CN1031875C - Process for preparation of liquid trace fertilizer - Google Patents
Process for preparation of liquid trace fertilizer Download PDFInfo
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- CN1031875C CN1031875C CN 91108063 CN91108063A CN1031875C CN 1031875 C CN1031875 C CN 1031875C CN 91108063 CN91108063 CN 91108063 CN 91108063 A CN91108063 A CN 91108063A CN 1031875 C CN1031875 C CN 1031875C
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Abstract
The present invention relates to a liquid trace element fertilizer and a preparation method thereof. The liquid trace element fertilizer is mainly composed of complexing agents (humic acid, or humic acid, citric acid and tartaric acid, or humic acid, citric acid, tartaric acid and disodium edta), trace elements (copper, zinc, manganese, ferrum, boron, molybdenum and compounds of cobalt), a stabilizing agent (urea), matrix objects, extension agents, plant growth regulators, nutrient elements of N, P, K, etc. and iodide. The liquid trace element fertilizer has the advantages of good water solubility, low preparation reaction temperature, saved irrigation water capacity, high fertilizer effect and obvious effect of increase in yield (16 to 66% of increase in yield), and has the action of drought resistance, cold resistance, alkali resistance and pest and disease damage prevention.
Description
The present invention relates to a kind of liquid fertilizer and preparation method thereof, belong to the agrochemical field.
Known liquid fertilizer has CN1042895A (89 years), it is a kind of micro-compound liquid fertilizer that is exclusively used in the mulberry leaf foliage spray, its nutrition is phosphoric acid salt, oxalate, nitrate, aluminate, muriate multielement complex compound, and the tensio-active agent of employing 0.05～5% is made extension agent.But it is water-soluble relatively poor, and owing to do not add the matrix thing, fertilizer is not strong to the sticking power of crop.CN87100319A provides a kind of plant-foliage fertilizer and preparation method thereof, it is a kind of a large amount of and micro-suspension fertilizer that contains, its liquid phase is for containing the whey of 2～4% proteolysates (amino acid), its preparation method is included under 60～80 ℃ inorganic salt is dissolved in the dispersion medium that contains fermented whey and protein hydrolystate strong solution, gained solution is sent into to make temperature drop to 20～25 ℃ refrigerating unit in 2～15 minutes at last.Adopt starch to make the matrix thing.This fertilizer has certain effect of increasing production, but temperature of reaction is higher.Nonreactive contrary (drought resisting, alkali resistant, cold-resistant) effect and prevention and elimination of disease and pests effect.
The purpose of this invention is to provide a kind of fertilizer efficiency height, good water solubility, the preparation feedback temperature is low, has degeneration-resistant effect and prevents the preparation method of the little fertilizer of full-service fluid of disease and pest effect.
For achieving the above object, the preparation method of liquid fertilizer of the present invention adopts 60-80 weight part humic acidss (salt), or adopt 60-80 weight part humates, 1,5-4,0 weight part citric acid and 1,0-2,5 weight part tartrate, or adopt 60-80 weight part humic acidss, 1,5-4,0 weight part citric acid, 1,0-2,5 weight part tartrate and 5,0-10,0 weight part disodium ethylene diamine tetraacetate to make complexing agent; Compound with copper, zinc, manganese, iron, cobalt, molybdenum and boron is made trace element, and its compound weight part respectively is 3-6 parts, 3-5 parts, 0,5-2 parts, 7-10 parts, 0,5 part, 0,5-3 parts, 8-11 parts; With 30-60 weight part urea used as stabilizers, make the matrix thing with fine polymkeric substance of starch-polypropylene or carboxymethyl starch, its weight part is 0,5-30 parts, make extension agent with dodecylbenzene sulfonate or aliphatic alcohol sulfate, its weight part is 0,05-1 part. and add an amount of N, P, K nutritive element, iodide and plant-growth regulator.
