CN102925013A - PVC (polyvinyl chloride) coating for plastic-coated fabric - Google Patents
PVC (polyvinyl chloride) coating for plastic-coated fabric Download PDFInfo
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- CN102925013A CN102925013A CN2012104592682A CN201210459268A CN102925013A CN 102925013 A CN102925013 A CN 102925013A CN 2012104592682 A CN2012104592682 A CN 2012104592682A CN 201210459268 A CN201210459268 A CN 201210459268A CN 102925013 A CN102925013 A CN 102925013A
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Abstract
The invention relates to a PVC (polyvinyl chloride) coating for plastic-coated fabric. The PVC coating is prepared from the following raw materials by weight portion: 92-115 portions of PVC resin, 54-70 portions of epoxy vegetable oil, 2.5-5 portions of environment-friendly stabilizer, 3-5.5 portions of environment-friendly plasticizer, 6-15 portions of white oil, 1-3 portions of viscosity reducer, 1.5-3.5 portions of fire retardant, 30-55 portions of liquid paraffin, 25-45 portions of light calcium carbonate and 15-30 portions of mountain flour, wherein the environment-friendly stabilizer is a stabilizer without lead salt and cadmium soap type components, and the environment-friendly plasticizer is a plasticizer without phthalic acid ester type components. The PVC plastic-coated fabric produced by the coating has the following advantages that the toxicity is low, the environment is protected, and producers, users and the natural environment are better protected; when the PVC plastic-coated fabric meets fire, a lot of smoke cannot be generated, and a fire source can be put out and escape is easier; the PVC plastic-coated fabric has good hand feeling and is non-sticky, and the surface is bright and clean; and the PVC plastic-coated fabric is more competitive in the market.
Description
Technical field
The present invention relates to a kind of PVC plastic-coated fabric coating.
Background technology
Polyvinyl chloride (PVC) RESINS (PVC) plastic-coated fabric has the advantages such as waterproof, mildew-resistant, low-temperature pliability, high strength, nonflammable, weather variation, has been widely used in the industrial or agricultural field.
Along with environmental consciousness is day by day strengthened, people have higher requirement to the environment friendly of PVC plastic-coated fabric.The toxicity of PVC plastic-coated fabric is mainly derived from plastic-coated fabric coating.But the PVC plastic-coated fabric of traditional coating prescription production has the following disadvantages: the stablizer that contains lead salt and cadmium soap constituents easily moves to product surface, enters by all means human body and nature, is detrimental to health, and pollutes physical environment; The softening agent that contains the phthalate composition has carinogenicity, enters behind the human body very big to human health damage; Halogen flame discharges large measurer pungency and corrodibility smog when meeting fire, increase danger, pollutes living environment; Bad, the easy adhesion of product surface feel, bright and clean not.
Summary of the invention
The technical problem to be solved in the present invention is the above-mentioned deficiency for prior art, a kind of eco-friendly PVC plastic-coated fabric coating is provided, PVC plastic-coated fabric toxicity with coating material production of the present invention is little, safer, good hand touch, adhesion, any surface finish, environmental friendliness, more can need by satisfying the market.
In order to solve the problems of the technologies described above, the technical scheme that the present invention takes is:
A kind of PVC plastic-coated fabric coating, it is comprised of several raw materials of following weight: polyvinyl chloride resin 92 ~ 115, epoxidized vegetable oil 54 ~ 70, environment-friendly stabilizer 2.5 ~ 5, environment-friendly type softening agent 3 ~ 5.5, white oil 6 ~ 15, viscosity-depression agent 1 ~ 3, fire retardant 1.5 ~ 3.5, whiteruss 30 ~ 55, light calcium carbonate 25 ~ 45, stone flour 15 ~ 30.
Above-mentioned PVC plastic-coated fabric coating, it comprises that also massfraction is 9～24 pigment dyestuff.
OnThe PVC plastic-coated fabric coating of stating, the parts by weight of each raw material are preferably: polyvinyl chloride resin 95 ~ 105, epoxy soybean oil 57 ~ 65, stablizer 3 ~ 4.5, softening agent 3.5 ~ 5, white oil 9 ~ 12, viscosity-depression agent 1.5 ~ 2.5, fire retardant 1.8 ~ 3, whiteruss 35 ~ 45, light calcium carbonate 30 ~ 40, stone flour 18 ~ 25, pigment dyestuff 10 ~ 22.
