CN102877092B - Silver or gold and silver peony prepared by adopting electrochemical plating method and preparation method thereof - Google Patents
Silver or gold and silver peony prepared by adopting electrochemical plating method and preparation method thereof Download PDFInfo
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- CN102877092B CN102877092B CN201210395488.3A CN201210395488A CN102877092B CN 102877092 B CN102877092 B CN 102877092B CN 201210395488 A CN201210395488 A CN 201210395488A CN 102877092 B CN102877092 B CN 102877092B
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Abstract
The invention relates to silver or gold and silver peony prepared by adopting an electrochemical plating method and a preparation method thereof. A metal or non-metal material is selected; the metal or non-metal material is made into a peony flower or bud shape; a resin adhesive layer containing a curing agent is sprayed on the surface of the metal or non-metal material; one or more of silver oil, copper oil, nano metal powder oil and conductive powder or conductive powder oil are uniformly sprayed on the surface of the resin adhesive layer; then a silver layer is plated in an electroplating bath filled with silver plating solution so as to obtain the silver peony prepared by adopting the electrochemical plating method; and the silver peony prepared by adopting the electrochemical plating method is plated with a gold layer in an electroplating bath filled with gold plating solution so as to obtain the gold and silver peony prepared by adopting the electrochemical plating method. According to the preparation method disclosed by the invention, the gold and silver layer and a carrier have strong binding force, the production process is simple, and the prepared product is ultrathin, the thickness is 0.1 to 0.3mm and high brightness and a good stereoscopic effect are realized.
Description
Technical field
The present invention relates to a kind of metal handicraft and preparation method thereof, specifically a kind of adopt electrochemical plating to prepare there is silver or the tectal Tree Peony flower of gold and silver and preparation method thereof.
Background technology
Tree peony is elegant and poised, have the good reputation of " aromatic ", " king in spending ", and China has just handed down and become social custom since the Tang and Song Dynasty, and being called national flower, is the famous flower that our people likes, (Tang) Liu Yu tin poem is said: " before front yard, Chinese herbaceous peony goblin is without lattice, and on pond, lotus lacks feelings only.Have the true reigning beauty of tree peony only, the flowers are in blossom, and the time moves capital." from that time, the aromatic synonym just becoming tree peony.Then directly claim " tree peony " for the king in spending in " mirror flower edge " book.
Existing various art flower class in the market, make mainly with raw materials such as plastics silk weaving, stationeries, its feature only possesses the effect of viewing and admiring, and by the colored class that gold and silver make, both there is sight, had again very high reserve value, integrate culture and wealth, the life of modern people can be met.
Summary of the invention
The object of the invention is to provide a kind of silver or gold and silver Tree Peony flower and preparation method thereof that adopt electrochemical plating to prepare for the problems referred to above, preparation method's environmental protection, the bonding force of gold and silver and carrier is strong, production technique is simple, prepared product is ultrathin, thickness is 0.1-0.3mm, and luminance brightness is high, and stereoeffect is good.
A kind of silver-colored Tree Peony flower adopting electrochemical plating to prepare and preparation method thereof, its concrete preparation process is:
Step one, select metal or non-metallic material, be made into the shape of peony petal and pistil; By after clean for the foreign material Fouling Cleaning of the peony petal for preparing and pistil, electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive of 1:1-1:2 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, peony petal after step 3 process of one or more material even application in conducting powder or conducting powder oil and pistil surface; Then be placed in drying baker and dry, temperature is 10-30 DEG C, and the time is 3-5 hour;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 1-3A/dm
2, the time is 3-10 hour, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the raising bonding force of silver layer and peony petal and pistil;
Step 6, to after step 5 process be coated with silver peony petal and pistil carry out integer after spray protection against oxidation agent;
Step 7, step 6 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers, be then equipped with tree peony leaf and the stem of emulation, namely obtain adopting the electrochemical plating silver-colored Tree Peony flower of preparing; It is assembled in the space of special picture frame, large-scale fresco frame or applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
A kind of gold and silver Tree Peony flower adopting electrochemical plating to prepare and preparation method thereof, its concrete preparation process is:
Step one, select metal or non-metallic material, be made into the shape of peony petal and pistil; By after clean for the foreign material Fouling Cleaning of the peony petal for preparing and pistil, electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive of 1:1-1:2 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, peony petal after step 3 process of one or more material even application in conducting powder or conducting powder oil and pistil surface; Then be placed in drying baker and dry, temperature is 10-30 DEG C, and the time is 3-5 hour;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 1-3A/dm
2, the time is 3-10 hour, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the raising bonding force of silver layer and peony petal and pistil;
Step 6, by after step 5 process with the peony petal of silver layer and pistil, be placed in the plating tank that gold plating solution is housed and carry out gold-plated, electrical current is 1-3A/dm
2, the time is 10-40 minute, and gold-plated end rear surface generates the uniform bright layer gold of one deck; Then by its residual solution with the clean layer gold surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the bonding force of silver layer and layer gold;
Step 7, integer is carried out to the peony petal being coated with gold and silver after step 6 process and pistil after spray protection against oxidation agent;
Step 8, step 7 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with tree peony leaf and the stem of emulation, namely obtain the gold and silver Tree Peony flower adopting electrochemical plating to prepare; It is assembled in the space of special picture frame, large-scale fresco frame or applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
Described non-metallic material are silk, plastics, timber or rubber etc., and metallic substance is iron, copper, tin, lead, zinc, aluminium or alloy etc.
