CN102907807B - Peony with silver or gold and silver covering layer and preparation method thereof - Google Patents
Peony with silver or gold and silver covering layer and preparation method thereof Download PDFInfo
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Abstract
The invention relates to a peony with a silver or gold and silver covering layer and a preparation method thereof. The preparation method comprises the following steps of: making selected metal or non-metal material into the shape of a peony flower or a flower bud, spraying a resin adhesive layer containing a curing agent on the surface, then firstly using a special chemical solution to spray the surface for activation, then using a double-head spray gun to simultaneously spray a chemical solution containing silver and an auxiliary chemical solution to the surface, and forming an uniform gold layer to get the peony with the silver covering layer; and placing the peony with the silver covering layer into a gold plating solution for performing gold-plating for 10-40min to get the peony with the gold and silver covering layer. The preparation method disclosed by the invention is environment-friendly, the bonding force between the gold-silver and a carrier is strong, the production process is simple, the prepared product is ultra-thin, the thickness is 0.1-0.3mm, the brightness is high, and the three-dimensional effect is good.
Description
Technical field
The present invention relates to a kind of metal handicraft and preparation method thereof, specifically a kind of silver or the tectal peony of gold and silver and preparation method thereof.
Background technology
Tree peony is elegant and poised, have the good reputation of " aromatic ", " king in spending ", and China has just handed down and become social custom since the Tang and Song Dynasty, and being called national flower, is the famous flower that our people likes, (Tang) Liu Yu tin poem is said: " before front yard, Chinese herbaceous peony goblin is without lattice, and on pond, lotus lacks feelings only.Have the true reigning beauty of tree peony only, the flowers are in blossom, and the time moves capital." from that time, the aromatic synonym just becoming tree peony.Then directly claim " tree peony " for the king in spending in " mirror flower edge " book.
Existing various art flower class in the market, make mainly with raw materials such as plastics silk weaving, stationeries, its feature only possesses the effect of viewing and admiring, and by the colored class that gold and silver make, both there is sight, had again very high reserve value, integrate culture and wealth, the life of modern people can be met.In addition, silver or gold and silver tectal peony brightness high, stereoeffect is good, and thickness is 0.1-0.3mm; And it has distinctive gloss, petal overlap plays building, and arrangement in order, can tree peony is magnificent, splendid and prosperity attitude incisively and vividly be presented in face of people; Although patent CN1936075A discloses a kind of cladding coating and technique of replacing electroplating, and this technique does not then reach required technique effect, and wherein adopt reagent hydrazine hydrate harmful, cost is higher, is further improved.
Summary of the invention
The object of the invention is to provide a kind of with silver or the tectal peony of gold and silver and preparation method thereof, preparation method's environmental protection for the problems referred to above, the adhesion of gold and silver and carrier is strong, production technology is simple, and prepared product is ultrathin, and thickness is 0.1-0.3mm, brightness is high, and stereoeffect is good.
A kind of with tectal peony of silver and preparation method thereof, its concrete preparation process is:
Step one, select metal or nonmetallic materials, be made into the shape of peony petal and pistil; After the foreign material Fouling Cleaning on the peony petal prepared and pistil surface is clean, electricity consumption dries up, for subsequent use;
Step 2, be the resin glue of 1:1-1:2 preparation containing curing agent according to the mass ratio of curing agent and resin glue; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repetition step 2 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform silver layer; Then after the residual solution of silver layer surface being cleaned up by deionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the adhesion of peony petal and pistil and silver layer;
Step 5, integer is carried out to the peony petal being coated with silver layer after step 4 process and pistil after spray protection against oxidation agent;
Step 6, step 5 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers, be then equipped with peony leaves and the stem of emulation, namely obtain adopting the galvanoplastic silver-colored peony of preparing
A kind of with tectal peony of gold and silver and preparation method thereof, its concrete preparation process is:
Step one, select metal or nonmetallic materials, be made into the shape of peony petal and pistil; After the foreign material Fouling Cleaning on the peony petal prepared and pistil surface is clean, electricity consumption dries up, for subsequent use;
Step 2, be the resin glue of 1:1-1:2 preparation containing curing agent according to the mass ratio of curing agent and resin glue; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repetition step 2 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform silver layer; Then after the residual solution of silver layer surface being cleaned up by deionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the adhesion of peony petal and pistil and silver layer;
Step 5, by peony petal and pistil after step 4 process, put into the gold-plated 10-40 minute of the electroplating bath that gold plating solution is housed, forming bright layer gold can take out; Then clean up after the residual solution on layer gold surface by deionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute; To improve the adhesion of silver layer and layer gold;
Step 6, integer is carried out to the peony petal being coated with gold and silver after step 5 process and pistil after spray protection against oxidation agent;
Step 7, step 8 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with peony leaves and the stem of emulation, namely obtain the gold and silver peony adopting galvanoplastic to prepare;
Described nonmetallic materials are silk, plastics, timber or rubber etc., and metal material is iron, copper, tin, lead, zinc, aluminium or alloy etc.
