CN103145890A - 干燥湿聚合物的方法 - Google Patents
干燥湿聚合物的方法 Download PDFInfo
- Publication number
- CN103145890A CN103145890A CN2012104258403A CN201210425840A CN103145890A CN 103145890 A CN103145890 A CN 103145890A CN 2012104258403 A CN2012104258403 A CN 2012104258403A CN 201210425840 A CN201210425840 A CN 201210425840A CN 103145890 A CN103145890 A CN 103145890A
- Authority
- CN
- China
- Prior art keywords
- steam
- heating unit
- fluid
- moisture eliminator
- polymkeric substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000001035 drying Methods 0.000 title claims abstract description 25
- 229920000642 polymer Polymers 0.000 title claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 56
- 239000013529 heat transfer fluid Substances 0.000 claims abstract description 16
- 239000000178 monomer Substances 0.000 claims description 51
- 239000000126 substance Substances 0.000 claims description 47
- 239000012530 fluid Substances 0.000 claims description 32
- 239000007859 condensation product Substances 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 238000009833 condensation Methods 0.000 claims description 8
- 230000005494 condensation Effects 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- 239000012736 aqueous medium Substances 0.000 claims description 5
- 229920005601 base polymer Polymers 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 238000007664 blowing Methods 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 26
- 239000007788 liquid Substances 0.000 description 13
- 150000004820 halides Chemical class 0.000 description 11
- 239000012065 filter cake Substances 0.000 description 10
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- -1 vinyl halide Chemical class 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 238000005243 fluidization Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 235000011089 carbon dioxide Nutrition 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- 230000004087 circulation Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
- 206010057040 Temperature intolerance Diseases 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- YTKRILODNOEEPX-NSCUHMNNSA-N crotyl chloride Chemical compound C\C=C\CCl YTKRILODNOEEPX-NSCUHMNNSA-N 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000008543 heat sensitivity Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000001990 intravenous administration Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/008—Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F114/02—Monomers containing chlorine
- C08F114/04—Monomers containing two carbon atoms
- C08F114/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/20—Concentration
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/24—Treatment of polymer suspensions
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/02—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
- F26B3/06—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried
- F26B3/08—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed
- F26B3/084—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed with heat exchange taking place in the fluidised bed, e.g. combined direct and indirect heat exchange
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Microbiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Drying Of Solid Materials (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0413706A FR2879608B1 (fr) | 2004-12-22 | 2004-12-22 | Procede de sechage d'un polymere humide |
| FR04.13706 | 2004-12-22 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200580044570XA Division CN101087817A (zh) | 2004-12-22 | 2005-12-20 | 干燥湿聚合物的方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103145890A true CN103145890A (zh) | 2013-06-12 |
