CN103053551A - Spinosad-containing insecticidal composition - Google Patents
Spinosad-containing insecticidal composition Download PDFInfo
- Publication number
- CN103053551A CN103053551A CN2012105872182A CN201210587218A CN103053551A CN 103053551 A CN103053551 A CN 103053551A CN 2012105872182 A CN2012105872182 A CN 2012105872182A CN 201210587218 A CN201210587218 A CN 201210587218A CN 103053551 A CN103053551 A CN 103053551A
- Authority
- CN
- China
- Prior art keywords
- killing teichomycin
- multiple killing
- rotenone
- matrine
- percentage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a spinosad-containing insecticidal composition. The spinosad-containing insecticidal composition comprises the following components in percentage by weight: 0.1 to 30 percent of spinosad, 0.1 to 30 percent of sophocarpidine or rotenone and the balance of auxiliary ingredient of pesticide preparation. The spinosad-containing insecticidal composition is used for preventing and controlling injurious insects such as rice leaf folders, plutella xylostella, asparagus caterpillar and cabbage caterpillar, is safe in use and environment-friendly, has excellent synergistic effect of preventing and controlling the injurious insects, improves the prevention and control effect, reduces the using amount of the pesticide and reduces the using cost of farmers.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination that contains multiple killing teichomycin.
Background technology
Multiple killing teichomycin has another name called pleocidin (Spinosad), is a kind of macrolides Nuisanceless high-efficient biological insecticides that extract in thorn sugared many born of the same parents bacterium (Saccharopolyspora spinosa) zymotic fluid.The mode of action of multiple killing teichomycin is novel, can sustained activation target insect acetylcholine nicotine receptor, but its binding site is different from nicotine and Imidacloprid.These compounds can cause that target plant-feed insect such as caterpillar, leaf miner, thrips and leaf-feeding beetle are dead rapidly, when using with 12～150g/hm, find no poisoning.Multiple killing teichomycin also can affect the GABA acceptor, but mechanism of action is unclear, can make insect benumb rapidly, paralyse, and causes at last death, and desinsection speed can compare favourably with chemical pesticide.Multiple killing teichomycin safe, and with present common insecticide without cross resistance, biological insecticides for low toxicity, efficient, low-residual, existing efficient insecticidal properties, have again the characteristic of beneficial insect and mammalian safe is arranged, the most suitable pollution-free vegetable, Production of fruit are used, and are the insecticides of a kind of low toxicity, efficient, wide spectrum.
Matrine is to extract a kind of alkaloid of making through organic solvents such as ethanol by the dry root of leguminous plant kuh-seng Sophora flavescens Ait, plant, fruit.Matrine is a kind of agricultural chemical of natural plant, and in a single day insect touches this medicine, namely benumbs nerve center, then makes the polypide protein coagulating, blocks the polypide pore, and insect is choked to death.This product is broad spectrum pesticide to people and animals' low toxicity, has stomach toxicity and action of contace poison.Matrine is to vegetables sucking mouth parts insect (such as aphid), lepidopterous insects (such as cabbage caterpillar, tea caterpillar, diamond-back moth etc.), and tea lesser leafhopper, trialeurodes vaporariorum etc. all have desirable preventive effect; In addition vegetables downy mildew, epidemic disease, anthracnose also there is good preventive effect.
Rotenone (Rotenone), claim again malicious trifoliate jewelvine (Tubatoxin), being a kind of natural insecticide from the root extraction of pulse family liane trifoliate jewelvine, is the main effectively insecticidal constituent in the derris root, has the characteristics such as wide, the free from environmental pollution and difficult generation drug resistance of insecticidal spectrum.Rotenone is present in the root skin zone of plant, is the very strong material of a kind of specificity in toxicology, especially cabbage caterpillar, diamond-back moth and aphid is had strong tagging and stomach poison function.Rotenone also can make the electron transport chain of insect cell be suppressed, thereby the ATP level that reduces in the organism makes insect can not get energy supply, then drumble, paralysis and slowly dead.All there are certain susceptibility in mitochondria in many biological cells, NADH dehydrase, succinic acid, mannitol and other material to rotenone.
