CN103215591A - Preparation method of imitated-metal enameled steel sheet - Google Patents
Preparation method of imitated-metal enameled steel sheet Download PDFInfo
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- CN103215591A CN103215591A CN2013100450672A CN201310045067A CN103215591A CN 103215591 A CN103215591 A CN 103215591A CN 2013100450672 A CN2013100450672 A CN 2013100450672A CN 201310045067 A CN201310045067 A CN 201310045067A CN 103215591 A CN103215591 A CN 103215591A
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- Prior art keywords
- imitative
- glaze
- parts
- metallic enamel
- steel plate
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 55
- 239000010959 steel Substances 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 23
- 239000002184 metal Substances 0.000 title claims abstract description 23
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 90
- 239000000375 suspending agent Substances 0.000 claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 21
- -1 sodium fluoroborate Chemical compound 0.000 claims abstract description 18
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004202 carbamide Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 238000000498 ball milling Methods 0.000 claims abstract description 7
- 235000015895 biscuits Nutrition 0.000 claims abstract description 7
- 239000007921 spray Substances 0.000 claims abstract description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 16
- 229910052700 potassium Inorganic materials 0.000 claims description 16
- 239000011591 potassium Substances 0.000 claims description 16
- 229910001495 sodium tetrafluoroborate Inorganic materials 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000005034 decoration Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 239000002002 slurry Substances 0.000 abstract 2
- 238000005202 decontamination Methods 0.000 abstract 1
- 230000003588 decontaminative effect Effects 0.000 abstract 1
- 238000004534 enameling Methods 0.000 description 16
- 238000000034 method Methods 0.000 description 6
- 229910052573 porcelain Inorganic materials 0.000 description 4
- 230000003670 easy-to-clean Effects 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Landscapes
- Glass Compositions (AREA)
- Finishing Walls (AREA)
Abstract
The invention relates to a preparation method of an imitated-metal enameled steel sheet. The prepared enameled steel sheet has the advantages of good mechanical properties, good heat resistance, excellent chemical stability, clean and gorgeous appearance, and easy cleaning and decontamination. The enameled steel sheet is suitable to be used in decorative enamel of building interior and exterior wall decorations and decorative enamel of public places such as tunnels and subways. The enameled steel sheet has good imitated metal effect. A production process of the enameled steel sheet comprises the steps that: a suspending agent, water, sodium fluoroborate, urea, and potassium fluorosilicate are added into a transparent base glaze; ball milling is carried out, such that a glaze slurry is obtained; imitated-metal powder is added into the glaze slurry, and the mixture is well mixed, such that an imitated-metal enamel glaze is obtained; the imitated-metal enamel glaze is sprayed on a biscuit by using a spray gun; and the material is fired under a temperature of 800-860 DEG C, such that the imitated-metal enameled steel sheet is obtained.
Description
Technical field
The present invention relates to a kind of preparation method of imitative metallic enamel steel plate, the imitative metallic enamel steel plate for preparing has the favorable mechanical performance, good heat resistance, and the chemical stability excellence, outward appearance cleaning, magnificent is easy to clean scrubbing.Be applicable to public places decoration enamel such as buildings decorating inner and external walls and tunnel, subway.
Background technology
Enamel the porcelain product and also is the back coated article, and it is a kind ofly to give function such as its preservative property, resistance to chemical reagents and weather proofing and improve the goods in steel plate life-span by form enamel layer on the substrate steel sheet surface.Enamel the porcelain product and is compared with the precoating goods, though have shortcomings such as manufacturing cost costliness, it all is possessed of good qualities at aspects such as hardness, weather proofing, detergency, thermotolerance and uninflammability; Simultaneously, enamel porcelain products itself and is also had highly inhibition pollution, can the effect of excellent restorative chemical-resistant by cleaning.At present, enameling sheet abroad building curtain wall and various upholstery work in be widely used, also having nearly ten years in China is applicating history.