Above-mentioned PVC plastic-coated fabric coating, the parts by weight of each raw material are: polyvinyl chloride resin 100, epoxy soybean oil 60, stablizer 4, softening agent 4, white oil 10, viscosity-depression agent 2, fire retardant 2, whiteruss 40, light calcium carbonate 35, stone flour 20, pigment dyestuff 20.
OnThe polyvinyl chloride resin of stating is selected acceptable end product polyvinyl chloride resin, and its vinyl chloride monomer content is not more than 0.001%, or premium grads polyvinyl chloride resin, and its vinyl chloride monomer content is not more than 0.0005%.
Above-mentioned epoxidized vegetable oil is epoxy rapeseed oil or epoxy cottonseed oil or epoxy soybean oil or epoxy sweet oil or epoxy oleum lini or epoxy peanut oil or epoxy palm oil or epoxy tea oil.
Above-mentioned environment-friendly stabilizer is the stablizer that does not contain lead salt and cadmium soap composition, as: calcium/zinc composite stabilizer or potassium/zinc composite stabilizer or calcium/magnesium/zinc composite stabilizer or magnesium/zinc composite stabilizer.
Above-mentioned environment-friendly type softening agent is the softening agent that does not contain the phthalate composition, as: acetyl triethyl citrate or trioctyl lemon acid or ATOC or tributyl citrate or tributyl acetylcitrate.
OnThe viscosity-depression agent of stating is butyl stearate or stearylamide or ethyl silicon oil.
Above-mentioned fire retardant is phosphorus-nitrogen expanding fire retardant.
A kind of as follows with the preparation method of coating for above-mentioned PVC plastic-coated fabric:
Epoxy oleum lini, environment-friendly stabilizer, environment-friendly type softening agent, white oil, viscosity-depression agent, fire retardant are rendered in the agitation vat, under room temperature (20 ~ 40 ℃), stirred; Then add whiteruss, polyvinyl chloride resin, light calcium carbonate, stone flour, pigment dyestuff and be stirred to homogeneous slurry; Grind finally by three-roll grinder, the particulate matter in the slurries is ground namely get coating.
The PVC plastic-coated fabric of coating material production of the present invention is different from the PVC plastic-coated fabric that traditional coating is produced, its advantage and beneficial effect:
1. the little or nontoxic raw material of coating selection toxicity of the present invention, the PVC plastic-coated fabric toxicity of production is little, environmental friendliness, has protected better the producer, user and physical environment.
2. the phosphorus-nitrogen expanding fire retardant that uses in the coating of the present invention, produce without a large amount of smog when meeting fire, more be conducive to put out burning things which may cause a fire disaster and escape.
3. used viscosity-depression agent in the coating of the present invention, plastic-coated fabric good hand touch, adhesion, any surface finish produced have more the market competitiveness.
Embodiment
Below by embodiment the present invention is described further, but the present invention not only is confined to following examples.
Embodiment 1
Be that 55 parts epoxy oleum lini, calcium/magnesium of 2.6 parts/zinc composite stabilizer, 3.2 parts acetyl triethyl citrate, 7 parts white oil, 1.2 parts butyl stearate, 1.8 parts fire retardant are rendered in the agitation vat with weight, under room temperature (20 ~ 40 ℃), stir; Then add weight and be 45 parts whiteruss, 95 parts acceptable end product polyvinyl chloride resin, 26 parts light calcium carbonate, 17 parts stone flour, 10 parts pigment dyestuff and be stirred to homogeneous slurry; Grind finally by three-roll grinder, the particulate matter in the slurries is ground namely get coating.Coating is inputted the plastic-coated streamline use, this coating was at room temperature deposited 0 ~ 720 hour, still can guarantee good processing characteristics.
Embodiment 2
Be that 68 parts epoxy sweet oil, 4.8 parts of potassium/zinc composite stabilizers, 5.2 parts tributyl acetylcitrate, 14 parts white oil, 2.8 parts of stearic amides, 3.2 parts fire retardant are rendered in the agitation vat with weight, at room temperature stir; Then add weight and be 53 parts whiteruss, 114 parts premium grads polyvinyl chloride resin, 43 parts light calcium carbonate, 28 parts stone flour and be stirred to homogeneous slurry; Grind finally by three-roll grinder, the particulate matter in the slurries is ground namely get coating.Coating is inputted the plastic-coated streamline use, this coating was at room temperature deposited 0 ~ 720 hour, still can guarantee good processing characteristics.