The composition of described special chemical solution is that surplus is deionized water containing stannous chloride 160-260g, hydrochloric acid 200-300ml in often liter of special chemical solution; Its concrete preparation method is: at normal temperatures, is added in 300ml ionized water by 160-260g stannous chloride, is stirred to after dissolving completely, slowly add 200-300ml hydrochloric acid while stirring, continue to be stirred to and clarify completely, be settled to 1L, room temperature is placed after 20-24 hour and can be used.
The composition of the described chemical solution containing silver is: often liter contains silver nitrate 15-25g, ammonium nitrate 2-8g, NaOH 3-15g, ammoniacal liquor 130-180ml containing in the chemical solution of silver, and surplus is deionized water; Its concrete preparation method is: by silver nitrate 15-25g, ammonium nitrate 2-8g, NaOH 3-15g, ammoniacal liquor 130-180ml, at normal temperatures after Homogeneous phase mixing, adds deionized water and is settled to 1L.
The composition of described assistant chemical solution is: containing hydrazine sulfate 30-70g, sucrose 25-55g, absolute alcohol 55-90ml in every 100ml assistant chemical solution, surplus is deionized water; Its concrete preparation method is: by hydrazine sulfate 50g, and sucrose 40g joins in 55-90ml absolute alcohol, adds deionized water and be settled to 100ml after being stirred to dissolving completely.
The composition of described gold plating solution is: containing gold sodium sulfide 1-2g, anhydrous sodium sulfite 10-15g, ethylenediamine 6-12g, potassium hydrogen phosphate 25-35g in often liter of gold plating solution, surplus is deionized water; Its concrete preparation method is: by gold sodium sulfide 1-2g, anhydrous sodium sulfite 10-15g, ethylenediamine 6-12g, and potassium hydrogen phosphate 25-35g is dissolved in 800ml deionized water, is stirred to and dissolves completely, regulates pH value to be 8, adds deionized water and be settled to 1L.
The composition of described protection against oxidation agent is: mass ratio is the curing agent of 1:1 and the mixture of resin glue, and its concrete preparation method is: 1:1 gets curing agent and resin glue in mass ratio, is mixed.
Beneficial effect
1, preparation method's environmental protection of the present invention, the adhesion of gold and silver and carrier is strong, and production technology is simple, and prepared product is ultrathin, and thickness is 0.1-0.3mm, and brightness is high, and stereoeffect is good.
2, with the tree peony that gold and silver makes, its distinctive gloss, more aobvious wealth and rank, petal overlap plays building, arrangement in order, add that pistil is displayed for the first time, folding is uneven, sets off with the emulation leaf between dense phase and scape, make overall series winding, folding, perspective, rhythm, density, collecting and distributing, irregular, circle lacks etc. has stereoeffect, implicit grace, is rich in rhythm graceful bearing, make tree peony more beautiful elegant rhythm colourful, brilliant, exquisite beyond compare, surprise the world.Tree peony is magnificent, splendid and prosperity attitude is incisively and vividly presented in face of people.
