CN102877092A - Silver or gold and silver peony prepared by adopting electrochemical plating method and preparation method thereof - Google Patents
Silver or gold and silver peony prepared by adopting electrochemical plating method and preparation method thereof Download PDFInfo
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- CN102877092A CN102877092A CN2012103954883A CN201210395488A CN102877092A CN 102877092 A CN102877092 A CN 102877092A CN 2012103954883 A CN2012103954883 A CN 2012103954883A CN 201210395488 A CN201210395488 A CN 201210395488A CN 102877092 A CN102877092 A CN 102877092A
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Abstract
The invention relates to silver or gold and silver peony prepared by adopting an electrochemical plating method and a preparation method thereof. A metal or non-metal material is selected; the metal or non-metal material is made into a peony flower or bud shape; a resin adhesive layer containing a curing agent is sprayed on the surface of the metal or non-metal material; one or more of silver oil, copper oil, nano metal powder oil and conductive powder or conductive powder oil are uniformly sprayed on the surface of the resin adhesive layer; then a silver layer is plated in an electroplating bath filled with silver plating solution so as to obtain the silver peony prepared by adopting the electrochemical plating method; and the silver peony prepared by adopting the electrochemical plating method is plated with a gold layer in an electroplating bath filled with gold plating solution so as to obtain the gold and silver peony prepared by adopting the electrochemical plating method. According to the preparation method disclosed by the invention, the gold and silver layer and a carrier have strong binding force, the production process is simple, and the prepared product is ultrathin, the thickness is 0.1 to 0.3mm and high brightness and a good stereoscopic effect are realized.
Description
Technical field
The present invention relates to a kind of metal handicraft and preparation method thereof, specifically a kind of adopt electrochemical plating preparations have silver or the tectal Tree Peony flower of gold and silver and preparation method thereof.
Background technology
Tree peony is elegant and poised, have " aromatic ", " king's in spending " good reputation, and China has just handed down since the Tang and Song Dynasty and become social custom, and is called national flower, is the famous flower that China people like, (Tang) Liu Yu tin poem is said: " the Chinese herbaceous peony goblin is without lattice before the front yard, and lotus is lacked feelings only on the pond.Have the true reigning beauty of tree peony only, the flowers are in blossom, and the time is moved the capital." from that time, the aromatic synonym that just becomes tree peony.Then directly claim " tree peony " to be the king in spending in " mirror flower edge " book.
Existing various art flower class is made mainly with raw materials such as plastics silk weaving, stationeries in the market, and its characteristics only possess the effect of viewing and admiring, and with the colored class that gold and silver are made, both had sight, very high reserve value is arranged again, integrate culture and wealth, can satisfy modern people's life.
Summary of the invention
The objective of the invention is provides a kind of silver that adopts electrochemical plating preparations or gold and silver Tree Peony flower and preparation method thereof for the problems referred to above, preparation method's environmental protection, the bonding force of gold and silver and carrier is strong, production technique is simple, prepared product is ultrathin, thickness is 0.1-0.3mm, and luminance brightness is high, and stereoeffect is good.
A kind of silver-colored Tree Peony flower of adopting the electrochemical plating preparation and preparation method thereof, its concrete preparation process is:
Step 1, select metal or non-metallic material, be made into the shape of peony petal and pistil; Behind the foreign material Fouling Cleaning of the peony petal for preparing and pistil is clean, the electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive that the 1:1-1:2 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 50-100 ℃, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time are cooled to 15-25 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, one or more materials in conducting powder or the conducting powder oil evenly are sprayed on peony petal and pistil surface after step 3 is processed; Then be placed in the drying baker and dry, temperature is 10-30 ℃, and the time is 3-5 hour;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 1-3A/dm, and the time is 3-10 hour, take out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 30-70 ℃, and the time is 30-60 minute, to improve the raising bonding force of silver layer and peony petal and pistil;
Step 6, the peony petal that is coated with silver after step 5 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 7, peony petal and pistil that step 6 is sprayed after the protection against oxidation agent are assembled into peony flowers, then are equipped with tree peony leaf and the stem of emulation, namely obtain adopting the silver-colored Tree Peony flower of electrochemical plating preparation; It is assembled in the space of special picture frame, large-scale fresco frame or suitable demand according to different styles, is equipped with the packing warehouse-in of demand.