Because humic acids (salt) or humic acids (salt), citric acid, tartrate or humic acids (salt) citric acid, tartrate, these organic complexing agents of disodium ethylene diamine tetraacetate and zinc, copper, manganese, iron, cobalt, molybdenum, the compound formation multicomponent complex of boron or polynary mixed ligand binding substances, this title complex is water-soluble better, and itself and copper humate, the mixture of Zn complex and iodide is the stable disease-resistant sterilant (table 3) of a kind of chemical property, in addition, the quinonyl of humic acids (salt) title complex-polyphenol base participates in the redox processes of crop, it is the activator of oxygen, it is again the rotaring carrier of hydrogen, can promote photosynthesis, improve the synthetic of invertase activity in sugar and organic phosphorus compound, increase the crop sugar degree, improving Premeabilisation of cells presses, thereby the enhancing crop is degeneration-resistant (cold-resistant, drought resisting, alkali resistant) effect, reduce moisture transpiration, save irrigation water (table 2, table 4).Contained fine polymkeric substance of starch one polypropylene or carboxymethyl starch are good matrix things, liquid fertilizer can be attached to plant surface during use, avoid the loss of liquid fertilizer, improve fertilizer efficiency and sterilizing ability.Adopt the urea used as stabilizers, both can increase the nutrition of little fertilizer, reduce and add the non-physiologic stable material, can prevent the crystallization of liquid fertilizer again, reduce production process, reduce reactivity.Dodecylbenzene sulfonate or aliphatic alcohol sulfate are a kind of good extension agents, both can increase the spreading ability of little fertilizer in crop surface, also strengthen simultaneously immersional wetting, strengthen the absorption (table 1) of crop cell trace element and other nutritive element to crop cell.In addition, humic acids (salt), citric acid, tartrate or humic acids (salt), the complex compound of citric acid, tartrate and disodium ethylene diamine tetraacetate and trace element is a good buffer system.
By as seen above-mentioned, because liquid fertilizer of the present invention is organic acid and the micro-complex compound that forms, this complex compound not only has good water solubility, and be a cover buffer system, cooperate the mixed solution of forming with various nutrient elements such as N, P, K, S, Si, Ca, Mg and plant-growth regulator etc. again, demonstrate the synergy of mutual gain, can satisfy, regulate and stimulate crop growth, increase fertilizer efficiency.In addition, liquid fertilizer of the present invention has conversion and dissolves mercury, and the effect (table 5) of arsenic heavy metal element reduces the richness of objectionable impurities in the product amasss, and to preventing product contamination, protects environment and HUMAN HEALTH, significant.
The preparation method of liquid fertilizer of the present invention is as follows:
The first step: in container, drop into the humic acids (salt) and an amount of water of some amount, soaked into 1～3 hour, abundant stirring and dissolving, clarification filtration makes humic acids (salt) solution that density (20 ℃) is 1.0～1.2g/ml.
Second step: be that 1.0～1.2 humic acids (salt) solution injects reactor at normal temperatures and pressures with proportion, starting agitator stirs, add urea or progressively add urea, citric acid, tartrate, disodium ethylene diamine tetraacetate (giving the earlier molten solution of concentration 15% that is) makes its whole dissolvings, makes the solution that contains complexing agent and stablizer.
The 3rd step: the compound, reacting generating complex and the mixing solutions thereof that in still, add copper, zinc, boron, manganese, iron, molybdenum, cobalt successively.
The 4th step: in reactor, add plant-growth regulator, phosphorus, sylvite class again, adjust about PH to 6～8 with bicarbonate of ammonia, question response is finished, add iodide, matrix thing and extension agent, stir, dissolving is made density for (20 ℃) g/ml1.0～1.3, and PH is the liquid fertilizer that 6～8 chocolate suspends.
