CN103084715A - Laser preprocessing wire filling tungsten inert gas (TIG) welding method of titanium sheet and aluminum sheet - Google Patents
Laser preprocessing wire filling tungsten inert gas (TIG) welding method of titanium sheet and aluminum sheet Download PDFInfo
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- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 86
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 77
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 31
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 229910052721 tungsten Inorganic materials 0.000 title claims abstract description 12
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- 238000007781 pre-processing Methods 0.000 title abstract 3
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- 239000007788 liquid Substances 0.000 claims abstract description 7
- 238000012545 processing Methods 0.000 claims abstract description 7
- 239000004411 aluminium Substances 0.000 claims description 62
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 50
- 229910052786 argon Inorganic materials 0.000 claims description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 238000013519 translation Methods 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 7
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052779 Neodymium Inorganic materials 0.000 claims description 5
- 244000137852 Petrea volubilis Species 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
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- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 5
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- 239000011574 phosphorus Substances 0.000 claims description 5
- 238000007747 plating Methods 0.000 claims description 5
- 238000005498 polishing Methods 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 238000001179 sorption measurement Methods 0.000 claims description 5
- WLTSUBTXQJEURO-UHFFFAOYSA-N thorium tungsten Chemical compound [W].[Th] WLTSUBTXQJEURO-UHFFFAOYSA-N 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 229910052727 yttrium Inorganic materials 0.000 claims description 5
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 5
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010058490 Hyperoxia Diseases 0.000 description 1
- 229910001051 Magnalium Inorganic materials 0.000 description 1
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Abstract
The invention provides a laser preprocessing wire filling tungsten inert gas (TIG) welding method of a titanium sheet and an aluminum sheet. Liquid immersing process processing is performed on a to-be-welded portion of the titanium sheet, and an aluminized coating with preferred thickness is formed. Then the to-be-welded surface of the lateral side of the titanium alloy sheet is preprocessed, wherein the surface of the lateral side of the titanium alloy sheet undergoes aluminizing so that the temperature of the surface which is radiated rapidly raises, and therefore aluminum of the aluminized coating is rapidly melted. Mutual diffusion exists between aluminum elements and titanium elements, and therefore a stable middle layer is easy to combine. Filter metal and aluminum sheet base materials are melted, and after the filter metal and the aluminum sheet are fully melted, mixed and solidified, a welded joint is formed. The laser preprocessing wire filling TIG welding method of a titanium sheet and an aluminum sheet has the advantages of being capable of improving production efficiency and improving joint performance, and convenient to operate.
Description
Technical field
The invention belongs to the welding technology field of foreign material, particularly the laser pre-treated of a kind of titanium plate and aluminium sheet silk filling TIG welding method.
Background technology
Many excellent characteristics such as that the titanium plate has is lightweight, intensity is large, heat resistance is strong, corrosion-resistant are described as " following metal ", are the new structural materials with development prospect.The application of titanium plate relates to many fields, and is the most outstanding with the application in aerospace field.Aluminium alloy is main structural material in aircraft manufacturing, most of crucial load bearing component (as wing, shell, empennage etc.) is by the aluminium alloy manufacturing, titanium and alloy thereof not only have very important application in aviation, space travel industry, and have begun extensive use in many industrial departments such as chemical industry, oil, light industry, metallurgy, generating.Aluminium has the advantages such as specific strength is high, processability good, Physical and mechanical properties is superior, anticorrosive, is considered to the most economical and the most practical material in a lot of applications.Under most of environmental conditions, be included in air, water (or salt solution), petrochemistry and a lot of chemical system, aluminium can demonstrate good corrosion resistance.The surface of aluminium has the reflectivity of height.Aluminium demonstrates good electrical conductivity and thermal conductivity usually, and some special aluminum alloy with high resistivity are also succeeded in developing, and these alloys can be used in motor as high torque (HT).Aluminium is often selected due to its excellent conductivity.On equiponderant basis, the electrical conductivity of aluminium is bordering on the twice of copper.Because titanium plate and aluminium alloy have some special performance, Ti and A1 composite component are applied at aerospace field and chemical industry electrolytic industry as a kind of new structural material, the Ti/Al composite construction has good stability, heat-insulating sound-insulating and the performance such as high temperature resistant, can bring into play to greatest extent the characteristic potentiality of bi-material, titanium plate and aluminium are extremely important in industrial application, the fields that have a lot of industry to intersect, it is significant that this makes aluminium be connected connection with titanium.