A kind of gold and silver Tree Peony flower of adopting the electrochemical plating preparation and preparation method thereof, its concrete preparation process is:
Step 1, select metal or non-metallic material, be made into the shape of peony petal and pistil; Behind the foreign material Fouling Cleaning of the peony petal for preparing and pistil is clean, the electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive that the 1:1-1:2 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 50-100 ℃, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time are cooled to 15-25 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, one or more materials in conducting powder or the conducting powder oil evenly are sprayed on peony petal and pistil surface after step 3 is processed; Then be placed in the drying baker and dry, temperature is 10-30 ℃, and the time is 3-5 hour;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 1-3A/dm, and the time is 3-10 hour, take out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 30-70 ℃, and the time is 30-60 minute, to improve the raising bonding force of silver layer and peony petal and pistil;
Step 6, step 5 processed after with peony petal and the pistil of silver layer, it is gold-plated to place the plating tank that gold plating solution is housed to carry out, electrical current is 1-3A/dm, the time is 10-40 minute, gold-plated end rear surface generates uniformly light gold layer of one deck; Then with its residual solution with the clean gold layer of washed with de-ionized water surface, be placed on and dry moisture content in the baking oven, the control temperature is at 30-70 ℃, and the time is 30-60 minute, to improve the bonding force of silver layer and gold layer;
Step 7, the peony petal that is coated with gold and silver after step 6 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 8, peony petal and pistil that step 7 is sprayed after the protection against oxidation agent are assembled into peony flowers; Then be equipped with tree peony leaf and the stem of emulation, namely obtain adopting the gold and silver Tree Peony flower of electrochemical plating preparation; It is assembled in the space of special picture frame, large-scale fresco frame or suitable demand according to different styles, is equipped with the packing warehouse-in of demand.
Described non-metallic material are silk, plastics, timber or rubber etc., and metallic substance is iron, copper, tin, lead, zinc, aluminium or alloy etc.
The composition of described silver plating solution: contain potassium cyanide 110g in every liter of silver plating solution, silver potassium cyanide 30-45g, salt of wormwood 15g opens cylinder agent 6ml, brightening agent 0.5ml, surplus is deionized water;
The composition of described gold plating solution: contain gold sodium sulfide 1-2g in every liter of gold plating solution, sodium sulphite anhydrous 99.3 10-15g, quadrol 6-12g, potassium hydrogen phosphate 25-35g, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, and it is mixed.
Beneficial effect
1, preparation method's environmental protection of the present invention, the bonding force of gold and silver and carrier is strong, and production technique is simple, and prepared product is ultrathin, and thickness is 0.1-0.3mm, and luminance brightness is high, and stereoeffect is good.
The tree peony of 2, making of gold and silver, its distinctive gloss, more aobvious wealth and rank, overlapping building of petal, arrange in order, add that pistil displays for the first time, folding is uneven, makes of the emulation leaf between dense phase and scape and sets off, make whole series winding, folding, perspective, rhythm, density, collecting and distributing, irregular, circle lacks etc. has stereoeffect, implicit grace is rich in the rhythm graceful bearing, make tree peony more beautiful elegant rhythm colourful, brilliant, exquisite beyond compare, surprise the world.Magnificent, splendid and flourishing incisively and vividly the attitude of tree peony be presented in people in face of.
3, gold and silver in all age has been the symbol of wealth in people's consciousness, the tree peony again identity with " king in spending " is widely known, the tree peony of making of gold and silver integrates precious metal, art, culture, it is the part of spiritual civilization and material progress during people live, market outlook are wide, demand is large, is a kind of cultural product of society.