The thickness of enameling sheet generally is not more than 0.3mm, deforms easily in sintering process, causes its surface finish relatively poor, during in addition as the finishing material of skin, can influence attractive in appearance.Simultaneously, the tension force unit elongation that stand during bending machining on the enamel surface is not less than 10%, and enamel layer is the low glassiness of a kind of unit elongation, in any case the cracking of then unavoidable enamel layer.So enameling sheet only when satisfying some basic demands, is just stood bending machining, these requirements are exactly that enamel layer will stick on the steel plate securely, even this layer cracking part can cause at all do not get rusty.
Traditional enameling sheet has excellent bendability, enamel adherence, glossiness and erosion resistance, also has good stability simultaneously, anti-advantage such as peel off.But traditional enameling sheet outward appearance is graceful inadequately, is not suitable for the application of some special occasions.
For this reason, press for a kind of surface of development and have color and luster, outward appearance cleaning, magnificent is fit to the imitative metallic enamel steel plate of various applications.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of preparation method of imitative metallic enamel steel plate, and the enameling sheet of this method preparation has favorable mechanical performance, good heat resistance, the chemical stability excellence, outward appearance cleaning, magnificent is easy to clean scrubbing, also has well imitative metal effect.
Above-mentioned technical problem of the present invention is implemented by the following technical programs: a kind of preparation method of imitative metallic enamel steel plate is characterized in that: may further comprise the steps:
(1) add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride in transparent basic glaze and carry out ball milling and get glaze slip, the fineness degree of control glaze slip is at 0.2g/100ml/150 order～0.3g/100ml/150 order, and glaze slip unit weight is at 165g/100ml～170gml;
In glaze slip, add imitative metal powder and mix, must imitate the metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant is sprayed at biscuit with spray gun, obtain imitative metallic enamel steel plate;
Above-mentioned imitative metallic enamel steel plate is placed under 100～250 ℃ of temperature oven dry 20～60min;
The imitative metallic enamel steel plate that to dry is again put into firing furnace, under 800～860 ℃, fires 4～6min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 90～110 parts in transparent basic glaze, 6～8 parts of suspension agents, 40～50 parts in water, 0.1～0.3 part of Sodium tetrafluoroborate, 0.3～0.7 part in urea, 0.1～0.3 part of potassium silicofluoride, 8～12 parts of imitative metal powders.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 95～105 parts in transparent basic glaze, 6.5～7.5 parts of suspension agents, 42～48 parts in water, 0.15～0.25 part of Sodium tetrafluoroborate, 0.45～0.55 part in urea, 0.15～0.25 part of potassium silicofluoride, 9～11 parts of imitative metal powders.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 100 parts in transparent basic glaze, 7 parts of suspension agents, 45 parts in water, 0.2 part of Sodium tetrafluoroborate, 0.5 part in urea, 0.2 part of potassium silicofluoride, 10 parts of imitative metal powders.
The preparation method of described imitative metallic enamel steel plate, described suspension agent is a clay.
The preparation method of described imitative metallic enamel steel plate, the imitative metallic enamel frit particles thickness in the described step (2) is 80～110 μ m.
The preparation method of described imitative metallic enamel steel plate, the imitative metal powder of stating has simulating golden colour powder, imitative silver color powder, imitation copper powder and artificial stainless steel toner.
In sum, the present invention compared with prior art has following advantage and beneficial effect:
The present invention makes enameling sheet porcelain facing effect have metallic color, as gold, silver color, coppery, stainless steel etc.Have the favorable mechanical performance, good heat resistance, the chemical stability excellence, outward appearance cleaning, magnificent is easy to clean scrubbing.
