CN103147209A - Stainless steel fiber radiation protection face fabric and fabrication method thereof - Google Patents
Stainless steel fiber radiation protection face fabric and fabrication method thereof Download PDFInfo
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Abstract
The invention provides stainless steel fiber radiation protection face fabric which is flat in surface, soft, smooth, lustrous, bright, and bright-colored. The radiation protection efficiency of the face fabric reaches above 92%. Warp yarns and weft yarns are stainless steel fiber/cotton fiber blended yarns, wherein the content of the stainless steel fiber is 5%, and the content of the cotton fiber is 95%. The fabrication method of the stainless steel fiber radiation protection face fabric comprises the following steps of a, spinning, b, weaving, c, printing and dyeing, and d, after finishing, wherein in Step a, the cotton fiber is subjected to blowing, cotton carding, combing, and multiple blending and combining processes, and then subjected to roving, spinning and spooling processes, and the stainless steel fiber is gradually blended in the multiple blending and combining processes; in Step b, pulp leveling, drafting and weaving are conducted; in Step c, mercerization staining is adopted; and in Step d, softening, shape finalization and preshrinking are conducted.
Description
Technical field
The present invention relates to a kind of radiation-proof fabric, especially a kind of stainless steel fibre radiation-proof fabric and preparation method thereof.
Background technology
Along with improving constantly of living standard, various electronic products enter into huge numbers of families, and the electronic products such as TV, refrigerator, micro-wave oven, electromagnetic oven, mobile phone are more and more universal, and electromagnetic radiation more and more is subject to people's attention the able-bodied impact of people.Electromagnetic radiation is to make organism produce fuel factor to the harm of human body on the one hand, and when surpassing a certain boundary, organism causes temperature to raise and comes to harm because not discharging the waste heat that produces in its body; Be to disturb the intrinsic faint electromagnetic field of human body on the other hand, affect the operation of blood and lymph, cellular plasm is changed, its summation meeting initiation insomnia is weak, immunity descends, lesion tissue, and then brings out leukaemia and cancer.Live in for a long time in addition in high-voltage line, telecommunication emitter, high-power electric appliance facility environment and the personnel that closely frequently use household electrical appliances and mobile phone, can cause anxious state of mind, and the super quick syndrome of electromagnetic radiation (EHS), as headache, tinnitus, unable, tired, insomnia, the loss of memory even, suffer from parkinsonism and senile dementia.Therefore, the clothes that possess electromagnetic radiation protection function become new period people and pursue one of consumer goods of healthy living, and more and more in widespread attention.
The method of common raising fabric shielding electromagnetic wave usefulness mainly contains 3 kinds on the market: 1. adopt metal or conductive fiber and other fiber blends or interweave; 2. adopt the coating agent of conductive material (some metal and its esters and carbon black etc.) to carry out coating to fabric; 3. by fabric being carried out coating processing.Civilian anti-electromagnetic radiation class fabric mainly contains stainless steel metal fibre blended yarn woven fabric and the large class of ionic silver fabric lining two.Wherein the stainless steel metal fibre blended yarn woven fabric mainly contains the fabric of 20%, 25% and 30% content, as contains 25% metal stainless steel fibre/40% cotton/35% polyester fabric.The shielding rate of 25% content can reach 95% left and right, and the shield effectiveness of 30% content can reach 98% left and right.Ionic silver fabric lining shield effectiveness can reach 99.99996%, can reach the requirement of shielding mobile phone signal.These products all have good wearability, can wear next to the skin, can normally wash, usefulness is lasting, is applicable to maternity dress and Work Clothes etc.Although the protection of electromagnetic radiation has been subject to numerous crowds' attention, practical application is not extensive.The one, consumer's cognition and penetration and promotion not enough, another is exactly selling at exorbitant prices, has retrained consumer's consumption wish.Therefore satisfying under the condition of civilian function, significantly the pressure drop cost, be the effective way that enlarges the radiation-proof fabric consumption market.
Summary of the invention
The purpose of this invention is to provide a kind of stainless steel fibre content and account for 5%, radiation proof usefulness reaches that cloth cover more than 92% is smooth, softness is smooth, gloss is beautiful, brightly painted stainless steel fibre radiation-proof fabric.
