CN103627307A - Coating capable of achieving orange grain/ripple effect and preparation method of coating - Google Patents
Coating capable of achieving orange grain/ripple effect and preparation method of coating Download PDFInfo
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- CN103627307A CN103627307A CN201310592765.4A CN201310592765A CN103627307A CN 103627307 A CN103627307 A CN 103627307A CN 201310592765 A CN201310592765 A CN 201310592765A CN 103627307 A CN103627307 A CN 103627307A
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- coating
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- tangerine line
- ripple
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Abstract
The invention discloses a coating capable of achieving an orange grain/ripple effect. The coating comprises the following components in parts by weight: 45-65 parts of resin, 0-2 parts of a conventional auxiliary agent, 10-20 parts of filler, 0.2-2 parts of a ripple auxiliary agent, 5-30 parts of a pigment, 8-15 parts of a solvent and 2-10 parts of an anti-settling agent. The invention also discloses a preparation method of the coating. The coating is simple in formula and has obvious orange grains/ripples after film forming, and the surface of a coating layer is strong in stereoscopic effect.
Description
Technical field
The present invention relates to a kind of solvent based coating, relate in particular to a kind of coating that can play tangerine line/ripple effect, the invention still further relates to the preparation method of this coating.
Background technology
Paint is a kind of generally acknowledged high efficiency, good film performance, ecological environment-friendly type, economical coating products, and twentieth century starts to enter China and obtained developing rapidly the nineties.Wrinkle varnish is a kind of in paint, and its coatingsurface forms the effect as tangerine line/ripple, strong adhesion, and paint film quick-drying, ripple stereoscopic sensation is strong, and decorative effect is better than other finish paint, can cover up general coarse ground.Ripple paint is that domestic each mechanical producer is used many a kind of novel high-grade industry art paints at present, and oil resistant water resistance is excellent, is applicable to the equipment applications such as bin, punch press, plastics subsidiary engine, hydropress, machining center.
Summary of the invention
First object of the present invention is to provide a kind of coating that can play tangerine line/ripple effect, and this formulation for coating material is simple, tangerine line/ripple is obvious after film forming, and coatingsurface stereoscopic sensation is strong.
Second object of the present invention is to provide the preparation method of above-mentioned coating.
First object of the present invention is achieved through the following technical solutions: a kind of coating that can play tangerine line/wrinkle varnish effect, comprises the component of following weight part:
45～65 parts of resins
0～2 part of conventional auxiliary agent
10～20 parts of fillers
0.2～2 part of ripple auxiliary agent
5～30 parts of pigment
8 ~ 15 parts of solvents
2 ~ 10 parts of anti-settling agents.
Described resin is soybean oil modified alkyd, and the hydroxyl value scope of resin is between 125 ~ 135, and acid number is less than 10mgKOH/g, and color and luster is in No. 2 looks, and viscosity is at 40,000/25 ℃ ~ 5.5 ten thousand/25 ℃ (rotational viscosimeter), and resin oil content is 36.
Described conventional auxiliary agent is organotin siccative, the silicone antifoam agent of applicable coating, the mixture of one or more of dispersion agent etc.
Described pigment is titanium dioxide, carbon black, permanent bordeaux, phthalocyanine blue, the mixture of one or more of phthalein viridescent etc.
Described filler is one or more mixtures of talcum powder, coarse whiting, barium sulfate etc.
The organosilicon compound that described ripple auxiliary agent is a kind of macromolecular structure.Be specially the polydimethyl siloxane fluid polymkeric substance of high molecular, by low high the diffusion slowly of surface tension of spreading fast and resin of surface tension of organosilicon auxiliary agent, form the strength of two different directions, make coating produce the phenomenon of mutually piling up, form the same effect of tangerine line.
Described solvent is one or more mixture of diformazan benzene,toluene,xylene, ethyl ester and butyl ester etc.
Described anti-settling agent is one or more mixture of silicon-dioxide, polyesteramide and organobentonite etc.
Second object of the present invention realizes by following technical approach: a kind of preparation method that can play the coating of tangerine line/ripple effect, comprises the following steps:
(1) take according to the above ratio resin, pigment, filler, solvent, part anti-settling agent, be placed in compounding jar, fully mix;
(2) mixed material enters in horizontal sand mill and grinds;
(3) add residue anti-settling agent blending dispersion;
(4) add ripple auxiliary agent blending dispersion;
(5) add conventional auxiliary agent blending dispersion, obtain rising the coating of tangerine line/ripple effect.
In described step (2), each component is mixed and time of grinding is 1 hour, to be ground to designated particles fineness, is as the criterion, and is ground to particularly particle 35um left and right.