But aluminium is connected the connection difficulty with titanium very large.The physicochemical properties of titanium and aluminium (as fusing point, crystal structure, thermal conductivity factor, thermal coefficient of expansion etc.) differ greatly, particularly embrittlement very easily occurs in titanium when heating and cooling, adopt conventional fusion welding method to realize Ti and acquire a certain degree of difficulty reliable connection of A1, when reaching the fusing point of Ti, the evaporation of A1 melting loss of elements.Ti is reactive metal, and 300 ℃ of strong oxidations of beginning, more the hyperoxia voltinism is more serious for temperature, generates TiO
2Deng oxide, form crisp hard Ti-A1 intermetallic compound brittle layer in weld seam, make weld seam embrittlement or generation, namely in welding process, because the solubility between Ti and Al is minimum at ambient temperature, because the hot physical and chemical performance between the aluminium titanium differs greatly, can produce the intermetallic compound of a large amount of fragility when welding with traditional welding method, thereby affect joint performance.At present, traditional welding method of Ti/Al different alloys mainly contains the molten soldering of electric arc, diffusion welding (DW), soldering, friction welding (FW) etc.
Electric arc heated is concentrated, and heat input is little, and is easy to operate, efficient energy-saving easily is automated again, after this welding method soldering the distortion very little, insensitive to the fit-up gap, and heat time heating time is short, consume littlely, cost is low, and the thermal treatment zone is narrow, heat more concentrated, heat input is little, and the heat affected area is narrow, and after soldering, distortion is little.But in realizing that the aluminium titanium dissimilar metal connects the process of moulding, if adopt general simple arc brazing method, welding process has following shortcoming: the heat radiation of titanium is large, existing equipment is expensive, the production cycle is long.
The scholar's research such as Li Yajiang the vacuum diffusion welding of Ti and Al, and near the tissue diffuse interface and micro structure are analyzed.Yet diffusion welding (DW) is that two weldments are closely superimposed, and contact area is larger, and need to keep a period of time under uniform temperature and pressure in vacuum or protective atmosphere, makes the atom phase counterdiffusion between contact-making surface complete welding.But this method is higher to welding procedure and parameter request, easily cause the compound component of weld and organize not of uniform size causing, and this welding method requirement vacuum environment compacted under, from economical production, cost is larger, is not suitable for aluminium titanium material in enormous quantities and connects moulding.
Summary of the invention
The present invention provides the laser pre-treated silk filling TIG welding method of a kind of titanium plate and aluminium sheet for solving the deficiency of above-mentioned existing solder technology.
To achieve these goals, the present invention adopts following technical scheme, and the laser pre-treated silk filling TIG welding method of titanium plate of the present invention and aluminium sheet comprises the following steps:
1) selecting thickness is titanium plate and the aluminium sheet of the equal thickness of 3-5mm, the joint of titanium plate and aluminium sheet is left the 20 °～groove of 40 ° and the root face of 1 ~ 2mm of equidimension;
2) first soldered surface is polished step by step with 400 orders, 500 orders, 600 orders, 800 orders, 1000 order abrasive paper for metallograph, then, carry out soak cleaning for the surface of above-mentioned polishing again, remove metal surface adsorption layer and oxide-film, aluminium sheet is at configuration HNO
3: the HCl ratio is to clean 30 seconds in the mixed acid dilution of 1:3, and the titanium plate cleaned 10 seconds in 5% HF solution, and cleaning temperature is room temperature, cleans with acetone after washing again, then dries;
3) prepare the solution of following proportioning: 93%-94% commercial-purity aluminium, 4% Fe and 2%-3% Si, then titanium plate part to be welded is carried out liquid and soak processing, the time of staying is 22-28 minute, and heating-up temperature is 690-720 ℃, and the plating aluminum layer thickness of formation is controlled at 80-130 μ m;