Stainless steel fibre radiation-proof fabric of the present invention, its warp thread and weft yarn are stainless steel fibre/cotton fiber mixed yarn, and stainless steel fibre content accounts for 5%, and cotton fiber content accounts for 95%.
Above-mentioned stainless steel fibre radiation-proof fabric, adopting highly dense plain weave is in order to guarantee radiation-proof effect, and by contrast test, better than twill, satin weave radiation-proof effect.
Beneficial effect of the present invention: mostly be the radiation-proof fabric of metal fibre content 25% on Vehicles Collected from Market, every increase by 1% stainless steel fibre content, every rice and flour material cost increases approximately 0.85 yuan, if adopt the content of 5% metal fibre, the fabric cost will descend approximately half.The present invention not only can cater to market to the requirement of this series products radiation proof function with lower cost, and product is more soft comfortable, after dyeing, color can be rich and varied, thereby satisfy the consumer to the demand of fabric outward appearance, color fashion attractive in appearance, have higher added value and market development potentiality, remarkable in economical benefits.Product softness of the present invention is comfortable, wash resistant, radiation-proof effect are good, and the radiation proof timeliness is long, is fit to make children, pregnant woman's protective clothing or household electrical appliance, Medical Instruments protective cover etc.Fabric similar with other compared, and at aspects such as function, economic benefits, obvious advantage arranged.
The present invention provides a kind of preparation method of stainless steel fibre radiation-proof fabric simultaneously, and it comprises the steps:
A, spinning; Cotton fiber mixes and operation through blowing, comb and parallel cotton fibers prior to spinning, combing, multiple tracks, and then through rove, spun yarn, winding procedure, mixes also in multiple tracks and in operation, stainless steel fibre is progressively sneaked into;
B, weave; Comprise whole slurry, gait, weave step;
C, printing and dyeing; Adopt Mercerization dyeing;
D, rear arrangement; Comprise softness, typing, preshrunk step.
The stainless steel fibre radiation-proof fabric that makes through said method, cloth cover is smooth, softness is smooth, gloss is beautiful, bright-colored, and radiation proof usefulness reaches more than 92%.
The preparation method of above-mentioned stainless steel fibre radiation-proof fabric closes the door cover of exposed electrical equipment in Workshop Production equipment or seal before spinning.Due to stainless steel fibre conduction, so its flyings easily make exposed electrical equipment be short-circuited and cause fault, exposed electrical equipment should cut out or seal before producing.
The preparation method of above-mentioned stainless steel fibre radiation-proof fabric adopts heavily pressurization, the technique of spacing tightly in mixed and operation in the multiple tracks of spinning, break the metal fibre of a part of overlength.Because stainless steel fibre only accounts for 5%, content is very low, mixes for making, and carries out multiple tracks and mix on drawing frame, guarantees radially to mix evenly.Drafting grips apart from little simultaneously, and adopts heavy pressing technology to break the metal fibre of a part of overlength, is convenient to the smooth spinning of later process.
The preparation method of above-mentioned stainless steel fibre radiation-proof fabric adopts the photo-electric type electricity clear in the winding procedure in spinning.Bobbin winder is because containing conductive fiber in yarn, equipment is taked certain technical measures: change capacitive battery clear (electronic yarn clearer) clear for the photo-electric type electricity, guarantee smooth winder, steady quality.
The preparation method of above-mentioned stainless steel fibre radiation-proof fabric, when weaving, the slashing size formula is:
The PVA:25 kilogram;
The PVA205MB:20 kilogram;
Esterification starch: 70 kilograms;
Polyacrylic acid size: 12.5 kilograms;
Wax disk(-sc): 1 kilogram;
Oil emulsion (piece): 2 kilograms;
Preservative agent: 0.35 kilogram;
Bleeding agent: 0.5 kilogram;
Defoamer: 0.2 kilogram;
The slashing technique parameter:
Slurry groove temperature: 98 ℃;
Viscosity: 10S;
Regain: 9%
The rate of sizing: 16%.
The ratio of PVA and esterification starch is transferred near 1:2, guaranteed that like this serous coat has certain pliability and permeability, improved the brute force of warp thread, guarantee that warp thread has certain percentage elongation, overcome crisp, the hard deficiency of PVA slurry serous coat, and the filoplume orthogenesis when reducing splitting is guaranteed the elastic wear-resisting of warp thread.
