Background technology
The annual dish washing detergent consumption of China between ten thousand tons of 30-40, about about 4,400,000,000 yuan of sales volume, and rising year by year.The major impetus of dish washing detergent industry development comes from the demand of human consumer and society and to the higher expectation of environmental protection, therefore this series products has following development trend: first, functions such as degerming sterilization, removal pesticide residue will replace traditional degreasing function becomes first of demand, consumer demand difference is increasing at present, and this also provides inherent foundation for the market segments; Second, to pay attention to economizing on resources, saving the energy more in the manufacturing of washing composition and the use, special concern is saved bath water and is reduced the washing energy consumption, applied and water-saving washing composition under the exploitation room temperature, exploitation heavy duty detergent and multifunctional type washing composition, cooperate the exploitation of novel washing powder, dishwasher, make washing process save time more, laborsaving and intelligent; The 3rd, the Betengent product function is with overstepping the bounds of propriety more thin; The 4th, meal in the function segmentation, trend green, environmental protection occurred pursue in the products material employing with Betengent product.From these trend as can be seen, the propensity to consume of following detergent market is towards personalization, diversification and green functional development.Yet, China's detergent market by white cat, strong, carving board, upright white, open large-lot producer of a few family such as rice and highly monopolize, Betengent product is similar, lack innovation, advanced and applicable technical superiority, difference is little each other, serious advolutionization (homogeneity) impetus occurs, between enterprise of detergent industry and products thereof, the brand, can almost do not had by client's sensation and cognitive, as to have strategy and marketing meaning difference (heterogeneous, differential).
Lag behind in this product innovation under the market environment of consumer demand, research and development can be satisfied the green wash agent product that modern people pursue health, green living aim, will be the directions that detergent industry further develops.Natural constituents, medicinal herb components have won people's favor owing to satisfied human consumer's green productive process and the consumer psychology of nutrition, safety, and exploitation mild, environment-friendly type washing composition are the fresh targets that articles for washing manufacturing enterprise competes.
Summary of the invention
The purpose of this invention is to provide a kind of tableware of mildness safely and efficiently antibacterial detergent and preparation method thereof.
Tableware antibacterial detergent of the present invention is that the component of adding following weight part in per 100 weight parts waters is made:
Chinese medicine concentrated solution 0.5 ~ 2 polyoxyethylenated alcohol sodium sulfate 8 ~ 12
Sodium lauryl sulphate 4 ~ 6 lauric acid diethyl amides 2 ~ 4
Witco 1298 Soft Acid 4 ~ 7 sodium hydroxide 0.5 ~ 1.5
Sodium-chlor 0.2 ~ 0.6 card pine 0.06 ~ 0.1
Essence 0.1 ~ 0.2.
Wherein, described Chinese medicine concentrated solution is to be raw material by following parts by weight of traditional Chinese medicines:
Root of Indigowoad 85 ~ 95 peppermints 15 ~ 25
Flos Caryophylli 10 ~ 20
It is the Chinese medicine extract that extracting solution extracts the d=1.5 ~ 1.8g/ml that obtains with water.
Tableware of the present invention may further comprise the steps with the concrete preparation method of antibacterial detergent:
1) take by weighing Chinese medicine material according to above-mentioned parts by weight, mix back boiling twice, the 5-10 that each amount of water is Chinese medicine weight doubly decocted 1 hour, merged decoction liquor, was concentrated into d=1.5 ~ 1.8g/ml, filtered, and obtained Chinese medicine extract;
2) sodium lauryl sulphate, polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate, sodium hydroxide, the lauric acid diethyl amide of above-mentioned parts by weight is soluble in water successively, be stirred to dissolving evenly;
3) stir down, add the Chinese medicine extract that step 1) obtains, and block pine, essence, sodium-chlor, to dissolving fully, make the tableware antibacterial detergent.
Tableware of the present invention is with in the employed Chinese medicine of antibacterial detergent, it is couroupitine A and indole derivatives that the Root of Indigowoad infusion all has the antibacterial effective constituent of restraining effect, Root of Indigowoad to gold-coloured staphylococci, staphylococcus epidermidis, Bacillus subtilus, sarcine, intestinal bacteria, Corynebacterium diphtheriae, alpha streptococcus, pneumococcus, hemophilus influenza, meningococcus, and wherein couroupitine A has stronger bacteriostatic action to 7 kinds of fungies such as microsporum lanosum, trichophyton tonsurans, microsporon gypseum, purple tinea bacterium, trichophyton gypseum, red mentagrophytes, purple dress epidermis tinea grape.The peppermint water decoction all has stronger anti-microbial effect to staphylococcus epidermidis, streptococcus aureus, Bacillus proteus, the special bacterium of segmental bronchus bag, micrococcus flavus, Pseudomonas aeruginosa, wax sample bud bacillus, the folded coccus of gamboge bar, intestinal bacteria, Bacillus subtilus, streptococcus pneumoniae etc., and peppermint main body of oil mentha camphor still is a kind of aromatic refrigerant agent simultaneously.Effective constituent total flavones and the chlorogenic acid of taraxacum all have tangible bacteriostatic action to streptococcus aureus, Bacillus proteus, alpha streptococcus, beta streptococcus, and the modern study proof drips public English water decoction and preserved material all has stronger killing action to multiple Gram-positive or negative bacteria.The Flos Caryophylli water decoction contains Syzygium aromaticum stem oil and Syzygium aromaticum stem oil phenols chemical ingredients, and staphylococcus, suis, intestinal bacteria, Corynebacterium diphtheriae, Pseudomonas aeruginosa etc. are had restraining effect.