The coating process of coating provided by the invention is: by the method for air compressing spraying, be coated on metal base, can hot setting, also can seasoning, its hot setting temperature is 120～130 ℃, be 25～45 minutes set time, can adopt baking box or pipelining, the seasoning time is more than 24 hours.
The present invention compared with prior art has the following advantages:
1. coating provided by the invention has formula simply, use resin and the auxiliary agent of high sag prevention, the strength producing in two different aspects, make coating produce tangerine line, and auxiliary agent produces the phenomenon of sagging while having controlled piling, filler has supplemented the gap of piling up coating, makes to form the tangerine line of piling up and can not subside, and forms very significantly coating of stereoscopic sensation.Coating after solidifying has the features such as excellent physical and mechanical properties, chemical resistance.
Use powder coating of the present invention, the coating after spraying is solidified has following characteristics character:
2. coating provided by the invention, in spraying process, can improve the thickness of paint film fast, and in the middle of same spraying coating process, the thickness of tangerine line paint/ripple coating is at least than the high 10um of plane paint, so can significantly improve the efficiency in coating process.
Embodiment
Below by a part of embodiment, the present invention will be described, is necessary to be pointed out that at this following specific embodiment, only for the invention will be further described, does not represent limiting the scope of the invention.Some nonessential modifications that other people make according to the present invention and adjustment still belong to protection scope of the present invention.
The hydroxyl value scope of soybean oil modified alkyd is between 125 ~ 135, and acid number is less than 10mgKOH/g, and color and luster is in No. 2 looks, and viscosity is at 40,000/25 ℃ ~ 5.5 ten thousand/25 ℃ (rotational viscosimeter), and resin oil content is 36.
Organotin siccative, silicone antifoam agent that conventional auxiliary agent is applicable coating, the mixture of one or more of dispersion agent etc.
Pigment is titanium dioxide, carbon black, permanent bordeaux, phthalocyanine blue, the mixture of one or more of phthalein viridescent etc.
Filler is one or more mixtures of talcum powder, coarse whiting, barium sulfate etc.
Ripple auxiliary agent is a kind of organosilicon compound of macromolecular structure.Be specially the polydimethyl siloxane fluid polymkeric substance of high molecular, by low high the diffusion slowly of surface tension of spreading fast and resin of surface tension of organosilicon auxiliary agent, form the strength of two different directions, make coating produce the phenomenon of mutually piling up, form the same effect of tangerine line.
Solvent is one or more the mixture in diformazan benzene,toluene,xylene, ethyl ester and butyl ester etc.
Anti-settling agent is one or more the mixture in silicon-dioxide, polyesteramide and organobentonite etc.
In the present invention, select the component in following scope all can realize object of the present invention.
embodiment 1
Ripple whitewash, its component and weight part proportioning are: (unit: part)
The soybean oil modified alkyd of acid number 8mgKOH/g (hydroxyl value is 126) 48
Titanium dioxide 30
Organotin siccative T-12 0.2
Coarse whiting 10
Toluene 8
Silicon-dioxide 2
Ripple auxiliary agent 0.8
Organobentonite 1
embodiment 2
Linen wrinkle varnish coating, its component and weight part proportioning are: (unit: part)
The carboxyl Synolac of acid number 8mgKOH/g (hydroxyl value is 130) 55
Titanium dioxide 20
Carbon black 2
Organotin siccative T-12 0.3
Coarse whiting 10
Dimethylbenzene 9
Silicon-dioxide 2
Ripple auxiliary agent 0.7
Organobentonite 1
embodiment 3
Blue wrinkle varnish coating, its component and weight part proportioning are: (unit: part)
The carboxyl Synolac of acid number 8mgKOH/g (hydroxyl value is 135) 53
Titanium dioxide 15
Phthalocyanine blue 3
Organotin siccative T-12 0.3
Coarse whiting 15
Dimethylbenzene 10
Silicon-dioxide 2
Ripple auxiliary agent 0.7
Organic Peng Run soil 1
embodiment 4
Red wrinkle varnish coating, its component and weight part proportioning are: (unit: part)
The carboxyl Synolac of acid number 5mgKOH/g (hydroxyl value is 125) 65
Titanium dioxide 25
Permanent bordeaux 5
Organotin siccative T-12 2
Barium sulfate 20
Ethyl ester 15
Silicon-dioxide 6
Ripple auxiliary agent 1.5
Organic Peng Run soil 4
embodiment 5
Green wrinkle varnish coating, its component and weight part proportioning are: (unit: part)
The carboxyl Synolac of acid number 9mgKOH/g (hydroxyl value is 130) 45
Titanium dioxide 5
Phthalein viridescent 3
Organotin siccative T-12 1
Barium sulfate 5
Butyl ester 15
Silicon-dioxide 3
Ripple auxiliary agent 0.5
Organic Peng Run soil 1
The preparation method of above embodiment
:
(1) take in proportion resin, pigment, filler, solvent and organobentonite, blending dispersion.
