CN102807810B - 用于无粉pvc手套的wpu涂料及其制备方法 - Google Patents
用于无粉pvc手套的wpu涂料及其制备方法 Download PDFInfo
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- CN102807810B CN102807810B CN201110144751.7A CN201110144751A CN102807810B CN 102807810 B CN102807810 B CN 102807810B CN 201110144751 A CN201110144751 A CN 201110144751A CN 102807810 B CN102807810 B CN 102807810B
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- hour
- emulsion
- wpu
- aqueous polyurethane
- coating
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- 239000011248 coating agent Substances 0.000 title claims abstract description 34
- 238000000576 coating method Methods 0.000 title claims abstract description 34
- 239000004814 polyurethane Substances 0.000 title claims abstract description 30
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims description 12
- 229920000915 polyvinyl chloride Polymers 0.000 title abstract description 29
- 239000004800 polyvinyl chloride Substances 0.000 title abstract description 29
- 239000000839 emulsion Substances 0.000 claims abstract description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- 239000008367 deionised water Substances 0.000 claims abstract description 24
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 15
- 239000000758 substrate Substances 0.000 claims abstract description 12
- 239000000080 wetting agent Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000002562 thickening agent Substances 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 16
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 14
- 125000002462 isocyano group Chemical group *[N+]#[C-] 0.000 claims description 13
- 230000008719 thickening Effects 0.000 claims description 13
- 238000004945 emulsification Methods 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000004970 Chain extender Substances 0.000 claims description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 239000011527 polyurethane coating Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 8
- 229920005906 polyester polyol Polymers 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 230000002459 sustained effect Effects 0.000 claims description 6
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 5
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 5
- HWJHZLJIIWOTGZ-UHFFFAOYSA-N n-(hydroxymethyl)acetamide Chemical compound CC(=O)NCO HWJHZLJIIWOTGZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229960001866 silicon dioxide Drugs 0.000 claims description 2
- 230000008961 swelling Effects 0.000 claims description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- -1 dicyclohexyl methyl Chemical group 0.000 description 3
- BCDGQXUMWHRQCB-UHFFFAOYSA-N glycine methyl ketone Natural products CC(=O)CN BCDGQXUMWHRQCB-UHFFFAOYSA-N 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201110144751.7A CN102807810B (zh) | 2011-05-31 | 2011-05-31 | 用于无粉pvc手套的wpu涂料及其制备方法 |
Applications Claiming Priority (1)
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CN201110144751.7A CN102807810B (zh) | 2011-05-31 | 2011-05-31 | 用于无粉pvc手套的wpu涂料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102807810A CN102807810A (zh) | 2012-12-05 |
CN102807810B true CN102807810B (zh) | 2015-02-18 |
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CN201110144751.7A Active CN102807810B (zh) | 2011-05-31 | 2011-05-31 | 用于无粉pvc手套的wpu涂料及其制备方法 |
Country Status (1)
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Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103013321B (zh) * | 2012-12-24 | 2015-08-19 | 中红普林(北京)医疗用品高新技术研究院有限公司 | 用于无粉pvc手套的高强度高伸长率水性涂饰剂及制备方法 |
CN106318185B (zh) * | 2015-07-08 | 2019-03-26 | 北京林氏精化新材料有限公司 | 一种高固体分pvc手套无粉水性涂层及其制备和使用方法 |
CN105131694B (zh) * | 2015-08-10 | 2017-05-17 | 洛阳盛嘉化工有限公司 | 无粉pvc手套涂料用的乳液型防粘增滑剂及其制备方法 |
CN106519948A (zh) * | 2015-09-15 | 2017-03-22 | 洛阳力海电子科技有限公司 | 一种用于无粉手套涂层的润滑材料 |
CN111040417B (zh) * | 2019-12-24 | 2022-01-28 | 上海华峰新材料研发科技有限公司 | 一种水性哑光型聚氨酯浸胶手套的制备方法 |
CN114058056A (zh) * | 2021-12-10 | 2022-02-18 | 河北宏福医疗用品有限公司 | 一种易穿戴pvc手套及其制备方法 |
CN114479629A (zh) * | 2021-12-24 | 2022-05-13 | 优美特(北京)环境材料科技股份公司 | 一种用于手套的浸渍涂料及制备丁腈橡胶-涂层复合手套的方法 |
CN114507499A (zh) * | 2022-01-13 | 2022-05-17 | 合肥市丰迪厚德新材料有限公司 | 一种天然橡胶手套用水性聚氨酯涂层 |
CN115521606B (zh) * | 2022-09-29 | 2023-10-31 | 广东金发科技有限公司 | 一种聚氨酯组合物、丁腈手套及其制备方法 |
