CN106065234A - A kind of disinfection cabinet outer surface powdery paints and preparation method thereof - Google Patents
A kind of disinfection cabinet outer surface powdery paints and preparation method thereof Download PDFInfo
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- CN106065234A CN106065234A CN201610418052.XA CN201610418052A CN106065234A CN 106065234 A CN106065234 A CN 106065234A CN 201610418052 A CN201610418052 A CN 201610418052A CN 106065234 A CN106065234 A CN 106065234A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of disinfection cabinet outer surface powdery paints, prepared by the component raw material of following weight portion: epoxy resin 30 40, fluorocarbon resin 60 70, acrylonitrile butadient styrene 35, zinc oxide 24, diamond dust 13 18, triethylene tetramine 0.7 1.0, polyester silicone oil 34, ethylene bis stearic acid amide 1 1.2, anilinomethyl triethoxysilane 2.7 3.3,70 90, aluminium hydroxide 10 15, magnesium hydroxide 12 16, ultra-fine magnesium carbonate 12, zirconium oxide 24, iron oxide 23, modified negative-ion powder 0.2 0.4.The powdery paints of the present invention has high temperature resistant, good flame resistance, and good insulating, storage stability are good, and solidification temperature is low simultaneously, and hardening time is short, film good leveling property, and adhesive force is strong, appearance of film good, acid and alkali-resistance, can purify air；Can be used on the household appliances such as electromagnetic oven, micro-wave oven, baking box, disinfection cabinet.
Description
Technical field
The invention belongs to paint field, specifically a kind of disinfection cabinet outer surface powdery paints and preparation method thereof.
Background technology
Development with the progress of modern science and technology and modern industry so that problem of environmental pollution becomes day by day to dash forward
Going out, the environment that it depends on for existence to the mankind itself and the mankind causes threat greatly.Traditional coating was either manufacturing
In journey or all can produce substantial amounts of poisonous and hazardous waste gas and waste water in using work progress, they can be to environment, air
And water resource pollutes, especially solvent based coating, work progress can discharge VOC (VOC) to greatly
In gas, its amount has reached more than 50% and has caused serious second time to pollute.This problem causes the attention of many industrial countries.
Powdery paints obtains in recent years as a class environmental type coating in terms of various fields particularly coated metal
It is widely applied.Powdery paints is often using organic resins such as epoxy, polyester, acrylic acid, polyurethane as matrix, due to by matrix
The impact of resin self structure and restriction, these conventional powdery paints also exist weak point in some performances, and result in should
The limitation used.
Compared with common organic resin, organic siliconresin has more excellent heat-resisting, weather-proof, resistance to water and electric insulation
Performance.Powdery paints uses organic siliconresin, its heat resistance and weatherability can be improved, but use merely organic siliconresin to deposit
Expensive, to problems such as base material poor adhesive force.Therefore, often utilize organic siliconresin other organic resins modified, can be by
The advantage of organic siliconresin and other organic resins combines, and makes up mutual deficiency, improves the property such as paint film is weather-proof, heat-resisting
Can, obtaining the powdery paints of excellent performance, this is also an effective way of development functional powder coating.But due to organic
Silicones differs greatly with the solubility parameters of organic resin, and compatibility is poor, and in the case of directly mixing, organosilicon has spilling existing
As at surface enrichment, being susceptible to microphase-separated.And the appearance of microphase-separated, to the hardness of modified resin, stability and machinery
Performance all has a great impact, and the overall performance of final film is bad.
Heat Resistant Powder Coatings can be widely applied to the row such as electrical equipment, metallurgy, oil, aviation field, chemical industry, medicine, food
The various high temperature resistant equipment of industry is (for example: oven, warm-air drier, high-power lamp decoration, caliduct, automobile and motorcycle silencer, height
Temperature stove, chimney etc.).Although existing Heat Resistant Powder Coatings is compared with oil paint environmental protection, but owing to its cost is too high and needs height
Temperature solidification (minimum 230 DEG C × 20 minutes of condition of cure) limits it and promotes the use of.
Developing low-cost normal temperature cure Heat Resistant Powder Coatings can make the powdery paints of environmental protection replace paint to be applied to above-mentioned
Various high temperature resistant equipment, have very much market.