3, gold and silver has been in all age the symbol of wealth in the consciousness of people, tree peony is widely known with the identity of " king in spending " again, noble metal, art, culture is integrated with the tree peony that gold and silver makes, it is a part for spiritual civilization and material progress during people live, wide market, demand is large, is a kind of cultural product of society.
Detailed description of the invention
A kind of with tectal peony of silver and preparation method thereof, its concrete preparation process is:
Step one, select metal or nonmetallic materials, be made into the shape of peony petal and pistil; After the foreign material Fouling Cleaning on the peony petal prepared and pistil surface is clean, electricity consumption dries up, for subsequent use;
Step 2, be the resin glue of 1:1-1:2 preparation containing curing agent according to the mass ratio of curing agent and resin glue; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repetition step 2 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform silver layer; Then after the residual solution of silver layer surface being cleaned up by deionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the adhesion of peony petal and pistil and silver layer;
Step 5, integer is carried out to the peony petal being coated with silver layer after step 4 process and pistil after spray protection against oxidation agent;
Step 6, step 5 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers, be then equipped with peony leaves and the stem of emulation, namely obtain adopting the galvanoplastic silver-colored peony of preparing
A kind of with tectal peony of gold and silver and preparation method thereof, its concrete preparation process is:
Step one, select metal or nonmetallic materials, be made into the shape of peony petal and pistil; After the foreign material Fouling Cleaning on the peony petal prepared and pistil surface is clean, electricity consumption dries up, for subsequent use;
Step 2, be the resin glue of 1:1-1:2 preparation containing curing agent according to the mass ratio of curing agent and resin glue; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repetition step 2 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform silver layer; Then after the residual solution of silver layer surface being cleaned up by deionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the adhesion of peony petal and pistil and silver layer;
Step 5, by peony petal and pistil after step 4 process, put into the gold-plated 10-40 minute of the electroplating bath that gold plating solution is housed, forming bright layer gold can take out; Then clean up after the residual solution on layer gold surface by deionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute; To improve the adhesion of silver layer and layer gold;
Step 6, integer is carried out to the peony petal being coated with gold and silver after step 5 process and pistil after spray protection against oxidation agent;
Step 7, step 8 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with peony leaves and the stem of emulation, namely obtain the gold and silver peony adopting galvanoplastic to prepare;
Described nonmetallic materials are silk, plastics, timber or rubber etc., and metal material is iron, copper, tin, lead, zinc, aluminium or alloy etc.
The composition of described special chemical solution is that surplus is deionized water containing stannous chloride 160-260g, hydrochloric acid 200-300ml in often liter of special chemical solution; Its concrete preparation method is: at normal temperatures, is added in 300ml ionized water by 160-260g stannous chloride, is stirred to after dissolving completely, slowly add 200-300ml hydrochloric acid while stirring, continue to be stirred to and clarify completely, be settled to 1L, room temperature is placed after 20-24 hour and can be used.
The composition of the described chemical solution containing silver is: often liter contains silver nitrate 15-25g, ammonium nitrate 2-8g, NaOH 3-15g, ammoniacal liquor 130-180ml containing in the chemical solution of silver, and surplus is deionized water; Its concrete preparation method is: by silver nitrate 15-25g, ammonium nitrate 2-8g, NaOH 3-15g, ammoniacal liquor 130-180ml, at normal temperatures after Homogeneous phase mixing, adds deionized water and is settled to 1L.
The composition of described assistant chemical solution is: containing hydrazine sulfate 30-70g, sucrose 25-55g, absolute alcohol 55-90ml in every 100ml assistant chemical solution, surplus is deionized water; Its concrete preparation method is: by hydrazine sulfate 50g, and sucrose 40g joins in 55-90ml absolute alcohol, adds deionized water and be settled to 100ml after being stirred to dissolving completely.
The composition of described gold plating solution is: containing gold sodium sulfide 1-2g, anhydrous sodium sulfite 10-15g, ethylenediamine 6-12g, potassium hydrogen phosphate 25-35g in often liter of gold plating solution, surplus is deionized water; Its concrete preparation method is: by gold sodium sulfide 1-2g, anhydrous sodium sulfite 10-15g, ethylenediamine 6-12g, and potassium hydrogen phosphate 25-35g is dissolved in 800ml deionized water, is stirred to and dissolves completely, regulates pH value to be 8, adds deionized water and be settled to 1L.