Embodiment
Below by embodiment, the technical scheme of inventing is described in further detail, in these embodiments, unless otherwise indicated, all percentage compositions are all in mass parts:
Embodiment 1:
A kind of preparation method of imitative metallic enamel steel plate is characterized in that: may further comprise the steps:
(1) add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride in transparent basic glaze and carry out ball milling and get glaze slip, the fineness degree of control glaze slip is at the 0.2g/100ml/150 order, and glaze slip unit weight is at 165g/100ml;
(2) in glaze slip, add imitative metal powder and mix, must imitate the metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant is sprayed at biscuit with spray gun, obtain imitative metallic enamel steel plate;
Above-mentioned imitative metallic enamel steel plate is placed under 100 ℃ of temperature oven dry 20min;
(3) the imitative metallic enamel steel plate that will dry is again put into firing furnace, under 800 ℃, fires 4min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 100 parts in transparent basic glaze, 7 parts of suspension agents, 45 parts in water, 0.2 part of Sodium tetrafluoroborate, 0.5 part in urea, 0.2 part of potassium silicofluoride, 10 parts in simulating golden colour powder.
Described suspension agent is a clay.
Imitative metallic enamel frit particles thickness in the described step (2) is 80 μ m.
Obtain the simulating golden colour enameling sheet by aforesaid method.
Embodiment 2:
A kind of preparation method of imitative metallic enamel steel plate is characterized in that: may further comprise the steps:
(1) add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride in transparent basic glaze and carry out ball milling and get glaze slip, the fineness degree of control glaze slip is at the 0.3g/100ml/150 order, and glaze slip unit weight is at 170g/ml;
(2) in glaze slip, add imitative metal powder and mix, must imitate the metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant is sprayed at biscuit with spray gun, obtain imitative metallic enamel steel plate;
Above-mentioned imitative metallic enamel steel plate is placed under 250 ℃ of temperature oven dry 60min;
(3) the imitative metallic enamel steel plate that will dry is again put into firing furnace, under 860 ℃, fires 4.5min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 110 parts in transparent basic glaze, 8 parts of suspension agents, 50 parts in water, 0.3 part of Sodium tetrafluoroborate, 0.7 part in urea, 0.3 part of potassium silicofluoride, 12 parts in imitative silver color powder.
Described suspension agent is a clay.
Imitative metallic enamel frit particles thickness in the described step (2) is 110 μ m.
Obtain imitative silver color enameling sheet by aforesaid method.
Embodiment 3:
A kind of preparation method of imitative metallic enamel steel plate is characterized in that: may further comprise the steps:
(1) add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride in transparent basic glaze and carry out ball milling and get glaze slip, the fineness degree of control glaze slip is at the 0.25g/100ml/150 order, and glaze slip unit weight is at 168g/100ml;
(2) in glaze slip, add imitative metal powder and mix, must imitate the metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant is sprayed at biscuit with spray gun, obtain imitative metallic enamel steel plate;
Above-mentioned imitative metallic enamel steel plate is placed under 200 ℃ of temperature oven dry 40min;
(3) the imitative metallic enamel steel plate that will dry is again put into firing furnace, under 820 ℃, fires 5min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 90 parts in transparent basic glaze, 6 parts of suspension agents, 40 parts in water, 0.1 part of Sodium tetrafluoroborate, 0.3 part in urea, 0.1 part of potassium silicofluoride, 8 parts in imitation copper powder.
Described suspension agent is a clay.
Imitative metallic enamel frit particles thickness in the described step (2) is 80 μ m.
Obtain the imitation copper enameling sheet by aforesaid method.
Embodiment 4:
A kind of preparation method of imitative metallic enamel steel plate is characterized in that: may further comprise the steps:
(1) add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride in transparent basic glaze and carry out ball milling and get glaze slip, the fineness degree of control glaze slip is at the 0.2g/100ml/150 order, and glaze slip unit weight is at 165g/100ml;
(2) in glaze slip, add imitative metal powder and mix, must imitate the metallic enamel glaze;
Above-mentioned imitative metallic enamel oil plant is sprayed at biscuit with spray gun, obtain imitative metallic enamel steel plate;
Above-mentioned imitative metallic enamel steel plate is placed under 150 ℃ of temperature oven dry 50min;
(3) the imitative metallic enamel steel plate that will dry is again put into firing furnace, under 840 ℃, fires 4.5min.
