CN103215145A - Baikal skullcap root skin-care tableware liquid detergent - Google Patents
Baikal skullcap root skin-care tableware liquid detergent Download PDFInfo
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- CN103215145A CN103215145A CN2013100528906A CN201310052890A CN103215145A CN 103215145 A CN103215145 A CN 103215145A CN 2013100528906 A CN2013100528906 A CN 2013100528906A CN 201310052890 A CN201310052890 A CN 201310052890A CN 103215145 A CN103215145 A CN 103215145A
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Abstract
The invention discloses a Baikal skullcap root skin-care tableware liquid detergent composed of the raw materials of, by weight, 4-6 parts of lauramide propyl amine oxide, 4-6 parts of myristamide propyl amine oxide, 2-4 parts of N,N-dimethyl decane-N-amine oxide, 5-7 parts of decyl glucoside, 0.05-0.15 parts of a Baikal skullcap root extract liquid, and 80 parts of water. According to the invention, a nonionic surfactant and an amphoteric surfactant are compounded, a traditional anionic surfactant is eliminated, good decontamination washing effect is ensured, and irritation to hand surface is greatly reduced. Also, the Baikal skullcap root extract liquid is compounded into the liquid detergent, such that hand skins can be effectively nourished when the liquid detergent is used for clearing tableware.
Description
Technical field:
The present invention relates to a kind of tableware liquid washing agent, particularly a kind of root of large-flowered skullcap skin care tableware liquid washing agent.
Background technology:
Liquid washing agent is a big class in the synthetic detergent, and the output maximum is washing powder in the synthetic detergent, and with fastest developing speed is liquid washing agent.Because liquid washing agent has many good qualities than solid detergent at aspects such as kind, performance, production technique, therefore manufacturing enterprise competitively develops both at home and abroad.
Liquid washing agent is that it has the characteristic of surfactant soln with water or other organic solvents articles for washing as base-material.The liquid product that generally will have cleaning function is called liquid washing agent.Be divided into tableware liquid washing agent, fabric liquid washing agent, shampoo and skin cleaner and hard surface cleaner according to purposes or function.
The tableware liquid washing agent is mainly used in wash dining set, tea set and kitchen tools etc.; Also can be used to wash the heavy clothing of fruit, vegetables and greasy dirt.It is the indispensable washing product of catering industry and family.
Dish washing detergent belongs to allotment type product, and development is very rapid at home in recent years.At present dish washing detergent on the market is a feast for the eyes, have superpower, that concentrated type is arranged and the strong sterilizing power of detersive power or the like.Along with the progressively enhancing of people's environmental consciousness, dish washing detergent development in future direction will be to be main flow with the environment-friendly and green type.Except strong detersive power, harmless, sterilization and disinfection, gentle high foaming function are arranged, also should degrade easily, free from environmental pollution.The effective constituent of dish washing detergent mainly is tensio-active agent, and traditional dish washing detergent is a raw material with synthetic surfactant (as LAS, AS, AES, SAS etc.) mainly.Maybe can't degrade but they are difficult for degraded mostly, environment is polluted.Therefore, exploitation environment-protection type tableware washing composition has been complied with the trend in epoch, and especially in Europe, the U.S. and Japan, the use of environment protecting tableware washing composition is quite general.But at home, the development of environment-protection type tableware washing composition is slower, and particularly Chinese medicine tableware liquid washing agent is just fewer.
Summary of the invention:
At the prior art above shortcomings, technical problem to be solved by this invention provides a kind of root of large-flowered skullcap skin care tableware liquid washing agent.
Technical problem of the present invention is achieved by following technical proposals:
A kind of root of large-flowered skullcap skin care tableware liquid washing agent, raw material by following weight part is formed: dodecanamide propyl amine oxide 4-6 part, myristic amide propyl group amine oxide 4-6 part, N, N-dimethyl decyl-N-amine oxide 2-4 part, Plantacare 818 5-7 part, root of large-flowered skullcap extracting solution 0.05-0.15 part, 80 parts in water.
With dodecanamide propyl amine oxide, myristic amide propyl group amine oxide, N, N-dimethyl decyl-N-amine oxide, Plantacare 818 and root of large-flowered skullcap extracting solution add in the entry, be heated to 40-60 ℃, mix, can make this root of large-flowered skullcap skin care tableware liquid washing agent.
Below, raw material involved in the present invention is made simple introduction:
The dodecanamide propyl amine oxide, CAS accession number: 69898-00-6.