Family
ID=34953800
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012104258403A Pending CN103145890A (zh) | 2004-12-22 | 2005-12-20 | 干燥湿聚合物的方法 |
| CNA200580044570XA Pending CN101087817A (zh) | 2004-12-22 | 2005-12-20 | 干燥湿聚合物的方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200580044570XA Pending CN101087817A (zh) | 2004-12-22 | 2005-12-20 | 干燥湿聚合物的方法 |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US20080127507A1 (enExample) |
| EP (1) | EP1831262B1 (enExample) |
| JP (1) | JP2008524551A (enExample) |
| KR (1) | KR101233473B1 (enExample) |
| CN (2) | CN103145890A (enExample) |
| BR (1) | BRPI0519182B8 (enExample) |
| CA (1) | CA2590301A1 (enExample) |
| EA (1) | EA012955B1 (enExample) |
| EG (1) | EG25047A (enExample) |
| ES (1) | ES2527421T3 (enExample) |
| FR (1) | FR2879608B1 (enExample) |
| MX (1) | MX2007007771A (enExample) |
| MY (1) | MY158268A (enExample) |
| NO (1) | NO20073174L (enExample) |
| TW (1) | TWI389785B (enExample) |
| UA (1) | UA96259C2 (enExample) |
| WO (1) | WO2006067126A1 (enExample) |
| ZA (1) | ZA200705124B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5440163B2 (ja) * | 2009-12-28 | 2014-03-12 | 東ソー株式会社 | ポリエチレン粒子回収方法及びポリエチレン粒子製造装置 |
| DE102011014131A1 (de) * | 2011-03-15 | 2012-09-20 | Thyssenkrupp Uhde Gmbh | Verfahren zur Trocknung von feuchtem Polymerpulver und dafür geeignete Vorrichtung |
| JP5959879B2 (ja) * | 2012-02-28 | 2016-08-02 | 三菱重工業株式会社 | 乾燥システム |
| JP6115973B2 (ja) * | 2012-08-09 | 2017-04-19 | パセオン オーストリア ゲーエムベーハー ウント ツェーオー カーゲー | ポリマー材料の乾燥方法 |
| CN106422986B (zh) * | 2016-09-12 | 2022-11-25 | 原初科技(北京)有限公司 | 煅烧装置 |
| US10556971B2 (en) | 2016-11-09 | 2020-02-11 | Exxonmobil Chemical Patents Inc. | Process for drying polymers |
| DE102017110534B4 (de) | 2017-05-15 | 2024-08-01 | Bma Braunschweigische Maschinenbauanstalt Gmbh | Verdampfungstrockner und Verfahren zu dessen Betrieb |
| KR102195921B1 (ko) * | 2017-06-23 | 2020-12-28 | 주식회사 엘지화학 | 유기질 재료의 건조 공정 중 탄화의 조기 감지방법 |
| CN107906940A (zh) * | 2017-12-15 | 2018-04-13 | 川田机械制造(上海)有限公司 | 干燥系统及相应的干燥系统集成 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2662844A (en) * | 1950-01-19 | 1953-12-15 | Heavy oil fractions in the presence | |
| JPH0979513A (ja) * | 1995-09-14 | 1997-03-28 | Tlv Co Ltd | 熱媒体による低圧蒸気加熱装置 |
| EP0992520A1 (en) * | 1998-04-28 | 2000-04-12 | Asahi Kasei Kogyo Kabushiki Kaisha | Porous dry crumbs of hydrogenated block copolymer |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3313035A (en) * | 1966-03-14 | 1967-04-11 | Crawford & Russell Inc | Apparatus for drying particulate material |
| DK125813B (da) | 1971-04-16 | 1973-05-07 | Niro Atomizer As | Apparat til tørring af fugtige pulvere. |
| DD156479A3 (de) | 1979-05-09 | 1982-09-01 | Vladimir M Uljanov | Verfahren zur herstellung von homo-und copolymeren des vinylchlorids |
| DK145807C (da) * | 1980-11-20 | 1983-08-29 | Niro Atomizer As | Fremgangsmaade og apparat til toerring af et partikelformet produkt |
| US4466202A (en) * | 1983-03-07 | 1984-08-21 | Bend Research, Inc. | Energy-efficient evaporation process with means for vapor recovery |
| JPH04289292A (ja) * | 1991-03-14 | 1992-10-14 | Motoyama Shinko Kk | 帯状材乾燥装置 |
| AU635457B2 (en) * | 1991-04-15 | 1993-03-18 | Tlv Co., Ltd. | Reduced pressure heat treating device |
| US5314579A (en) * | 1992-01-13 | 1994-05-24 | Quantum Chemical Corporation | Process for removing hydrocarbons from polymer slurries |
| JP3169673B2 (ja) * | 1992-02-10 | 2001-05-28 | 信越化学工業株式会社 | 塩化ビニル系重合体の製造方法 |
| JPH0688084A (ja) * | 1992-05-29 | 1994-03-29 | Kawasaki Steel Corp | スチーム管を備えた回転加熱式ドライヤの運転方法 |
| JP2837644B2 (ja) * | 1995-07-03 | 1998-12-16 | 進栄株式会社 | 低温蒸気発生装置 |