4) to the side edge surface employing laser pre-treated of titanium plate through aluminising, adopting output wavelength is the neodymium doped yttrium aluminium garnet laser of 1064nm, the focus lamp focal length is 170-180mm, the absolute value of the side edge surface that laser spot is to be welded apart from the titanium plate is 2.8-3.5 mm, the output continuous wave laser, pretreatment laser power 2 ~ 3 kW, sweep speed is 1.5 ~ 2.5 m/min, pretreated titanium plate in translation also with the direction of translation vertical on move back and forth, rate travel is 1.2 ~ 2m/min;
5) adopting diameter is the magnadure welding wire of 2-3mm, and its mass percent composition is:
Magnesium: 4.2-4.35%, silicon: 0.09-0.12 %, manganese: 0.12-0.2 %, iron: 0.25-0.4 %, carbon: 0.05-0.1 %, titanium: 0.05-0.15 %, phosphorus: 0.05-0.07%, surplus is aluminium;
Welding wire is immersed 50%H
2O+50%HNO
3Solution rinses post-drying with clear water after 15-20min, then polishes with sand paper;
6) the titanium plate is docked placement with aluminium sheet in same plane, the fit-up gap is 0.06mm-0.12mm;
7) first butt-welding fitting just, the back side logical argon shield 8-10min simultaneously, protective gas is purity greater than 99.98% argon gas; Adopt the TIG welding that fills silk, argon arc welding adopts tungsten-thorium electrode again, and the content of tungsten is 99.9%, tungsten electrode diameter 1.8-2.8mm, and the end is taper; Technological parameter is: weldingvoltage 12V, and welding current 80-120A, speed of welding is 60-90mm/min, argon flow amount is 8-10L/min; In the welding process, keep 60-75 ° of angle between welding wire and weldment, welding wire is sent into the molten bath steadily, uniformly along the molten bath front end;
8) after welding finishes, continue logical argon shield 6-10min.
As preferred embodiment, the focus lamp focal length is 175mm, and the laser spot side edge surface to be welded apart from the titanium plate is 2.9-3.3 mm.
As preferred embodiment, the titanium plate docks placement in same plane with aluminium sheet, and the fit-up gap at narrow place is 0.1mm.
Directly be superimposed together from titanium and aluminum surface layer and weld and have at the combination interface place that interrupted micro-crack, joint bond strength are very low different is, the present invention first adopts and titanium plate part to be welded is carried out liquid soaks processing, the aluminized coating with preferred thickness of formation; Then adopt laser instrument to carry out pretreatment to the titanium plate side edge surface through aluminising to be welded, make irradiated surface temperature rise rapidly, thereby the accelerated fusing of the aluminium that makes aluminized coating, thereby make aluminium element and titanium elements counterdiffusion mutually, form the intermediate layer of stable easier combination, create condition for follow-up soldering, can use too harsh welding condition and step; Simultaneously, after laser treatment, self-quench hardening is carried out on the surface to be welded of titanium plate, crystallite dimension obtains obvious refinement, the refinement of crystal grain means that crystal boundary increases, under identical external cooling and sweating heat initial conditions, welding heat affected zone obviously reduces, and the welding heat loss also obviously reduces, help the enforcement of follow-up welding process, and be conducive to the homogenising of welding point microstructure.Thereby make by welding at last and be connected intermediate layer realization connection at the titanium plate with aluminium sheet, it is the magnalium welding wire of 640-670 ℃ that the present invention adopts the fusing point of constituent optimization, in welding process, filler wire is filled metal and the abundant melt-blended after coagulation formation weld seam of aluminium alloy mother metal, and has obvious fusion area; Do not have fusion defects in whole welding process, weld hot cracking tendency and organize the heat affected area, jointing quality and stability thereof are better; Thereby overcome the defective that partial melting that existing melting welding interface temperature easily causes high-melting-point mother metal titanium plate when too high forms blocked up intermetallic compounds layer, avoided the generation of crackle, from plasticity and the toughness that has improved weld seam.Simple to operate, cost is low, good connecting effect.
