CN103045360A - Cigarette filter stick essence capsule, method for preparing same and cigarette - Google Patents
Cigarette filter stick essence capsule, method for preparing same and cigarette Download PDFInfo
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- CN103045360A CN103045360A CN2012105189148A CN201210518914A CN103045360A CN 103045360 A CN103045360 A CN 103045360A CN 2012105189148 A CN2012105189148 A CN 2012105189148A CN 201210518914 A CN201210518914 A CN 201210518914A CN 103045360 A CN103045360 A CN 103045360A
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- filter stick
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- cigarette
- essence capsule
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Abstract
The invention discloses a cigarette filter stick essence capsule, a method for preparing the same and a cigarette. The cigarette filter stick essence capsule comprises dried calcium alginate gel beads and a polyelectrolyte film which wraps the dried calcium alginate gel beads. The method comprises the following steps that: cigarette essence is taken as a main raw material, auxiliary raw materials of calcium chloride, tween, span and the like and a sodium alginate aqueous solution with an appropriate concentration are added, the following methods are used to prepare the capsule: the core material components of the cigarette essence, the calcium chloride, the tween, the span and the like are mixed and stirred to form emulsion, the emulsion is dropped into the sodium alginate aqueous solution to react for a certain time, and after washing and two times of curing, the essence capsule which is solid but not tough and easy to break is formed after drying. A cigarette filter stick comprises the essence capsule. Compared with the prior art, the essence capsule has the advantages of difficulty in deterioration and volatilization and long guarantee period; and the method has the beneficial effects of simplicity in technology and high production efficiency.
Description
Technical field
The present invention relates to a kind of cigarette filter stick essence capsule and preparation method thereof and a kind of cigarette.
Background technology
The effect of perfuming cigarette is to improve the physicochemical property of cigarette, mellow and full fragrance, modifies cigarette perfume, improves and inhale flavor, and the style of establishing product, affects to a certain extent human consumer's sense of smell, the sense of taste and sense of touch, the acceptability of enhancement product.Existing perfuming method is mainly directly and adds essence in pipe tobacco, or adds the fragrant line with essence in filter tip.The total shortcoming of these two kinds of methods is: the essence residence time is shorter, and the cigarette quality guaranteed period is short, and essence discharges inhomogeneous.
Summary of the invention
One of technical problem to be solved by this invention provides a kind of cigarette filter stick essence capsule, and this capsule is for being positioned in the cigarette filter stick, and its fragrance matter only just begins to discharge after crowded breaking before suction, can effectively prolong the retention period of essence.
Above-mentioned technical problem of the present invention is solved by following technique means:
A kind of cigarette filter stick essence capsule comprises dry calcium alginate gel beads, contains essence in the described calcium alginate gel beads; Also comprise the polyelectrolyte film that coats described calcium alginate gel beads.
Preferably, described polyelectrolyte film is the polyelectrolyte film that amino on the chitosan molecule chain and the carboxyl generation electrostatic interaction on the alginate calcium molecular chain form.
Compared with prior art, the essence capsule of technique scheme is that the type capsule is broken in a kind of brand-new squeezing, that is: owing to utilize chitosan to form one deck polyelectrolyte film on the calcium alginate gel beads surface, this membrane gel beads can effectively be avoided the volatilization of fragrance matter before suction, this capsule can be squeezed broken before the cigarette suction easily simultaneously, so that fragrance only begins to discharge, therefore, can effectively solve fragrance volatilizing and responsive spices spoilage problems when suction.
Another technical problem to be solved by this invention provides a kind of preparation method of cigarette filter stick essence capsule, and a kind of cigarette.