The preparation method of described imitative metallic enamel steel plate, described imitative metallic enamel glaze is made up of the compound of following mass parts: 95 parts in transparent basic glaze, 6.5 parts of suspension agents, 42 parts in water, 0.15 part of Sodium tetrafluoroborate, 0.45 part in urea, 0.15 part of potassium silicofluoride, 9 parts of artificial stainless steel toners.
Described suspension agent is a clay.
Imitative metallic enamel frit particles thickness in the described step (2) is 90 μ m.
Obtain the artificial stainless steel colour enameling sheet by aforesaid method.
Simulating golden colour enameling sheet, imitative silver color enameling sheet, imitation copper enameling sheet, artificial stainless steel colour enameling sheet that production is obtained carry out testing performance index: four kinds of enameling sheets that above-mentioned production is obtained are placed under 540 ℃ of temperature, thermostatically heating 30 minutes is cooled to room temperature; Above-mentioned steps is carried out 5 times repeatedly.
The testing performance index contrast table is as follows:
Through performance is tested us and is found, imitative metallic enamel does not weaken on performance with respect to common enamel, and partial properties also promotes to some extent, and has imitative metal effect, more attractive in appearance in appearance, magnificent, be applicable to public places decoration enamel such as buildings decorating inner and external walls and tunnel, subway.
Claims (7)
1. the preparation method of an imitative metallic enamel steel plate is characterized in that: may further comprise the steps:
(1) add suspension agent, water, Sodium tetrafluoroborate, urea, potassium silicofluoride in transparent basic glaze and carry out ball milling and get glaze slip, the fineness degree of control glaze slip is at 0.2g/100ml/150 order～0.3 g/100ml/150 order, and glaze slip unit weight is at 165g/100ml～170g/ml;
(2) in glaze slip, add imitative metal powder and mix, must imitate the metallic enamel glaze;
(3) above-mentioned imitative metallic enamel oil plant is sprayed at biscuit with spray gun, obtain imitative metallic enamel steel plate;
(4) above-mentioned imitative metallic enamel steel plate is placed under 100～250 ℃ of temperature oven dry 20～60min;
(5) the imitative metallic enamel steel plate that will dry is again put into firing furnace, under 800～860 ℃, fires 4～6min.
2. the preparation method of imitative metallic enamel steel plate according to claim 1 is characterized in that, described imitative metallic enamel glaze is made up of the compound of following mass parts:
90～110 parts in transparent basic glaze, 6～8 parts of suspension agents, 40～50 parts in water, 0.1～0.3 part of Sodium tetrafluoroborate, 0.3～0.7 part in urea, 0.1～0.3 part of potassium silicofluoride, 8～12 parts of imitative metal powders.
3. the preparation method of imitative metallic enamel steel plate according to claim 2 is characterized in that, described imitative metallic enamel glaze is made up of the compound of following mass parts:
95～105 parts in transparent basic glaze, 6.5～7.5 parts of suspension agents, 42～48 parts in water, 0.15～0.25 part of Sodium tetrafluoroborate, 0.45～0.55 part in urea, 0.15～0.25 part of potassium silicofluoride, 9～11 parts of imitative metal powders.
4. the preparation method of imitative metallic enamel steel plate according to claim 3 is characterized in that, described imitative metallic enamel glaze is made up of the compound of following mass parts:
100 parts in transparent basic glaze, 7 parts of suspension agents, 45 parts in water, 0.2 part of Sodium tetrafluoroborate, 0.5 part in urea, 0.2 part of potassium silicofluoride, 10 parts of imitative metal powders.
5. according to the preparation method of any described imitative metallic enamel steel plate in the claim 1～4, it is characterized in that described suspension agent is a clay.
6. the preparation method of imitative metallic enamel steel plate according to claim 1 is characterized in that, the imitative metallic enamel frit particles thickness in the described step (2) is 80～110 μ m.