The composition of described protection against oxidation agent is: mass ratio is the curing agent of 1:1 and the mixture of resin glue, and its concrete preparation method is: 1:1 gets curing agent and resin glue in mass ratio, is mixed.
embodiment 1
A kind of with tectal peony of gold and silver and preparation method thereof, its concrete preparation process is:
Step one, select plastics as material, be made into the shape of peony petal and pistil; After the foreign material Fouling Cleaning on the peony petal prepared and pistil surface is clean, hair dryer dries up, for subsequent use;
Step 2, be the resin glue of 1:1 preparation containing curing agent according to the mass ratio of curing agent and resin adhesive layer; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50 DEG C, and the time is 20 minutes;
Step 3, repetition step 21 time, repeat to spray containing the resin glue solidified by peony petal and pistil and toast 1 time;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform bright metal layer; Then by the residual solution of the clean layer on surface of metal of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30 DEG C, and the time is 30 minutes;
Step 5, by peony petal and pistil after step 4 process, put into the electroplating bath that gold plating solution is housed gold-plated 10 minutes, forming bright metal layer can take out; Then by its residual solution with the clean layer on surface of metal of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30 DEG C, and the time is 30 minutes, to improve adhesion;
Step 6, integer is carried out to the peony petal being coated with gold and silver after step 5 process and pistil after spray protection against oxidation agent;
Step 7, step 6 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with peony leaves and the stem of emulation, namely obtain the gold and silver peony adopting galvanoplastic to prepare;
Then be equipped with emulation peony leaves and stem, namely obtain with the tectal peony of gold and silver; It is assembled in special picture frame or large-scale fresco frame or in the space of applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
The concrete preparation method of described special chemical solution is: at normal temperatures, is added in 300ml ionized water by 160g stannous chloride, is stirred to after dissolving completely, slowly add 200ml hydrochloric acid while stirring, continue to be stirred to and clarify completely, be settled to 1L, can use after room temperature places 20 hours.
The concrete preparation method of the described chemical solution containing silver is: by silver nitrate 15g, ammonium nitrate 2g, NaOH 3g, ammoniacal liquor 130ml, at normal temperatures after Homogeneous phase mixing, add deionized water and be settled to 1L.
The concrete preparation method of described assistant chemical solution is: by hydrazine sulfate 50g, and sucrose 40g joins in 55-90ml absolute alcohol, adds deionized water and be settled to 100ml after being stirred to dissolving completely.
The concrete preparation method of described gold plating solution is: by gold sodium sulfide 1g, anhydrous sodium sulfite 10g, ethylenediamine 6g, and potassium hydrogen phosphate 25g is dissolved in 800ml deionized water, is stirred to and dissolves completely, regulates pH value to be 8, adds deionized water and be settled to 1L.
The concrete preparation method of described protection against oxidation agent is: 1:1 gets curing agent and resin glue in mass ratio, is mixed.
embodiment 2
A kind of with tectal peony of gold and silver and preparation method thereof, its concrete preparation process is:
Step one, select silk as material, be made into the shape of peony petal and pistil; After the foreign material Fouling Cleaning on the peony petal prepared and pistil surface is clean, hair dryer dries up, for subsequent use;
Step 2, be the resin glue of 1:1 preparation containing curing agent according to the mass ratio of curing agent and resin adhesive layer; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 60 DEG C, and the time is 30 minutes;
Step 3, repetition step 23 times, repeat to spray containing the resin glue solidified by peony petal and pistil and toast 3 times, it is good for not exposing reticulate pattern with silk;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform bright metal layer; Then by the residual solution of the clean layer on surface of metal of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 40 DEG C, and the time is 50 minutes;
Step 5, by peony petal and pistil after step 4 process, put into the electroplating bath that gold plating solution is housed gold-plated 20 minutes, forming bright metal layer can take out; Then by its residual solution with the clean layer on surface of metal of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 40 DEG C, and the time is 40 minutes;
Step 6, integer is carried out to the peony petal being coated with gold and silver after step 5 process and pistil after spray protection against oxidation agent;
Step 7, step 6 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with peony leaves and the stem of emulation, namely obtain the gold and silver peony adopting galvanoplastic to prepare; It is assembled in special picture frame or large-scale fresco frame or in the space of applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
The concrete preparation method of described special chemical solution is: at normal temperatures, is added in 300ml ionized water by 200g stannous chloride, is stirred to after dissolving completely, slowly add 230ml hydrochloric acid while stirring, continue to be stirred to and clarify completely, be settled to 1L, can use after room temperature places 22 hours.
