CN102822282B - 用于木材部分的乙酰化的方法 - Google Patents

用于木材部分的乙酰化的方法 Download PDF

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Publication number
CN102822282B
CN102822282B CN201180009580.5A CN201180009580A CN102822282B CN 102822282 B CN102822282 B CN 102822282B CN 201180009580 A CN201180009580 A CN 201180009580A CN 102822282 B CN102822282 B CN 102822282B
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matrix material
temperature
hours
test sample
woodwork
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Chinese (zh)
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CN102822282A (zh
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米歇尔·马斯
贝诺·波尔
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Titan Wood Ltd
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Titan Wood Ltd
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Priority claimed from GBGB1001750.7A external-priority patent/GB201001750D0/en
Priority claimed from GBGB1022090.3A external-priority patent/GB201022090D0/en
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Publication of CN102822282A publication Critical patent/CN102822282A/zh
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/04Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
    • B05D3/0466Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being a non-reacting gas
    • B05D3/0473Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being a non-reacting gas for heating, e.g. vapour heating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27MWORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
    • B27M1/00Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching
    • B27M1/08Working of wood not provided for in subclasses B27B - B27L, e.g. by stretching by multi-step processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/64Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/64Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6492Lignin containing materials; Wood resins; Wood tars; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08HDERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H8/00Macromolecular compounds derived from lignocellulosic materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J165/00Adhesives based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Adhesives based on derivatives of such polymers
    • C09J165/02Polyphenylenes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31971Of carbohydrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31971Of carbohydrate
    • Y10T428/31975Of cellulosic next to another carbohydrate
    • Y10T428/31978Cellulosic next to another cellulosic
    • Y10T428/31986Regenerated or modified
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31971Of carbohydrate
    • Y10T428/31989Of wood
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/4935Impregnated naturally solid product [e.g., leather, stone, etc.]
    • Y10T428/662Wood timber product [e.g., piling, post, veneer, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Forests & Forestry (AREA)
  • Biochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
CN201180009580.5A 2010-02-04 2011-02-04 用于木材部分的乙酰化的方法 Active CN102822282B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB1001750.7 2010-02-04
GBGB1001750.7A GB201001750D0 (en) 2010-02-04 2010-02-04 Composite and process thereof
GB1022090.3 2010-12-30
GBGB1022090.3A GB201022090D0 (en) 2010-12-30 2010-12-30 Manufacturing process
PCT/GB2011/050202 WO2011095824A1 (en) 2010-02-04 2011-02-04 Process for the acetylation of wood elements

Publications (2)

Publication Number Publication Date
CN102822282A CN102822282A (zh) 2012-12-12
CN102822282B true CN102822282B (zh) 2016-03-02

Family

ID=43901358

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180009580.5A Active CN102822282B (zh) 2010-02-04 2011-02-04 用于木材部分的乙酰化的方法

Country Status (19)