7. according to the preparation method of any described imitative metallic enamel steel plate in the claim 1～4, it is characterized in that described imitative metal powder has simulating golden colour powder, imitative silver color powder, imitation copper powder and artificial stainless steel toner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310045067.2A CN103215591B (en) | 2013-02-01 | 2013-02-01 | Preparation method of imitated-metal enameled steel sheet |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310045067.2A CN103215591B (en) | 2013-02-01 | 2013-02-01 | Preparation method of imitated-metal enameled steel sheet |
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| CN103215591B CN103215591B (en) | 2015-05-27 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105271751A (en) * | 2015-10-16 | 2016-01-27 | 湖南天欣科技股份有限公司 | High-temperature glaze for anti-skid ceramic tiles as well as production method and application method of high-temperature glaze |
| CN105271752A (en) * | 2015-10-16 | 2016-01-27 | 浙江开尔新材料股份有限公司 | Preparation method of low-gloss colored enamel glaze surface |
| CN105695994A (en) * | 2016-03-01 | 2016-06-22 | 吴申龙 | Nano-ceramic technology for inner wall of stainless steel |
| CN108423992A (en) * | 2018-05-28 | 2018-08-21 | 浙江开尔新材料股份有限公司 | It is a kind of to be used to produce glaze and technique with cobblestone-imitated male and fomale(M＆F) enamelled pressed steel |
| CN110372208A (en) * | 2019-07-02 | 2019-10-25 | 浙江开尔新材料股份有限公司 | The method for discharging the enamel glaze slip of anion and preparing anion enamel plate using it |
| CN112062469A (en) * | 2020-08-28 | 2020-12-11 | 浙江开尔新材料股份有限公司 | Bottom glaze material of stainless steel enamel plate and preparation method and application thereof |
| CN112573825A (en) * | 2020-11-24 | 2021-03-30 | 杭州方泰搪瓷制品有限公司 | Enamel cover glaze slip and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105271751A (en) * | 2015-10-16 | 2016-01-27 | 湖南天欣科技股份有限公司 | High-temperature glaze for anti-skid ceramic tiles as well as production method and application method of high-temperature glaze |
| CN105271752A (en) * | 2015-10-16 | 2016-01-27 | 浙江开尔新材料股份有限公司 | Preparation method of low-gloss colored enamel glaze surface |
| CN105695994A (en) * | 2016-03-01 | 2016-06-22 | 吴申龙 | Nano-ceramic technology for inner wall of stainless steel |
| CN108423992A (en) * | 2018-05-28 | 2018-08-21 | 浙江开尔新材料股份有限公司 | It is a kind of to be used to produce glaze and technique with cobblestone-imitated male and fomale(M＆F) enamelled pressed steel |
| CN108423992B (en) * | 2018-05-28 | 2021-01-15 | 浙江开尔新材料股份有限公司 | Process for producing enameled steel plate with cobblestone-imitated concave-convex surface |
| CN110372208A (en) * | 2019-07-02 | 2019-10-25 | 浙江开尔新材料股份有限公司 | The method for discharging the enamel glaze slip of anion and preparing anion enamel plate using it |
| CN110372208B (en) * | 2019-07-02 | 2021-12-31 | 浙江开尔新材料股份有限公司 | Enamel glaze slip capable of releasing negative ions and method for preparing negative ion enamel plate by using enamel glaze slip |
| CN112062469A (en) * | 2020-08-28 | 2020-12-11 | 浙江开尔新材料股份有限公司 | Bottom glaze material of stainless steel enamel plate and preparation method and application thereof |
| CN112062469B (en) * | 2020-08-28 | 2022-06-03 | 浙江开尔新材料股份有限公司 | Bottom glaze material of stainless steel enamel plate and preparation method and application thereof |
| CN112573825A (en) * | 2020-11-24 | 2021-03-30 | 杭州方泰搪瓷制品有限公司 | Enamel cover glaze slip and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103215591B (en) | 2015-05-27 |
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