Embodiment 3
Be that 60 parts epoxy soybean oil, calcium/zinc composite stabilizer of 4 parts, 4 parts trioctyl lemon acid, 10 parts white oil, 2 parts ethyl silicon oil, 2 parts fire retardant are rendered in the agitation vat with weight, at room temperature stir; Then add weight and be 40 parts whiteruss, 100 parts premium grads polyvinyl chloride resin, 28 parts light calcium carbonate, 20 parts stone flour, 20 parts pigment dyestuff and be stirred to homogeneous slurry; Grind finally by three-roll grinder, the particulate matter in the slurries is ground namely get coating.Coating is inputted the plastic-coated streamline use, this coating was at room temperature deposited 0 ~ 720 hour, still can guarantee good processing characteristics.
Embodiment 4
Be that 64 parts epoxy tea oil, magnesium/zinc composite stabilizer of 4.2 parts, 3.6 parts tributyl citrate, 12 parts white oil, 2 parts butyl stearate, 2.5 parts fire retardant are rendered in the agitation vat with weight, at room temperature stir; Then add weight and be 45 parts whiteruss, 105 parts acceptable end product polyvinyl chloride resin, 37 parts light calcium carbonate, 22 parts stone flour, 16 parts pigment dyestuff and be stirred to homogeneous slurry; Grind finally by three-roll grinder, the particulate matter in the slurries is ground and the use of input plastic-coated streamline.This solution was at room temperature deposited 0 ~ 720 hour, still can guarantee good processing characteristics.
Claims (9)
1. PVC plastic-coated fabric coating, it is characterized in that: it is comprised of several raw materials of following weight: polyvinyl chloride resin 92 ~ 115, epoxidized vegetable oil 54 ~ 70, environment-friendly stabilizer 2.5 ~ 5, environment-friendly type softening agent 3 ~ 5.5, white oil 6 ~ 15, viscosity-depression agent 1 ~ 3, fire retardant 1.5 ~ 3.5, whiteruss 30 ~ 55, light calcium carbonate 25 ~ 45, stone flour 15 ~ 30.
2. PVC plastic-coated fabric coating according to claim 1, it is characterized in that: it comprises that also weight fraction is 9～24 pigment dyestuffs.
3. PVC plastic-coated fabric coating according to claim 2, it is characterized in that: the parts by weight of each raw material are preferably: polyvinyl chloride resin 95 ~ 105, epoxy soybean oil 57 ~ 65, stablizer 3 ~ 4.5, softening agent 3.5 ~ 5, white oil 9 ~ 12, viscosity-depression agent 1.5 ~ 2.5, fire retardant 1.8 ~ 3, whiteruss 35 ~ 45, light calcium carbonate 30 ~ 40, stone flour 18 ~ 25, pigment dyestuff 10 ~ 22.
4. PVC plastic-coated fabric coating according to claim 3, it is characterized in that: the parts by weight of each raw material are: polyvinyl chloride resin 100, epoxy soybean oil 60, stablizer 4, softening agent 4, white oil 10, viscosity-depression agent 2, fire retardant 2, whiteruss 40, light calcium carbonate 35, stone flour 20, pigment dyestuff 20.
5. PVC plastic-coated fabric coating according to claim 4, it is characterized in that: described epoxidized vegetable oil is epoxy rapeseed oil or epoxy cottonseed oil or epoxy soybean oil or epoxy sweet oil or epoxy oleum lini or epoxy peanut oil or epoxy palm oil or epoxy tea oil.
6.. PVC plastic-coated fabric coating according to claim 4 is characterized in that: described environment-friendly stabilizer is calcium/zinc composite stabilizer or potassium/zinc composite stabilizer or calcium/magnesium/zinc composite stabilizer or magnesium/zinc composite stabilizer.
7. PVC plastic-coated fabric coating according to claim 4, it is characterized in that: described environment-friendly type softening agent is acetyl triethyl citrate or trioctyl lemon acid or ATOC or tributyl citrate or tributyl acetylcitrate.
8. PVC plastic-coated fabric coating according to claim 4, it is characterized in that: described viscosity-depression agent is butyl stearate or stearylamide or ethyl silicon oil.