The concrete preparation method of the described chemical solution containing silver is: by silver nitrate 20g, ammonium nitrate 5g, NaOH 7g, ammoniacal liquor 150ml, at normal temperatures after Homogeneous phase mixing, add deionized water and be settled to 1L.
The concrete preparation method of described assistant chemical solution is: by hydrazine sulfate 50g, and sucrose 40g joins in 55-90ml absolute alcohol, adds deionized water and be settled to 100ml after being stirred to dissolving completely.
The concrete preparation method of described gold plating solution is: by gold sodium sulfide 2g, anhydrous sodium sulfite 12g, ethylenediamine 10g, and potassium hydrogen phosphate 30g is dissolved in 800ml deionized water, is stirred to and dissolves completely, regulates pH value to be 8, adds deionized water and be settled to 1L.
The concrete preparation method of described protection against oxidation agent is: 1:1 gets curing agent and resin glue in mass ratio, is mixed.
embodiment 3
A kind of with tectal peony of gold and silver and preparation method thereof, its concrete preparation process is:
Step one, select stainless steel as material, be made into the shape of peony petal and pistil; By clean for the foreign material Fouling Cleaning on the peony petal for preparing and pistil surface, after electricity consumption dries up, for subsequent use;
Step 2, be the resin glue of 1:2 preparation containing curing agent according to the mass ratio of curing agent and resin adhesive layer; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 100 DEG C, and the time is 60 minutes;
Step 3, repetition step 25 times, repeat to spray containing the resin glue solidified by peony petal and pistil and toast 5 times;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform bright metal layer; Then by the residual solution of the clean layer on surface of metal of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 70 DEG C, and the time is 60 minutes;
Step 5, by peony petal and pistil after step 4 process, put into the electroplating bath that gold plating solution is housed gold-plated 40 minutes, forming bright metal layer can take out; Then by its residual solution with the clean layer on surface of metal of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 70 DEG C, and the time is 60 minutes, to improve adhesion;
Step 6, integer is carried out to the peony petal being coated with gold and silver after step 5 process and pistil after spray protection against oxidation agent;
Step 7, step 6 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with peony leaves and the stem of emulation, namely obtain the gold and silver peony adopting galvanoplastic to prepare; It is assembled in special picture frame or large-scale fresco frame or in the space of applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
The concrete preparation method of described special chemical solution is: at normal temperatures, is added in 300ml ionized water by 260g stannous chloride, is stirred to after dissolving completely, slowly add 300ml hydrochloric acid while stirring, continue to be stirred to and clarify completely, be settled to 1L, can use after room temperature places 24 hours.
The concrete preparation method of the described chemical solution containing silver is: by silver nitrate 25g, ammonium nitrate 8g, NaOH 15g, ammoniacal liquor 180ml, at normal temperatures after Homogeneous phase mixing, add deionized water and be settled to 1L.
The concrete preparation method of described assistant chemical solution is: by hydrazine sulfate 50g, and sucrose 40g joins in 55-90ml absolute alcohol, adds deionized water and be settled to 100ml after being stirred to dissolving completely.
The concrete preparation method of described gold plating solution is: by gold sodium sulfide 2g, anhydrous sodium sulfite 15g, ethylenediamine 12g, and potassium hydrogen phosphate 25-35g is dissolved in 800ml deionized water, is stirred to and dissolves completely, regulates pH value to be 8, adds deionized water and be settled to 1L.