The patent documentation that much contains the insecticide of multiple killing teichomycin, matrine or rotenone is disclosed both at home and abroad.For example CN201110424900.5 discloses a kind of Pleocidin compound insecticide, and its effective ingredient is pleocidin and nimbin, and the mass ratio of pleocidin and nimbin is 1～50: 1.Advantage of the present invention is: insecticidal spectrum is wide, and speed of action is fast, can delay pest resistance to insecticide and generation, reduces simultaneously cost of material.Can be applicable to prevent and treat the insects such as Lepidoptera on the crops, diptera, thrips, Homoptera and mite class.
For example CN201210233867.2 discloses a kind of medicament and manufacture method of preventing and treating cabbage caterpillar, and described medicament comprises balsam pear powder 100～200 grams, kudzu-vine root powder 200～250 grams, fishbone dust 100～150 grams, matrine water 50～80 grams, garlic powder 50～80 grams, Tolfenpyrad 150～200 grams.Described balsam pear powder, kudzu-vine root powder, fishbone dust, matrine water, garlic powder, Tolfenpyrad are smashed, and mix, and soak 20～30 minutes after boiling, and filter and remove residue is got supernatant, then carries out sterilization treatment.The present invention is used for the control cabbage caterpillar, and because a lot of composition is vegetal material, so residue of pesticide are few, less to crop and human injury.
CN201110318651.1 for example, a kind of Synergistic insecticidal compositions that contains rotenone and Affirm (Merck Co.) is disclosed, each component is as follows by weight percentage: rotenone 0.5～5%, Affirm (Merck Co.) 1～10%, solvent 5～40%, Anionic-nonionic mixed surfactant 5～20%, assistant for emulsifying agent 0.05～5%, stabilizing agent 0.5～3%, all the other waters complement to 100%.The present invention can overcome pest resistance to insecticide, and the expanding prevention spectrum reduces dosage.The present invention is applicable to the control of insect of the nuisanceless production of agriculture field.
At present, also do not find to be re-dubbed as active component take multiple killing teichomycin and matrine or rotenone the Patents document of insecticide.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of Pesticidal combination that contains multiple killing teichomycin, take multiple killing teichomycin and matrine or rotenone as active component, is used for the insects such as control rice leaf roller, diamond-back moth, beet armyworm, cabbage caterpillar; Said composition is used safety, and is environmentally friendly, and pest control is had excellent synergistic function, can improve control efficiency, reduces the usage amount of agricultural chemicals and peasant's use cost.
For solving the problems of the technologies described above, the present invention by the following technical solutions:
A kind of Pesticidal combination that contains multiple killing teichomycin comprises effective active components A and effective active composition B, and effective active composition A is multiple killing teichomycin, and effective active composition B is selected from any one in matrine, the rotenone.
In the such scheme, described Pesticidal combination comprises the component of following percentage by weight: multiple killing teichomycin 0.1～30%, and matrine or rotenone 0.1～30%, surplus is the pesticidal preparations auxiliary element.Preferably, when by multiple killing teichomycin and matrine compound, the percentage by weight of described multiple killing teichomycin is 5%, and the percentage by weight of matrine is 0.5%; When composite by multiple killing teichomycin and rotenone, the percentage by weight of described multiple killing teichomycin is 5%, and the percentage by weight of rotenone is 2.5%.
In the such scheme, described pesticidal preparations auxiliary element comprises auxiliary agent, and all the other are solvent, demineralized water or filler, or the combination of solvent and demineralized water; Described auxiliary agent is auxiliary agent commonly used in the technical field of pesticide, can but be not limited to comprise one or more combination in emulsifier, thickener, antifreezing agent, wetting agent, dispersant, the binding agent; Described solvent is organic solvent commonly used in the technical field of pesticide, such as dimethylbenzene etc.; Described filler is filler commonly used in the technical field of pesticide, such as kaolin, fine particle calcium carbonate, starch etc.
In the such scheme, the percentage by weight of described auxiliary agent is 5～20%.