The composition of described silver plating solution: containing potassium cyanide 110g, silver potassium cyanide 30-45g, salt of wormwood 15g, open cylinder agent 6ml, brightening agent 0.5ml in often liter of silver plating solution, surplus is deionized water; ;
The composition of described gold plating solution: containing gold sodium sulfide 1-2g, sodium sulphite anhydrous 99.3 10-15g, quadrol 6-12g, potassium hydrogen phosphate 25-35g in often liter of gold plating solution, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, is mixed.
Beneficial effect
1, preparation method's environmental protection of the present invention, the bonding force of gold and silver and carrier is strong, and production technique is simple, and prepared product is ultrathin, and thickness is 0.1-0.3mm, and luminance brightness is high, and stereoeffect is good.
2, with the tree peony that gold and silver makes, its distinctive gloss, more aobvious wealth and rank, petal overlap plays building, arrangement in order, add that pistil is displayed for the first time, folding is uneven, sets off with the emulation leaf between dense phase and scape, make overall series winding, folding, perspective, rhythm, density, collecting and distributing, irregular, circle lacks etc. has stereoeffect, implicit grace, is rich in rhythm graceful bearing, make tree peony more beautiful elegant rhythm colourful, brilliant, exquisite beyond compare, surprise the world.Tree peony is magnificent, splendid and prosperity attitude is incisively and vividly presented in face of people.
3, gold and silver has been in all age the symbol of wealth in the consciousness of people, tree peony is widely known with the identity of " king in spending " again, precious metal, art, culture is integrated with the tree peony that gold and silver makes, it is a part for spiritual civilization and material progress during people live, wide market, demand is large, is a kind of cultural product of society.
Embodiment
A kind of silver-colored Tree Peony flower adopting electrochemical plating to prepare and preparation method thereof, its concrete preparation process is:
Step one, select metal or non-metallic material, be made into the shape of peony petal and pistil; By after clean for the foreign material Fouling Cleaning of the peony petal for preparing and pistil, electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive of 1:1-1:2 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, peony petal after step 3 process of one or more material even application in conducting powder or conducting powder oil and pistil surface; Then be placed in drying baker and dry, temperature is 10-30 DEG C, and the time is 3-5 hour;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 1-3A/dm
2, the time is 3-10 hour, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the raising bonding force of silver layer and peony petal and pistil;
Step 6, to after step 5 process be coated with silver peony petal and pistil carry out integer after spray protection against oxidation agent;
Step 7, step 6 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers, be then equipped with tree peony leaf and the stem of emulation, namely obtain adopting the electrochemical plating silver-colored Tree Peony flower of preparing; It is assembled in the space of special picture frame, large-scale fresco frame or applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
A kind of gold and silver Tree Peony flower adopting electrochemical plating to prepare and preparation method thereof, its concrete preparation process is:
Step one, select metal or non-metallic material, be made into the shape of peony petal and pistil; By after clean for the foreign material Fouling Cleaning of the peony petal for preparing and pistil, electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive of 1:1-1:2 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, peony petal after step 3 process of one or more material even application in conducting powder or conducting powder oil and pistil surface; Then be placed in drying baker and dry, temperature is 10-30 DEG C, and the time is 3-5 hour;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 1-3A/dm
2, the time is 3-10 hour, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the raising bonding force of silver layer and peony petal and pistil;
Step 6, by after step 5 process with the peony petal of silver layer and pistil, be placed in the plating tank that gold plating solution is housed and carry out gold-plated, electrical current is 1-3A/dm
2, the time is 10-40 minute, and gold-plated end rear surface generates the uniform bright layer gold of one deck; Then by its residual solution with the clean layer gold surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute, to improve the bonding force of silver layer and layer gold;
Step 7, integer is carried out to the peony petal being coated with gold and silver after step 6 process and pistil after spray protection against oxidation agent;
Step 8, step 7 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with tree peony leaf and the stem of emulation, namely obtain the gold and silver Tree Peony flower adopting electrochemical plating to prepare; It is assembled in the space of special picture frame, large-scale fresco frame or applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
Described non-metallic material are silk, plastics, timber or rubber etc., and metallic substance is iron, copper, tin, lead, zinc, aluminium or alloy etc.
