel
TMSK, SuperGel
TMAmong the EW one or more; The preferred organic semisynthetic modified cellulose class of described organic semisynthetic water-soluble polymer or modified starch series, further preferred hydroxyethyl-cellulose or hydroxypropyl cellulose; Described pH regulator agent is citric acid, sodium citrate, one or more in phosphoric acid or the triethanolamine.
Described pH regulator agent is citric acid, sodium citrate, one or more in phosphoric acid or the triethanolamine.
A kind of hair conditioner composition, said composition comprises: (A) account for composition total weight 0.05%～5.0%, preferred 0.3%～1.5% zinc glycyrrhetate; (B) account for the surfactant of composition total weight 1.0%～15%; (C) account for the conditioner of composition total weight 0.1%～10%; (D) account for the rheology modifier of composition total weight 0.1%～20%; (E) account for pearling agent, essence, pH regulator agent, anti-dandruff dose, the antiseptic of composition total weight 0.01%～8%; (F) surplus is water.
Wherein, described surfactant is quaternary cationic surfactant and/or non-ionic surface active agent.
Described quaternary cationic surfactant is hexadecyltrimethylammonium chloride, one or more in octadecyl trimethyl ammonium chloride, mountain Yu amido propyl pg dimonium chloride, dioctadecyl dimethyl ammonium chloride or the inferior oleamide propyl group pg dimonium chloride phosphate ester.
In the described hair conditioner composition, also comprise in glycerol, white oil or the hexadeca-octadecyl alcohol one or more.
Using method:
For active substance such as zinc glycyrrhetate are fully contacted with hair with scalp, and in hair and an amount of deposition of scalp generation, well bring into play maintaining hair, eliminate the effect of scalp surface inflammation, so when use contains the shampoo of zinc glycyrrhetate and hair conditioner, may further comprise the steps:
A) at first will be with hair and the abundant moistening of scalp water;
B) a certain amount of shampoo or hair conditioner are coated on the hair of water in advance moistening, amount ranges is at 1 gram～50 grams, and preferred 1 gram～30 restrains;
C) on hair and scalp, rub fully and smear shampoo or hair conditioner, about 3～5 minutes;
D) with the clean hair of clear water rinsing and scalp.
As required, can repeatedly repeat above step, reach antiinflammatory, antipruritic, eliminate dandruff, the effect of maintaining hair.
Beneficial effect of the present invention:
The anti-inflammatory anti-itch compositions that contains zinc glycyrrhetate provided by the present invention, can effectively eliminate scalp inflammation, improve hair that common anti-dandruff shampoo causes effectively and send out withered phenomenon puckery, play hair and preserve moisture, reduce the dandruff, the effect that reaches removing scurf and relieving itching and improve hair quality.
The present invention adopts zinc glycyrrhetate as the removing scurf and relieving itching active component of shampoo and hair conditioner, has improved the safety in utilization of shampoo and hair conditioner, has reduced the zest of other compositions to skin, has improved the comfort level of skin.
Specific embodiment
Be the non-limiting example that contains zinc glycyrrhetate shampoo and hair conditioner composition to of the present invention below.These embodiment only are to explanation of the present invention, can not be interpreted as limitation of the invention.Do not breaking away from spirit of the present invention and the basis, can make many changes to the present invention.In these embodiments, unless stated otherwise, all concentration all is percentage by weight.
Shampoo prepares embodiment
Example 1 and example 2 contrasts in the present embodiment, example 3 and example 4 contrasts, example 5 and example 6 contrasts, example 7 and example 8 contrasts.
Under the room temperature condition, polymer powders such as the polyquaternary ammonium salt-10 in the moistening A component or guar hydroxypropyltrimonium chloride in water in advance, stir, be heated to 75 ℃, add the various surfactants in the B component successively in the A system, the system that is stirred to dissolve fully and evenly after, stop heating, cool to 45 ℃, add in the C component after scattered in advance acrylate copolymer such as acrylic resin copolymer or carbomer stir, regulate pH with the citric acid in the D component or triethanolamine, add the anti-dandruff dose of Zinc Pyrithione (ZPT) in the scattered E component of water in advance then, zinc glycyrrhetate adds the antiseptic in an amount of F component at last as required successively, materials such as essence, stirring gets final product.
Table 1 shampoo prepares example
Embodiment 3 shampoo effect embodiment
Removing scurf and relieving itching effect evaluation method for the present composition is: choose and have the crowd of the dandruff and head pruritus symptom (each 30 people) in various degree, do the half a head test: use earlier the water-soaked hair, fully spread upon on the scalp with containing a certain amount of anti-dandruff dose shampoo then, rubbed 3-4 minute, clear water is cleaned, the first week washing 3 times is washed weekly later on 2 times, observed and recorded after 4 weeks.Example 1 and example 2 contrasts, example 3 and example 4 contrasts, example 5 and example 6 contrasts, example 7 and example 8 contrasts.