The preparation method of above-mentioned stainless steel fibre radiation-proof fabric gaits in weaving and adopts total quantity of warps 11520, and ground is organized as 1/1 plain weave.8 pages of heald frames, porter 85# combines the method 1,3,5,7,2,4,6,8 of wearing, and it is 2 that reed imports number, and menopause tablet is worn method 1,2,3,4,5,6.Adopt 8 pages when gaiting and combine, combine the method 1,3,5,7,2,4,6,8 of wearing.Notice that menopause tablet is unsuitable overweight, in order to avoid tick fiber, the injury warp thread guarantees wovenly to carry out smoothly.
The specific embodiment
One, preparation stainless steel fibre radiation-proof fabric, stainless steel fibre radiation-proof fabric are take stainless steel fibre and cotton fiber as raw material, produce cloth required be cotton fiber 95/ stainless steel fibre 5 32 through weft yarn
S
Fabric tissue: highly dense plain weave.
Two, technological process
1, spinning process
Cotton fiber-blowing-comb and parallel cotton fibers prior to spinning-combing-(stainless steel fibre is progressively sneaked into) multiple tracks is mixed also-rove-spun yarn-winder
2, weaving process
Whole slurry-gait-weave;
3, dyeing and printing process
4, postfinishing process
Softness-typing-preshrunk.
Three, technique emphasis
(1) product tissue, specification
Adopting highly dense plain weave is in order to guarantee radiation-proof effect, and by contrast test, better than twill, satin weave radiation-proof effect; Color requires to select redness, purple, aubergine or the color such as light yellow according to rear road clothes, satisfies consumer's diversified demand.
(2) spinning process
Stainless steel fibre has conductive characteristic, and its willow catkins flying in the air easily make exposed electrical equipment be short-circuited and burn out, thus the door cover of exposed electrical equipment in Workshop Production equipment should be closed or sealed before producing, and production equipment and other neighbouring devices are separated.Because the stainless steel fibre blending rate only has 5%, content is very low, mixes for making, and on drawing frame, stainless steel fibre is progressively sneaked into and carries out multiple tracks and mix, and guarantees radially to mix.The slubbing drafting is in the spinning process, and stainless steel fibre is drawing-off smoothly sometimes, sometimes becomes not drawing-off state, be a slubbing, by adjusting process, the multiple of first break draft be amplified to more than 2.0, increase simultaneously drawing-off pressurization again examination spin, head also can be driven smoothly, rear road each and drive all more smooth.Rove is driven smoothly, and spun yarn causes broken end higher because there is overcut fibre in metal fibre, has tried to transform as slip draft, greatly reduces broken end, has improved quality.Bobbin winder is because containing conductive fiber in yarn, equipment is taked certain technical measures, changes capacitive battery clearly for the photo-electric type electricity is clear, guarantees smooth winder, steady quality.
(2) weaving process
1, whole slurry process
Adopt domestic advanced person's sizing warper to carry out the warping sizing, total quantity of warps 11520, middle open-width, 960 * 12 axles, rolling density 0.53g/cm3.Through close larger, warping technology is grasped " few mill, protect and stretch " principle due to this kind, guarantees tension force, arranges and reels and be three even, and the difference between minimizing warp beam and warp beam, thereby be conducive to clear and cloth cover smooth of shed open.In the sizing operation, guarantee that the tension force of yarn, filoplume paste volt, yarn is smooth and reduce and through being to make to weave to obtain one of high efficiency, high-quality necessary condition.Configuration to selection, formula and the slashing technique of slurry is optimized selection.Selecting on formula, cause blended strength lower situation poor according to the stainless steel fibre cohesive force, starching is mainly stretched as main take enhancing and guarantor, adopted tough and hard wear resistant, intensity high, extend, PVA slurry that adherence is good, add esterification starch, through test and the contrast of kinds of schemes, determine that at last formula is as follows:
| Project | Formula (kg) |
| PVA | 25 |
| PVA-205MB | 20 |
| Esterification starch | 70 |
| Polyacrylic acid size | 12.5 |
| Wax disk(-sc) | 1 |
| Oil emulsion (piece) | 2 |
| Preservative agent | 0.35 |
| Bleeding agent/defoamer | 0.5/0.2 |
| Regain | 9±2% |
| The rate of sizing | 16±1% |
| Slurry groove temperature/viscosity (℃/S) | ≥98/10±1 |
As can be seen from the above, the ratio of PVA and esterification starch is transferred near 1:2, guaranteed that like this serous coat has certain pliability and permeability, improved the brute force of warp thread, guarantee that warp thread has certain percentage elongation, overcome crisp, the hard deficiency of PVA slurry serous coat, and the filoplume orthogenesis when reducing splitting, the elastic wear-resisting of warp thread is guaranteed.