In the such scheme, described Pesticidal combination can be prepared as missible oil, aqueous emulsion, microemulsion, wetting powder or water dispersible granules.
The present invention has the following advantages:
1, the present invention has developed a kind of new pesticide species take multiple killing teichomycin and matrine or rotenone as active component.
2, the present invention has excellent synergistic function to preventing and treating disease, can improve control efficiency, reduces the usage amount of agricultural chemicals, reduces peasant's use cost.
3, toxicity of pesticide of the present invention is lower, residual less, uses safety, and environmentally friendly, infringement and less pollution to ecotope are conducive to protect the person poultry safety.
4, the present invention has enlarged the control spectrum to agricultural disease, can be used for for control paddy rice rice leaf roller, the insects such as vegetables diamond-back moth, beet armyworm, cabbage caterpillar, applied range.
Embodiment
The below is described further with embodiment, but the present invention is not limited to these embodiment.Among the following embodiment, as be not particularly limited, the percentage composition of the composition of mentioning (%) is weight percentage.
Embodiment 1
Multiple killing teichomycin becomes missible oil with matrine compound: multiple killing teichomycin 5%, and matrine 0.5%, emulsifier (weight ratio of agricultural newborn 500# and NP-10 is 1:3) 8%, surplus is dimethylbenzene.
Embodiment 2
Multiple killing teichomycin becomes aqueous emulsion with matrine compound: multiple killing teichomycin 5%, and matrine 0.5%, dimethylbenzene 10%, emulsifier (EW-01) 3%, thickener (0486) 2%, antifreezing agent (isopropyl alcohol) 4%, surplus is demineralized water.
Embodiment 3
Multiple killing teichomycin becomes microemulsion with matrine compound: multiple killing teichomycin 5%, and matrine 0.5%, emulsifier (502, the weight ratio of T60 and NP-10 be 1:2:2) 15%, dimethylbenzene 10%, antifreezing agent (ethanol) 5%, surplus is demineralized water.
Embodiment 4
Multiple killing teichomycin becomes wetting powder with matrine compound: multiple killing teichomycin 5%, and matrine 0.5%, emulsifier (0203B) 4%, wetting agent (K12) 0.5%, dispersant (white carbon) 5%, surplus is filler (kaolin).
Embodiment 5
Multiple killing teichomycin becomes water dispersible granules with matrine compound: multiple killing teichomycin 5%, and matrine 0.5%, dispersant (D2001) 5%, wetting agent (D2002) 1%, binding agent (polyvinyl alcohol) 0.5%, surplus is filler (starch).
Embodiment 6
Multiple killing teichomycin becomes missible oil with matrine compound: multiple killing teichomycin 0.1%, and matrine 10%, emulsifier (weight ratio of agricultural newborn 500# and NP-10 is 1:2) 20%, surplus is dimethylbenzene.
Embodiment 7
Multiple killing teichomycin becomes aqueous emulsion with matrine compound: multiple killing teichomycin 5%, and matrine 30%, dimethylbenzene 10%, emulsifier (EW-01) 3%, thickener (0486) 2%, antifreezing agent (isopropyl alcohol) 4%, surplus is demineralized water.
Embodiment 8
Multiple killing teichomycin becomes microemulsion with matrine compound: multiple killing teichomycin 30%, and matrine 0.1%, emulsifier (502, the weight ratio of T60 and NP-10 be 2:2:1) 10%, dimethylbenzene 10%, antifreezing agent (ethanol) 5%, surplus is demineralized water.
Embodiment 9
Multiple killing teichomycin becomes wetting powder with matrine compound: multiple killing teichomycin 0.1%, and matrine 30%, emulsifier (0203B) 4%, wetting agent (K12) 0.5%, dispersant (white carbon) 5%, surplus is filler (fine particle calcium carbonate).
Embodiment 10
Multiple killing teichomycin becomes water dispersible granules with matrine compound: multiple killing teichomycin 20%, and matrine 0.1%, dispersant (D2001) 5%, wetting agent (D2002) 1%, binding agent (polyvinyl alcohol) 0.5%, surplus is filler (starch).
