CN102816492A - Water-based aminoacrylic conductive flame-retardant dip-coating paint - Google Patents

Water-based aminoacrylic conductive flame-retardant dip-coating paint Download PDF

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Publication number
CN102816492A
CN102816492A CN2012103422307A CN201210342230A CN102816492A CN 102816492 A CN102816492 A CN 102816492A CN 2012103422307 A CN2012103422307 A CN 2012103422307A CN 201210342230 A CN201210342230 A CN 201210342230A CN 102816492 A CN102816492 A CN 102816492A
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China
Prior art keywords
mass parts
water
parts
retardant
conducts electricity
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Pending
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CN2012103422307A
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Chinese (zh)
Inventor
庄亚东
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WUJIANG WUHUA HARDWARE PRODUCTS CO Ltd
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WUJIANG WUHUA HARDWARE PRODUCTS CO Ltd
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Priority to CN2012103422307A priority Critical patent/CN102816492A/en
Publication of CN102816492A publication Critical patent/CN102816492A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a water-based aminoacrylic conductive flame-retardant dip-coating paint which contains the following components in parts by mass: 70-90 parts of electrolytic copper powder, 5-10 parts of flame retardant, 40-50 parts of water-based acrylic resin, 10-20 parts of amino resin, 1-5 parts of aluminum tripolyphosphate, 1-5 parts of porcelain clay, 1-3 parts of high-pigment carbon black, 1-3 parts of precipitated barium sulfate, 0.1-1 part of strontium yellow and 25-35 parts of distilled water. The water-based aminoacrylic conductive flame-retardant dip-coating paint provided by the invention can be used as a refrigerator compressor paint, can be coated on automobile parts, instruments and meters as well as household appliances to shield electromagnetic waves generated thereby, and has a flame retardant effect.