Content of the invention
The invention provides a kind of disinfection cabinet outer surface powdery paints, the powdery paints of the present invention has high temperature resistant, resistance
Combustion property is good, and good insulating, simultaneously solidification temperature are low, and hardening time is short, film good leveling property, and adhesive force is strong, appearance of film good, resistance to
Soda acid, can be used on the household appliances such as electromagnetic oven, micro-wave oven, baking box, disinfection cabinet.
Technical scheme is as follows:
A kind of disinfection cabinet outer surface powdery paints, it is characterised in that: prepared by the component raw material of following weight portion: epoxy
Resin 30-40, fluorocarbon resin 60-70, acrylonitrile-butadiene-styrene copolymer 3-5, zinc oxide 2-4, diamond dust 13-18,
Triethylene tetramine 0.7-1.0, polyester silicone oil 3-4, ethylene bis stearic acid amide 1-1.2, anilinomethyl triethoxysilane 2.7-
3.3rd, 70-90, aluminium hydroxide 10-15, magnesium hydroxide 12-16, ultra-fine magnesium carbonate 1-2, zirconium oxide 2-4, iron oxide 2-3, modification
Negative ion powder 0.2-0.4,
Described negative ion powder is made up of by mass parts following component: strange ice stone 10-15, astroies 8-10, tourmaline
10-15, opal 30-50, medical stone 2-4, zeolite 2-4, hokutolite 2-4, jade powder 2-4, diatomite 15-20, three oxidations two
Iron 2-4, alundum (Al2O3) 3-4, weigh each component raw material by formula rate, is placed in Muffle furnace and is heated to 300-600 DEG C
Rear insulation 1-2h makes it activate, and is cooled to carry out ultra-fine grinding to particle at below 100nm, by it in normal temperature addition grinding equipment
Being placed in high speed agitator, first normal temperature mixed at high speed 5-10 of silane coupler KH560 being subsequently adding powder quality 1-3% is divided
Clock, the superfine light calcium carbonate of addition powder quality 20-30%, the diethylaminopropylamine of 1-2%, high-speed stirred 10-20 minute,
Sieve, be dried, can be prepared by negative ion powder.
Described disinfection cabinet outer surface powdery paints, it is characterised in that: prepared by the component raw material of following weight portion: ring
Epoxy resins the 38th, fluorocarbon resin the 65th, acrylonitrile-butadiene-styrene copolymer the 4th, zinc oxide the 3rd, diamond dust the 15th, triethylene tetramine
0.8th, polyester silicone oil the 3rd, ethylene bis stearic acid amide the 1.1st, anilinomethyl triethoxysilane the 3.0th, aluminium hydroxide the 13rd, magnesium hydroxide
15th, ultra-fine magnesium carbonate the 2nd, zirconium oxide the 3rd, iron oxide the 2nd, modified negative-ion powder 0.3,
Described negative ion powder is made up of by mass parts following component: strange ice stone the 14th, astroies the 9th, tourmaline the 13rd, albumen
Stone the 40th, medical stone the 3rd, zeolite the 3rd, hokutolite the 3rd, jade powder the 3rd, diatomite the 18th, di-iron trioxide the 3rd, alundum (Al2O3) 3, by recipe ratio
Example weighs each component raw material, and being placed in Muffle furnace insulation 2h after being heated to 500 DEG C makes it activate, and is cooled to normal temperature and adds stone roller
Mill equipment carries out ultra-fine grinding to particle at below 100nm, be placed in high speed agitator, be subsequently adding powder quality
The first normal temperature mixed at high speed of the silane coupler KH560 of 2% 8 minutes, adds the superfine light calcium carbonate of powder quality 25%,
The diethylaminopropylamine of 1.5%, high-speed stirred 15 minutes, sieve, be dried, can be prepared by negative ion powder.