Myristic amide propyl group amine oxide, CAS accession number: 67806-10-4.
N, N-dimethyl decyl-N-amine oxide, CAS accession number: 2605-79-0.
Plantacare 818, CAS accession number: 141464-42-8.
The root of large-flowered skullcap is a kind of conventional Chinese medicine, is documented in the version in 2010 at Chinese Pharmacopoeia.
Root of large-flowered skullcap extracting solution of the present invention can pass through commercially available getting.Also can adopt the preparation of following method and get: after root of large-flowered skullcap pulverizing, add the deionized water of 6-10 times of weight, soaked 1-3 hour, ultrasonic extraction 10-15 minute, filter, centrifugal, discard precipitation with supernatant concentration, make root of large-flowered skullcap extracting solution, control root of large-flowered skullcap extracting solution density is 1.02-1.08g/cm
3
Root of large-flowered skullcap skin care tableware liquid washing agent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, when guaranteeing good decontamination washing effect, greatly reduce pungency to watch face, composite root of large-flowered skullcap extracting solution uses the present invention can effectively nourish hand skin in the cleaning tableware simultaneously.
Embodiment:
Following embodiment further specifies of the present invention, rather than limits the scope of the invention.In the present invention, if no special instructions, each raw material is 100% in working substance content all.
Embodiment 1
After root of large-flowered skullcap pulverizing, add the deionized water of 8 times of weight, to soak 2 hours, ultrasonic extraction 15 minutes is filtered, and is centrifugal, discards precipitation with supernatant concentration, and making density is 1.05g/cm
3Root of large-flowered skullcap extracting solution.
With 5 kilograms of dodecanamide propyl amine oxides, 5 kilograms of myristic amide propyl group amine oxides, N, 0.1 kilogram of N-dimethyl decyl-3 kilograms of N-amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned root of large-flowered skullcap extracting solution that makes add in 80 kilograms the deionized water, be heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative Examples 1
0.1 kilogram of 13 kilograms of dodecanamide propyl amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned root of large-flowered skullcap extracting solution that makes added in 80 kilograms the deionized water, be heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative Examples 2
0.1 kilogram of 13 kilograms of myristic amide propyl group amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned root of large-flowered skullcap extracting solution that makes added in 80 kilograms the deionized water, be heated to 50 ℃, mix, be cooled to room temperature, can make this tableware liquid washing agent.
Comparative Examples 3
With N, 0.1 kilogram of N-dimethyl decyl-13 kilograms of N-amine oxides, 6 kilograms of Plantacare 818s and the above-mentioned root of large-flowered skullcap extracting solution that makes add in 80 kilograms the deionized water, are heated to 50 ℃, mix, and are cooled to room temperature, can make this tableware liquid washing agent.
Test case 1:
Detergency test:
1) preparation of artificial dirt
The mixing oil prescription: with butter, lard, vegetables oil mass ratio is the 0.5:0.5:1 preparation, and adds the glyceryl monostearate of its total mass 5%, and this is artificial dirt.
Artificial dirt put be heated to 180 ℃ on the electric furnace, stir and keep this temperature 10min, beaker is moved to magnetic stirrer stir, naturally cool to temperature required standby.The temperature of defiling is recommended reference: when room temperature is 20 ℃, need 80 ℃ of oil temperature; When room temperature is 25 ℃, need 45 ℃ of oil temperature; When room temperature is lower than 17 ℃ or when being higher than 27 ℃, test should not be carried out, and need carry out at air conditioning room.Should use the vertical spotter of attached freezing plant in case of necessity.
2) preparation of dirty sheet
With the slide glass upper edge 10mm line that draws, be limited in this below line to show to defile; With the slide glass lower edge 5mm line that draws, be limited in this below line to show the unnecessary greasy dirt of wiping.
3) newly purchase slide glass and need in detergent solution, boil 15min after, the clear water washing to do not hang the globule put again soak 1h in the acid wash liquid after, clear water rinsing and distilled water flushing are put after the loft drier drying standby.
4) preparation of standard dish washing detergent
Take by weighing 14 parts of sodium alkyl benzene sulfonates, 1 part of ethoxylated alkyl sulfate, 5 parts of dehydrated alcohols, 5 parts in urea adds water to 100 parts, and mixing is regulated pH to 7-8 with hydrochloric acid or sodium hydroxide, and is standby.