Description

The water-based aminoacrylic acid conducts electricity fire-retardant paint dipping
Technical field
The present invention relates to a kind of WATERBORNE ACRYLIC DIPPING PAINT, relate in particular to a kind of water-based aminoacrylic acid and conduct electricity fire-retardant paint dipping.
Background technology
China's electrical apparatus industry development at present is very fast, and output also constantly raises.But; A lot of used japannings of household electrical appliance mostly contain a large amount of toluene, inflammable and explosive, the hazardous and noxious substances of YLENE lamp; The organic solvent that is discharged in the atmosphere just reaches tens thousand of tons, has caused serious environmental to pollute and the wasting of resources, has also influenced the healthy of resident.
Summary of the invention
The objective of the invention is to overcome the deficiency of above-mentioned prior art, provide a kind of water-based aminoacrylic acid to conduct electricity fire-retardant paint dipping, can be used for the application of household electrical appliance, shield the hertzian wave of its generation, also have fire-retardant effect.
Technical scheme: a kind of water-based aminoacrylic acid conducts electricity fire-retardant paint dipping, with mass parts in respect of following composition: electrolytic copper powder 70~90 mass parts, fire retardant 5~10 mass parts; Water-borne acrylic resin 40~50 mass parts, aminoresin 10~20 mass parts, aluminium triphosphate 1~5 mass parts; China clay 1~5 mass parts, high-carbon black pigment 1~3 mass parts, process white 1~3 mass parts; Strontium yellow 0.1~1 mass parts, zero(ppm) water 25~35 mass parts.
Above-mentioned described water-borne acrylic resin, with mass parts in respect of following composition: vinylformic acid 19.80 mass parts, vinylbenzene 19.22 mass parts; Bing Xisuandingzhi 9.97 mass parts; Alcohol ether solvents 49.07 mass parts, tert-butyl peroxide 0.5 mass parts, diethylamine 1.5 mass parts.
Above-mentioned described fire retardant contains following composition by weight percentage: pitch 42%, ore deposit essential oil 25%, vermiculite 15%, meticulous asbestos 8%, borax 3%, mica powder 7%.
Above-mentioned described aminoresin is under 25 ℃, and its viscosity is 2500~4500mPas, and density is 1120kg/m 3
Above-mentioned described aluminium triphosphate density is 2~3g/cm 3, moisture≤1.5%, the pH value is 5.5~7.
The particle size range of above-mentioned described high-carbon black pigment is 10~16.
Above-mentioned described process white pH value is 6.5~8.0, moisture≤0.2%, sulfide≤0.003%.
Content of strontium (in SrO)>=43% in the above-mentioned described strontium yellow, chromium trioxide content>=41%, chloride content (in Cl)≤0.1%, sulphate content (SO 4)≤0.2%, moisture≤1%.
Beneficial effect: water-based aminoacrylic acid provided by the invention conducts electricity fire-retardant paint dipping; Save resource, VOC content is low, discharging is few, and complex-shaped Workpiece coating is oversimplified; Can be used for the application of freezer compressor; Also can be used for the application of trolley part, instrument and household electrical appliance, shield the hertzian wave of its generation, and have fire-retardant effect.
Embodiment
Embodiment 1
1. water-based aminoacrylic acid of the present invention conducts electricity fire-retardant paint dipping; The preparation of said water-borne acrylic resin: alcohol ether solvents 23.3 mass parts are added reaction kettle; Heat up; Stir; The mixture and tert-butyl peroxide 0.39 mass parts of vinylformic acid 19.80 mass parts, vinylbenzene 19.22 mass parts and Bing Xisuandingzhi 9.97 mass parts are added header tank, be warming up to the mixture and tert-butyl peroxide 0.39 mass parts that begin dropwise addition of acrylic acid, vinylbenzene and Bing Xisuandingzhi when refluxing, the dropping time is controlled at 1.5~2.0h.After dripping, be incubated 20min, then drip the mixed solution of tert-butyl peroxide 0.09 mass parts and alcohol ether solvents 2.6 mass parts, in 10~15min, drip, be incubated backflow polymerization 4h then.Cooling during to 100~110 ℃ of temperature of charge, slowly adds the mixed solution of diethylamine and alcohol ether solvents 23.05 mass parts, stirring 10~15min.Be cooled to 65~80 ℃ of dischargings, silk screen filter makes.
2. water-based aminoacrylic acid of the present invention conducts electricity fire-retardant paint dipping, the preparation of said fire retardant: with pitch 42%, and ore deposit essential oil 25%, vermiculite 15%, meticulous asbestos 8%, borax 3%, mica powder 7% thorough mixing makes.
3. water-based aminoacrylic acid of the present invention conducts electricity the preparation of fire-retardant paint dipping: with water-borne acrylic resin 49.89 mass parts, high-carbon black pigment 1.5 mass parts, strontium yellow 0.65 mass parts, aluminium triphosphate 3 mass parts, china clay 1.86 mass parts, process white 1.5 mass parts and zero(ppm) water 30.32 mass parts one reinstate impeller pre-dispersed evenly after; Be ground to fineness<30 μ m with sand mill again; Add aminoresin 11.46 mass parts then; Again grind one time; Through silk screen filter, add electrolytic copper powder 80 mass parts, fire retardant 8 mass parts thorough mixing again, get finished product.
Water-based aminoacrylic acid provided by the invention conducts electricity fire-retardant paint dipping, and the hertzian wave ability that shields its generation reaches 1.8T, conductive effect≤0.023 Ω/cm 2, good flame retardation effect.
The above is the preferred embodiments of the present invention, but the present invention also is not limited to above only embodiment, on embodiment, does improvement slightly and also will be regarded as protection scope of the present invention.