The concrete preparation method of described protection against oxidation agent is: 1:1 gets curing agent and resin glue in mass ratio, is mixed.
embodiment 4
A kind of with tectal peony of silver and preparation method thereof, its concrete preparation process is:
Step one, select plastics as material, be made into the shape of peony petal and pistil; By clean for the foreign material Fouling Cleaning on the peony petal for preparing and pistil surface, after electricity consumption dries up, for subsequent use;
Step 2, be the resin glue of 1:1 preparation containing curing agent according to the mass ratio of curing agent and resin adhesive layer; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50 DEG C, and the time is 20 minutes;
Step 3, repetition step 21 time, repeat to spray containing the resin glue solidified by peony petal and pistil and toast 1 time;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform bright metal layer; Then after the residual solution with the clean layer on surface of metal of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 50 DEG C, and the time is 50 minutes;
Step 5, integer is carried out to the peony petal being coated with silver layer after step 4 process and pistil after spray protection against oxidation agent;
Step 6, step 5 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with peony leaves and the stem of emulation, namely obtain the gold and silver peony adopting galvanoplastic to prepare; It is assembled in special picture frame or large-scale fresco frame or in the space of applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
The concrete preparation method of described special chemical solution is: at normal temperatures, is added in 300ml ionized water by 160g stannous chloride, is stirred to after dissolving completely, slowly add 200ml hydrochloric acid while stirring, continue to be stirred to and clarify completely, be settled to 1L, can use after room temperature places 20 hours.
The concrete preparation method of the described chemical solution containing silver is: by silver nitrate 15g, ammonium nitrate 2g, NaOH 3g, ammoniacal liquor 130ml, at normal temperatures after Homogeneous phase mixing, add deionized water and be settled to 1L.
The concrete preparation method of described assistant chemical solution is: by hydrazine sulfate 50g, and sucrose 40g joins in 55-90ml absolute alcohol, adds deionized water and be settled to 100ml after being stirred to dissolving completely.
The concrete preparation method of described protection against oxidation agent is: 1:1 gets curing agent and resin glue in mass ratio, is mixed.
Stannous chloride described in the present invention, hydrochloric acid, silver nitrate, ammonium nitrate, NaOH, ammoniacal liquor, hydrazine sulfate, sucrose, absolute alcohol, gold sodium sulfide, anhydrous sodium sulfite, ethylenediamine, potassium hydrogen phosphate curing agent and resin glue are all bought by market and are obtained.
Claims (4)
1. with a preparation method for the tectal peony of silver, it is characterized in that: its concrete preparation process is:
Step one, select metal or nonmetallic materials, be made into the shape of peony petal and pistil; After the foreign material Fouling Cleaning on the peony petal prepared and pistil surface is clean, electricity consumption dries up, for subsequent use;
Step 2, be the resin glue of 1:1-1:2 preparation containing curing agent according to the mass ratio of curing agent and resin glue; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repetition step 2 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform silver layer; Then after the residual solution of silver layer surface being cleaned up by deionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute;
Step 5, integer is carried out to the peony petal being coated with silver layer after step 4 process and pistil after spray protection against oxidation agent;
Step 6, step 5 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers, be then equipped with peony leaves and the stem of emulation, namely obtain adopting the galvanoplastic silver-colored peony of preparing;
The composition of described special chemical solution: containing stannous chloride 160-260g, hydrochloric acid 200-300ml in often liter of special chemical solution, surplus is deionized water;
The composition of the described chemical solution containing silver: often liter contains silver nitrate 15-25g, ammonium nitrate 2-8g, NaOH 3-15g, ammoniacal liquor 130-180ml containing in the chemical solution of silver, and surplus is deionized water;
The composition of described assistant chemical solution: containing hydrazine sulfate 30-70g, sucrose 25-55g, absolute alcohol 55-90ml in every 100ml assistant chemical solution, surplus is deionized water;
Described protection against oxidation agent is mass ratio is the curing agent of 1:1 and the mixture of resin glue.