Country Link
US (1) US8865318B2 (uk)
EP (1) EP2531561A1 (uk)
JP (2) JP2013518743A (uk)
KR (1) KR101921340B1 (uk)
CN (1) CN102822282B (uk)
AU (1) AU2011212184B2 (uk)
BR (1) BR112012019630B1 (uk)
CA (1) CA2788597C (uk)
CL (1) CL2012002179A1 (uk)
CO (1) CO6571904A2 (uk)
CR (1) CR20120441A (uk)
EC (1) ECSP12012133A (uk)
MX (1) MX336534B (uk)
NZ (1) NZ601675A (uk)
PE (1) PE20130617A1 (uk)
RU (1) RU2569536C2 (uk)
SG (1) SG183181A1 (uk)
UA (1) UA118832C2 (uk)
WO (1) WO2011095824A1 (uk)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012168446A1 (en) 2011-06-10 2012-12-13 Titan Wood Ltd. Wood fibre acetylation
CO6910042A1 (es) * 2011-09-28 2014-03-31 Titan Wood Ltd Paneles de fibras de densidad media
EP2623281A1 (en) * 2012-01-31 2013-08-07 Titan Wood Limited Acetylated wood
JP6498442B2 (ja) * 2012-02-07 2019-04-10 タイタン ウッド リミテッド 木材をアセチル化する方法
CN108160015B (zh) * 2012-05-22 2022-02-25 泰坦木业有限公司 木质纤维素材料的乙酰化的方法和反应器系统及应用
US20140065340A1 (en) * 2012-08-29 2014-03-06 Eastman Chemical Company Moisturized acetylated wood and methods for making the same
GB2511120B (en) * 2013-02-26 2017-06-21 Medite Europe Ltd Acetylated wood fibre
GB2511121B (en) * 2013-02-26 2017-10-04 Medite Europe Ltd Process for manufacturing products from acetylated wood fibre
US20160122440A1 (en) * 2013-06-03 2016-05-05 CC Wood B.V. Modified wood fibres for manufacture in composites
WO2015177242A1 (en) * 2014-05-21 2015-11-26 Titan Wood Limited Process for acetylation of wood in the presence of an acetylation catalyst
WO2016166177A1 (en) * 2015-04-13 2016-10-20 Tricoya Technologies Ltd Method for the acetylation of wood
CA2982023A1 (en) * 2015-04-13 2016-10-20 Tricoya Technologies Ltd Method for continuous acetylation of wood elements
US11338468B2 (en) 2015-04-13 2022-05-24 Tricoya Technologies Ltd. Method for continuous acetylation of wood elements
HUE036992T2 (hu) * 2015-11-18 2018-08-28 SWISS KRONO Tec AG OSB (Oriented Strand Board - irányított forgácselrendezésû lap) faanyag lap javított tulajdonságokkal és eljárás annak elõállítására
PL3178622T3 (pl) 2015-12-07 2018-12-31 SWISS KRONO Tec AG Sposób wytwarzania płyty drewnopochodnej o obniżonej emisji lotnych związków organicznych (voc)
CN106042110B (zh) * 2016-06-01 2017-10-27 江苏科技大学 一种阻燃木板的生产工艺
MX2019000034A (es) * 2016-06-23 2019-05-02 Tricoya Tech Ltd Enfriamiento de elementos de madera acetilada.
DK201800137A1 (en) * 2018-03-28 2019-10-02 Danish Wood Technology A/S Treatment of wood
ES2952147T3 (es) 2018-04-13 2023-10-27 Tricoya Tech Ltd Madera acetilada y método de fabricación de la misma
KR20210138013A (ko) 2019-02-01 2021-11-18 트리코야 테크놀러지스 엘티디 아세틸화 러버우드(rubberwood)로부터 제조된 보드(board)
EP3741793A1 (de) 2019-05-22 2020-11-25 Basf Se Faserformteile
CN111251400B (zh) * 2020-01-16 2022-04-26 北京市飞宇商贸有限公司 一种红木家具的制作方法
CN115989213A (zh) 2020-07-28 2023-04-18 泰坦木业有限公司 木材乙酰化流体的纯化
US20220371219A1 (en) * 2021-05-20 2022-11-24 Washington State University Thermally modified composite wood-strand products for construction and other applications
WO2024100210A1 (en) 2022-11-09 2024-05-16 Tricoya Technologies Ltd Purification of acetic acid by heteroazeotropic distillation with water

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995023168A1 (en) * 1994-02-24 1995-08-31 A-Cell Acetyl Cellulosics Ab Acetylation of lignocellulosic materials
US6632326B1 (en) * 1999-09-30 2003-10-14 Yamaha Corporation Modifying method for wood elements
GB2456915A (en) * 2008-02-01 2009-08-05 Titan Wood Ltd A process for the acetylation of wood

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4388378A (en) * 1980-12-05 1983-06-14 United States Gypsum Company Thermoplastic hardboard from acetylated mat
JP3090067B2 (ja) * 1996-10-30 2000-09-18 ヤマハ株式会社 木質パネル及びその製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995023168A1 (en) * 1994-02-24 1995-08-31 A-Cell Acetyl Cellulosics Ab Acetylation of lignocellulosic materials
US6632326B1 (en) * 1999-09-30 2003-10-14 Yamaha Corporation Modifying method for wood elements
GB2456915A (en) * 2008-02-01 2009-08-05 Titan Wood Ltd A process for the acetylation of wood

Also Published As

Publication number Publication date
MX336534B (es) 2016-01-21
US8865318B2 (en) 2014-10-21
EP2531561A1 (en) 2012-12-12
CA2788597C (en) 2018-09-18
JP6262180B2 (ja) 2018-01-17
JP2013518743A (ja) 2013-05-23
ECSP12012133A (es) 2012-12-28
KR101921340B1 (ko) 2018-11-22
CO6571904A2 (es) 2012-11-30
NZ601675A (en) 2014-02-28
RU2012137514A (ru) 2014-03-10
CR20120441A (es) 2013-01-24
SG183181A1 (en) 2012-09-27
MX2012009021A (es) 2012-11-29
WO2011095824A1 (en) 2011-08-11
KR20130009759A (ko) 2013-01-23
RU2569536C2 (ru) 2015-11-27
AU2011212184A1 (en) 2012-08-30
PE20130617A1 (es) 2013-06-23
BR112012019630B1 (pt) 2020-10-20
BR112012019630A2 (pt) 2016-05-03
JP2016027958A (ja) 2016-02-25
AU2011212184B2 (en) 2014-12-04
CL2012002179A1 (es) 2013-01-11
CN102822282A (zh) 2012-12-12
US20130209822A1 (en) 2013-08-15
UA118832C2 (uk) 2019-03-25
CA2788597A1 (en) 2011-08-11

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