Embodiment
A kind of silver-colored Tree Peony flower of adopting the electrochemical plating preparation and preparation method thereof, its concrete preparation process is:
Step 1, select metal or non-metallic material, be made into the shape of peony petal and pistil; Behind the foreign material Fouling Cleaning of the peony petal for preparing and pistil is clean, the electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive that the 1:1-1:2 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 50-100 ℃, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time are cooled to 15-25 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, one or more materials in conducting powder or the conducting powder oil evenly are sprayed on peony petal and pistil surface after step 3 is processed; Then be placed in the drying baker and dry, temperature is 10-30 ℃, and the time is 3-5 hour;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 1-3A/dm, and the time is 3-10 hour, take out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 30-70 ℃, and the time is 30-60 minute, to improve the raising bonding force of silver layer and peony petal and pistil;
Step 6, the peony petal that is coated with silver after step 5 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 7, peony petal and pistil that step 6 is sprayed after the protection against oxidation agent are assembled into peony flowers, then are equipped with tree peony leaf and the stem of emulation, namely obtain adopting the silver-colored Tree Peony flower of electrochemical plating preparation; It is assembled in the space of special picture frame, large-scale fresco frame or suitable demand according to different styles, is equipped with the packing warehouse-in of demand.
A kind of gold and silver Tree Peony flower of adopting the electrochemical plating preparation and preparation method thereof, its concrete preparation process is:
Step 1, select metal or non-metallic material, be made into the shape of peony petal and pistil; Behind the foreign material Fouling Cleaning of the peony petal for preparing and pistil is clean, the electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive that the 1:1-1:2 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 50-100 ℃, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time are cooled to 15-25 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, one or more materials in conducting powder or the conducting powder oil evenly are sprayed on peony petal and pistil surface after step 3 is processed; Then be placed in the drying baker and dry, temperature is 10-30 ℃, and the time is 3-5 hour;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 1-3A/dm, and the time is 3-10 hour, take out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 30-70 ℃, and the time is 30-60 minute, to improve the raising bonding force of silver layer and peony petal and pistil;
Step 6, step 5 processed after with peony petal and the pistil of silver layer, it is gold-plated to place the plating tank that gold plating solution is housed to carry out, electrical current is 1-3A/dm, the time is 10-40 minute, gold-plated end rear surface generates uniformly light gold layer of one deck; Then with its residual solution with the clean gold layer of washed with de-ionized water surface, be placed on and dry moisture content in the baking oven, the control temperature is at 30-70 ℃, and the time is 30-60 minute, to improve the bonding force of silver layer and gold layer;
Step 7, the peony petal that is coated with gold and silver after step 6 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 8, peony petal and pistil that step 7 is sprayed after the protection against oxidation agent are assembled into peony flowers; Then be equipped with tree peony leaf and the stem of emulation, namely obtain adopting the gold and silver Tree Peony flower of electrochemical plating preparation; It is assembled in the space of special picture frame, large-scale fresco frame or suitable demand according to different styles, is equipped with the packing warehouse-in of demand.
Described non-metallic material are silk, plastics, timber or rubber etc., and metallic substance is iron, copper, tin, lead, zinc, aluminium or alloy etc.
The composition of described silver plating solution: contain potassium cyanide 110g in every liter of silver plating solution, silver potassium cyanide 30-45g, salt of wormwood 15g opens cylinder agent 6ml, brightening agent 0.5ml, surplus is deionized water;
The composition of described gold plating solution: contain gold sodium sulfide 1-2g in every liter of gold plating solution, sodium sulphite anhydrous 99.3 10-15g, quadrol 6-12g, potassium hydrogen phosphate 25-35g, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, and it is mixed.
