CN102844336B - 通过反应器内扩链生产缩聚物的方法及其产物 - Google Patents

通过反应器内扩链生产缩聚物的方法及其产物 Download PDF

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Publication number
CN102844336B
CN102844336B CN201080041127.8A CN201080041127A CN102844336B CN 102844336 B CN102844336 B CN 102844336B CN 201080041127 A CN201080041127 A CN 201080041127A CN 102844336 B CN102844336 B CN 102844336B
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chain
chain extender
polycondensate
extended
meth
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CN102844336A (zh
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加里·A·迪特尔
马可·A·比利亚洛沃斯
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/02—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonates or saturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C08F212/10—Styrene with nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201080041127.8A 2009-07-21 2010-07-21 通过反应器内扩链生产缩聚物的方法及其产物 Expired - Fee Related CN102844336B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US22714909P 2009-07-21 2009-07-21
US61/227,149 2009-07-21
PCT/US2010/042722 WO2011011498A2 (en) 2009-07-21 2010-07-21 Process for the production of condensation polymers via in-reactor chain extension and products thereof

Publications (2)

Publication Number Publication Date
CN102844336A CN102844336A (zh) 2012-12-26
CN102844336B true CN102844336B (zh) 2015-07-15

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Country Status (7)

Country Link
US (1) US8785558B2 (https=)
EP (1) EP2456792B1 (https=)
JP (2) JP5941843B2 (https=)
KR (1) KR101765347B1 (https=)
CN (1) CN102844336B (https=)
ES (1) ES2457552T3 (https=)
WO (1) WO2011011498A2 (https=)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012103208A2 (en) * 2011-01-28 2012-08-02 Anderson Development Company Compositions of glycidyl methacrylate copolymer suitable as chain extender for poly(lactic acid)
US9045630B2 (en) 2011-06-29 2015-06-02 Fina Technology, Inc. Epoxy functional polystyrene for enhanced PLA miscibility
CN102936307B (zh) * 2012-11-27 2015-10-21 山西省化工研究所 一种环氧官能化扩链剂、环氧官能化扩链剂的制备方法及其应用
WO2014173985A1 (en) * 2013-04-25 2014-10-30 Basf Se Copolymers having epoxy groups and their use as chain extenders
WO2014199913A1 (ja) * 2013-06-11 2014-12-18 日油株式会社 共重合体の製造方法
WO2015006547A1 (en) 2013-07-12 2015-01-15 Polyone Corporation Polyester compounds having enhanced hydrophobic surface properties
WO2015100517A1 (zh) * 2013-12-31 2015-07-09 内蒙古蒙西高新技术集团有限公司 含多个环氧官能团的物质、其制备方法、其与二氧化碳和环氧丙烷的三元共聚物及共聚方法
WO2016025263A1 (en) * 2014-08-13 2016-02-18 Basf Corporation Oxazoline containing chain extenders for polycondensates
TWI628227B (zh) * 2015-06-10 2018-07-01 喬福泡綿股份有限公司 Cross-linking composite high-performance ABS/PLA environmentally friendly green material preparation method
KR102193133B1 (ko) * 2017-11-29 2021-03-26 롯데케미칼 주식회사 폴리에스터 제조방법 및 이에 의해 제조된 폴리에스터
LT6658B (lt) * 2017-12-08 2019-09-25 Douglas Craig Pet apdorojimo būdas
CN110452325A (zh) * 2019-07-26 2019-11-15 广州华新科智造技术有限公司 三元共聚物及其制备方法
JP2023512771A (ja) * 2020-02-05 2023-03-29 カネカ アメリカズ ホールディング，インコーポレイティド 溶融粘度を改善するポリエステル用の調整剤
CN112552444B (zh) * 2020-04-17 2022-12-09 佳易容聚合物(上海)有限公司 无溶剂型增粘扩链剂的制备方法
JP7838473B2 (ja) * 2020-12-15 2026-04-01 東洋紡エムシー株式会社 ポリエステル樹脂
JP7826934B2 (ja) * 2020-12-15 2026-03-10 東洋紡エムシー株式会社 ポリエステル樹脂
US20240117107A1 (en) * 2020-12-15 2024-04-11 Toyobo Mc Corporation Polyester resin
JPWO2023032920A1 (https=) * 2021-08-31 2023-03-09
CN113943387A (zh) * 2021-09-22 2022-01-18 佳易容聚合物(上海)有限公司 无单体残留、高活性增粘扩链剂的制备方法及其应用
EP4410861A4 (en) * 2021-09-27 2025-10-15 Toyo Boseki Polyester resin
CN114369213B (zh) * 2022-01-14 2023-07-14 河北明润复合材料科技有限公司 Pet增粘剂、pet发泡材料及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1563138A (zh) * 2004-03-25 2005-01-12 同济大学 本体聚合制备高支化聚乳酸的方法
CN1622963A (zh) * 2002-02-01 2005-06-01 约翰逊聚合物有限责任公司 用来处理、后处理和再生缩聚物的低聚增链剂、合成、组合物和应用
CN102164983A (zh) * 2008-09-29 2011-08-24 巴斯夫欧洲公司 脂族聚酯