CN115851098A (zh) * | 2022-12-23 | 2023-03-28 | 优美特(北京)环境材料科技股份公司 | 一次性pvc手套用水性聚氨酯涂层原液及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101074343A (zh) * | 2006-05-15 | 2007-11-21 | 北京高盟化工有限公司 | 一种pvc手套的涂饰剂 |
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- 2011-05-31 CN CN201110144751.7A patent/CN102807810B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101074343A (zh) * | 2006-05-15 | 2007-11-21 | 北京高盟化工有限公司 | 一种pvc手套的涂饰剂 |
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Address after: 101309 No. two, No. two longitudinal road, Yang Zhen Town, Shunyi District, Beijing Patentee after: Environmental Science & Technology (Beijing) Co., Ltd. Address before: 101309 No. two, No. two longitudinal road, Yang Zhen Town, Shunyi District, Beijing Patentee before: Beijing Newmat Nano Material Technology Co., Ltd. |
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Denomination of invention: WPU (Water-soluble Polyurethane) coating applied to powder-free PVC (Poly Vinyl Chloride) glove and preparation method thereof Effective date of registration: 20180828 Granted publication date: 20150218 Pledgee: Haidian Beijing science and technology enterprise financing Company limited by guarantee Pledgor: Environmental Science & Technology (Beijing) Co., Ltd. Registration number: 2018990000758 |
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Date of cancellation: 20190719 Granted publication date: 20150218 Pledgee: Haidian Beijing science and technology enterprise financing Company limited by guarantee Pledgor: Environmental Science & Technology (Beijing) Co., Ltd. Registration number: 2018990000758 |
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Denomination of invention: WPU (Water-soluble Polyurethane) coating applied to powder-free PVC (Poly Vinyl Chloride) glove and preparation method thereof Effective date of registration: 20190801 Granted publication date: 20150218 Pledgee: Beijing technology intellectual property financing Company limited by guarantee Pledgor: Environmental Science & Technology (Beijing) Co., Ltd. Registration number: 2019990000828 |
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Date of cancellation: 20200916 Granted publication date: 20150218 Pledgee: Beijing technology intellectual property financing Company limited by guarantee Pledgor: NEWMAT (BEIJING) ENVIRONMENTAL MATERIALS TECHNOLOGY Corp. Registration number: 2019990000828 |
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Denomination of invention: WPU coating for powder free PVC gloves and its preparation Effective date of registration: 20200916 Granted publication date: 20150218 Pledgee: Beijing technology intellectual property financing Company limited by guarantee Pledgor: NEWMAT (BEIJING) ENVIRONMENTAL MATERIALS TECHNOLOGY Corp. Registration number: Y2020990001123 |
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Date of cancellation: 20210831 Granted publication date: 20150218 Pledgee: Beijing technology intellectual property financing Company limited by guarantee Pledgor: NEWMAT (BEIJING) ENVIRONMENTAL MATERIALS TECHNOLOGY Corp. Registration number: Y2020990001123 |
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Denomination of invention: WPU coating for powder free PVC gloves and its preparation method Effective date of registration: 20210831 Granted publication date: 20150218 Pledgee: Beijing technology intellectual property financing Company limited by guarantee Pledgor: NEWMAT (BEIJING) ENVIRONMENTAL MATERIALS TECHNOLOGY Corp. Registration number: Y2021110000039 |
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Date of cancellation: 20220217 Granted publication date: 20150218 Pledgee: Beijing technology intellectual property financing Company limited by guarantee Pledgor: NEWMAT (BEIJING) ENVIRONMENTAL MATERIALS TECHNOLOGY Corp. Registration number: Y2021110000039 |
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Denomination of invention: WPU coating for powder free PVC gloves and its preparation method Effective date of registration: 20220518 Granted publication date: 20150218 Pledgee: Agricultural Bank of China Limited Beijing Shunyi sub branch Pledgor: NEWMAT (BEIJING) ENVIRONMENTAL MATERIALS TECHNOLOGY Corp. Registration number: Y2022990000273 |
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