Embodiment 1
A kind of gold and silver Tree Peony flower of adopting the electrochemical plating preparation and preparation method thereof, its concrete preparation process is:
Step 1, select silk as material, be made into the shape of petal or pistil; After the foreign material dirt electricity consumption blowing on the peony petal for preparing and pistil surface is clean, for subsequent use;
Step 2, be the Resin adhesive that the 1:1 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 50 ℃, and the time is 20 minutes;
Step 3, repeating step 21 times are cooled to 15 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, peony petal and the pistil surface of one or more materials in conducting powder or the conducting powder oil after evenly being sprayed on step 3 that temperature is cooled to 15 ℃ and processing; Then be placed in the drying baker and dry, temperature is 10 ℃, and the time is 3-5 hour;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 1A/dm, and the time is 10 hours, take out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 30 ℃, and the time is 30 minutes, to improve the bonding force of silver layer and peony petal and pistil;
Step 6, step 5 processed after with peony petal and the pistil of silver layer, it is gold-plated to place the plating tank that gold plating solution is housed to carry out, electrical current is 1A/dm, 40 minutes time, gold-plated end rear surface generates uniformly light gold layer of one deck; Then with its residual solution with the clean gold layer of washed with de-ionized water surface, be placed on and dry moisture content in the baking oven, the control temperature is at 30 ℃, and the time is 60 minutes, to improve the bonding force of silver layer and gold layer;
Step 7,, the peony petal that is coated with gold and silver after step 6 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 8, the peony petal that is coated with gold and silver after step 7 processed and pistil carry out spraying protection against oxidation agent after the integer; Then be equipped with tree peony leaf and the stem of emulation, namely obtain adopting the gold and silver Tree Peony flower of electrochemical plating preparation; Be assembled in special picture frame or large-scale fresco frame according to different styles it or in the space of suitable demand, be equipped with the packing warehouse-in of demand.
The composition of described silver plating solution: contain potassium cyanide 110g in every liter of silver plating solution, silver potassium cyanide 30g, salt of wormwood 15g opens cylinder agent 6ml, brightening agent 0.5ml, surplus is deionized water;
The composition of described gold plating solution: contain gold sodium sulfide 1-2g in every liter of gold plating solution, sodium sulphite anhydrous 99.3 10g, quadrol 6g, potassium hydrogen phosphate 25g, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, and it is mixed.
Embodiment 2
A kind of gold and silver Tree Peony flower of adopting the electrochemical plating preparation and preparation method thereof, its concrete preparation process is:
Step 1, select rubber as material, be made into the shape of peony petal and pistil; After the foreign material dirt electricity consumption blowing on the peony petal for preparing and pistil surface is clean, for subsequent use;
Step 2, be the Resin adhesive that the 1:2 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 80 ℃, and the time is 40 minutes;
Step 3, repeating step 23 times are cooled to 20 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, peony petal and the pistil surface of one or more materials in conducting powder or the conducting powder oil after evenly being sprayed on step 3 that temperature is cooled to 20 ℃ and processing; Then be placed in the drying baker and dry, temperature is 20 ℃, and the time is 4 hours;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 2A/dm, and the time is 6 hours, takes out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 50 ℃, and the time is 40 minutes, to improve bonding force;
Step 6, step 5 processed after with peony petal and the pistil of silver layer, it is gold-plated to place the plating tank that gold plating solution is housed to carry out, electrical current is 2A/dm, the time is 30 minutes, gold-plated end rear surface generates uniformly light gold layer of one deck; Then with its residual solution with the clean gold layer of washed with de-ionized water surface, be placed on and dry moisture content in the baking oven, the control temperature is at 40 ℃, and the time is 50 minutes, to improve bonding force;
Step 7,, the peony petal that is coated with gold and silver after step 6 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 8, the peony petal that is coated with gold and silver after step 7 processed and pistil carry out spraying protection against oxidation agent after the integer; Then be equipped with tree peony leaf and the stem of emulation, namely obtain adopting the gold and silver Tree Peony flower of electrochemical plating preparation; Be assembled in special picture frame or large-scale fresco frame according to different styles it or in the space of suitable demand, be equipped with the packing warehouse-in of demand.
The composition of described silver plating solution: contain potassium cyanide 110g in every liter of silver plating solution, silver potassium cyanide 40g, salt of wormwood 15g opens cylinder agent 6ml, brightening agent 0.5ml, surplus is deionized water;
The composition of described gold plating solution: contain gold sodium sulfide 2g in every liter of gold plating solution, sodium sulphite anhydrous 99.3 12g, quadrol 8g, potassium hydrogen phosphate 28g, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, and it is mixed.