The composition of described silver plating solution: containing potassium cyanide 110g, silver potassium cyanide 30-45g, salt of wormwood 15g, open cylinder agent 6ml, brightening agent 0.5ml in often liter of silver plating solution, surplus is deionized water; ;
The composition of described gold plating solution: containing gold sodium sulfide 1-2g, sodium sulphite anhydrous 99.3 10-15g, quadrol 6-12g, potassium hydrogen phosphate 25-35g in often liter of gold plating solution, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, is mixed.
embodiment 1
A kind of gold and silver Tree Peony flower adopting electrochemical plating to prepare and preparation method thereof, its concrete preparation process is:
Step one, select silk as material, be made into the shape of petal or pistil; After clean for the foreign material dirt electricity consumption blowing on the peony petal for preparing and pistil surface, for subsequent use;
Step 2, be the Resin adhesive of 1:1 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50 DEG C, and the time is 20 minutes;
Step 3, repeating step 21 times, be cooled to 15 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, one or more material even application in conducting powder or conducting powder oil are cooled to the peony petal after the step 3 process of 15 DEG C and pistil surface in temperature; Then be placed in drying baker and dry, temperature is 10 DEG C, and the time is 3-5 hour;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 1A/dm
2, the time is 10 hours, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30 DEG C, and the time is 30 minutes, to improve the bonding force of silver layer and peony petal and pistil;
Step 6, by after step 5 process with the peony petal of silver layer and pistil, be placed in the plating tank that gold plating solution is housed and carry out gold-plated, electrical current is 1A/dm
2, 40 minutes time, gold-plated end rear surface generates the uniform bright layer gold of one deck; Then by its residual solution with the clean layer gold surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30 DEG C, and the time is 60 minutes, to improve the bonding force of silver layer and layer gold;
Step 7, integer is carried out to the peony petal being coated with gold and silver after step 6 process and pistil after spray protection against oxidation agent;
Step 8, integer is carried out to the peony petal being coated with gold and silver after step 7 process and pistil after spray protection against oxidation agent; Then be equipped with tree peony leaf and the stem of emulation, namely obtain the gold and silver Tree Peony flower adopting electrochemical plating to prepare; It is assembled in special picture frame or large-scale fresco frame or in the space of applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
The composition of described silver plating solution: containing potassium cyanide 110g, silver potassium cyanide 30g, salt of wormwood 15g, open cylinder agent 6ml, brightening agent 0.5ml in often liter of silver plating solution, surplus is deionized water;
The composition of described gold plating solution: containing gold sodium sulfide 1-2g, sodium sulphite anhydrous 99.3 10g, quadrol 6g, potassium hydrogen phosphate 25g in often liter of gold plating solution, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, is mixed.