(2) after blending dispersion, grind 1 hour, to fineness≤35um.
(3) add silicon-dioxide blending dispersion.
(4) add ripple auxiliary agent blending dispersion, adjust tangerine line effect.
(5) add conventional auxiliary agent blending dispersion, obtain rising the coating of tangerine line/ripple effect.
Film performance after the product painting spontaneous curing being obtained by above-described embodiment is as follows:
Claims (10)
1. the coating that can play tangerine line/wrinkle varnish effect, is characterized in that, comprises the component of following weight part:
45～65 parts of resins
0～2 part of conventional auxiliary agent
10～20 parts of fillers
0.2～2 part of ripple auxiliary agent
5～30 parts of pigment
8 ~ 15 parts of solvents
2 ~ 10 parts of anti-settling agents.
2. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, it is characterized in that, described resin is soybean oil modified alkyd, the hydroxyl value scope of resin is between 125 ~ 135, acid number is less than 10mgKOH/g, color and luster is in No. 2 looks, and viscosity is at 40,000/25 ℃ ~ 5.5 ten thousand/25 ℃, and resin oil content is 36.
3. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, is characterized in that, described conventional auxiliary agent is one or more the mixture in organotin siccative, silicone antifoam agent and dispersion agent.
4. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, is characterized in that, described pigment is titanium dioxide, carbon black, permanent bordeaux, the mixture of one or more in phthalocyanine blue and phthalein viridescent.
5. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, is characterized in that, described filler is one or more the mixture in talcum powder, coarse whiting and barium sulfate.
6. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, is characterized in that, the polydimethyl siloxane fluid polymkeric substance that described ripple auxiliary agent is high molecular.
7. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, is characterized in that, described solvent is one or more the mixture in diformazan benzene,toluene,xylene, ethyl ester and butyl ester.
8. the coating that can play tangerine line/wrinkle varnish effect according to claim 1, is characterized in that, described anti-settling agent is one or more the mixture in silicon-dioxide, polyesteramide and organobentonite.
9. the preparation method of the coating that can play tangerine line/ripple effect described in claim 1 ~ 8 any one, is characterized in that, comprises the following steps:
(1) take according to the above ratio resin, pigment, filler, solvent, part anti-settling agent, be placed in compounding jar, fully mix;
(2) mixed material enters in horizontal sand mill and grinds;
(3) add residue anti-settling agent blending dispersion;
(4) add ripple auxiliary agent blending dispersion;
(5) add conventional auxiliary agent blending dispersion, obtain rising the coating of tangerine line/ripple effect.
10. the preparation method that can play the coating of tangerine line/ripple effect according to claim 9, is characterized in that, in described step (2), each component is mixed and time of grinding is 1 hour, and grain diameter is 35um.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310592765.4A CN103627307B (en) | 2013-11-22 | 2013-11-22 | A kind ofly can play coating of tangerine line/ripple effect and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310592765.4A CN103627307B (en) | 2013-11-22 | 2013-11-22 | A kind ofly can play coating of tangerine line/ripple effect and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN103627307A true CN103627307A (en) | 2014-03-12 |
| CN103627307B CN103627307B (en) | 2016-04-06 |
Family
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Family Applications (1)
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| CN201310592765.4A Active CN103627307B (en) | 2013-11-22 | 2013-11-22 | A kind ofly can play coating of tangerine line/ripple effect and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194595A (en) * | 2014-08-29 | 2014-12-10 | 苏州圣谱拉新材料科技有限公司 | Acrylic polyurethane alkyd resin orange peel coating |
| CN104312226A (en) * | 2014-08-29 | 2015-01-28 | 苏州圣谱拉新材料科技有限公司 | Self-drying acrylic acid orange peel paint |