The preparation method of described disinfection cabinet outer surface powdery paints, it is characterised in that comprise the following steps:
(1) first by raw materials used coarse crushing before use to 70 mesh, each component raw material is weighed by formula rate；
(2) hydrochloric acid solution diamond dust, zirconium oxide being put into 10% soaks 20-30 minute, is subsequently adding NaOH
In solution and filter, first put into filter residue in high temperature furnace, 500-600 DEG C calcine 50-60min, then naturally cool to room
Temperature, then the silane coupler by filter residue gross mass 5% join filter residue high speed stirring mixing 20-30 minute, be subsequently adding poly-
Ester silicone oil, then high-speed stirred mixing 10-20 minute, be dried, stand-by；
(3) then will weigh raw material by formula rate and mixed material that step (1) obtains put into homogenizer in high
Speed mixes；
(4) then input extruder, after 65-95 DEG C of melting mixing 20min, is extruded, is cooled to room temperature, then pulverizes and sieves
To 190 mesh, i.e. obtain finished product.
Beneficial effect
The present invention uses fluorocarbon resin and epoxy resin hybrid resin as film forming matter, and the two combines two kinds of resins
Advantage combines, and makes up mutual deficiency, improves the performances such as paint film heat-resisting, corrosion resistance, wearability, obtains high temperature resistant etc. excellent
Different powdery paints；
Coating adds modification self-control negative ion powder, can in room anion releasing, release anion tool
Killing germ, absorbing the foreign flavor indoors such as formaldehyde, purify the effect of air, improve indoor environment, modified negative ion powder carries
The high compatibility with coating, improves the weatherability of film, improves the storage stability of thermosetting powder coating；
In the preparation, after first diamond dust, zirconium oxide being acidified, at high-temperature activation, then with silane coupler modified, then with
Polyester silicone oil is sufficiently mixed, good dispersion in coating for the mixed material of gained, increases with the compatibility of other compositions such as resin
By force, promote the reactivity of each material composition, reduce solidification temperature, shorten hardening time.
In a word, the powdery paints of the present invention has high temperature resistant, good flame resistance, and good insulating, storage stability are good, simultaneously solid
Changing temperature low, hardening time is short, film good leveling property, and adhesive force is strong, appearance of film good, acid and alkali-resistance, can purify air, available
On the household appliances such as electromagnetic oven, micro-wave oven, baking box, disinfection cabinet.
Detailed description of the invention:
A kind of disinfection cabinet outer surface powdery paints, is prepared by the component raw material of following weight (kg): epoxy resin the 38th, fluorine
Carbon resin the 65th, acrylonitrile-butadiene-styrene copolymer the 4th, zinc oxide the 3rd, diamond dust the 15th, triethylene tetramine the 0.8th, polyester silicone oil
3rd, ethylene bis stearic acid amide the 1.1st, anilinomethyl triethoxysilane the 3.0th, aluminium hydroxide the 13rd, magnesium hydroxide the 15th, ultra-fine carbonic acid
Magnesium the 2nd, zirconium oxide the 3rd, iron oxide the 2nd, modified negative-ion powder 0.3,
Wherein negative ion powder is made up of by mass parts following component: strange ice stone the 14th, astroies the 9th, tourmaline the 13rd, opal
40th, medical stone the 3rd, zeolite the 3rd, hokutolite the 3rd, jade powder the 3rd, diatomite the 18th, di-iron trioxide the 3rd, alundum (Al2O3) 3, by formula rate
Weighing each component raw material, being placed in Muffle furnace insulation 2h after being heated to 500 DEG C makes it activate, and is cooled to normal temperature addition and mills
Equipment carries out ultra-fine grinding to particle at below 100nm, be placed in high speed agitator, be subsequently adding powder quality 2%
The first normal temperature mixed at high speed of silane coupler KH560 8 minutes, add the superfine light calcium carbonate of powder quality 25%, 1.5%
Diethylaminopropylamine, high-speed stirred 15 minutes, sieve, be dried, can be prepared by negative ion powder.