embodiment 2
A kind of gold and silver Tree Peony flower adopting electrochemical plating to prepare and preparation method thereof, its concrete preparation process is:
Step one, select rubber as material, be made into the shape of peony petal and pistil; After clean for the foreign material dirt electricity consumption blowing on the peony petal for preparing and pistil surface, for subsequent use;
Step 2, be the Resin adhesive of 1:2 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 80 DEG C, and the time is 40 minutes;
Step 3, repeating step 23 times, be cooled to 20 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, one or more material even application in conducting powder or conducting powder oil are cooled to the peony petal after the step 3 process of 20 DEG C and pistil surface in temperature; Then be placed in drying baker and dry, temperature is 20 DEG C, and the time is 4 hours;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 2A/dm
2, the time is 6 hours, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 50 DEG C, and the time is 40 minutes, to improve bonding force;
Step 6, by after step 5 process with the peony petal of silver layer and pistil, be placed in the plating tank that gold plating solution is housed and carry out gold-plated, electrical current is 2A/dm
2, the time is 30 minutes, and gold-plated end rear surface generates the uniform bright layer gold of one deck; Then by its residual solution with the clean layer gold surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 40 DEG C, and the time is 50 minutes, to improve bonding force;
Step 7, integer is carried out to the peony petal being coated with gold and silver after step 6 process and pistil after spray protection against oxidation agent;
Step 8, integer is carried out to the peony petal being coated with gold and silver after step 7 process and pistil after spray protection against oxidation agent; Then be equipped with tree peony leaf and the stem of emulation, namely obtain the gold and silver Tree Peony flower adopting electrochemical plating to prepare; It is assembled in special picture frame or large-scale fresco frame or in the space of applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
The composition of described silver plating solution: containing potassium cyanide 110g, silver potassium cyanide 40g, salt of wormwood 15g, open cylinder agent 6ml, brightening agent 0.5ml in often liter of silver plating solution, surplus is deionized water;
The composition of described gold plating solution: containing gold sodium sulfide 2g, sodium sulphite anhydrous 99.3 12g, quadrol 8g, potassium hydrogen phosphate 28g in often liter of gold plating solution, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, is mixed.
embodiment 3
A kind of gold and silver Tree Peony flower adopting electrochemical plating to prepare and preparation method thereof, its concrete preparation process is:
Step one, select iron as material, be made into the shape of peony petal and pistil; After clean for the foreign material dirt electricity consumption blowing on the peony petal for preparing and pistil surface, for subsequent use;
Step 2, be the Resin adhesive of 1:1 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 100 DEG C, and the time is 20 minutes;
Step 3, repeating step 25 times, be cooled to 25 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, one or more material even application in conducting powder or conducting powder oil are cooled to the peony petal after the step 3 process of 25 DEG C and pistil surface in temperature; Then be placed in drying baker and dry, temperature is 30 DEG C, and the time is 3 hours;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 3A/dm
2, the time is 3 hours, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 70 DEG C, and the time is 30 minutes, to improve bonding force;
Step 6, by after step 5 process with the peony petal of silver layer and pistil, be placed in the plating tank that gold plating solution is housed and carry out gold-plated, electrical current is 3A/dm
2, the time is 10 minutes, and gold-plated end rear surface generates the uniform bright layer gold of one deck; Then by its residual solution with the clean layer gold surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 70 DEG C, and the time is 30 minutes, to improve bonding force;
Step 7, integer is carried out to the peony petal being coated with gold and silver after step 6 process and pistil after spray protection against oxidation agent;
Step 8, integer is carried out to the peony petal being coated with gold and silver after step 7 process and pistil after spray protection against oxidation agent; Then be equipped with tree peony leaf and the stem of emulation, namely obtain the gold and silver Tree Peony flower adopting electrochemical plating to prepare; It is assembled in special picture frame or large-scale fresco frame or in the space of applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
The composition of described silver plating solution: containing potassium cyanide 110g, silver potassium cyanide 45g, salt of wormwood 15g, open cylinder agent 6ml, brightening agent 0.5ml in often liter of silver plating solution, surplus is deionized water;
The composition of described gold plating solution: containing gold sodium sulfide 2g, sodium sulphite anhydrous 99.3 15g, quadrol 12g, potassium hydrogen phosphate 35g in often liter of gold plating solution, surplus is deionized water.