Embodiment 11
Multiple killing teichomycin and rotenone are re-dubbed missible oil: multiple killing teichomycin 5%, and rotenone 2.5%, emulsifier (weight ratio of agricultural newborn 500# and NP-10 is 1:3.5) 8%, surplus is dimethylbenzene.
Embodiment 12
Multiple killing teichomycin and rotenone are re-dubbed aqueous emulsion: multiple killing teichomycin 5%, and rotenone 2.5%, dimethylbenzene 10%, emulsifier (EW-01) 3%, thickener (0486) 2%, antifreezing agent (isopropyl alcohol) 4%, surplus is deionized water.
Embodiment 13
Multiple killing teichomycin and rotenone are re-dubbed microemulsion: the more killing teichomycin 5%, rotenone 2.5%, and emulsifier (502, the weight ratio of T60 and NP-10 be 1:2:2) 15%, dimethylbenzene 8%, antifreezing agent (ethanol) 5%, surplus is demineralized water.
Embodiment 14
Multiple killing teichomycin and rotenone are re-dubbed wetting powder: multiple killing teichomycin 5%, and rotenone 2.5%, emulsifier (0203B) 4%, wetting agent (K12) 0.5%, dispersant (white carbon) 5%, surplus is filler (kaolin).
Embodiment 15
Multiple killing teichomycin and rotenone are re-dubbed water dispersible granules: multiple killing teichomycin 5%, and rotenone 2.5%, dispersant (D2001) 5%, wetting agent (D2002) 1%, binding agent (polyvinyl alcohol) 0.5%, surplus is filler (starch).
Embodiment 16
Multiple killing teichomycin and rotenone are re-dubbed missible oil: multiple killing teichomycin 30%, and rotenone 0.1%, emulsifier (weight ratio of agricultural newborn 500# and NP-10 is 3:1) 15%, surplus is dimethylbenzene.
Embodiment 17
Multiple killing teichomycin and rotenone are re-dubbed aqueous emulsion: multiple killing teichomycin 0.1%, and rotenone 2.5%, dimethylbenzene 10%, emulsifier (EW-01) 7%, thickener (0486) 7%, antifreezing agent (isopropyl alcohol) 6%, surplus is demineralized water.
Embodiment 18
Multiple killing teichomycin and rotenone are re-dubbed microemulsion: multiple killing teichomycin 5%, and rotenone 30%, emulsifier (502, the weight ratio of T60 and NP-10 be 1:0.5:4) 5%, dimethylbenzene 8%, antifreezing agent (ethanol) 3%, surplus is demineralized water.
Embodiment 19
Multiple killing teichomycin and rotenone are re-dubbed wetting powder: multiple killing teichomycin 30%, and rotenone 0.1%, emulsifier (0203B) 8%, wetting agent (K12) 2%, dispersant (white carbon) 5%, surplus is filler (fine particle calcium carbonate).
Embodiment 20
Multiple killing teichomycin and rotenone are re-dubbed water dispersible granules: multiple killing teichomycin 0.1%, and rotenone 30%, dispersant (D2001) 10%, wetting agent (D2002) 2%, binding agent (polyvinyl alcohol) 1%, surplus is filler (starch).
Experimental example 1
Press the prescription of above-described embodiment 1, be modulated into missible oil with conventional technique.Spray cucumber behind 2000～2500 times of the dilute with waters, the control cabbage caterpillar, two space-based instincts are eliminated insect pest after spraying, and control efficiency reaches 95%.Spray again two days later 1 time, increase output 20% than cucumber on every side after spraying.
Experimental example 2
Press the prescription of above-described embodiment 3, be modulated into microemulsion with conventional technique.Spray Chinese cabbage behind 2500～3000 times of the dilute with waters, the control diamond-back moth, three space-based instincts are eliminated insect pest after spraying, and control efficiency reaches 96%, and Chinese cabbage grows fine.