The preparation method of disinfection cabinet outer surface powdery paints, comprises the following steps:
(1) first by raw materials used coarse crushing before use to 70 mesh, each component raw material is weighed by formula rate；
(2) hydrochloric acid solution diamond dust, zirconium oxide being put into 10% soaks 20-30 minute, is subsequently adding NaOH
In solution and filter, first put into filter residue in high temperature furnace, 500-600 DEG C calcine 50-60min, then naturally cool to room
Temperature, then the silane coupler by filter residue gross mass 5% join filter residue high speed stirring mixing 20-30 minute, be subsequently adding poly-
Ester silicone oil, then high-speed stirred mixing 10-20 minute, be dried, stand-by；
(3) then will weigh raw material by formula rate and mixed material that step (1) obtains put into homogenizer in high
Speed mixes；
(4) then input extruder, after 65-95 DEG C of melting mixing 20min, is extruded, is cooled to room temperature, then pulverizes and sieves
To 190 mesh, i.e. obtain finished product.
By the electrostatic spraying apparatus used for powder coating (voltage 50KV, air pressure 0.05MPa, spray distance about 15cm) of the present invention
Even application on the tinplate piece (150x20mmx0.28mm) through pretreated (sand papering and alcohol washes), Ma Kou
Iron plate should be at vertical hanging state, it is simple to powdery paints uniformly sprays above；Be hung vertically in an oven 120 DEG C,
Solidification 20min film forming, forms the figure layer that thickness is about 80 μm, naturally cools to room temperature, takes out after placing 24h, measures coating
Can, film performance detection is as shown in table 1:
The performance of table 1 spray equipment gained film
As seen from Table 1, the properties at 120 DEG C of solidification 20min gained films is all relatively good, and this powdery paints is described
Solidification temperature low, hardening time is short.
Claims (3)
1. a disinfection cabinet outer surface powdery paints, it is characterised in that: prepared by the component raw material of following weight portion: epoxy
Resin 30-40, fluorocarbon resin 60-70, acrylonitrile-butadiene-styrene copolymer 3-5, zinc oxide 2-4, diamond dust 13-
18th, triethylene tetramine 0.7-1.0, polyester silicone oil 3-4, ethylene bis stearic acid amide 1-1.2, anilinomethyl triethoxysilane
2.7-3.3,70-90, aluminium hydroxide 10-15, magnesium hydroxide 12-16, ultra-fine magnesium carbonate 1-2, zirconium oxide 2-4, iron oxide 2-
3rd, modified negative-ion powder 0.2-0.4,
Described negative ion powder is made up of by mass parts following component: strange ice stone 10-15, astroies 8-10, tourmaline 10-
15th, opal 30-50, medical stone 2-4, zeolite 2-4, hokutolite 2-4, jade powder 2-4, diatomite 15-20, di-iron trioxide 2-
4th, alundum (Al2O3) 3-4, weighs each component raw material by formula rate, is placed on and protects after being heated to 300-600 DEG C in Muffle furnace
Temperature 1-2h makes it activate, and is cooled to carry out ultra-fine grinding to particle at below 100nm in normal temperature addition grinding equipment, is put
It in high speed agitator, is subsequently adding the first normal temperature mixed at high speed 5-10 minute of silane coupler KH560 of powder quality 1-3%, adds
Enter the superfine light calcium carbonate of powder quality 20-30%, the diethylaminopropylamine of 1-2%, high-speed stirred 10-20 minute, sieve,
It is dried, can be prepared by negative ion powder.
2. disinfection cabinet outer surface powdery paints according to claim 1, it is characterised in that: by the component of following weight portion
Raw material prepares: epoxy resin the 38th, fluorocarbon resin the 65th, acrylonitrile-butadiene-styrene copolymer the 4th, zinc oxide the 3rd, diamond dust
15th, triethylene tetramine the 0.8th, polyester silicone oil the 3rd, ethylene bis stearic acid amide the 1.1st, anilinomethyl triethoxysilane the 3.0th, hydrogen
Aluminum oxide the 13rd, magnesium hydroxide the 15th, ultra-fine magnesium carbonate the 2nd, zirconium oxide the 3rd, iron oxide the 2nd, modified negative-ion powder 0.3,
Described negative ion powder is made up of by mass parts following component: strange ice stone the 14th, astroies the 9th, tourmaline the 13rd, opal
40th, medical stone the 3rd, zeolite the 3rd, hokutolite the 3rd, jade powder the 3rd, diatomite the 18th, di-iron trioxide the 3rd, alundum (Al2O3) 3, by formula rate
Weighing each component raw material, being placed in Muffle furnace insulation 2h after being heated to 500 DEG C makes it activate, and is cooled to normal temperature and adds
Grinding equipment carries out ultra-fine grinding to particle at below 100nm, be placed in high speed agitator, be subsequently adding powder quality
The first normal temperature mixed at high speed of the silane coupler KH560 of 2% 8 minutes, the superfine light calcium carbonate of addition powder quality 25%, 1.5%
Diethylaminopropylamine, high-speed stirred 15 minutes, sieve, be dried, can be prepared by negative ion powder.