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, is mixed.
embodiment 4
A kind of silver-colored Tree Peony flower adopting electrochemical plating to prepare and preparation method thereof, its concrete preparation process is:
Step one, select plastics as material, be made into the shape of peony petal and pistil; After clean for the foreign material dirt electricity consumption blowing on the peony petal for preparing and pistil surface, for subsequent use;
Step 2, be the Resin adhesive of 1:1 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50 DEG C, and the time is 20 minutes;
Step 3, repeating step 21 times, be cooled to 23 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, one or more material even application in conducting powder or conducting powder oil are cooled to the peony petal after the step 3 process of 15 DEG C and pistil surface in temperature; Then be placed in drying baker and dry, temperature is 10 DEG C, and the time is 3-5 hour;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 1A/dm
2, the time is 10 hours, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30 DEG C, and the time is 30 minutes, to improve bonding force;
Step 6, integer is carried out to the peony petal being coated with gold and silver after step 5 process and pistil after spray protection against oxidation agent;
Step 7, integer is carried out to the peony petal being coated with gold and silver after step 6 process and pistil after spray protection against oxidation agent; Then be equipped with tree peony leaf and the stem of emulation, namely obtain the gold and silver Tree Peony flower adopting electrochemical plating to prepare; It is assembled in special picture frame or large-scale fresco frame or in the space of applicable demand according to different styles, is equipped with the packaging warehouse-in of demand.
The composition of described silver plating solution: containing potassium cyanide 110g, silver potassium cyanide 30g, salt of wormwood 15g, open cylinder agent 6ml, brightening agent 0.5ml in often liter of silver plating solution, surplus is deionized water;
The composition of described anti-oxidant protective agent is: mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive, and its concrete preparation method is: 1:1 gets solidifying agent and Resin adhesive in mass ratio, is mixed.
Potassium cyanide described in the present invention, silver potassium cyanide, salt of wormwood, open cylinder agent, brightening agent, gold sodium sulfide, quadrol, potassium hydrogen phosphate, solidifying agent and Resin adhesive, all buy by market and obtain.
Claims (2)
1. a preparation method for the silver-colored Tree Peony flower adopting electrochemical plating to prepare, is characterized in that: its concrete preparation process is:
Step one, select metal or non-metallic material, be made into the shape of peony petal and pistil; By after clean for the foreign material Fouling Cleaning of the peony petal for preparing and pistil, electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive of 1:1-1:2 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, peony petal after step 3 process of one or more material even application in conducting powder or conducting powder oil and pistil surface; Then be placed in drying baker and dry, temperature is 10-30 DEG C, and the time is 3-5 hour;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 1-3A/dm
2, the time is 3-10 hour, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute;
Step 6, to after step 5 process be coated with silver peony petal and pistil carry out integer after spray protection against oxidation agent;
Step 7, step 6 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers, be then equipped with tree peony leaf and the stem of emulation, namely obtaining flower sheet thickness is silver-colored Tree Peony flower prepared by the employing electrochemical plating of 0.1-0.3mm;
The composition of described silver plating solution: containing potassium cyanide 110g, silver potassium cyanide 30-45g, salt of wormwood 15g, open cylinder agent 6ml, brightening agent 0.5ml in often liter of silver plating solution, surplus is deionized water;
Described anti-oxidant protective agent is mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive;
Described non-metallic material are silk, plastics, timber or rubber one wherein, and metallic substance is iron, copper, tin, lead, zinc, aluminium or alloy one wherein.