The invention has the beneficial effects as follows, reduced the vacuum environment welding cost, and improved production efficiency, improve joint performance, easy to operate.
The specific embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1
1) selecting thickness is TC4 titanium plate and the LF6 aluminium sheet of the equal thickness of 3mm, and the joint of titanium plate and aluminium sheet is left the groove of 20 ° of equidimension and the root face of 1mm;
2) first soldered surface is polished step by step with 400 orders, 500 orders, 600 orders, 800 orders, 1000 order abrasive paper for metallograph, then, carry out soak cleaning for the surface of above-mentioned polishing again, remove metal surface adsorption layer and oxide-film, aluminium sheet is at configuration HNO
3: the HCl ratio is to clean 30 seconds in the mixed acid dilution of 1:3, and the titanium plate cleaned 10 seconds in 5% HF solution, and cleaning temperature is room temperature, cleans with acetone after washing again, then dries;
3) prepare the solution of following proportioning: 93% commercial-purity aluminium, 4% Fe and 3% Si, then titanium plate part to be welded to be carried out liquid and soak processing, the time of staying is 22 minutes, and heating-up temperature is 690 ℃, and the plating aluminum layer thickness of formation is controlled at 80 μ m;
4) to the side edge surface employing laser pre-treated of titanium plate through aluminising, adopting output wavelength is the neodymium doped yttrium aluminium garnet laser of 1064nm, the focus lamp focal length is 170mm, the absolute value of the side edge surface that laser spot is to be welded apart from the titanium plate is 3.1-3.5 mm, the output continuous wave laser, pretreatment laser power 2kW, sweep speed is 1.5m/min, pretreated titanium plate in translation also with the direction of translation vertical on move back and forth, rate travel is 2m/min;
5) adopting diameter is the magnadure welding wire of 2mm, and its mass percent composition is:
Magnesium: 4.2%, silicon: 0.09 %, manganese: 0.12 %, iron: 0.25 %, carbon: 0.05 %, titanium: 0.05 %, phosphorus: 0.05%, surplus is aluminium;
Welding wire is immersed 50%H
2O+50%HNO
3Solution rinses post-drying with clear water after 15min, then polishes with sand paper;
6) the titanium plate is docked placement with aluminium sheet in same plane, the fit-up gap is 0.06mm;
7) first butt-welding fitting just, the back side logical argon shield 8min simultaneously, protective gas is purity greater than 99.98% argon gas; Adopt the TIG welding that fills silk, argon arc welding adopts tungsten-thorium electrode again, and the content of tungsten is 99.9%, tungsten electrode diameter 1.8mm, and the end is taper; Technological parameter is: weldingvoltage 12V, and welding current 80A, speed of welding is 60mm/min, argon flow amount is 8L/min; In the welding process, keep 60 ° of angles between welding wire and weldment, welding wire is sent into the molten bath steadily, uniformly along the molten bath front end;
8) after welding finishes, continue logical argon shield 6min.
Resulting TC4 titanium plate and LF6 aluminium sheet banjo fixing butt jointing appearance of weld are attractive in appearance.Do not find the microdefects such as crackle, pore through the metallography microscope sem observation, connector area is in conjunction with good, and the shear strength of welding point is 245MPa.