| CN104356788A (en) * | 2014-11-20 | 2015-02-18 | 深圳市广田环保涂料有限公司 | Orange-peel-effect fluorocarbon paint, and preparation method and application method thereof |
| CN105602431A (en) * | 2016-03-15 | 2016-05-25 | 广东绿色大地化工有限公司 | Water-based acrylic orange-figured paint and construction technique thereof |
| CN105694695A (en) * | 2016-03-15 | 2016-06-22 | 广东绿色大地化工有限公司 | Water-based acrylic corrugated paint and preparation method thereof |
| CN105885659A (en) * | 2016-05-23 | 2016-08-24 | 清远市贝客音涂料有限公司 | Bicomponent water-borne paint with orange peel texture/ripple effect and preparation method thereof |
| CN105969173A (en) * | 2016-07-17 | 2016-09-28 | 广东三和化工科技有限公司 | High-temperature resistant low-toxicity hammer spray paint and preparation method thereof |
| CN110760241A (en) * | 2019-11-11 | 2020-02-07 | 河北晨阳工贸集团有限公司 | Orange peel anti-slip coating and preparation method thereof |
| CN111440476A (en) * | 2020-05-24 | 2020-07-24 | 华月圆 | Orange-peel auxiliary and orange-peel paint |
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| CN1033189A (en) * | 1987-11-19 | 1989-05-31 | 湖南造漆厂 | The manufacture method of auto-drying, matt and tangerine-grained paint |
| JPH03174280A (en) * | 1989-12-04 | 1991-07-29 | Mitsubishi Materials Corp | Coating method giving appearance of peel |
| CN101070376A (en) * | 2007-05-14 | 2007-11-14 | 江苏长江涂料有限公司 | Alcohol-acid type wrinkled resin and preparing method |
| CN102140305A (en) * | 2011-03-07 | 2011-08-03 | 中国海洋石油总公司 | Polyurethane orange-peel coating |
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Patent Citations (4)
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| CN1033189A (en) * | 1987-11-19 | 1989-05-31 | 湖南造漆厂 | The manufacture method of auto-drying, matt and tangerine-grained paint |
| JPH03174280A (en) * | 1989-12-04 | 1991-07-29 | Mitsubishi Materials Corp | Coating method giving appearance of peel |
| CN101070376A (en) * | 2007-05-14 | 2007-11-14 | 江苏长江涂料有限公司 | Alcohol-acid type wrinkled resin and preparing method |
| CN102140305A (en) * | 2011-03-07 | 2011-08-03 | 中国海洋石油总公司 | Polyurethane orange-peel coating |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194595A (en) * | 2014-08-29 | 2014-12-10 | 苏州圣谱拉新材料科技有限公司 | Acrylic polyurethane alkyd resin orange peel coating |
| CN104312226A (en) * | 2014-08-29 | 2015-01-28 | 苏州圣谱拉新材料科技有限公司 | Self-drying acrylic acid orange peel paint |
| CN104356788A (en) * | 2014-11-20 | 2015-02-18 | 深圳市广田环保涂料有限公司 | Orange-peel-effect fluorocarbon paint, and preparation method and application method thereof |
| CN105602431A (en) * | 2016-03-15 | 2016-05-25 | 广东绿色大地化工有限公司 | Water-based acrylic orange-figured paint and construction technique thereof |
| CN105694695A (en) * | 2016-03-15 | 2016-06-22 | 广东绿色大地化工有限公司 | Water-based acrylic corrugated paint and preparation method thereof |
| CN105694695B (en) * | 2016-03-15 | 2017-12-12 | 广东绿色大地化工有限公司 | A kind of water soluble acrylic acid wrinkle varnish and preparation method thereof |
| CN105885659A (en) * | 2016-05-23 | 2016-08-24 | 清远市贝客音涂料有限公司 | Bicomponent water-borne paint with orange peel texture/ripple effect and preparation method thereof |
| CN105969173A (en) * | 2016-07-17 | 2016-09-28 | 广东三和化工科技有限公司 | High-temperature resistant low-toxicity hammer spray paint and preparation method thereof |
| CN105969173B (en) * | 2016-07-17 | 2018-02-06 | 广东三和化工科技有限公司 | A kind of high temperature resistant low toxicity mallear stria spray painting and preparation method thereof |
| CN110760241A (en) * | 2019-11-11 | 2020-02-07 | 河北晨阳工贸集团有限公司 | Orange peel anti-slip coating and preparation method thereof |
| CN111440476A (en) * | 2020-05-24 | 2020-07-24 | 华月圆 | Orange-peel auxiliary and orange-peel paint |
Also Published As
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|---|---|
| CN103627307B (en) | 2016-04-06 |
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Effective date of registration: 20191112 Address after: 513059 No.8, Jinnan 3rd road, fine chemical industry zone, Qingyuan overseas Chinese Industrial Park, Donghua Town, Yingde City, Qingyuan City, Guangdong Province Patentee after: Qingyuan Beikeyin Coating Co., Ltd. Address before: 511363, Guangdong, Guangzhou, Luogang District Jiulong Town, Guangzhou highway, and paragraph Patentee before: GUANGZHOU BEIKEYIN PAINT CO., LTD. |