CN102874853B - 一种环状镁铝双羟基复合金属氢氧化物及其制备方法 - Google Patents
一种环状镁铝双羟基复合金属氢氧化物及其制备方法 Download PDFInfo
- Publication number
- CN102874853B CN102874853B CN201110193652.8A CN201110193652A CN102874853B CN 102874853 B CN102874853 B CN 102874853B CN 201110193652 A CN201110193652 A CN 201110193652A CN 102874853 B CN102874853 B CN 102874853B
- Authority
- CN
- China
- Prior art keywords
- reaction
- metal hydroxide
- ring
- hydrotalcite
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910000000 metal hydroxide Inorganic materials 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000002131 composite material Substances 0.000 title claims description 5
- 150000004692 metal hydroxides Chemical class 0.000 title claims description 5
- 229910003023 Mg-Al Inorganic materials 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims abstract description 35
- 239000002063 nanoring Substances 0.000 claims abstract description 26
- 239000002070 nanowire Substances 0.000 claims abstract description 19
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004202 carbamide Substances 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- 239000003960 organic solvent Substances 0.000 claims abstract description 9
- 239000011148 porous material Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000012046 mixed solvent Substances 0.000 claims description 17
- 239000011777 magnesium Substances 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- -1 deionized water compound Chemical class 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 8
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000376 reactant Substances 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000000084 colloidal system Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 229910001051 Magnalium Inorganic materials 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical group Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 claims 1
- 238000007605 air drying Methods 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 150000001457 metallic cations Chemical class 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 230000003068 static effect Effects 0.000 claims 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 abstract description 37
- 229960001545 hydrotalcite Drugs 0.000 abstract description 35
- 229910001701 hydrotalcite Inorganic materials 0.000 abstract description 35
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 abstract description 9
- 238000004729 solvothermal method Methods 0.000 abstract description 7
- 238000001179 sorption measurement Methods 0.000 abstract description 5
- 238000006555 catalytic reaction Methods 0.000 abstract description 4
- 125000004122 cyclic group Chemical group 0.000 abstract description 4
- 229940079593 drug Drugs 0.000 abstract description 3
- 239000003814 drug Substances 0.000 abstract description 3
- 238000013268 sustained release Methods 0.000 abstract description 3
- 239000012730 sustained-release form Substances 0.000 abstract description 3
- 239000002243 precursor Substances 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 13
- 239000000047 product Substances 0.000 description 8
- 239000002244 precipitate Substances 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000012295 chemical reaction liquid Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
Images
Landscapes
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110193652.8A CN102874853B (zh) | 2011-07-12 | 2011-07-12 | 一种环状镁铝双羟基复合金属氢氧化物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110193652.8A CN102874853B (zh) | 2011-07-12 | 2011-07-12 | 一种环状镁铝双羟基复合金属氢氧化物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102874853A CN102874853A (zh) | 2013-01-16 |
CN102874853B true CN102874853B (zh) | 2014-04-09 |
Family
ID=47476418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201110193652.8A Expired - Fee Related CN102874853B (zh) | 2011-07-12 | 2011-07-12 | 一种环状镁铝双羟基复合金属氢氧化物及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102874853B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104944548A (zh) * | 2015-06-08 | 2015-09-30 | 徐强富 | 多羟基氯化铝水处理剂及生产方法 |