Embodiment 2:
1) selecting thickness is TC4 titanium plate and the LF6 aluminium sheet of the equal thickness of 4mm, and the joint of titanium plate and aluminium sheet is left the groove of 40 ° of equidimension and the root face of 1.5 mm;
2) first soldered surface is polished step by step with 400 orders, 500 orders, 600 orders, 800 orders, 1000 order abrasive paper for metallograph, then, carry out soak cleaning for the surface of above-mentioned polishing again, remove metal surface adsorption layer and oxide-film, aluminium sheet is at configuration HNO
3: the HCl ratio is to clean 30 seconds in the mixed acid dilution of 1:3, and the titanium plate cleaned 10 seconds in 5% HF solution, and cleaning temperature is room temperature, cleans with acetone after washing again, then dries;
3) prepare the solution of following proportioning: 93% commercial-purity aluminium, 4% Fe and 3% Si, then titanium plate part to be welded to be carried out liquid and soak processing, the time of staying is 22 minutes, and heating-up temperature is 690 ℃, and the plating aluminum layer thickness of formation is controlled at 80 μ m;
4) to the side edge surface employing laser pre-treated of titanium plate through aluminising, adopting output wavelength is the neodymium doped yttrium aluminium garnet laser of 1064nm, the focus lamp focal length is 175mm, the absolute value of the side edge surface that laser spot is to be welded apart from the titanium plate is 2.9-3.3 mm, the output continuous wave laser, pretreatment laser power 2.5 kW, sweep speed is 2 m/min, pretreated titanium plate in translation also with the direction of translation vertical on move back and forth, rate travel is 1.5m/min;
5) adopting diameter is the magnadure welding wire of 2.5mm, and its mass percent composition is:
Magnesium: 4.28 %, silicon: 0.1 %, manganese: 0.15 %, iron: 0.35 %, carbon: 0.08 %, titanium: 0.09 %, phosphorus: 0.06 %, surplus is aluminium;
Welding wire is immersed 50%H
2O+50%HNO
3Solution rinses post-drying with clear water after 20min, then polishes with sand paper;
6) the titanium plate is docked placement with aluminium sheet in same plane, the fit-up gap at narrow place is 0.1mm;
7) first butt-welding fitting just, the back side logical argon shield 8min simultaneously, protective gas is purity greater than 99.98% argon gas; Adopt the TIG welding that fills silk, argon arc welding adopts tungsten-thorium electrode again, and the content of tungsten is 99.9%, tungsten electrode diameter 2.5mm, and the end is taper; Technological parameter is: weldingvoltage 12V, and welding current 90A, speed of welding is 70mm/min, argon flow amount is 9L/min; In the welding process, keep 70 ° of angles between welding wire and weldment, welding wire is sent into the molten bath steadily, uniformly along the molten bath front end;
8) after welding finishes, continue logical argon shield 8min.
because the present embodiment adopts laser instrument, the titanium plate side edge surface through aluminising to be welded is carried out pretreatment, make irradiated surface temperature rise rapidly, thereby the accelerated fusing of the aluminium that makes aluminized coating, thereby make aluminium element and titanium elements counterdiffusion mutually, form the intermediate layer of stable easier combination, simultaneously, after laser treatment, self-quench hardening is carried out on the surface to be welded of titanium plate, crystallite dimension obtains obvious refinement, the refinement of crystal grain means that crystal boundary increases, the conduction of welding heat is subject to larger obstruction, under identical external cooling and sweating heat initial conditions, welding heat affected zone obviously reduces, the welding heat loss also obviously reduces, help the enforcement of follow-up welding process, and be conducive to the homogenising of welding point microstructure.Resulting TC4 titanium plate and LF6 aluminium sheet banjo fixing butt jointing appearance of weld are attractive in appearance.Do not find the microdefects such as crackle, pore through the metallography microscope sem observation, connector area is in conjunction with good, and the shear strength of welding point is 249MPa.