5) defile
The slide glass of cleaning is one group with four puts on the weighing frame, with analytical balance accurately weigh (accurately to 1mg) be m0, the slide glass after weighing is sandwiched on the film airing stand one by one, clip should be clipped on the slide glass along the line more than, film airing stand put to ward off prepares in the dish to defile.
When treating that greasy dirt remains on definite temperature, one by one slide glass is taken off from film airing stand together with clip, hand-held clip immerses in the greasy dirt slide glass to 10mm goes up following (1-2) s along the line, slowly taking-up, after treating that the following speed of greasy dirt is slack-off, hang back and prepare dirty sheet on the original film airing stand successively.After greasy dirt solidifies, dirty sheet taken off with filter paper or absorbent cotton the unnecessary greasy dirt in base and both sides in the dirty sheet lower edge 5mm is wiped, speckle with the absorbent cotton wiped clean of sherwood oil again with the tweezers folder.After hanging 4h under the room temperature, on the weighing frame, be m1 with the accurate weighing of analytical balance.Dirty amount should guarantee (0.5 ± 0.05) g on every group of dirt this moment sheet.
6) testing sequence
The slide glass of the known amount of defiling is inserted preparation washing in the corresponding wash stand.
Spotter is connected power supply, and wash temperature is set to 30 ℃, and velocity of rotation is set to 160r/min, and washing time is set to 3min.
Take by weighing the 5.00g sample to be tested in 2500mL hard water; after shaking up; measure the 800mL test solution respectively in three washing becks of vertical spotter; when treating that the test solution temperature rises to 30 ℃; rapidly the dirty sheet of known weight is put into washing beck accordingly together with wash stand; after last wash stand is put into washing beck, begin to count soak time, rapidly agitator is installed simultaneously, when soaking 1min; start spotter; begin washing, during 3min, the machine auto stop; rapidly agitator is taken off; take out wash stand, press from both sides one by one and hang on the original film airing stand washing the dirty sheet in back, hanging and dirty sheet being put the weighing of corresponding weighing frame behind the 3h that dries in the air is m2.
(5) result represent to deoil rate ω=(m1-m2)/(m1-m0)
In the formula: m0---slide glass quality before defiling, g; M1---the back slide glass quality of defiling, g; M2---the quality of the dirty sheet in washing back, g.
The rate of deoiling test chart
| ? | The rate of deoiling ω, % |
| Embodiment 1 | 44.8 |
| The standard dish washing detergent | 38.2 |
| Comparative Examples 1 | 38.6 |
| Comparative Examples 2 | 37.5 |
| Comparative Examples 3 | 38.0 |
Root of large-flowered skullcap skin care tableware liquid washing agent of the present invention, adopt nonionogenic tenside and amphoterics composite, abandoned traditional anion surfactant, and amphoterics osmanthus LAO, myristic amide propyl group amine oxide and N as can be seen from the above table, N-dimethyl decyl-N-amine oxide and nonionogenic tenside Plantacare 818 composite (embodiment 1) synergy, composite (Comparative Examples 1-3) compares with single amphoterics and nonionogenic tenside Plantacare 818, and detersive power obviously improves.
Test case 2:
The pungency test
The simulation irritant experiment carries out in the laboratory, and experimenter (each 5 people of men and women) washs in the water-detergent solution of 1wt%, 25 ± 2 ℃ of water temperatures, and institute's water is conventional tap water, washs every day 2 times, each 3 hours, continuous 1 week.Average after marking according to the standard of following table for the pungency of wrist-watch skin, it is high more to mark again, and pungency is more little.
Pungency test data table
| ? | Scoring |
| Embodiment 1 | 100 |
| The standard dish washing detergent | 50 |
| Comparative Examples 1 | 95 |
| Comparative Examples 2 | 90 |
| Comparative Examples 3 | 95 |
Embodiment 2
Further, owing to added Chinese medicine extract in the prescription, inevitable, its quality guaranteed period will descend.For prolonging the quality guaranteed period of the present invention, the contriver has made following research pioneeringly.
In the prepared tableware liquid washing agent of embodiment 1, add 0.05 kilogram of composite environmental-friendly sanitas.Described composite environmental-friendly sanitas, form by weight by following component: 1,3-dihydroxymethyl-5,20 parts of 40 parts of 5-T10s (CAS:6640-58-0), 40 parts of iodine propiolic alcohol butyl mephenesin Carbamates (CAS:55406-53-6) and Salvins (CAS:3650-09-7).