The consumption of above-mentioned various materials is as follows: (weight ratio)
1.5～4.0 parts of 60～80 parts of citric acids of humic acids (salt)
5～10 parts of 1～2.3 part of sodium ethylene diamine tetracetates of tartrate
30～60 parts in 30～60 parts of bicarbonate of ammonia of urea
3～5 parts in 15～25 parts of zinc sulfate of potassium primary phosphate
0.5～2 part of 3～6 parts of manganous sulfate of sulfuric acid steel
0.5 part of 7～10 parts of rose vitriol of ferrous sulfate
0.5～3 part of 8～11 parts of ammonium molybdate of boric acid
0.5～30 part in the fine polymkeric substance of 0.1～0.5 part of starch-polypropylene of iodide
Or carboxymethyl starch
6～8 parts of plant-growth regulator
0.051 part of Witco 1298 Soft Acid hydrochlorate or Fatty Alcohol(C12-C14 and C12-C18) hydrochlorate
350～550 parts in water
Embodiment one:
45 parts of 45 parts of carbon ammoniums of 65 parts of urea of humic acid (salt)
4.2 parts in 35 parts of copper sulfate of 17 parts of zinc sulfate of potassium primary phosphate
8.5 parts in 1.0 parts of ferrous sulfate of 9 parts of manganous sulfates of boric acid
0.3 part of 1 part of carboxymethyl starch of 0.5 part of ammonium molybdate of cobalt chloride
6.5 parts of 0.2 part of plant-growth regulator of dodecylbenzene sulfonate
400 parts in 0.1 part of water of sulfonated bodies
Continuous 2 years of 600～750 times of the liquid fertilizer dilute with waters of component are as follows to wheat field experiment result in the utilization: (each controlled trial, selected kind soil, fertility, level of management unanimity)
Table 1 wheat yield
| 1987 | 1988 | ||
| Different treatment per mu yield (kilogram/mu) | Volume increase (%) | Per mu yield (kilogram/mu) | Volume increase (%) |
| Clear water contrasts 249.5 the present invention (soak 441.5 kinds, three leaves, turn green, be in the milk with 20+30+ 40+60 millimeter) | 0.00 66.90 | 372 458.5 | 0.00 22.4 |
Embodiment two (weight ratio)
2.5 parts of 65 parts of citric acids of humate
5 parts of 1.5 parts of disodium ethylene diamine tetraacetate of tartrate
45 parts in 45 parts of bicarbonate of ammonia of urea
3.5 parts in 17 parts of zinc sulfate of potassium primary phosphate
9 parts of 4.2 parts of boraxs of copper sulfate
8.5 parts in 1.0 parts of ferrous sulfate of manganous sulfate
1 part of 0.5 part of ammonium molybdate of cobalt chloride
0.5 part in the fine polymkeric substance of 0.2 part of starch-propylene of sodium iodide
6.5 parts of 0.2 part of plant-growth regulator of Sodium dodecylbenzene sulfonate
The component dilute with water is 600-750 parts in the utilization, and wheat is carried out field experiment, and test area is 66.7 square metres, and three iteron test-results are as follows:
Table 2 wheat yield
| Different treatment is amounted to per mu yield (kilogram/mu) | Increase (subtracting) and produce (%) | Irrigation frequency |
| Clear water contrasts 249.5 the present invention, and (three leaves are turned green, 305.1 be in the milk with 30+30+60 milliliter) wither-resistant agent (three leaves, 267.9 turn green, grouting 40+60+80 milliliter) | 0.00 +22.28 +7.33 | 3 0 2 |
Embodiment three
2 parts of 65 parts of citric acids of humic acids (salt)
30 parts in 2.5 parts of urea of tartrate
2 parts of 30 parts of ammonium molybdates of bicarbonate of ammonia
5 parts in 15 parts of zinc oxide of potassium primary phosphate
2 parts of 5 parts of manganous sulfates of neutralized verdigris
7 parts of 0.3 part of iron trichlorides of potassiumiodide
0.1 part of 10 parts of carboxymethyl starch of borax
7 parts of 0.5 part of plant-growth regulator of Sodium dodecylbenzene sulfonate
0.5 part of 350 parts of rose vitriol of water
Component is as follows to watermelon damping-off control effect in the utilization, (investigation is mid-term as a result period, 100 strain investigation results):
Table 3 pair watermelon damping-off control effect
| Different treatment | Control rate (%) |
| Derosal (connect the phase of bearing fruit～mid-term and spray 3 times) the present invention's (the same) anti-wither chemical (the same) | 39.89 79.64 41.72 |
Embodiment four
2 parts of 70 parts of citric acids of humic acids
16 parts of 2 parts of potassium primary phosphates of tartrate
2 parts of 5 parts of manganous sulfates of zinc sulfate
0.5 part of 3 parts of Sodium orthomolybdate of copper sulfate
6 parts of 0.5 part of plant-growth regulator of rose vitriol
30 parts in the fine polymkeric substance of 0.5 part of starch-polypropylene of sodium alkyl sulfate
450 parts in water
To the test of corn surviving rate, the loudspeaker phase is investigated 500 strain results to component under drought condition in the utilization.