Embodiment 3
A kind of gold and silver Tree Peony flower of adopting the electrochemical plating preparation and preparation method thereof, its concrete preparation process is:
Step 1, select iron as material, be made into the shape of peony petal and pistil; After the foreign material dirt electricity consumption blowing on the peony petal for preparing and pistil surface is clean, for subsequent use;
Step 2, be the Resin adhesive that the 1:1 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 100 ℃, and the time is 20 minutes;
Step 3, repeating step 25 times are cooled to 25 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, peony petal and the pistil surface of one or more materials in conducting powder or the conducting powder oil after evenly being sprayed on step 3 that temperature is cooled to 25 ℃ and processing; Then be placed in the drying baker and dry, temperature is 30 ℃, and the time is 3 hours;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 3A/dm, and the time is 3 hours, takes out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 70 ℃, and the time is 30 minutes, to improve bonding force;
Step 6, step 5 processed after with peony petal and the pistil of silver layer, it is gold-plated to place the plating tank that gold plating solution is housed to carry out, electrical current is 3A/dm, the time is 10 minutes, gold-plated end rear surface generates uniformly light gold layer of one deck; Then with its residual solution with the clean gold layer of washed with de-ionized water surface, be placed on and dry moisture content in the baking oven, the control temperature is at 70 ℃, and the time is 30 minutes, to improve bonding force;
Step 7,, the peony petal that is coated with gold and silver after step 6 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 8, the peony petal that is coated with gold and silver after step 7 processed and pistil carry out spraying protection against oxidation agent after the integer; Then be equipped with tree peony leaf and the stem of emulation, namely obtain adopting the gold and silver Tree Peony flower of electrochemical plating preparation; Be assembled in special picture frame or large-scale fresco frame according to different styles it or in the space of suitable demand, be equipped with the packing warehouse-in of demand.
The composition of described silver plating solution: contain potassium cyanide 110g in every liter of silver plating solution, silver potassium cyanide 45g, salt of wormwood 15g opens cylinder agent 6ml, brightening agent 0.5ml, surplus is deionized water;
The composition of described gold plating solution: contain gold sodium sulfide 2g in every liter of gold plating solution, sodium sulphite anhydrous 99.3 15g, quadrol 12g, potassium hydrogen phosphate 35g, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, and it is mixed.
Embodiment 4
A kind of silver-colored Tree Peony flower of adopting the electrochemical plating preparation and preparation method thereof, its concrete preparation process is:
Step 1, select plastics as material, be made into the shape of peony petal and pistil; After the foreign material dirt electricity consumption blowing on the peony petal for preparing and pistil surface is clean, for subsequent use;
Step 2, be the Resin adhesive that the 1:1 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 50 ℃, and the time is 20 minutes;
Step 3, repeating step 21 times are cooled to 23 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, peony petal and the pistil surface of one or more materials in conducting powder or the conducting powder oil after evenly being sprayed on step 3 that temperature is cooled to 15 ℃ and processing; Then be placed in the drying baker and dry, temperature is 10 ℃, and the time is 3-5 hour;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 1A/dm, and the time is 10 hours, take out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 30 ℃, and the time is 30 minutes, to improve bonding force;
Step 6, the peony petal that is coated with gold and silver after step 5 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 7, the peony petal that is coated with gold and silver after step 6 processed and pistil carry out spraying protection against oxidation agent after the integer; Then be equipped with tree peony leaf and the stem of emulation, namely obtain adopting the gold and silver Tree Peony flower of electrochemical plating preparation; Be assembled in special picture frame or large-scale fresco frame according to different styles it or in the space of suitable demand, be equipped with the packing warehouse-in of demand.
The composition of described silver plating solution: contain potassium cyanide 110g in every liter of silver plating solution, silver potassium cyanide 30g, salt of wormwood 15g opens cylinder agent 6ml, brightening agent 0.5ml, surplus is deionized water;
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, and it is mixed.
Potassium cyanide described in the present invention, silver potassium cyanide, salt of wormwood, open cylinder agent, brightening agent, gold sodium sulfide, quadrol, potassium hydrogen phosphate, solidifying agent and Resin adhesive, all can buy by market and obtain.