Promptly, this root of large-flowered skullcap skin care tableware liquid washing agent is made up of the raw material of following weight part: 5 kilograms of dodecanamide propyl amine oxides, 5 kilograms of myristic amide propyl group amine oxides, N, 3 kilograms of N-dimethyl decyls-N-amine oxide, 6 kilograms of Plantacare 818s, 0.1 kilogram of root of large-flowered skullcap extracting solution, 80 kilograms in water, 0.05 kilogram of composite environmental-friendly sanitas.
By on the basis of embodiment 1, adding the sanitas of specific proportioning, prolonged the quality guaranteed period of this root of large-flowered skullcap skin care tableware liquid washing agent greatly.By 10 days 1 quality guaranteed perioves of embodiment, extend to 18 months.In addition, correlated, with the general single sanitas 1 of the industry of the composite environmental-friendly sanitas among the embodiment 2,3-dihydroxymethyl-5, the 5-T10 is replaced, and add-on is constant, and its quality guaranteed period is December.
Claims (2)
1. a root of large-flowered skullcap skin care tableware liquid washing agent is characterized in that, is made up of following raw material: dodecanamide propyl amine oxide, myristic amide propyl group amine oxide, N, N-dimethyl decyl-N-amine oxide, Plantacare 818, root of large-flowered skullcap extracting solution and water.
2. root of large-flowered skullcap skin care tableware liquid washing agent as claimed in claim 1, raw material by following weight part is formed: dodecanamide propyl amine oxide 4-6 part, myristic amide propyl group amine oxide 4-6 part, N, N-dimethyl decyl-N-amine oxide 2-4 part, Plantacare 818 5-7 part, root of large-flowered skullcap extracting solution 0.05-0.15 part, 80 parts in water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310052890.6A CN103215145B (en) | 2013-02-18 | 2013-02-18 | Baikal skullcap root skin-care tableware liquid detergent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310052890.6A CN103215145B (en) | 2013-02-18 | 2013-02-18 | Baikal skullcap root skin-care tableware liquid detergent |
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| CN103215145A true CN103215145A (en) | 2013-07-24 |
| CN103215145B CN103215145B (en) | 2014-04-30 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275820A (en) * | 2013-05-28 | 2013-09-04 | 上海艳紫化工科技有限公司 | Mango seed oil skin-protecting detergent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999019441A1 (en) * | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
| WO2008157754A2 (en) * | 2007-06-20 | 2008-12-24 | The Clorox Company | Natural cleaning composition |
-
2013
- 2013-02-18 CN CN201310052890.6A patent/CN103215145B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999019441A1 (en) * | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
| WO2008157754A2 (en) * | 2007-06-20 | 2008-12-24 | The Clorox Company | Natural cleaning composition |
Non-Patent Citations (2)
| Title |
|---|
| 刘庆刚等: "脂肪酰胺丙基二甲基氧化胺的合成及在酸性体系中的增稠研究", 《日用化学品科学》 * |
| 夏邦旗: "黄芩精的提取及其系列化妆品的配制", 《中外技术情报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275820A (en) * | 2013-05-28 | 2013-09-04 | 上海艳紫化工科技有限公司 | Mango seed oil skin-protecting detergent |
| CN103275820B (en) * | 2013-05-28 | 2015-01-21 | 安徽省林锦记食品工业有限公司 | Mango seed oil skin-protecting detergent |
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| CN103215145B (en) | 2014-04-30 |
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Effective date of registration: 20190924 Address after: 233010 Incubation Workshop, 414 Changle Road, Yuhui District, Bengbu City, Anhui Province Patentee after: Bengbu Xingshi Intellectual Property Operations Co.,Ltd. Address before: 201111 Shanghai city Minhang District Yuanjiang Road No. 5500 building first room E2128 Patentee before: SHANGHAI YANZI CHEMICAL TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20221202 Address after: 276000 science and technology Avenue, high tech Industrial Development Zone, Linyi City, Shandong Province Patentee after: SHANDONG LUJIAN BIO PHARMACEUTICAL TECHNOLOGY Co.,Ltd. Address before: 233010 1st floor, incubation workshop, Industrial Automation Research Institute, 414 Changle Road, Yuhui District, Bengbu City, Anhui Province Patentee before: Bengbu Xingshi Intellectual Property Operations Co.,Ltd. |
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