Above-mentioned technical problem of the present invention is solved by following technique means:
A kind of preparation method of cigarette filter stick essence capsule is characterized in that, may further comprise the steps:
1) it is for subsequent use to make respectively following preparation:
Emulsion: in calcium chloride water, add tween 80 and Si Ban 80, after stirring, add thickening material and dissolving, then under whipped state, add essence, form thick emulsion; The content of calcium chloride is 0.16%-5% in this emulsion, and the content of tween 80 and Si Ban 80 is respectively 0.1%-3%, and the content of thickening material is 0.03%-1%, and essence content is 16%-80%, and described content is mass percent;
Sodium alginate aqueous solution: massfraction is the sodium alginate aqueous solution of 0.5%-2.5%;
The first solid solution: massfraction is the calcium chloride water of 1%-20%;
The second solid solution: massfraction is the chitosan acidic aqueous solution of 0.2%-1%;
2) encystation: described emulsion is splashed in the described sodium alginate aqueous solution, form calcium alginate gel beads, stir and solidified 10-30 minute;
3) after the calcium alginate gel beads after stirring is solidified curing: with step 2) is used the clear water rinsing, put into the first solid solution curing 10-30 minute; Then the calcium alginate gel beads after solidifying in the first solid solution being put into described the second solid solution solidified 10-30 minute;
4) drying: behind the calcium alginate gel beads natural air drying that is cured in the step 3), place 30-50 ℃ of environment oven dry to obtain the cigarette filter stick essence capsule in 2-5 hour.
Compared with prior art, the prepared cigarette filter stick essence capsule of preparation method of the present invention is a kind of essence capsule that squeezes broken type, it not only has the beneficial effect that can effectively solve fragrance volatilizing and responsive spices spoilage problems that aforementioned cigarette filter stick essence capsule possesses, but also have following further effect: the emulsion among this preparation method is based on its viscosity, flowability and chemical property, in the encystation step, this emulsion splashes in the sodium alginate soln can instantaneous gelation, form the reticulated structure of complete polymerization, need not to utilize complicated equipment also to need not to adopt complicated step, preparation section is simple, and prepared gel beads granule type is good; The first solid solution further solidifies the gel beads appearance, and after the second solid solution solidify to form polyelectrolyte film, adopt the drying mode that reheats oven dry behind the first natural air drying, can guarantee that prepared essence capsule quality is hard and not tough, thereby can be squeezed broken easily, guarantee the timely release of fragrance matter.
Preferably, described thickening material is xanthan gum.It is little that the xanthan gum that this preferred version adopts has an addition, the advantage that thickening effectiveness is good, and physico-chemical property is stable, also need not to heat.
Preferably, contain the acetic acid that massfraction is 0.3%-1.5% in the described solid solution.Adopt acidifying with acetic acid solution to increase the solubleness of chitosan and since acetic acid this as edible material, have toxicological harmless, have no side effect a bit.
Preferably, described step 2) the middle peristaltic pump coutroi velocity that adopts, described emulsion is splashed in the described sodium alginate aqueous solution, flow velocity preferably is controlled in the 1-2mL/min.This preferred version can be enhanced productivity, and can guarantee the even of capsule grain diameter by flow rate control simultaneously, and particle diameter preferably is controlled between the 2.5-3.5mm, and positive negative error can be controlled within the 0.1mm.
Preferably, the time of described natural air drying was greater than 12 hours.
A kind of cigarette filter stick essence capsule, this cigarette filter stick essence capsule are the cigarette filter stick essence capsule of the described method preparation of aforementioned any one.
A kind of cigarette comprises cigarette filter stick, is placed with aforesaid cigarette filter stick essence capsule in the described cigarette filter stick.
Embodiment
Below in conjunction with preferred embodiment the invention will be further described.
Present embodiment provides a kind of cigarette filter stick essence capsule, comprises dry calcium alginate gel beads, contains essence in this calcium alginate gel beads; The outside surface of this calcium alginate gel beads is coated with polyelectrolyte film; Wherein, described polyelectrolyte film is the polyelectrolyte film that amino on the chitosan molecule chain and the carboxyl generation electrostatic interaction on the alginate calcium molecular chain form.This polyelectrolyte film can prevent the spices volatilization in the calcium alginate gel beads or go bad before suction, can be squeezed easily before suction simultaneously and break, thereby make spices begin release in suction the time.