| JPH09122401A (ja) * | 1995-10-31 | 1997-05-13 | Nara Kikai Seisakusho:Kk | 液状物質中の固形成分の乾燥回収方法 |
| JPH1073375A (ja) * | 1996-08-28 | 1998-03-17 | Nippon Synthetic Chem Ind Co Ltd:The | 乾燥機 |
| JP2001525884A (ja) * | 1997-05-23 | 2001-12-11 | ザ ダウ ケミカル カンパニー | 触媒不活性化によるシンジオタクチック芳香族ポリマーの固相揮発分除去 |
| RU2146778C1 (ru) * | 1998-08-25 | 2000-03-20 | Попов Сергей Анатольевич | Способ работы насосно-эжекторной установки и насосно-эжекторная установка для реализации способа ее работы |
| US6242562B1 (en) * | 1998-12-28 | 2001-06-05 | Shin-Etsu Chemical Co., Ltd. | Process for producing vinyl chloride polymer |
| JP3852894B2 (ja) * | 1998-12-28 | 2006-12-06 | 信越化学工業株式会社 | 塩化ビニル系重合体の製造方法 |
| KR100370882B1 (ko) * | 2000-06-15 | 2003-02-05 | 한국생명공학연구원 | 서머스 칼도필러스 지케이24 균주 유래 재조합 효소 및이를 이용한 알파-1,4-아밀로오스 제조방법 |
| JP2003137923A (ja) * | 2001-11-01 | 2003-05-14 | Gantsu Kasei Kk | ポリマー粉末の乾燥法 |
| JP2004144308A (ja) * | 2002-10-21 | 2004-05-20 | Ebara Corp | 複合発電システム |
-
2004
- 2004-12-22 FR FR0413706A patent/FR2879608B1/fr not_active Expired - Lifetime
-
2005
- 2005-12-13 TW TW094144142A patent/TWI389785B/zh not_active IP Right Cessation
- 2005-12-14 MY MYPI20055886A patent/MY158268A/en unknown
- 2005-12-20 EA EA200701346A patent/EA012955B1/ru not_active IP Right Cessation
- 2005-12-20 US US11/722,258 patent/US20080127507A1/en not_active Abandoned
- 2005-12-20 BR BRPI0519182A patent/BRPI0519182B8/pt not_active IP Right Cessation
- 2005-12-20 KR KR1020077014214A patent/KR101233473B1/ko not_active Expired - Fee Related
- 2005-12-20 WO PCT/EP2005/056935 patent/WO2006067126A1/en not_active Ceased
- 2005-12-20 JP JP2007547479A patent/JP2008524551A/ja active Pending
- 2005-12-20 EP EP05847512.0A patent/EP1831262B1/en not_active Expired - Lifetime
- 2005-12-20 ES ES05847512.0T patent/ES2527421T3/es not_active Expired - Lifetime
- 2005-12-20 CA CA002590301A patent/CA2590301A1/en not_active Abandoned
- 2005-12-20 CN CN2012104258403A patent/CN103145890A/zh active Pending
- 2005-12-20 CN CNA200580044570XA patent/CN101087817A/zh active Pending
- 2005-12-20 MX MX2007007771A patent/MX2007007771A/es active IP Right Grant
- 2005-12-20 UA UAA200708136A patent/UA96259C2/ru unknown
-
2007
- 2007-06-17 EG EGNA2007000601 patent/EG25047A/xx active
- 2007-06-19 ZA ZA200705124A patent/ZA200705124B/xx unknown
- 2007-06-22 NO NO20073174A patent/NO20073174L/no not_active Application Discontinuation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2662844A (en) * | 1950-01-19 | 1953-12-15 | Heavy oil fractions in the presence | |
| JPH0979513A (ja) * | 1995-09-14 | 1997-03-28 | Tlv Co Ltd | 熱媒体による低圧蒸気加熱装置 |
| EP0992520A1 (en) * | 1998-04-28 | 2000-04-12 | Asahi Kasei Kogyo Kabushiki Kaisha | Porous dry crumbs of hydrogenated block copolymer |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2527421T3 (es) | 2015-01-23 |
| KR101233473B1 (ko) | 2013-02-14 |
| EP1831262A1 (en) | 2007-09-12 |
| NO20073174L (no) | 2007-09-13 |
| EA012955B1 (ru) | 2010-02-26 |
| MX2007007771A (es) | 2007-08-21 |
| EA200701346A1 (ru) | 2007-10-26 |
| KR20070103368A (ko) | 2007-10-23 |
| US20080127507A1 (en) | 2008-06-05 |
| FR2879608A1 (fr) | 2006-06-23 |
| BRPI0519182B8 (pt) | 2017-03-21 |
| BRPI0519182A2 (pt) | 2008-12-30 |
| BRPI0519182B1 (pt) | 2016-11-08 |
| EP1831262B1 (en) | 2014-10-08 |
| CN101087817A (zh) | 2007-12-12 |
| WO2006067126A1 (en) | 2006-06-29 |
| UA96259C2 (ru) | 2011-10-25 |
| TWI389785B (zh) | 2013-03-21 |
| CA2590301A1 (en) | 2006-06-29 |
| TW200633832A (en) | 2006-10-01 |
| ZA200705124B (en) | 2009-02-25 |
| JP2008524551A (ja) | 2008-07-10 |
| EG25047A (en) | 2011-07-19 |
| MY158268A (en) | 2016-09-30 |
| FR2879608B1 (fr) | 2007-03-16 |
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Application publication date: 20130612 |