Claims (8)

1. a water-based aminoacrylic acid conducts electricity fire-retardant paint dipping, it is characterized in that with mass parts in respect of following composition: electrolytic copper powder 70~90 mass parts, fire retardant 5~10 mass parts; Water-borne acrylic resin 40~50 mass parts, aminoresin 10~20 mass parts, aluminium triphosphate 1~5 mass parts; China clay 1~5 mass parts, high-carbon black pigment 1~3 mass parts, process white 1~3 mass parts; Strontium yellow 0.1~1 mass parts, zero(ppm) water 25~35 mass parts.
2. water-based aminoacrylic acid according to claim 1 conducts electricity fire-retardant paint dipping; It is characterized in that said water-borne acrylic resin with mass parts in respect of following composition: vinylformic acid 19.80 mass parts; Vinylbenzene 19.22 mass parts, Bing Xisuandingzhi 9.97 mass parts, alcohol ether solvents 49.07 mass parts; Tert-butyl peroxide 0.5 mass parts, diethylamine 1.5 mass parts.
3. water-based aminoacrylic acid according to claim 1 conducts electricity fire-retardant paint dipping, it is characterized in that said fire retardant contains following composition by weight percentage: pitch 42%, ore deposit essential oil 25%, vermiculite 15%, meticulous asbestos 8%, borax 3%, mica powder 7%.
4. water-based aminoacrylic acid according to claim 1 conducts electricity fire-retardant paint dipping, it is characterized in that said aminoresin under 25 ℃, and its viscosity is 2500~4500mPas, and density is 1120kg/m 3
5. water-based aminoacrylic acid according to claim 1 conducts electricity fire-retardant paint dipping, it is characterized in that said aluminium triphosphate density is 2~3g/cm 3, moisture≤1.5%, the pH value is 5.5~7.
6. water-based aminoacrylic acid according to claim 1 conducts electricity fire-retardant paint dipping, and the particle size range that it is characterized in that said high-carbon black pigment is 10~16.
7. water-based aminoacrylic acid according to claim 1 conducts electricity fire-retardant paint dipping, it is characterized in that said process white pH value is 6.5~8.0, moisture≤0.2%, sulfide≤0.003%.
8. water-based aminoacrylic acid according to claim 1 conducts electricity fire-retardant paint dipping, it is characterized in that content of strontium in the said strontium yellow (in SrO)>=43%, chromium trioxide content>=41%, chloride content (in Cl)≤0.1%, sulphate content (SO 4)≤0.2%, moisture≤1%.
CN2012103422307A 2012-09-17 2012-09-17 Water-based aminoacrylic conductive flame-retardant dip-coating paint Pending CN102816492A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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CN2012103422307A CN102816492A (en) 2012-09-17 2012-09-17 Water-based aminoacrylic conductive flame-retardant dip-coating paint

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103382336A (en) * 2013-07-08 2013-11-06 吴江市物华五金制品有限公司 Flame-retardant anti-corrosion paint
CN105602328A (en) * 2014-11-23 2016-05-25 武汉鸿信通科技有限公司 Method for preparing fireproof paint
CN105694573A (en) * 2014-11-23 2016-06-22 武汉鸿信通科技有限公司 Fireproof coating
CN105913943A (en) * 2016-07-07 2016-08-31 李保集 Special cable for railway traffic

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102344707A (en) * 2010-08-05 2012-02-08 南通玺运贸易有限公司 Fire resisting paint
CN102516849A (en) * 2011-12-12 2012-06-27 费近峰 Acrylic resin electric conductive paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102344707A (en) * 2010-08-05 2012-02-08 南通玺运贸易有限公司 Fire resisting paint
CN102516849A (en) * 2011-12-12 2012-06-27 费近峰 Acrylic resin electric conductive paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄玉媛等: "《涂料配方》", 31 January 2008, article "《涂料配方》", pages: 315-316 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103382336A (en) * 2013-07-08 2013-11-06 吴江市物华五金制品有限公司 Flame-retardant anti-corrosion paint
CN103382336B (en) * 2013-07-08 2015-06-17 吴江华诚复合材料科技有限公司 Flame-retardant anti-corrosion paint
CN105602328A (en) * 2014-11-23 2016-05-25 武汉鸿信通科技有限公司 Method for preparing fireproof paint
CN105694573A (en) * 2014-11-23 2016-06-22 武汉鸿信通科技有限公司 Fireproof coating
CN105913943A (en) * 2016-07-07 2016-08-31 李保集 Special cable for railway traffic
CN105913943B (en) * 2016-07-07 2017-08-25 李烈熊 A kind of track traffic special cable

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Application publication date: 20121212