Present embodiment also provides a kind of preparation method of cigarette filter stick essence capsule, may further comprise the steps:
1) it is for subsequent use to make respectively following preparation:
Emulsion: in calcium chloride water, add tween 80 and Si Ban 80, after stirring, add thickening material and dissolving, then under whipped state, add essence, form thick emulsion; The content of calcium chloride is 0.16%-5% in this emulsion, the content of tween 80 and Si Ban 80 is respectively 0.1%-3%, the content of thickening material is 0.03%-1%, easily cause too thickness of emulsion greater than this content ratio, thickening material less than this content then can cause emulsion excessively rare, finally all can cause encystation step dropping liquid restive; Essence content is 16%-80%, and described content is mass percent;
Sodium alginate aqueous solution: massfraction is the sodium alginate aqueous solution of 0.5%-2.5%, also can add an amount of dyestuff in this sodium alginate aqueous solution in the practice, for example: the light blue of 0.03%-0.3%;
The first solid solution: massfraction is the calcium chloride water of 1%-20%;
The second solid solution: massfraction is the chitosan acidic aqueous solution of 0.2%-1%, and the acidic component in this aqueous solution is preferably the acetic acid that massfraction is 0.3%-1.5%;
2) encystation: described emulsion is splashed in the described sodium alginate aqueous solution, form calcium alginate gel beads, stir and solidified 10-30 minute, can adopt existing dropper to carry out the dropping liquid encystation in this step, the preferred peristaltic pump coutroi velocity that adopts carries out dropping liquid, and flow rate control is at 1-2mL/min;
3) after the calcium alginate gel beads after stirring is solidified curing: with step 2) is used the clear water rinsing, put into the first solid solution curing 10-30 minute; Then the calcium alginate gel beads after solidifying in the first solid solution being put into described the second solid solution solidified 10-30 minute, in this step, if set time was greater than 30 minutes, then can cause the polyelectrolyte film thickness excessive, less than 10 minutes then excessively thin, all can be so that final can't produce heavily fortified point and not tough effect;
4) drying: behind the calcium alginate gel beads natural air drying that is cured in the step 3), air-dry time is preferably greater than 12 hours, places 30-50 ℃ of environment oven dry to obtain the cigarette filter stick essence capsule in 2-5 hour.
Utilize the cigarette filter stick essence capsule of aforesaid method preparation, except aforementioned control advantage to spices release, also have heavily fortified point and not tough physical properties, squeezed broken easily, and break up rear one-tenth powder state, so that spices fully discharges when suction.
For further illustrating above-mentioned embodiment, hereinafter provide a plurality of preferred specific embodiments:
Embodiment 1
Take by weighing 0.1g calcium chloride, add 5mL water, after the dissolving, add 0.03g tween 80 and Si Ban 80 fully, after stirring, add the 0.01g xanthan gum, after the dissolving, under whipped state, add 5g essence fully, make the essence emulsion.
Take by weighing the 0.5g sodium alginate, add in the 100mL water, after the dissolving, add 0.03g light blue dyestuff fully, make sodium alginate aqueous solution.
Take by weighing 5g calcium chloride, add 100mL water, make solid solution 1.
Take by weighing 0.3g acetic acid, add 100mL water, after stirring, add the 0.2g chitosan, make solid solution 2.
Use the peristaltic pump coutroi velocity, emulsion is splashed in the sodium alginate aqueous solution, form immediately calcium alginate gel beads, stir and solidified 10 minutes.
After the gel beads usefulness clear water rinsing of stirring after solidifying, put into solid solution 1 and solidified 10 minutes; After the clear water rinsing is clean, puts into solid solution 2 and solidified 10 minutes.
After transparent, 30 ℃ of oven dry 5 hours both must have been squeezed brokenly type cigarette filter stick essence capsule with the gel beads natural air drying that is cured.
Embodiment 2
Take by weighing 0.2g calcium chloride, add 5mL water, after the dissolving, add 0.04g tween 80 and Si Ban 80 fully, after stirring, add the 0.02g xanthan gum, after the dissolving, under whipped state, add 8g essence fully, make the essence emulsion.
Take by weighing the 0.7g sodium alginate, add in the 100mL water, after the dissolving, add 0.06g light blue dyestuff fully, make sodium alginate aqueous solution.
Take by weighing 8g calcium chloride, add 100mL water, make solid solution 1.
Take by weighing 0.5g acetic acid, add 100mL water, after stirring, add the 0.4g chitosan, make solid solution 2.
Use the peristaltic pump coutroi velocity, emulsion is splashed in the sodium alginate aqueous solution, form immediately calcium alginate gel beads, stir and solidified 15 minutes.
After the gel beads usefulness clear water rinsing of stirring after solidifying, put into solid solution 1 and solidified 15 minutes; After the clear water rinsing is clean, puts into solid solution 2 and solidified 15 minutes.
After the gel beads natural air drying that is cured is extremely transparent, dried 5 hours for 40 ℃, namely get and squeeze broken type cigarette filter stick essence capsule.