Claims (6)
1. preparation method who adopts the silver-colored Tree Peony flower of electrochemical plating preparations, it is characterized in that: its concrete preparation process is:
Step 1, select metal or non-metallic material, be made into the shape of peony petal and pistil; Behind the foreign material Fouling Cleaning of the peony petal for preparing and pistil is clean, the electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive that the 1:1-1:2 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 50-100 ℃, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time are cooled to 15-25 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, one or more materials in conducting powder or the conducting powder oil evenly are sprayed on peony petal and pistil surface after step 3 is processed; Then be placed in the drying baker and dry, temperature is 10-30 ℃, and the time is 3-5 hour;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 1-3A/dm, and the time is 3-10 hour, take out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 30-70 ℃, and the time is 30-60 minute;
Step 6, the peony petal that is coated with silver after step 5 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 7, peony petal and pistil that step 6 is sprayed after the protection against oxidation agent are assembled into peony flowers, then are equipped with tree peony leaf and the stem of emulation, namely obtain adopting the silver-colored Tree Peony flower of electrochemical plating preparation;
The composition of described silver plating solution: contain potassium cyanide 110g in every liter of silver plating solution, silver potassium cyanide 30-45g, salt of wormwood 15g opens cylinder agent 6ml, brightening agent 0.5ml, surplus is deionized water.
2. a kind of preparation method who adopts the silver-colored Tree Peony flower of electrochemical plating preparations as claimed in claim 1, it is characterized in that: described anti-oxidant protective agent is that mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive.
3. a kind of preparation method who adopts the silver-colored Tree Peony flower of electrochemical plating preparations as claimed in claim 1, it is characterized in that: described non-metallic material are its a kind of of silk, plastics, timber or rubber, and metallic substance is wherein a kind of of iron, copper, tin, lead, zinc, aluminium or alloy.
4. preparation method who adopts the gold and silver Tree Peony flower of electrochemical plating preparations, it is characterized in that: its concrete preparation process is:
Step 1, select metal or non-metallic material, be made into the shape of peony petal and pistil; Behind the foreign material Fouling Cleaning of the peony petal for preparing and pistil is clean, the electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive that the 1:1-1:2 preparation contains solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; The Resin adhesive that contains solidifying agent that then will prepare evenly is sprayed on the prepared peony petal of step 1 and pistil surface; Be placed in the baking oven after spraying finishes and toast, temperature is at 50-100 ℃, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time are cooled to 15-25 ℃ afterwards;
Step 4, with silver oil, copper is oily, Nano metal powder is oily, one or more materials in conducting powder or the conducting powder oil evenly are sprayed on peony petal and pistil surface after step 3 is processed; Then be placed in the drying baker and dry, temperature is 10-30 ℃, and the time is 3-5 hour;
Step 5, peony petal and pistil after step 4 processed, it is silver-plated to place the plating tank that silver plating solution is housed to carry out, and electrical current is 1-3A/dm, and the time is 3-10 hour, take out the uniform bright silver layer of peony petal and pistil Surface Creation one deck after the silver-plated end; Then with the residual solution of the clean silver layer surface of washed with de-ionized water, be placed on and dry moisture content in the baking oven, the control temperature is at 30-70 ℃, and the time is 30-60 minute;
Step 6, step 5 processed after with peony petal and the pistil of silver layer, it is gold-plated to place the plating tank that gold plating solution is housed to carry out, electrical current is 1-3A/dm, the time is 10-40 minute, gold-plated end rear surface generates uniformly light gold layer of one deck; Then with its residual solution with the clean gold layer of washed with de-ionized water surface, be placed on and dry moisture content in the baking oven, the control temperature is at 30-70 ℃, and the time is 30-60 minute;
Step 7, the peony petal that is coated with gold and silver after step 6 processed and pistil carry out spraying protection against oxidation agent after the integer;
Step 8, peony petal and pistil that step 7 is sprayed after the protection against oxidation agent are assembled into peony flowers; Then be equipped with tree peony leaf and the stem of emulation, namely obtain adopting the gold and silver Tree Peony flower of electrochemical plating preparation;
The composition of described silver plating solution: contain potassium cyanide 110g in every liter of silver plating solution, silver potassium cyanide 30-45g, salt of wormwood 15g opens cylinder agent 6ml, brightening agent 0.5ml, surplus is deionized water;
The composition of described gold plating solution: contain gold sodium sulfide 1-2g in every liter of gold plating solution, sodium sulphite anhydrous 99.3 10-15g, quadrol 6-12g, potassium hydrogen phosphate 25-35g, surplus is deionized water.