Experimental example 3
Press the prescription of above-described embodiment 7, be modulated into aqueous emulsion with conventional technique.Spray cowpea behind 2500～3000 times of the dilute with waters, the control beet armyworm, three space-based instincts are eliminated insect pest after spraying, and control efficiency reaches 95%.Spray again 1 time after spending three days, increase output 19% than cowpea on every side after spraying.
Experimental example 4
Press the prescription of above-described embodiment 10, be modulated into water dispersible granules with conventional technique.Spray paddy rice behind 2000～2500 times of the dilute with waters, control paddy rice rice leaf roller, three space-based instincts are eliminated insect pest after spraying, and control efficiency reaches 90%.Spray again 1 time after spending three days, increase output 10% than paddy rice on every side after spraying.
Experimental example 5
Press the prescription of above-described embodiment 12, be modulated into aqueous emulsion with conventional technique.Spray cauliflower behind 2000～2500 times of the dilute with waters, the control cabbage caterpillar, three space-based instincts are eliminated insect pest after spraying, and control efficiency reaches 95%, and cauliflower grows fine.
Experimental example 6
Press the prescription of above-described embodiment 14, be modulated into wetting powder with conventional technique.Spray leaf mustard behind 2500～3000 times of the dilute with waters, the control diamond-back moth, three space-based instincts are eliminated insect pest after spraying, and control efficiency reaches 93%, and leaf mustard grows fine.
Experimental example 7
Press the prescription of above-described embodiment 16, be modulated into missible oil with conventional technique.Spray cowpea behind 2500～3000 times of the dilute with waters, the control beet armyworm, three space-based instincts are eliminated insect pest after spraying, and control efficiency reaches 95%.Spray again 1 time after spending three days, increase output 15% than cowpea on every side after spraying.
Experimental example 8
Press the prescription of above-described embodiment 18, be modulated into microemulsion with conventional technique.Spray paddy rice behind 2000～2500 times of the dilute with waters, control paddy rice rice leaf roller, three space-based instincts are eliminated insect pest after spraying, and control efficiency reaches 95%.Spray again 1 time after spending three days, increase output 13% than paddy rice on every side after spraying.
Claims (6)
1. a Pesticidal combination that contains multiple killing teichomycin is characterized in that, comprises the composition of following percentage by weight: multiple killing teichomycin 0.1～30%, and matrine or rotenone 0.1～30%, surplus is the pesticidal preparations auxiliary element.
2. the Pesticidal combination that contains multiple killing teichomycin according to claim 1, it is characterized in that: the percentage by weight of described multiple killing teichomycin is 5%, the percentage by weight of matrine is 0.5%.
3. the Pesticidal combination that contains multiple killing teichomycin according to claim 1, it is characterized in that: the percentage by weight of described multiple killing teichomycin is 5%, the percentage by weight of rotenone is 2.5%.
4. each described Pesticidal combination that contains multiple killing teichomycin according to claim 1～3, it is characterized in that: described pesticidal preparations auxiliary element comprises auxiliary agent, all the other are solvent, demineralized water or filler, or the combination of solvent and demineralized water; Described auxiliary agent comprises one or more the combination in emulsifier, thickener, antifreezing agent, wetting agent, dispersant, the binding agent.
5. the Pesticidal combination that contains multiple killing teichomycin according to claim 4, it is characterized in that: the percentage by weight of described auxiliary agent is 5～20%.