Embodiment 3
Take by weighing 0.3g calcium chloride, add 5mL water, after the dissolving, add 0.05g tween 80 and Si Ban 80 fully, after stirring, add the 0.05g xanthan gum, after the dissolving, under whipped state, add 10g essence fully, make the essence emulsion.
Take by weighing the 0.8g sodium alginate, add in the 100mL water, after the dissolving, add 0.1g light blue dyestuff fully, make sodium alginate aqueous solution.
Take by weighing 10g calcium chloride, add 100mL water, make solid solution 1.
Take by weighing 0.8g acetic acid, add 100mL water, after stirring, add the 0.6g chitosan, make solid solution 2.
Use the peristaltic pump coutroi velocity, emulsion is splashed in the sodium alginate aqueous solution, form immediately calcium alginate gel beads, stir and solidified 15 minutes.
After the gel beads usefulness clear water rinsing of stirring after solidifying, put into solid solution 1 and solidified 15 minutes; After the clear water rinsing is clean, puts into solid solution 2 and solidified 15 minutes.
After the gel beads natural air drying that is cured is extremely transparent, dried 5 hours, both must squeeze brokenly type cigarette filter stick essence capsule for 40 ℃.
Above content is the further description of the present invention being done in conjunction with concrete preferred implementation, can not assert that implementation of the present invention is confined to these explanations.For those skilled in the art, without departing from the inventive concept of the premise, can also make some being equal to substitute or obvious modification, and performance or purposes are identical, all should be considered as belonging to protection scope of the present invention.
Claims (10)
1. a cigarette filter stick essence capsule is characterized in that: comprise dry calcium alginate gel beads, contain essence in the described calcium alginate gel beads; The polyelectrolyte film that also comprises the described calcium alginate gel beads of coating that utilizes chitosan formation.
2. cigarette filter stick essence capsule according to claim 1 is characterized in that: described polyelectrolyte film is the polyelectrolyte film that amino on the chitosan molecule chain and the carboxyl generation electrostatic interaction on the alginate calcium molecular chain form.
3. the preparation method of a cigarette filter stick essence capsule is characterized in that, may further comprise the steps:
1) it is for subsequent use to make respectively following preparation:
Emulsion: in calcium chloride water, add tween 80 and Si Ban 80, after stirring, add thickening material and dissolving, then under whipped state, add essence, form thick emulsion; The content of calcium chloride is 0.16%-5% in this emulsion, and the content of tween 80 and Si Ban 80 is respectively 0.1%-3%, and the content of thickening material is 0.03%-1%, and essence content is 16%-80%, and described content is mass percent;
Sodium alginate aqueous solution: massfraction is the sodium alginate aqueous solution of 0.5%-2.5%;
The first solid solution: massfraction is the calcium chloride water of 1%-20%;
The second solid solution: massfraction is the chitosan acidic aqueous solution of 0.2%-1%;
2) encystation: described emulsion is splashed in the described sodium alginate aqueous solution, form calcium alginate gel beads, stir and solidified 10-30 minute;
3) after the calcium alginate gel beads after stirring is solidified curing: with step 2) is used the clear water rinsing, put into the first solid solution curing 10-30 minute; Then the calcium alginate gel beads after solidifying in the first solid solution being put into described the second solid solution solidified 10-30 minute;
4) drying: behind the calcium alginate gel beads natural air drying that is cured in the step 3), place 30-50 ℃ of environment oven dry to obtain the cigarette filter stick essence capsule in 2-5 hour.
4. the preparation method of cigarette filter stick essence capsule according to claim 3 is characterized in that, described thickening material is xanthan gum.
5. the preparation method of cigarette filter stick essence capsule according to claim 3 is characterized in that, contains the acetic acid that massfraction is 0.3%-1.5% in described the second solid solution.
6. the preparation method of described cigarette filter stick essence capsule according to claim 3 is characterized in that described step 2) in adopt the peristaltic pump coutroi velocity, described emulsion is splashed in the described sodium alginate aqueous solution.
7. the preparation method of described cigarette filter stick essence capsule according to claim 3 is characterized in that the natural air drying duration was greater than 12 hours in the described drying step.
8. the preparation method of described cigarette filter stick essence capsule according to claim 6 is characterized in that described flow velocity is 1-2ml/min.