2. a preparation method for the gold and silver Tree Peony flower adopting electrochemical plating to prepare, is characterized in that: its concrete preparation process is:
Step one, select metal or non-metallic material, be made into the shape of peony petal and pistil; By after clean for the foreign material Fouling Cleaning of the peony petal for preparing and pistil, electricity consumption blowing, for subsequent use;
Step 2, be the Resin adhesive of 1:1-1:2 preparation containing solidifying agent according to the mass ratio of solidifying agent and Resin adhesive; Then by prepare containing peony petal prepared by step one of the Resin adhesive even application of solidifying agent and pistil surface; Be placed in baking oven after spraying terminates and toast, temperature is at 50-100 DEG C, and the time is 20-60 minute;
Step 3, repeating step two 1-5 time, be cooled to 15-25 DEG C afterwards;
Step 4, by silver oil, copper is oily, Nano metal powder is oily, peony petal after step 3 process of one or more material even application in conducting powder or conducting powder oil and pistil surface; Then be placed in drying baker and dry, temperature is 10-30 DEG C, and the time is 3-5 hour;
Step 5, by the peony petal after step 4 process and pistil, be placed in the plating tank that silver plating solution is housed and carry out silver-plated, electrical current is 1-3A/dm
2, the time is 3-10 hour, takes out after silver-plated end, peony petal and the uniform bright silver layer of pistil Surface Creation one deck; Then by the residual solution of the clean silver layer surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute;
Step 6, by after step 5 process with the peony petal of silver layer and pistil, be placed in the plating tank that gold plating solution is housed and carry out gold-plated, electrical current is 1-3A/dm
2, the time is 10-40 minute, and gold-plated end rear surface generates the uniform bright layer gold of one deck; Then by its residual solution with the clean layer gold surface of washed with de-ionized water, be placed in baking oven and dry moisture content, control temperature is at 30-70 DEG C, and the time is 30-60 minute;
Step 7, integer is carried out to the peony petal being coated with gold and silver after step 6 process and pistil after spray protection against oxidation agent;
Step 8, step 7 is sprayed protection against oxidation agent after peony petal and pistil be assembled into peony flowers; Then be equipped with tree peony leaf and the stem of emulation, namely obtaining flower sheet thickness is gold and silver Tree Peony flower prepared by the employing electrochemical plating of 0.1-0.3mm;
The composition of described silver plating solution: containing potassium cyanide 110g, silver potassium cyanide 30-45g, salt of wormwood 15g, open cylinder agent 6ml, brightening agent 0.5ml in often liter of silver plating solution, surplus is deionized water;
The composition of described gold plating solution: containing gold sodium sulfide 1-2g, sodium sulphite anhydrous 99.3 10-15g, quadrol 6-12g, potassium hydrogen phosphate 25-35g in often liter of gold plating solution, surplus is deionized water;
Described anti-oxidant protective agent is mass ratio is the solidifying agent of 1:1 and the mixture of Resin adhesive;
Described non-metallic material are silk, plastics, timber or rubber one wherein, and metallic substance is iron, copper, tin, lead, zinc, aluminium or alloy one wherein.
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| CN201210395488.3A CN102877092B (en) | 2012-10-18 | 2012-10-18 | Silver or gold and silver peony prepared by adopting electrochemical plating method and preparation method thereof |
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| CN102877092B true CN102877092B (en) | 2015-06-03 |
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| CN103668372B (en) * | 2013-11-04 | 2016-05-25 | 上海应用技术学院 | A kind of electro-plating method of carbon skeleton material Direct Electroplating |
| CN109680312A (en) * | 2019-01-24 | 2019-04-26 | 南京理工大学 | The method for plating the preparation super-hydrophobic Zinc material of sheet as template electric using natural timber |
| CN110584248A (en) * | 2019-09-25 | 2019-12-20 | 铜陵铜官府文化创意股份公司 | Method for simulating ultrathin flower and leaf plants by using copper process |
| CN113136542B (en) * | 2021-04-26 | 2023-08-15 | 河南机电职业学院 | Preparation method of gold-coated silver bonding wire |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2031024A (en) * | 1978-10-06 | 1980-04-16 | Standards Inst Singapore | Process for Electroforming from Natural Flowers |
| CN1524978A (en) * | 2003-02-26 | 2004-09-01 | 夏红元 | Electroplating method for flowers and tree leaves |
| CN200987382Y (en) * | 2006-01-19 | 2007-12-12 | 宏江科技有限公司 | Plant flower surface electroplating structure |
| CN101361603A (en) * | 2008-10-14 | 2009-02-11 | 深圳市金龙珠宝首饰有限公司 | Living rose gold-plating production technique flow |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI315748B (en) * | 2006-07-21 | 2009-10-11 | Lotes Co Ltd | Forming method for manufacturing model |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2031024A (en) * | 1978-10-06 | 1980-04-16 | Standards Inst Singapore | Process for Electroforming from Natural Flowers |
| CN1524978A (en) * | 2003-02-26 | 2004-09-01 | 夏红元 | Electroplating method for flowers and tree leaves |
| CN200987382Y (en) * | 2006-01-19 | 2007-12-12 | 宏江科技有限公司 | Plant flower surface electroplating structure |
| CN101361603A (en) * | 2008-10-14 | 2009-02-11 | 深圳市金龙珠宝首饰有限公司 | Living rose gold-plating production technique flow |
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