2, gait and weave
Total quantity of warps 11520, ground are organized as 1/1 plain weave.8 pages of heald frames, porter 85# combines the method 1,3,5,7,2,4,6,8 of wearing, and it is 2 that reed imports number, and menopause tablet is worn method 1,2,3,4,5,6.Notice that menopause tablet is unsuitable overweight, in order to avoid tick fiber, the injury warp thread guarantees wovenly to carry out smoothly.
Adopt Italian Somet-340 Rapier looms to weave, the situation of and easy brittle failure lower according to the stainless steel fibre blended strength suitably reduces warp tension and the speed of a motor vehicle, and the speed of a motor vehicle is 400rpm; In addition, cause the sky phenomenon of cut-offfing for preventing from conducting electricity flyings, this menopause tablet changes lower contact into by upper contact, can greatly reduce the mistakenly stop car, improves weaving efficiency, thereby guarantees fabric quality.
(3) printing and dyeing and postfinishing process
The stainless steel fibre soft smooth, without curling, cohesive force is little in the yarn body, causes the blended strength of itself and cotton fiber also lower, the therefore moderate grasp of cloth gripper broadwise pulling force when dyeing mercerizing avoids that Bradley is bad.Shallow high-grade popular colour during color adopts is as purple, redness, aubergine, crocus etc.Rear arrangement needs to process through operations such as softness typing preshrunks, makes the radiation-proof fabric that cloth cover is bright and clean, softness is smooth, color is beautiful, makes product have higher added value.
Four, technological parameter
1, spinning
Warp thread, weft yarn: cotton fiber 95/ stainless steel fibre 5 32S
Cotton fiber:
1. carded sliver dry weight 19.6g/5m, sliver exporting speed 70m/min, the cylinder-cover plate 8*7*7*7*8 that spaces ";
2. pre-and quantitative dry weight 20.3g/5m, 6 of number of doubling;
3. bar and roll up quantitative dry weight 65g/m, number of doubling 24;
4. combing type E62, dry weight 20.5g/5m, linters rate 18%.
5. combing end and dry weight 21g/5m.
Stainless steel fibre: pre-drawing dry weight 17.7g/5m.
Mix also: three roads
The 11*18mm that spaces, the speed of a motor vehicle is at 200m/min
Drafting: 1 metal fibre+7 combing cotton strip quantity 18.3g/5m
Two draftings: 4 drafting+4 combing cotton strip quantity 18.5g/5m
Three draftings: 6 quantitative 18g/5m of number of doubling
Rove: roller gauge 10*25*38mm, design weight 4.8g/10m, the twist 3.75 sth. made by twisting/10cm
Spun yarn: roller gauge 18*23mm, design weight 1.693g/100m, the twist 87.7 sth. made by twisting/10cm
2, weave
(1) warping
Type: ASGA236 technical ability type itemize sizing warper;
Total warping radical: 11520;
Radical * number of axle: 960 * 12;
Winding speed: 600m/min;
Rolling density: 0.53g/cm3;
Tension force: segmentation is controlled.
(2) sizing
Starching form: tandem sizing box;
The rate of sizing: 16 ± 1%;
Regain: 9 ± 2%;
Percentage elongation :≤0.8%;
Sizing China ink seal length: 57m;
Winding speed: 70m/min;
Slurry groove temperature/viscosity (℃/S): 〉=92/10 ± 1;
Stock tank pH value: 7-8.
The formula (unit: kilogram) of sizing mixing
PVA 25
PVA-205MB 20
Esterification starch 70
ADC 12.5
Wax disk(-sc) 1
Oil emulsion (piece) 2
Preservative agent 0.35
Supply staving to amass/H(L/cm): 740/80
Supply barrel temperature/viscosity (℃/S): 98/10 ± 1.