5. a kind of preparation method who adopts the gold and silver Tree Peony flower of electrochemical plating preparations as claimed in claim 4, it is characterized in that: described anti-oxidant protective agent is that mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive.
6. a kind of preparation method who adopts the gold and silver Tree Peony flower of electrochemical plating preparations as claimed in claim 4, it is characterized in that: described non-metallic material are its a kind of of silk, plastics, timber or rubber, and metallic substance is wherein a kind of of iron, copper, tin, lead, zinc, aluminium or alloy.
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| CN201210395488.3A CN102877092B (en) | 2012-10-18 | 2012-10-18 | Silver or gold and silver peony prepared by adopting electrochemical plating method and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103668372A (en) * | 2013-11-04 | 2014-03-26 | 上海应用技术学院 | Direct electroplating method of carbon skeleton material |
| CN109680312A (en) * | 2019-01-24 | 2019-04-26 | 南京理工大学 | The method for plating the preparation super-hydrophobic Zinc material of sheet as template electric using natural timber |
| CN110584248A (en) * | 2019-09-25 | 2019-12-20 | 铜陵铜官府文化创意股份公司 | Method for simulating ultrathin flower and leaf plants by using copper process |
| CN113136542A (en) * | 2021-04-26 | 2021-07-20 | 河南机电职业学院 | Preparation method of gold-coated silver bonding wire |
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| GB2031024A (en) * | 1978-10-06 | 1980-04-16 | Standards Inst Singapore | Process for Electroforming from Natural Flowers |
| CN1524978A (en) * | 2003-02-26 | 2004-09-01 | 夏红元 | Electroplating method for flowers and tree leaves |
| CN200987382Y (en) * | 2006-01-19 | 2007-12-12 | 宏江科技有限公司 | Plant flower surface electroplating structure |
| US20080017515A1 (en) * | 2006-07-21 | 2008-01-24 | Lotes Co., Ltd | Forming method for manufacturing model |
| CN101361603A (en) * | 2008-10-14 | 2009-02-11 | 深圳市金龙珠宝首饰有限公司 | Living rose gold-plating production technique flow |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2031024A (en) * | 1978-10-06 | 1980-04-16 | Standards Inst Singapore | Process for Electroforming from Natural Flowers |
| CN1524978A (en) * | 2003-02-26 | 2004-09-01 | 夏红元 | Electroplating method for flowers and tree leaves |
| CN200987382Y (en) * | 2006-01-19 | 2007-12-12 | 宏江科技有限公司 | Plant flower surface electroplating structure |
| US20080017515A1 (en) * | 2006-07-21 | 2008-01-24 | Lotes Co., Ltd | Forming method for manufacturing model |
| CN101361603A (en) * | 2008-10-14 | 2009-02-11 | 深圳市金龙珠宝首饰有限公司 | Living rose gold-plating production technique flow |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103668372A (en) * | 2013-11-04 | 2014-03-26 | 上海应用技术学院 | Direct electroplating method of carbon skeleton material |
| CN109680312A (en) * | 2019-01-24 | 2019-04-26 | 南京理工大学 | The method for plating the preparation super-hydrophobic Zinc material of sheet as template electric using natural timber |
| CN110584248A (en) * | 2019-09-25 | 2019-12-20 | 铜陵铜官府文化创意股份公司 | Method for simulating ultrathin flower and leaf plants by using copper process |
| CN113136542A (en) * | 2021-04-26 | 2021-07-20 | 河南机电职业学院 | Preparation method of gold-coated silver bonding wire |
| CN113136542B (en) * | 2021-04-26 | 2023-08-15 | 河南机电职业学院 | Preparation method of gold-coated silver bonding wire |
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| CN102877092B (en) | 2015-06-03 |
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