6. the Pesticidal combination that contains multiple killing teichomycin according to claim 5, it is characterized in that: described Pesticidal combination can be prepared as missible oil, aqueous emulsion, microemulsion, wetting powder or water dispersible granules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105872182A CN103053551A (en) | 2012-12-28 | 2012-12-28 | Spinosad-containing insecticidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105872182A CN103053551A (en) | 2012-12-28 | 2012-12-28 | Spinosad-containing insecticidal composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103053551A true CN103053551A (en) | 2013-04-24 |
Family
ID=48096697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012105872182A Pending CN103053551A (en) | 2012-12-28 | 2012-12-28 | Spinosad-containing insecticidal composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103053551A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103404521A (en) * | 2013-08-16 | 2013-11-27 | 丹阳市金色田野蔬菜有限公司 | Seed treatment agent |
| CN106719846A (en) * | 2016-11-22 | 2017-05-31 | 恒大园林集团有限公司 | A kind of complex ecological agricultural chemicals and preparation method thereof |
| CN107683864A (en) * | 2017-10-17 | 2018-02-13 | 张颂忠 | Containing the composition pesticide for killing white butterfly element |
| CN115039781A (en) * | 2022-06-14 | 2022-09-13 | 沈阳化工大学 | Insecticidal composition containing spinosad and matrine and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1309910A (en) * | 2001-02-20 | 2001-08-29 | 华南农业大学 | Mixed rotenone preparation |
| CN102669124A (en) * | 2012-05-22 | 2012-09-19 | 江苏省绿盾植保农药实验有限公司 | Biological source compound insecticide and application thereof |
-
2012
- 2012-12-28 CN CN2012105872182A patent/CN103053551A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1309910A (en) * | 2001-02-20 | 2001-08-29 | 华南农业大学 | Mixed rotenone preparation |
| CN102669124A (en) * | 2012-05-22 | 2012-09-19 | 江苏省绿盾植保农药实验有限公司 | Biological source compound insecticide and application thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103404521A (en) * | 2013-08-16 | 2013-11-27 | 丹阳市金色田野蔬菜有限公司 | Seed treatment agent |
| CN106719846A (en) * | 2016-11-22 | 2017-05-31 | 恒大园林集团有限公司 | A kind of complex ecological agricultural chemicals and preparation method thereof |
| CN107683864A (en) * | 2017-10-17 | 2018-02-13 | 张颂忠 | Containing the composition pesticide for killing white butterfly element |
| CN115039781A (en) * | 2022-06-14 | 2022-09-13 | 沈阳化工大学 | Insecticidal composition containing spinosad and matrine and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102349539B (en) | Insecticidal composition containing lythidathion and antibiotic compound | |
| CN102640762A (en) | Hot fogging concentrate containing acetamiprid | |
| CN102057941A (en) | Pesticidal compound composite containing dinotefuran | |
| CN102805088A (en) | Insecticidal composition as well as preparation and application thereof | |
| CN101305723B (en) | Insecticidal composition containing spinosad and its use | |
| CN105028470A (en) | Nematicidal composition containing fosthiazate and application thereof | |
| CN105941451A (en) | Insecticide composition containing chromafenozide and neonicotinoid | |
| CN101317572B (en) | Mixed plant source insecticide | |
| CN103283767A (en) | Spirotetramat-containing pesticidal composition | |
| CN103053551A (en) | Spinosad-containing insecticidal composition | |
| CN104970038B (en) | A kind of composition pesticide | |
| CN105145663A (en) | Botanical pesticide composition containing azadirachtin and eucalyptus oil | |
| CN100411523C (en) | Compound pesticide of triperygium wilfordii alkaloid | |
| CN103053569A (en) | Tolfenpyrad-containing insecticidal composition | |
| CN101485329B (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN103039526B (en) | Disinsection composition containing larvatrol | |
| CN109717216A (en) | It is a kind of to utilize garlic, capsicum, Chinese prickly ash, the sterilization and disinfestation agent of ginger extract | |
| CN101578990A (en) | Compound preparation of spiromesifen and antibiotic pesticide | |
| CN103300021B (en) | A kind of ring tebufenozide and the composition pesticide of biogenic substances | |
| CN101796962B (en) | Insecticidal composition containing clothianidin and malathion | |
| CN103404531A (en) | Biological compound insecticide containing toosedarin and imidacloprid and preparation method and application thereof | |
| CN104522006B (en) | A kind of preventing and treating Lepidoptera and homoptera pest compositions | |
| CN102318636A (en) | A kind of Synergistic insecticidal compositions | |
| CN101524080A (en) | Indoxacarb and pymetozine insecticide composition | |
| CN103621543A (en) | Synergistic insecticidal composition containing dinotefuran and clothianidin and applications thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130424 |