Detect the bacteriostasis property that tableware of the present invention is used antibacterial detergent according to " disinfection technology standard " (version in 2002), concrete outcome is as follows:
A. 50% pair of concentration 1.98 * 10 of washing composition of the present invention
4The coli test of cfu/mL is with bacteria suspension effect 2min, and each time bacteriostasis rate is equal〉80%, product has stronger bacteriostatic action for intestinal bacteria.
B. 50% pair of concentration 2.80 * 10 of washing composition of the present invention
4The streptococcus aureus of cfu/mL is tested with bacteria suspension effect 2min, and each time bacteriostasis rate is 100%, and product has stronger bacteriostatic action for streptococcus aureus.
C. 50% pair of concentration 1.78 * 10 of washing composition of the present invention
4The Candida albicans of cfu/mL is tested with bacteria suspension effect 2min, and each time bacteriostasis rate is 100%, and product has stronger bacteriostatic action for Candida albicans.
D. washing composition of the present invention through 37 ℃ the insulation 90 days after, its 50% concentration acts on 2min to intestinal bacteria, each time bacteriostasis rate is equal〉80%, to the test of streptococcus aureus and Candida albicans with bacteria suspension effect 2min, each time bacteriostasis rate is all greater than 90%, do not have significant difference with the fungistatic effect before depositing, show the fungistatic effect of intestinal bacteria, streptococcus aureus, Candida albicans stable.
Tableware of the present invention can not only resist various bacteriums with antibacterial detergent, various pathogenic funguses there is restraining effect, and it is few to have a consumption, degreasing power is strong, sterilization effect is good, the temperature of not restricting water supply, the characteristics of safety non-toxic, by chemical actions such as infiltration, saponification, emulsification, suspensions, can remove the residual stain of various foods and grease fast.Washing composition pH of the present invention is neutral, and foam is abundant, and it is easy to cross the water capacity, is applicable to all water quality, cleans the back tableware and does not stay spot.
The present invention adds the Chinese herbal medicine formula with efficient sterilizing effect in washing composition, greatly reduce the addition of sanitas in the product, drug residue is low safer, do not add more environmental protection of phosphorus containing components, detergent formulation is novel unique simple, can satisfy modern market and require natural, environmental protection, high-effective cleansing, antibiotic demand.
Embodiment
Embodiment 1
Take by weighing Root of Indigowoad 90kg, peppermint 20kg, Flos Caryophylli 15kg mixes, and adds water 1250kg, decocts 1 hour after-filtration, adds water 1000kg again, decocts 1 hour after-filtration.Merge decoction liquor twice, be concentrated into 1.8g/ml and obtain the Chinese medicine concentrated solution.
Get the 200kg purified water, under agitation slowly add sodium lauryl sulphate 10kg, polyoxyethylenated alcohol sodium sulfate 14kg, Witco 1298 Soft Acid 12kg, sodium hydroxide 1.78 kg, lauric acid diethyl amide 5kg successively, to dissolving fully evenly, add above-mentioned Chinese medicine concentrated solution, 0.16kg card pine, 0.4kg essence, 0.9kg sodium-chlor at last and stir.Make the tableware antibacterial detergent through can after the assay was approved.
Embodiment 2
Take by weighing Root of Indigowoad 93kg, peppermint 18kg, Flos Caryophylli 14kg mixes, and adds water 1250kg, decocts 1 hour after-filtration, adds water 1000kg again, decocts 1 hour after-filtration.Merge decoction liquor twice, be concentrated into 1.8g/ml and obtain the Chinese medicine concentrated solution.
Get the 200kg purified water, under agitation slowly add sodium lauryl sulphate 8kg, polyoxyethylenated alcohol sodium sulfate 16kg, Witco 1298 Soft Acid 10kg, sodium hydroxide 1.5kg, lauric acid diethyl amide 4kg successively, to dissolving fully evenly, add above-mentioned Chinese medicine concentrated solution, 0.16kg card pine, 0.4kg essence, 2.0kg sodium-chlor at last and stir.Make the tableware antibacterial detergent through can after the assay was approved.
Embodiment 3
Take by weighing Root of Indigowoad 88kg, peppermint 22kg, Flos Caryophylli 15kg mixes, and adds water 1250kg, decocts 1 hour after-filtration, adds water 1000kg again, decocts 1 hour after-filtration.Merge decoction liquor twice, be concentrated into 1.8g/ml and obtain the Chinese medicine concentrated solution.
Get the 200kg purified water, under agitation slowly add sodium lauryl sulphate 6kg, polyoxyethylenated alcohol sodium sulfate 18kg, Witco 1298 Soft Acid 8kg, sodium hydroxide 1.3kg, lauric acid diethyl amide 6kg successively, to dissolving fully evenly, add above-mentioned Chinese medicine concentrated solution, 0.16kg card pine, 0.4kg essence, 1.5kg sodium-chlor at last and stir.Make the tableware antibacterial detergent through can after the assay was approved.