Table 4 corn surviving rate
| Different treatment | Surviving rate (%) |
| Contrast anti-wither chemical (0.15%) seed soaking airing sowing the present invention (0.15%) in 8 hours seed soaking airing sowing (band dressing) in 8 hours | 21.5 35.1 81.7 |
The wheat, the corn that utilize liquid fertilizer of the present invention to handle, as follows to its product quality test result:
Table 5 wheat, corn product attribute test result
| Wheat | Corn | |||
| The clear water contrast | The present invention | The clear water contrast | The present invention | |
| Moisture content (%) crude protein (%) starch (%) crude fat (%) ash (%) butt calcium (mg/100g) phosphorus (mg/100g) iron (mg/100g) zinc (mg/100g) arsenic (mg/kg) mercury (mg/kg) | 9.06 12.98 64.2 1.70 1.63 39.93 200.00 7.02 3.50 0.19 0.003 | 9.04 13.98 70.9 1.80 1.67 46.34 200.00 8.04 3.78 0.18 0.002 | 8.79 9.51 71.00 4.30 1.18 6.26 180.00 6.31 2.41 0.21 0.0024 | 8.93 9.92 77.20 3.70 1.38 8.66 260.00 6.44 2.60 0.19 0.0021 |
Claims (4)
1, a kind of preparation method of liquid fertilizer, it is characterized in that: under normal temperature and pressure, humic acids or its salt at 60-80 weight parts, or 60-80 weight part humic acids or its salt, 1.5-4.0 weight part citric acids and 1-2.5 weight part tartrate, or 60-80 weight part humic acids or its salt, 1.5-4.0 weight part citric acids, in the complexing agent aqueous solution of 1-2.5 weight part tartrate and 5-10 weight part disodium ethylene diamine tetraacetate and contain in the urea of stablizer 30-60 weight parts, add 3-6 weight part copper compounds successively, 3-5 weight part zn cpdss, 0.5-2 weight part manganic compounds, 7-10 weight part iron compounds, 0.5-3 weight part molybdenum compounds, 0.5 weight part cobalt compound and 8-11 weight part boron compounds, and add 15-25 weight part potassium primary phosphates, after adjusting solution pH value to 6-8, add 0.1-0.5 weight part iodide again, 0.5-30 weight part matrix things and 0.05-1 weight part extension agent.
2, the preparation method of liquid fertilizer according to claim 1 is characterized in that: described matrix thing is fine polymkeric substance of starch-polypropylene or carboxymethyl starch.
3, the preparation method of liquid fertilizer according to claim 1 is characterized in that: described extension agent is dodecylbenzene sulfonate or Fatty Alcohol(C12-C14 and C12-C18) hydrochlorate.
4, the preparation method of liquid fertilizer according to claim 1 is characterized in that: described adjustment solution PH is to adopt bicarbonate of ammonia to adjust.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91108063 CN1031875C (en) | 1991-10-24 | 1991-10-24 | Process for preparation of liquid trace fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91108063 CN1031875C (en) | 1991-10-24 | 1991-10-24 | Process for preparation of liquid trace fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1064670A CN1064670A (en) | 1992-09-23 |
| CN1031875C true CN1031875C (en) | 1996-05-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91108063 Expired - Fee Related CN1031875C (en) | 1991-10-24 | 1991-10-24 | Process for preparation of liquid trace fertilizer |
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-
1991
- 1991-10-24 CN CN 91108063 patent/CN1031875C/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN1064670A (en) | 1992-09-23 |
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