9. PVC plastic-coated fabric coating according to claim 4, it is characterized in that: described fire retardant is phosphorus-nitrogen expanding fire retardant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104592682A CN102925013A (en) | 2012-11-15 | 2012-11-15 | PVC (polyvinyl chloride) coating for plastic-coated fabric |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012104592682A CN102925013A (en) | 2012-11-15 | 2012-11-15 | PVC (polyvinyl chloride) coating for plastic-coated fabric |
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| CN102925013A true CN102925013A (en) | 2013-02-13 |
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| CN2012104592682A Pending CN102925013A (en) | 2012-11-15 | 2012-11-15 | PVC (polyvinyl chloride) coating for plastic-coated fabric |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254699A (en) * | 2013-05-22 | 2013-08-21 | 苏州富通高新材料科技股份有限公司 | Coating suitable for PVC (Poly Vinyl Chloride) plastic-coated cloth |
| CN105088895A (en) * | 2014-05-05 | 2015-11-25 | 江苏东宇墙纸有限公司 | Mildewproof wallpaper PVC coating and preparation method therefor |
| CN105462386A (en) * | 2016-01-04 | 2016-04-06 | 金戈炜业（江苏）壁纸有限公司 | Wallpaper mirror surface sizing agent |
| US20180112062A1 (en) * | 2015-10-27 | 2018-04-26 | Lg Chem, Ltd. | Plasticizer composition, resin composition, and methods for preparing same |
| CN110144040A (en) * | 2019-05-14 | 2019-08-20 | 东华大学 | A kind of drop sticks additive agent modified nylon 66 composite material and its preparation and application |
| CN115637594A (en) * | 2022-12-07 | 2023-01-24 | 厦门妙杏科技有限公司 | Formula and process of disposable gloves |
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| US4013603A (en) * | 1974-02-20 | 1977-03-22 | Labofina S.A. | Coating compositions for protecting metals |
| CN1404989A (en) * | 2002-11-12 | 2003-03-26 | 四川金路集团股份有限公司 | Decorative wall leather and its making method |
| CN102173335A (en) * | 2011-04-02 | 2011-09-07 | 上海永利带业股份有限公司 | Manufacturing method for environment-friendly antiseptic polyvinyl chloride light-type conveyer belt and antiseptic coating material |
| CN102505478A (en) * | 2011-10-19 | 2012-06-20 | 宁波双盾纺织帆布实业有限公司 | Coating for polyester filament yarn flame-retardant PVC (polyvinyl chloride) coated fabric |
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2012
- 2012-11-15 CN CN2012104592682A patent/CN102925013A/en active Pending
Patent Citations (4)
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| US4013603A (en) * | 1974-02-20 | 1977-03-22 | Labofina S.A. | Coating compositions for protecting metals |
| CN1404989A (en) * | 2002-11-12 | 2003-03-26 | 四川金路集团股份有限公司 | Decorative wall leather and its making method |
| CN102173335A (en) * | 2011-04-02 | 2011-09-07 | 上海永利带业股份有限公司 | Manufacturing method for environment-friendly antiseptic polyvinyl chloride light-type conveyer belt and antiseptic coating material |
| CN102505478A (en) * | 2011-10-19 | 2012-06-20 | 宁波双盾纺织帆布实业有限公司 | Coating for polyester filament yarn flame-retardant PVC (polyvinyl chloride) coated fabric |
Non-Patent Citations (1)
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| 贡长生等: "《绿色精细化工导论》", 31 July 2005, 化学工业出版社 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254699A (en) * | 2013-05-22 | 2013-08-21 | 苏州富通高新材料科技股份有限公司 | Coating suitable for PVC (Poly Vinyl Chloride) plastic-coated cloth |
| CN105088895A (en) * | 2014-05-05 | 2015-11-25 | 江苏东宇墙纸有限公司 | Mildewproof wallpaper PVC coating and preparation method therefor |
| US20180112062A1 (en) * | 2015-10-27 | 2018-04-26 | Lg Chem, Ltd. | Plasticizer composition, resin composition, and methods for preparing same |
| US10590260B2 (en) * | 2015-10-27 | 2020-03-17 | Lg Chem, Ltd. | Plasticizer composition, resin composition, and methods for preparing same |
| CN105462386A (en) * | 2016-01-04 | 2016-04-06 | 金戈炜业（江苏）壁纸有限公司 | Wallpaper mirror surface sizing agent |
| CN110144040A (en) * | 2019-05-14 | 2019-08-20 | 东华大学 | A kind of drop sticks additive agent modified nylon 66 composite material and its preparation and application |
| CN115637594A (en) * | 2022-12-07 | 2023-01-24 | 厦门妙杏科技有限公司 | Formula and process of disposable gloves |
| CN115637594B (en) * | 2022-12-07 | 2024-02-09 | 厦门妙杏科技有限公司 | Disposable glove formula and process |
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Application publication date: 20130213 |