2. as claimed in claim 1 a kind of with tectal peony of silver and preparation method thereof, it is characterized in that: described nonmetallic materials are silk, plastics, timber or rubber one wherein, metal material is iron, copper, tin, lead, zinc, aluminium or alloy one wherein.
3. with a preparation method for the tectal peony of gold and silver, it is characterized in that: its concrete preparation process is:
Step one, select metal or nonmetallic materials, be made into the shape of peony petal and pistil; After the foreign material Fouling Cleaning on the peony petal prepared and pistil surface is clean, electricity consumption dries up, for subsequent use;
Step 2, be the resin glue of 1:1-1:2 preparation containing curing agent according to the mass ratio of curing agent and resin glue; Then by prepare containing peony petal prepared by step one of the resin glue even application of curing agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repetition step 2 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by the peony petal after step 3 process and pistil, first to activate with special chemical solution spraying surface, then spray chemical solution containing silver and assistant chemical solution to surface with double head spray gun simultaneously, form a kind of uniform silver layer; Then after the residual solution of silver layer surface being cleaned up by deionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute;
Step 5, by peony petal and pistil after step 4 process, put into the gold-plated 10-40 minute of the electroplating bath that gold plating solution is housed, forming bright layer gold can take out; Then clean up after the residual solution on layer gold surface by deionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute;
Step 6, integer is carried out to the peony petal being coated with gold and silver after step 5 process and pistil after spray protection against oxidation agent;
Step 7, step 6 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with peony leaves and the stem of emulation, namely obtain the gold and silver peony adopting galvanoplastic to prepare;
The composition of described special chemical solution: containing stannous chloride 160-260g, hydrochloric acid 200-300ml in often liter of special chemical solution, surplus is deionized water;
The composition of the described chemical solution containing silver: often liter contains silver nitrate 15-25g, ammonium nitrate 2-8g, NaOH 3-15g, ammoniacal liquor 130-180ml containing in the chemical solution of silver, and surplus is deionized water;
The composition of described assistant chemical solution: containing hydrazine sulfate 30-70g, sucrose 25-55g, absolute alcohol 55-90ml in every 100ml assistant chemical solution, surplus is deionized water;
The composition of described gold plating solution: containing gold sodium sulfide 1-2g, anhydrous sodium sulfite 10-15g, ethylenediamine 6-12g, potassium hydrogen phosphate 25-35g in often liter of gold plating solution, surplus is deionized water;
Described protection against oxidation agent is mass ratio is the curing agent of 1:1 and the mixture of resin glue.
4. as claimed in claim 3 a kind of with tectal peony of gold and silver and preparation method thereof, it is characterized in that: described nonmetallic materials are its one of silk, plastics, timber or rubber, and metal material is iron, copper, tin, lead, zinc, aluminium or alloy one wherein.
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| CN114775009A (en) * | 2022-04-26 | 2022-07-22 | 上海瑞尔实业有限公司 | Highlight electroplating process for air inlet grille |
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| CN101752456A (en) * | 2008-12-22 | 2010-06-23 | 上海欧菲尔光电技术有限公司 | Fabrication process of package window of infrared focal plane detector |
| JP4711435B2 (en) * | 2004-07-09 | 2011-06-29 | Ｊｘ日鉱日石金属株式会社 | Electroless gold plating solution |
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| JP4711435B2 (en) * | 2004-07-09 | 2011-06-29 | Ｊｘ日鉱日石金属株式会社 | Electroless gold plating solution |
| CN1936075A (en) * | 2005-09-19 | 2007-03-28 | 广州爱先化工有限公司 | Electroplating-substituted cladding coating and process |
| CN101752456A (en) * | 2008-12-22 | 2010-06-23 | 上海欧菲尔光电技术有限公司 | Fabrication process of package window of infrared focal plane detector |
| CN102513283A (en) * | 2011-12-14 | 2012-06-27 | 温州市汇泰隆科技有限公司 | Nano multi-group spray-coating production line process and equipment |
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