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3942330A1 (de) 1989-12-21 1991-06-27 Basf Ag Verfahren zur herstellung von flexiblen polyurethan-weichschaumstoffen mit viskoelastischen, koerperschalldaempfenden eigenschaften und hierzu verwendbare polyoxyalkylen-polyol-mischungen
US5268438A (en) * 1991-09-06 1993-12-07 Rohm And Haas Company Aromatic polyester melt strength improver
US5401796A (en) * 1993-04-02 1995-03-28 Mitsui Toatsu Chemicals, Inc. Aliphatic polyester and preparation process thereof
DE19752747A1 (de) * 1997-11-28 1999-06-24 Herberts Gmbh Verfahren zur Herstellung von Glycidyl(meth)acrylat-Copolymeren
DE19810220C2 (de) 1998-03-10 2001-04-19 Herberts & Co Gmbh Überzugsmittel und deren Verwendung zur Herstellung von Mehrschichtlackierungen
JP2000141955A (ja) * 1998-06-03 2000-05-23 Mitsubishi Plastics Ind Ltd 生分解性カード
MXPA02000469A (es) * 1999-07-14 2004-05-21 Johnson Polymer Inc Proceso para la produccion continua de polimeros epoxi-(met) acrilico-estireno y su uso en revestimiento.
EP1491585B1 (en) * 2002-04-02 2011-05-18 Mitsubishi Plastics, Inc. Heat-shrinkable polylactic acid film
US20040147678A1 (en) 2003-01-29 2004-07-29 Clariant International, Ltd. Solid concentrate composition for polymeric chain extension
JP2009079124A (ja) * 2007-09-26 2009-04-16 Unitika Ltd 生分解性ポリエステル樹脂組成物およびそれからなる成形体
US7855252B2 (en) * 2008-06-16 2010-12-21 Basf Corporation End capping additive for polycondensate polymer resins
DE102009021566A1 (de) * 2009-05-15 2010-11-18 Advansa Bv Biaxial gestreckte Polyesterfolie, enthaltend einen Decarboxylierungskatalysator, Verfahren zu ihrer Herstellung und ihre Verwendung in Elektroisolieranwendungen

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1622963A (zh) * 2002-02-01 2005-06-01 约翰逊聚合物有限责任公司 用来处理、后处理和再生缩聚物的低聚增链剂、合成、组合物和应用
CN1563138A (zh) * 2004-03-25 2005-01-12 同济大学 本体聚合制备高支化聚乳酸的方法
CN102164983A (zh) * 2008-09-29 2011-08-24 巴斯夫欧洲公司 脂族聚酯

Also Published As

Publication number Publication date
CN102844336A (zh) 2012-12-26
EP2456792A2 (en) 2012-05-30
US20120184678A1 (en) 2012-07-19
EP2456792B1 (en) 2014-03-12
JP2013500355A (ja) 2013-01-07
JP2016056384A (ja) 2016-04-21
EP2456792A4 (en) 2012-12-19
KR20120089238A (ko) 2012-08-09
KR101765347B1 (ko) 2017-08-07
ES2457552T3 (es) 2014-04-28
JP5941843B2 (ja) 2016-06-29
US8785558B2 (en) 2014-07-22
JP6180562B2 (ja) 2017-08-16
WO2011011498A3 (en) 2011-04-28
WO2011011498A2 (en) 2011-01-27

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Granted publication date: 20150715