Embodiment 3:
1) select thickness be 5mm equal thickness TC4 titanium plate and LF6 aluminium sheet, the joint of titanium plate and aluminium sheet is left the groove of 30 ° of equidimension and the root face of 2 mm;
2) first soldered surface is polished step by step with 400 orders, 500 orders, 600 orders, 800 orders, 1000 order abrasive paper for metallograph, then, carry out soak cleaning for the surface of above-mentioned polishing again, remove metal surface adsorption layer and oxide-film, aluminium sheet is at configuration HNO
3: the HCl ratio is to clean 30 seconds in the mixed acid dilution of 1:3, and the titanium plate cleaned 10 seconds in 5% HF solution, and cleaning temperature is room temperature, cleans with acetone after washing again, then dries;
3) first prepare the solution of following proportioning: 94% commercial-purity aluminium, 4% Fe and 2%Si, then titanium plate part to be welded to be carried out liquid and soak processing, the time of staying is 28 minutes, and heating-up temperature is 720 ℃, and the plating aluminum layer thickness of formation is controlled at 130 μ m;
4) to the side edge surface employing laser pre-treated of titanium plate through aluminising, adopting output wavelength is the neodymium doped yttrium aluminium garnet laser of 1064nm, the focus lamp focal length is 180mm, the absolute value of the side edge surface that laser spot is to be welded apart from the titanium plate is 2.8-3.2 mm, the output continuous wave laser, pretreatment laser power 2 ~ 3 kW, sweep speed is 2.5 m/min, pretreated titanium plate in translation also with the direction of translation vertical on move back and forth, rate travel is 2 m/min;
5) adopting diameter is the magnadure welding wire of 3mm, and its mass percent composition is:
Magnesium: 4.35 %, silicon: 0.12 %, manganese 0.2 %, iron: 0.4 %, carbon: 0.1 %, titanium: 0.15 %, phosphorus: 0.07 %, surplus is aluminium;
Welding wire is immersed 50%H
2O+50%HNO
3Solution rinses post-drying with clear water after 18min, then polishes with sand paper;
6) the titanium plate is docked placement with aluminium sheet in same plane, the fit-up gap is 0.12mm;
7) first butt-welding fitting just, the back side logical argon shield 8-10min simultaneously, protective gas is purity greater than 99.98% argon gas; Adopt the TIG welding that fills silk, argon arc welding adopts tungsten-thorium electrode again, and the content of tungsten is 99.9%, tungsten electrode diameter 2.8mm, and the end is taper; Technological parameter is: weldingvoltage 12V, and welding current 120A, speed of welding is 90 mm/min, argon flow amount is 10 L/min; In the welding process, keep 75 ° of angles between welding wire and weldment, welding wire is sent into the molten bath steadily, uniformly along the molten bath front end;
8) after welding finishes, continue logical argon shield 10min.
Resulting TC4 titanium plate and LF6 aluminium sheet banjo fixing butt jointing appearance of weld are attractive in appearance.Do not find the microdefects such as crackle, pore through the metallography microscope sem observation, connector area is in conjunction with good, and the shear strength of welding point is 254 MPa.
Obviously, above-described embodiment is only for example clearly is described, and is not the restriction to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here need not also can't give all embodiments exhaustive.And the apparent variation of being extended out thus or the change still be in the protection domain of the invention within.
Claims (3)
1. the laser pre-treated of a titanium plate and the aluminium sheet TIG welding method that fills silk, is characterized in that, comprises the following steps:
1) selecting thickness is titanium plate and the aluminium sheet of the equal thickness of 3-5mm, the joint of titanium plate and aluminium sheet is left the 20 °～groove of 40 ° and the root face of 1 ~ 2mm of equidimension;
2) first soldered surface is polished step by step with 400 orders, 500 orders, 600 orders, 800 orders, 1000 order abrasive paper for metallograph, then, carry out soak cleaning for the surface of above-mentioned polishing again, remove metal surface adsorption layer and oxide-film, aluminium sheet is at configuration HNO
3: the HCl ratio is to clean 30 seconds in the mixed acid dilution of 1:3, and the titanium plate cleaned 10 seconds in 5% HF solution, and cleaning temperature is room temperature, cleans with acetone after washing again, then dries;
3) prepare the solution of following proportioning: 93%-94% commercial-purity aluminium, 4% Fe and 2%-3% Si, then titanium plate part to be welded is carried out liquid and soak processing, the time of staying is 22-28 minute, and heating-up temperature is 690-720 ℃, and the plating aluminum layer thickness of formation is controlled at 80-130 μ m;
4) to the side edge surface employing laser pre-treated of titanium plate through aluminising, adopting output wavelength is the neodymium doped yttrium aluminium garnet laser of 1064nm, the focus lamp focal length is 170-180mm, the absolute value of the side edge surface that laser spot is to be welded apart from the titanium plate is 2.8-3.5 mm, the output continuous wave laser, pretreatment laser power 2 ~ 3 kW, sweep speed is 1.5 ~ 2.5 m/min, pretreated titanium plate in translation also with the direction of translation vertical on move back and forth, rate travel is 1.2 ~ 2m/min;
5) adopting diameter is the magnadure welding wire of 2-3mm, and its mass percent composition is:
Magnesium: 4.2-4.35%, silicon: 0.09-0.12 %, manganese: 0.12-0.2 %, iron: 0.25-0.4 %, carbon: 0.05-0.1 %, titanium: 0.05-0.15 %, phosphorus: 0.05-0.07%, surplus is aluminium;
Welding wire is immersed 50%H
2O+50%HNO
3Solution rinses post-drying with clear water after 15-20min, then polishes with sand paper;
6) the titanium plate is docked placement with aluminium sheet in same plane, the fit-up gap is 0.06mm-0.12mm;
7) first butt-welding fitting just, the back side logical argon shield 8-10min simultaneously, protective gas is purity greater than 99.98% argon gas; Adopt the TIG welding that fills silk, argon arc welding adopts tungsten-thorium electrode again, and the content of tungsten is 99.9%, tungsten electrode diameter 1.8-2.8mm, and the end is taper; Technological parameter is: weldingvoltage 12V, and welding current 80-120A, speed of welding is 60-90mm/min, argon flow amount is 8-10L/min; In the welding process, keep 60-75 ° of angle between welding wire and weldment, welding wire is sent into the molten bath steadily, uniformly along the molten bath front end;
8) after welding finishes, continue logical argon shield 6-10min.