The tester uses shampoo sample, one month trial period according to identical method.The tester estimates using the removing scurf and relieving itching effect behind the shampoo according to the sensation of oneself, and the standard of evaluation adopts 5 fens systems, 5 be divided into best, 1 be divided into the poorest.
The various shampoos of table 2 use the effect evaluation
| Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 | Example 7 | Example 8 | |
| Hair uses sensation | 2.3 | 3.4 | 2.0 | 4.1 | 4.3 | 2.0 | 3.5 | 4.6 |
| The scalp comfort level | 2.1 | 3.1 | 2.5 | 3.8 | 4.5 | 2.7 | 3.3 | 4.8 |
| Anti-dandruff effect | 1.0 | 2.6 | 2.0 | 3.2 | 4.1 | 3.1 | 3.5 | 4.3 |
| Antipruritic effect | 1.0 | 2.9 | 2.0 | 3.6 | 4.3 | 2.5 | 3.2 | 4.5 |
Embodiment 4 hair conditioner embodiment
During following hair conditioner with anti-dandruff and itching-relieving efficacies is filled a prescription, example 9 and example 10 contrasts, example 11 and example 12 contrasts, example 13 and example 14 contrasts, example 15 and example 16 contrasts.
Hair conditioner preparation method: with the guar gum hydroxypropyl-trimethyl ammonium chloride in the A component, polymer powders such as cellulose are dispersed in water or the glycerine water solution in advance, stirring at room a few minutes, powder body is uniformly dispersed, be warming up to 70 ℃, add cationic surfactant such as hexadecyltrimethylammonium chloride in the B component, octadecyl trimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, mountain Yu amido propyl pg dimonium chloride (30%), inferior oleamide propyl group pg dimonium chloride phosphate ester and components such as non-ionic monoglyceride monostearate and stearyl alcohol stearate, stirring fully dissolves it and mix homogeneously, add silicone oil then, white oil, 16-18 alcohol, American Avocado Tree oil amide DEA, hair care components such as inferior oleamide DEA, mix the back and use homogenizer emulsifying 5 minutes, stirring is cooled to 40 ℃, adds the scattered anti-dandruff dose of Zinc Pyrithione (ZPT) of water in advance in the C component successively, zinc glycyrrhetate, emulsified silicone oil, polyquaternary ammonium salt-7 after stirring, adds the essence in an amount of D component as required successively, antiseptic, stirring gets final product.
Table 3 hair conditioner prescription comparison example
Embodiment 5 hair conditioner effect embodiment
The use effect evaluation of hair conditioner is similar to shampoo, and comparative sample is carried out half a head test, 30 days trial periods, feel overall assessment marking according to the trier, and adopt 5 fens systems, it is wherein every that to feel best be 5 minutes, the poorest is 1 minute.
The various hair conditioner results of use of table 4 are estimated
Claims (10)
1. the application of zinc glycyrrhetate in preparation shampoo and/or hair conditioner.
2. application according to claim 1 is characterized in that the consumption of described zinc glycyrrhetate in shampoo is 0.05%～5.0%wt of shampoo system gross weight, and preferable amount is 0.3%～2.0% of shampoo system gross weight; The consumption of zinc glycyrrhetate in the hair conditioner system is 0.05%～5.0% of hair conditioner gross weight, and preferable amount is 0.3%～1.5% of shampoo system gross weight.
3. a shampoo compositions is characterized in that comprising: (A) account for composition total weight 0.05%～5.0%, preferred 0.3%～2.0% zinc glycyrrhetate; (B) account for the surfactant of composition total weight 5.0%～50%; (C) account for the conditioner of composition total weight 0.1%～10%; (D) account for the rheology modifier of composition total weight 0.1%～20%; (E) account for pearling agent, essence, pH regulator agent, anti-dandruff dose, the antiseptic of composition total weight 0.01%～8%; (F) surplus is water.
4. shampoo compositions according to claim 3, it is characterized in that described surfactant is selected from anion surfactant, non-ionic surface active agent, in the amphoteric surfactant one or more, be the first type surface activating agent with the anion surfactant preferably, non-ionic surface active agent and amphoteric surfactant are used; Described anion surfactant is selected from carboxylate, carboxylate salts, sulfuric acid, N-acylamino acid and salt thereof; in sulfonic acid and the salt thereof one or more; preferred fat alcohol ether sodium sulfate salt; the fatty alcohol ether ammonium sulfate, one or more in lauryl sulfate sodium salt or the lauryl sulfate ammonium salt.