3. the preparation method of disinfection cabinet outer surface powdery paints as claimed in claim 1, it is characterised in that include following step
Rapid:
(1) first by raw materials used coarse crushing before use to 70 mesh, each component raw material is weighed by formula rate；
(2) hydrochloric acid solution diamond dust, zirconium oxide being put into 10% soaks 20-30 minute, is subsequently adding in sodium hydroxide solution
And filtration, first put into filter residue in high temperature furnace, calcine 50-60min at 500-600 DEG C, then naturally cool to room temperature, then will
The silane coupler of filter residue gross mass 5% joins filter residue high speed stirring mixing 20-30 minute, is subsequently adding polyester silicone oil, then
High-speed stirred mixes 10-20 minute, is dried, stand-by；
(3) then will weigh raw material by formula rate and mixed material that step (1) obtains put into homogenizer in mixed at a high speed
Close uniformly；
(4) then input extruder, after 65-95 DEG C of melting mixing 20 min, is extruded, is cooled to room temperature, then pulverized
It is sieved to 190 mesh, i.e. obtain finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610418052.XA CN106065234A (en) | 2016-06-08 | 2016-06-08 | A kind of disinfection cabinet outer surface powdery paints and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610418052.XA CN106065234A (en) | 2016-06-08 | 2016-06-08 | A kind of disinfection cabinet outer surface powdery paints and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106584029A (en) * | 2016-12-09 | 2017-04-26 | 李如武 | Production method of high-performance wardrobe |
| CN106670741A (en) * | 2016-12-09 | 2017-05-17 | 李如武 | Manufacturing method of environment-friendly wardrobe |
| CN106670742A (en) * | 2016-12-09 | 2017-05-17 | 李如武 | Manufacturing method of environment-friendly durable wardrobe |
| CN110684406A (en) * | 2019-10-31 | 2020-01-14 | 湖南盛业土工材料制造有限公司 | Manufacturing process of corrosion-resistant waterproof board |
| CN111019448A (en) * | 2019-12-16 | 2020-04-17 | 江门市壹家美环境工程有限公司 | Environment-friendly coating capable of releasing negative ions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102061121A (en) * | 2010-12-06 | 2011-05-18 | 老虎粉末涂料制造（太仓）有限公司 | Environmental-protection anti-corrosive heat-dissipation powder paint, and preparation method and application thereof |
| CN102702833A (en) * | 2012-01-12 | 2012-10-03 | 上海韬鸿化工科技有限公司 | Anion powder |
-
2016
- 2016-06-08 CN CN201610418052.XA patent/CN106065234A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102061121A (en) * | 2010-12-06 | 2011-05-18 | 老虎粉末涂料制造（太仓）有限公司 | Environmental-protection anti-corrosive heat-dissipation powder paint, and preparation method and application thereof |
| CN102702833A (en) * | 2012-01-12 | 2012-10-03 | 上海韬鸿化工科技有限公司 | Anion powder |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106584029A (en) * | 2016-12-09 | 2017-04-26 | 李如武 | Production method of high-performance wardrobe |
| CN106670741A (en) * | 2016-12-09 | 2017-05-17 | 李如武 | Manufacturing method of environment-friendly wardrobe |
| CN106670742A (en) * | 2016-12-09 | 2017-05-17 | 李如武 | Manufacturing method of environment-friendly durable wardrobe |
| CN110684406A (en) * | 2019-10-31 | 2020-01-14 | 湖南盛业土工材料制造有限公司 | Manufacturing process of corrosion-resistant waterproof board |
| CN111019448A (en) * | 2019-12-16 | 2020-04-17 | 江门市壹家美环境工程有限公司 | Environment-friendly coating capable of releasing negative ions |
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