9. cigarette filter stick essence capsule is characterized in that: this cigarette filter stick essence capsule is the cigarette filter stick essence capsule of the described method preparation of claim 3-8 any one.
10. a cigarette comprises cigarette filter stick, it is characterized in that: be placed with cigarette filter stick essence capsule claimed in claim 9 in the described cigarette filter stick.
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| CN2012105189148A CN103045360A (en) | 2012-12-06 | 2012-12-06 | Cigarette filter stick essence capsule, method for preparing same and cigarette |
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| CN2012105189148A CN103045360A (en) | 2012-12-06 | 2012-12-06 | Cigarette filter stick essence capsule, method for preparing same and cigarette |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103233397A (en) * | 2013-04-18 | 2013-08-07 | 湖北中烟工业有限责任公司 | Reversible temperature-sensitive cigarette packing paper preparation method |
| CN103271424A (en) * | 2013-05-28 | 2013-09-04 | 上海交通大学 | Preparing method of fragrant microcapsule |
| CN103584276A (en) * | 2013-11-13 | 2014-02-19 | 川渝中烟工业有限责任公司 | Ambergris cigarette and ambergris spices |
| CN105520191A (en) * | 2015-12-29 | 2016-04-27 | 东莞波顿香料有限公司 | Capsule for cigarette and preparing method of capsule |
| CN105628553A (en) * | 2015-12-22 | 2016-06-01 | 贵州中烟工业有限责任公司 | Method for judging use end point of film forming liquid |
| CN108013507A (en) * | 2017-12-05 | 2018-05-11 | 武汉黄鹤楼新材料科技开发有限公司 | A kind of cigarette dripping pill and preparation method |
| CN110074456A (en) * | 2019-05-24 | 2019-08-02 | 江南大学 | A kind of peppermint oil gel beads and preparation method thereof |
| CN110584194A (en) * | 2019-09-25 | 2019-12-20 | 湖北中烟工业有限责任公司 | Preparation method of coffee-flavor blasting bead for cigarettes |
| CN110584196A (en) * | 2019-10-21 | 2019-12-20 | 上海康舍医疗器械有限公司 | Preparation method of blasting bead with essential oil components |
| CN110652029A (en) * | 2019-09-25 | 2020-01-07 | 湖北中烟工业有限责任公司 | Preparation method and method of lemon mint flavor type blasting bead for cigarettes |
| CN111019158A (en) * | 2019-12-11 | 2020-04-17 | 山东将军烟草新材料科技有限公司 | Solid water and preparation method and application thereof |
| CN111436651A (en) * | 2019-01-16 | 2020-07-24 | 深圳波顿香料有限公司 | Blasting bead for cigarette and preparation method thereof |
| CN113101880A (en) * | 2021-04-08 | 2021-07-13 | 武汉黄鹤楼香精香料有限公司 | Water-soluble dripping pill prepared by crosslinking technology and preparation method thereof |
| CN114903205A (en) * | 2022-05-07 | 2022-08-16 | 江苏万腾新材料科技有限公司 | Plant essential oil flavored capsule and preparation method thereof |
| CN116172154A (en) * | 2022-12-21 | 2023-05-30 | 曲靖师范学院 | Ginger pungency removing process |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101972619A (en) * | 2010-09-01 | 2011-02-16 | 浙江中烟工业有限责任公司 | Preparation method of menthol microcapsules |
| CN102140387A (en) * | 2011-01-20 | 2011-08-03 | 深圳市如烟生物科技有限公司 | Method for preparing microcapsule essence for cigarette |
| CN102626603A (en) * | 2012-03-30 | 2012-08-08 | 中国海洋大学 | Method for preparing carboxymethyl chitosan composite nanocapsules |
| CN102653704A (en) * | 2011-03-04 | 2012-09-05 | 上海爱普植物科技有限公司 | Preparation method of small peppermint essence soft capsule taking calcium alginate as wall material |
| CN102784600A (en) * | 2012-08-04 | 2012-11-21 | 盐城工学院 | Preparation method of lutein microcapsule |
-
2012