(3) gait
Porter: 85#;
Reed width: 345.5cm;
Heald frame number of pages: 8 pages;
The ground tissue is combined the method for wearing: 1,3,5,7,2,4,6,8
The ground tissue is combined into number: 1;
The limit tissue is combined into number: 1;
Organize reed to enter number: 2;
Menopause tablet is worn method: 1,2,3,4,5,6.
(4) weaving process technical parameter
Type: Somet-340 Rapier looms;
Speed: 430rpm;
Upper machine filling density: 68/English inch;
Opening pattern: electronic dobby;
Opening time: 315 degree;
Advance the sword time: 65 degree;
Connect the sword time: 180 degree;
Back beam height: 50mm;
Predetermined tension: 360kg;
Control cloth width: 164～167.5cm on machine;
The cloth number falls: 4;
Temperature/relative humidity 25 ± 2 ℃/76 ± 3%.
(5) arranging process
Finished product lump length: 100m;
Folding length: 1m;
Check Baling Length: 400m.
3, dyeing and rear arrangement
Technological process:
The stand stitches → singes → and cold-pad-batch preparation → decatize washing → mercerising → oxygen floats → cold-rolling heap staining → softness → loose formula oven dry → typing → preshrunk → finished product inspection;
(1) singe: a positive and a negative, 1500 ℃ of fiery temperature;
(2) cold-pad-batch process: NaOH35 grams per liter, scouring agent 10 grams per liters, bleeding agent 2 grams per liters, 40 m/mins of the speed of a motor vehicle, stacking at room temperature 24 hours;
(3) decatize is 102 ℃, 2min;
(4) washing: heat is washed, 75～80 ℃ of first and second grooves, 100 ℃ of third and fourth grooves;
(5) mercerization flow process: dried cloth (wet cloth → squezzing) → alkali immerging → cloth that stretches tight is ventilative → and alkali immerging → expanding rinses → steams and wash → wash → neutralize → wash.
Roll alkali time 50S, NaOH concentration 180g/l, temperature: below 15 ℃, speed of a motor vehicle 40m/min;
(6) oxygen floats: crawler belt 066 oxygen bleaching machine, and hydrogen peroxide 3～3.5g/l, Na2SiO3 3-4 g/l, scouring agent 5 g/l, NaOH1g/l, speed of a motor vehicle 40m/min, 60min banks up.
(7) cold-rolling heap staining
Technological process: semi-products pre-treatment → pad dye liquor → clot → bank up → wash → soap → wash → dry.
Dyestuff is selected the REACTIVE DYES that diffusivity is good, permeability is good, alkali resistance is good, and the detergency excellence of dyestuff, color light stabilizing, favorable reproducibility, degree of fixation are high.
The preparation of alkali lye: dye liquor and alkali lye are prepared respectively, groove volume 30L.
The 16h that banks up soaps 70 ℃, washes 90 ℃
(8) softness: adopt amino silicone softener;
(9) typing: finalize the design after adopting loose formula oven dry, setting process condition: the speed of a motor vehicle: 70m/min, temperature: 180 degree.
(10) preshrunk: the finished product shrinkage is controlled in 3%;
(11) finished product packing: batching, inner lining plastic bag, outsourcing snakeskin bag; Finished product length 150m.
It is 7.3um that the present invention adopts the fineness of import, length is stainless steel short fiber and the cotton fiber blending of 51mm, Rapier looms is weaved, the radiation-proof fabric that processes through finishing process in printing and dye-ing again is a low content metal fibre radiation-proof fabric (metal fibre content accounts for 5%), and radiation proof usefulness can reach more than 92%, and product is more soft comfortable, after dyeing, color can be rich and varied, thereby satisfy the consumer to the demand of fabric outward appearance, color fashion attractive in appearance, therefore this series products has higher added value and market development potentiality, remarkable in economical benefits.
Claims (8)
1. stainless steel fibre radiation-proof fabric, it is characterized in that: its warp thread and weft yarn are stainless steel fibre/cotton fiber mixed yarn, and stainless steel fibre content accounts for 5%, and cotton fiber content accounts for 95%.
2. stainless steel fibre radiation-proof fabric as claimed in claim 1, it is characterized in that: its fabric tissue is highly dense plain weave.