CN110129815B (zh) * | 2019-04-24 | 2020-10-16 | 北京大学深圳研究生院 | 改性的tm-ldh纳米材料、其制备方法及应用 |
CN113699375A (zh) * | 2021-09-01 | 2021-11-26 | 河北工程大学 | 一种提高微生物浸出稀土元素浸出率的添加液及制备方法和应用 |
CN115304925A (zh) * | 2022-01-27 | 2022-11-08 | 山东建筑大学 | 一种低融点速溶高黏沥青改性剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101239733A (zh) * | 2008-03-05 | 2008-08-13 | 北京化工大学 | 一种用做混凝土外加剂的钙铝水滑石制备方法 |
CN101797492A (zh) * | 2010-04-16 | 2010-08-11 | 北京化工大学 | 一种层状双羟基复合金属氢氧化物多孔微球的制备方法 |
CN101822981A (zh) * | 2010-04-30 | 2010-09-08 | 北京化工大学 | 一种负载型金催化剂及其制备方法 |
EP2263976A1 (en) * | 2009-06-03 | 2010-12-22 | Akzo Nobel Chemicals International B.V. | Layered double hydroxide with a specific morphology, its preparation and use |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4997705B2 (ja) * | 2005-02-24 | 2012-08-08 | 富士ゼロックス株式会社 | 表面被覆難燃性粒子及びその製造方法、並びに難燃性樹脂組成物及びその製造方法 |
-
2011
- 2011-07-12 CN CN201110193652.8A patent/CN102874853B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101239733A (zh) * | 2008-03-05 | 2008-08-13 | 北京化工大学 | 一种用做混凝土外加剂的钙铝水滑石制备方法 |
EP2263976A1 (en) * | 2009-06-03 | 2010-12-22 | Akzo Nobel Chemicals International B.V. | Layered double hydroxide with a specific morphology, its preparation and use |
CN101797492A (zh) * | 2010-04-16 | 2010-08-11 | 北京化工大学 | 一种层状双羟基复合金属氢氧化物多孔微球的制备方法 |
CN101822981A (zh) * | 2010-04-30 | 2010-09-08 | 北京化工大学 | 一种负载型金催化剂及其制备方法 |
Non-Patent Citations (3)
Title |
---|
fan weiliu.Solvothermal synthesis of Mg(OH)2 nanotubes using Mg10(OH)18Cl2?5H2O nanowires as precursors.《materials》.2003,第3062-3065页. |
JP特开2006-232982A 2006.09.07 |
Solvothermal synthesis of Mg(OH)2 nanotubes using Mg10(OH)18Cl2?5H2O nanowires as precursors;fan weiliu;《materials》;20031031;第3062-3065页 * |
Also Published As
Publication number | Publication date |
---|---|
CN102874853A (zh) | 2013-01-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Cai et al. | Template-free hydrothermal fabrication of hierarchically organized γ-AlOOH hollow microspheres | |
CN103011215B (zh) | 一种勃姆石微纳结构球及其制备方法 | |
Wang et al. | Structure and catalytic property of Li–Al metal oxides from layered double hydroxide precursors prepared via a facile solution route | |
CN102874853B (zh) | 一种环状镁铝双羟基复合金属氢氧化物及其制备方法 | |
CN103754837B (zh) | 利用多孔氧化铋为模板制备含铋纳米空心球的方法 | |
CN103922390B (zh) | 一种用于光催化的多孔氧化锌单晶纳米片的制备方法 | |
CN104857960B (zh) | 石墨烯导向多级结构复合氧化物催化剂及其制备方法 | |
CN103537237A (zh) | 一种Fe3O4@C@PAM核壳磁性纳米材料的制备方法 | |
CN104150525A (zh) | 氧化物多孔材料及其普适性制备方法 | |
CN108502926B (zh) | BiOCl纳米环及其合成方法 | |
CN106582602B (zh) | 一种高效的系列尖晶石纳米结构材料的合成方法 | |
CN103121665B (zh) | 三维花状水杨酸根插层层状氢氧化物纳米材料的制备方法 | |
CN101785982A (zh) | 一种热乳液法制备中空纳米球的方法 | |
CN102633285B (zh) | 一种一维形貌类水滑石材料及其制备方法 | |
CN103111254A (zh) | 一种分级结构空心微球的制备方法 | |
CN106865587A (zh) | 一种微米尺寸的氧化铝微球的制备方法 | |
CN105253877A (zh) | 一种三维连通有序介孔石墨烯球的制备方法 | |
CN106186044A (zh) | 一种花状氧化锌纳米片团簇的制备方法 | |
CN106082298B (zh) | 一种铈铋复合氧化物纳米棒材料的制备方法 | |
Zhu et al. | Size-controlled synthesis of alumina nanoparticles through an additive-free reverse cation–anion double hydrolysis method | |
CN102992348B (zh) | 一种以埃洛石为原料制备Al-SBA-15有序复合介孔材料的方法 | |
CN104671289A (zh) | 一种Fe2O3纳米片及其制备方法 | |
CN104477976A (zh) | 具有可控微纳结构的钛酸钙粉体的制备方法 | |
CN104445364B (zh) | 一种ZnAl-层状双金属氢氧化物的合成方法 | |
Yang et al. | Mg/Al-CO 3 layered double hydroxide nanorings |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Sun Xiaoming Inventor after: Yang Miaosen Inventor after: Chang Zheng Inventor after: Duan Xue Inventor after: Ren Jian Inventor before: Sun Xiaoming Inventor before: Yang Miaosen Inventor before: Chang Zheng Inventor before: Duan Xue |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: XIAO MINGCHAO WANG YOUJUN WU ZHIQIANG PENG MENGJIN TO: XIAO MINGCHAO WANG YOUJUN WU ZHIQIANG PENG MENGJIN LIN XINGCHUN |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140409 Termination date: 20150712 |
|
EXPY | Termination of patent right or utility model |