- 2012-12-06 CN CN2012105189148A patent/CN103045360A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101972619A (en) * | 2010-09-01 | 2011-02-16 | 浙江中烟工业有限责任公司 | Preparation method of menthol microcapsules |
| CN102140387A (en) * | 2011-01-20 | 2011-08-03 | 深圳市如烟生物科技有限公司 | Method for preparing microcapsule essence for cigarette |
| CN102653704A (en) * | 2011-03-04 | 2012-09-05 | 上海爱普植物科技有限公司 | Preparation method of small peppermint essence soft capsule taking calcium alginate as wall material |
| CN102626603A (en) * | 2012-03-30 | 2012-08-08 | 中国海洋大学 | Method for preparing carboxymethyl chitosan composite nanocapsules |
| CN102784600A (en) * | 2012-08-04 | 2012-11-21 | 盐城工学院 | Preparation method of lutein microcapsule |
Non-Patent Citations (2)
| Title |
|---|
| 张志辰等: "壳聚糖-海藻酸钠液芯微胶囊机械强度优化研究", 《江苏农业科学》 * |
| 赵彬然等: "壳聚糖/海藻酸钙微胶囊的通透性能", 《化工进展》 * |
Cited By (20)
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|---|---|---|---|---|
| CN103233397A (en) * | 2013-04-18 | 2013-08-07 | 湖北中烟工业有限责任公司 | Reversible temperature-sensitive cigarette packing paper preparation method |
| CN103271424A (en) * | 2013-05-28 | 2013-09-04 | 上海交通大学 | Preparing method of fragrant microcapsule |
| CN103271424B (en) * | 2013-05-28 | 2015-08-12 | 上海交通大学 | A kind of preparation method of essence microcapsule |
| CN103584276A (en) * | 2013-11-13 | 2014-02-19 | 川渝中烟工业有限责任公司 | Ambergris cigarette and ambergris spices |
| CN103584276B (en) * | 2013-11-13 | 2015-05-20 | 川渝中烟工业有限责任公司 | Ambergris cigarette and ambergris spices |
| CN105628553B (en) * | 2015-12-22 | 2020-08-07 | 贵州中烟工业有限责任公司 | Method for judging use end point of film-forming solution |
| CN105628553A (en) * | 2015-12-22 | 2016-06-01 | 贵州中烟工业有限责任公司 | Method for judging use end point of film forming liquid |
| CN105520191A (en) * | 2015-12-29 | 2016-04-27 | 东莞波顿香料有限公司 | Capsule for cigarette and preparing method of capsule |
| CN108013507B (en) * | 2017-12-05 | 2020-05-26 | 武汉黄鹤楼新材料科技开发有限公司 | Dropping pill for cigarette and preparation method thereof |
| CN108013507A (en) * | 2017-12-05 | 2018-05-11 | 武汉黄鹤楼新材料科技开发有限公司 | A kind of cigarette dripping pill and preparation method |
| CN111436651A (en) * | 2019-01-16 | 2020-07-24 | 深圳波顿香料有限公司 | Blasting bead for cigarette and preparation method thereof |
| CN110074456A (en) * | 2019-05-24 | 2019-08-02 | 江南大学 | A kind of peppermint oil gel beads and preparation method thereof |
| CN110584194A (en) * | 2019-09-25 | 2019-12-20 | 湖北中烟工业有限责任公司 | Preparation method of coffee-flavor blasting bead for cigarettes |
| CN110652029A (en) * | 2019-09-25 | 2020-01-07 | 湖北中烟工业有限责任公司 | Preparation method and method of lemon mint flavor type blasting bead for cigarettes |
| CN110652029B (en) * | 2019-09-25 | 2022-03-04 | 湖北中烟工业有限责任公司 | Preparation method and method of lemon mint flavor type blasting bead for cigarettes |
| CN110584196A (en) * | 2019-10-21 | 2019-12-20 | 上海康舍医疗器械有限公司 | Preparation method of blasting bead with essential oil components |
| CN111019158A (en) * | 2019-12-11 | 2020-04-17 | 山东将军烟草新材料科技有限公司 | Solid water and preparation method and application thereof |
| CN113101880A (en) * | 2021-04-08 | 2021-07-13 | 武汉黄鹤楼香精香料有限公司 | Water-soluble dripping pill prepared by crosslinking technology and preparation method thereof |
| CN114903205A (en) * | 2022-05-07 | 2022-08-16 | 江苏万腾新材料科技有限公司 | Plant essential oil flavored capsule and preparation method thereof |
| CN116172154A (en) * | 2022-12-21 | 2023-05-30 | 曲靖师范学院 | Ginger pungency removing process |
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Application publication date: 20130417 |