2. the laser pre-treated of titanium plate according to claim 1 and aluminium sheet silk filling TIG welding method, is characterized in that, the focus lamp focal length is preferably 175mm, and the laser spot side edge surface to be welded apart from the titanium plate is 2.9-3.3 mm.
3. the laser pre-treated of titanium plate according to claim 1 and 2 and the aluminium sheet TIG welding method that fills silk, is characterized in that, the titanium plate docks placement in same plane with aluminium sheet, and the fit-up gap at narrow place is 0.1mm.
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| CN105328310A (en) * | 2015-12-01 | 2016-02-17 | 山东省科学院新材料研究所 | Automatic argon arc slotting and filler wire welding method for magnesium alloy lap welding |
| CN110541093A (en) * | 2019-09-19 | 2019-12-06 | 常州工程职业技术学院 | Metal filling material for regulating brittle phase in titanium-aluminum dissimilar metal welding joint and application thereof |
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| FI65177C (en) * | 1981-05-07 | 1984-04-10 | Finnish Chemicals Oy | SAETT ATT FOGA ALUMINUM TILL TITAN GENOM SVETSNING OCH EN SVETSPRODUKT AOSTADKOMMEN HAERIGENOM |
| JP2000015448A (en) * | 1998-06-29 | 2000-01-18 | Nippon Yuteku Kk | Joining method of titanium and aluminum |
| JP3992592B2 (en) * | 2002-11-11 | 2007-10-17 | 株式会社神戸製鋼所 | Method for producing welded joint made of dissimilar metals |
| CN100464925C (en) * | 2007-02-14 | 2009-03-04 | 哈尔滨工业大学 | AC tungsten inert gases welding electric arc micro-melting brazing procedure for aluminium, titanium and diverse metal alloy thereof |
| CN102112263B (en) * | 2008-07-07 | 2014-07-16 | 肯联铝业瑞士有限公司 | Fusion welding process to join aluminium and titanium |
| CN102615402A (en) * | 2012-04-25 | 2012-08-01 | 山东大学 | Tungsten electrode argon arc welding method for filler wires of titanium alloy and aluminum alloy |
| CN102896406A (en) * | 2012-10-16 | 2013-01-30 | 夏雨 | TIG welding method of titanium alloy and pure aluminum plates |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105328310A (en) * | 2015-12-01 | 2016-02-17 | 山东省科学院新材料研究所 | Automatic argon arc slotting and filler wire welding method for magnesium alloy lap welding |
| CN110541093A (en) * | 2019-09-19 | 2019-12-06 | 常州工程职业技术学院 | Metal filling material for regulating brittle phase in titanium-aluminum dissimilar metal welding joint and application thereof |
| CN110541093B (en) * | 2019-09-19 | 2021-01-19 | 常州工程职业技术学院 | Metal filling material for regulating brittle phase in titanium-aluminum dissimilar metal welding joint and application thereof |
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