5. shampoo compositions according to claim 3 is characterized in that described conditioner is one or more in cationic surfactant, cationic polymer, lubricant, wetting agent, hydrolytic collagen, hydrolyzed protein or other conditioners; Described cationic surfactant is selected from the cationic surfactant of quaternary ammonium salinization, one or more in preferred mountain Yu amido propyl pg dimonium chloride, the inferior oil base ammonium chloride of dihydroxypropyl PEG-5 or the inferior oleamide propyl group pg dimonium chloride phosphate ester; Described cationic polymer is selected from hydroxyethyl-cellulose, the guar hydroxypropyltrimonium chloride of quaternary ammonium salinization, in polyquaternary ammonium salt-4, quaternary ammonium salt-7, quaternary ammonium salt-10, quaternary ammonium salt-17, quaternary ammonium salt-18, quaternary ammonium salt-47 or the quaternary ammonium salt-39 one or more, one or more in preferred guar hydroxypropyltrimonium chloride or the polyquaternary ammonium salt-10; Described lubricant is selected from silicone oil, silicone grease, one or more in ethylene glycol fatty acid or the isopropyl fatty acid ester; Described other conditioners are selected from pantothenylol or N-oleoyl dihydrosphingosine.
6. shampoo compositions according to claim 3, it is characterized in that described rheology modifier is one or more in the water-soluble polymer of organic synthesis, organic semisynthetic water-soluble polymer or the natural water-soluble polymer, the water-soluble polymer of described organic synthesis preferably is usually used in the acrylic copolymer of the organic synthesis of shampoo system, further preferred CarbopolAQUA
TMSF-1, SuperGel
TMAC30, Aculyn 33, Aculyn 22 or its mixture, or carbomer series of products: Carbopol 980, Carbopol 981, Carbopol 940, Carbopol 941, Ultrez 10, Ultrez 20, Ultrez 21, SuperGel
TMCE, SuperGel
TMSK, SuperGel
TMAmong the EW one or more; The preferred organic semisynthetic modified cellulose class of described organic semisynthetic water-soluble polymer or modified starch series, further preferred hydroxyethyl-cellulose or hydroxypropyl cellulose; Described pH regulator agent is citric acid, sodium citrate, one or more in phosphoric acid or the triethanolamine.
7. a hair conditioner composition is characterized in that said composition comprises: (A) account for composition total weight 0.05%～5.0%, the zinc glycyrrhetate of preferred 0.3%-1.5%; (B) account for the surfactant of composition total weight 1.0%～15%; (C) account for the conditioner of composition total weight 0.1%～10%; (D) account for the rheology modifier of composition total weight 0.1%～20%; (E) account for pearling agent, essence, pH regulator agent, anti-dandruff dose, the antiseptic of composition total weight 0.01%～8%; (F) surplus is water.
8. hair conditioner composition according to claim 7 is characterized in that described surfactant is selected from quaternary cationic surfactant and/or non-ionic surface active agent.
9. hair conditioner composition according to claim 8, it is characterized in that described quaternary cationic surfactant is selected from hexadecyltrimethylammonium chloride, octadecyl trimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, mountain Yu amido propyl pg dimonium chloride, or in the inferior oleamide propyl group pg dimonium chloride phosphate ester one or more.
10. hair conditioner composition according to claim 7 is characterized in that in the described hair conditioner composition, also comprises in glycerol, white oil or the hexadeca-octadecyl alcohol one or more.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2018018487A1 (en) * | 2016-07-28 | 2018-02-01 | Beiersdorf Daily Chemical (Wuhan) Co., Ltd. | A hair composition for hair care containing rose hip oil and use thereof |
| CN109464294A (en) * | 2018-12-26 | 2019-03-15 | 广州蜜妆生物科技有限公司 | A kind of hydrolysis of keratin hair conditioner and preparation method thereof |
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| KR100817669B1 (en) * | 2007-04-20 | 2008-03-27 | 주식회사 엘지생활건강 | Hair coating product and method giving superior elasticity and volume to hair |
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- 2012-02-17 CN CN2012100371464A patent/CN103251517A/en active Pending
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| KR100817669B1 (en) * | 2007-04-20 | 2008-03-27 | 주식회사 엘지생활건강 | Hair coating product and method giving superior elasticity and volume to hair |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018018487A1 (en) * | 2016-07-28 | 2018-02-01 | Beiersdorf Daily Chemical (Wuhan) Co., Ltd. | A hair composition for hair care containing rose hip oil and use thereof |
| CN109640944A (en) * | 2016-07-28 | 2019-04-16 | 拜尔斯道夫日化（武汉）有限公司 | Hair care composition containing rose hip oil and its use |
| CN109464294A (en) * | 2018-12-26 | 2019-03-15 | 广州蜜妆生物科技有限公司 | A kind of hydrolysis of keratin hair conditioner and preparation method thereof |
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Application publication date: 20130821 |