3. the preparation method of stainless steel fibre radiation-proof fabric as claimed in claim 1 or 2, it is characterized in that: it comprises the steps:
A, cotton fiber mix and operation through blowing, comb and parallel cotton fibers prior to spinning, combing, multiple tracks, and then through rove, spun yarn, winding procedure, mix also in multiple tracks and in operation, stainless steel fibre is progressively sneaked into;
B, weave; Comprise whole slurry, gait, weave step;
C, printing and dyeing; Adopt Mercerization dyeing;
D, rear arrangement; Comprise softness, typing, preshrunk step.
4. the preparation method of stainless steel fibre radiation-proof fabric as claimed in claim 3, is characterized in that: before spinning, the door cover of exposed electrical equipment in Workshop Production equipment is closed or sealed.
5. the preparation method of stainless steel fibre radiation-proof fabric as claimed in claim 3 is characterized in that: adopt heavily pressurization, the technique of spacing tightly in the multiple tracks of spinning in mixed and operation, break the metal fibre of a part of overlength.
6. the preparation method of stainless steel fibre radiation-proof fabric as claimed in claim 3, is characterized in that: adopt the photo-electric type electricity clear in the winding procedure in spinning.
7. the preparation method of stainless steel fibre radiation-proof fabric as claimed in claim 3, it is characterized in that: when weaving, the slashing size formula is:
The PVA:25 kilogram;
The PVA-205MB:20 kilogram;
Esterification starch: 70 kilograms;
Polyacrylic acid size: 12.5 kilograms;
Wax disk(-sc): 1 kilogram;
Oil emulsion (piece): 2 kilograms;
Preservative agent: 0.35 kilogram;
Bleeding agent: 0.5 kilogram;
Defoamer: 0.2 kilogram;
The slashing technique parameter:
Slurry groove temperature: 98 ℃;
Viscosity: 10 ± 1S;
Regain: 9 ± 2%
The rate of sizing: 16 ± 1%.
8. the preparation method of stainless steel fibre radiation-proof fabric as claimed in claim 3, it is characterized in that: gait in weaving and adopt total quantity of warps 11520, ground is organized as 1/1 plain weave.8 pages of heald frames, porter 85# combines the method 1,3,5,7,2,4,6,8 of wearing, and it is 2 that reed imports number, and menopause tablet is worn method 1,2,3,4,5,6.
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| CN103993406A (en) * | 2014-05-21 | 2014-08-20 | 江阴福斯特纺织有限公司 | Low-carbon and environment-friendly superfine cotton silk woven fabric and production process thereof |
| CN103993406B (en) * | 2014-05-21 | 2016-08-24 | 江阴福斯特纺织有限公司 | The ultra-fine special cotton silkworm silk interwoven fabric of low-carbon environment-friendly and production technology thereof |
| CN104389075A (en) * | 2014-11-28 | 2015-03-04 | 常熟市钟杰针织有限公司 | Preparation method of antistatic radiation-proof fabric |
| CN104818564A (en) * | 2015-04-02 | 2015-08-05 | 安徽龙盛纺织科技有限公司 | Processing technique of stainless steel fiber ray-proof fabric |
| CN105648629A (en) * | 2016-02-26 | 2016-06-08 | 宁波萌恒抽纱有限公司 | Multifunctional shell fabric and manufacturing method thereof |
| CN105671734A (en) * | 2016-02-26 | 2016-06-15 | 宁波高新区弘邦信息咨询有限公司 | Composite fiber fabric and preparation method thereof |
| CN105908504A (en) * | 2016-05-13 | 2016-08-31 | 武汉纺织大学 | Compound size for denim warp sizing and preparation method and application thereof |
| CN108796717A (en) * | 2018-05-31 | 2018-11-13 | 江苏康溢臣生命科技有限公司 | A kind of fabric and its weaving process with copper alloy base shield |
| CN108796774A (en) * | 2018-06-20 | 2018-11-13 | 保定三源纺织科技有限公司 | A kind of camouflage shielding cloth and its production method |
| CN110029425A (en) * | 2019-04-15 | 2019-07-19 | 中山市仕春纺织印染实业有限公司 | A kind of Composite anti-radiation material garment material |
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Application publication date: 20130612 |