CN102633475B - Non-glue diatom ooze building material - Google Patents

Non-glue diatom ooze building material Download PDF

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Publication number
CN102633475B
CN102633475B CN 201210138658 CN201210138658A CN102633475B CN 102633475 B CN102633475 B CN 102633475B CN 201210138658 CN201210138658 CN 201210138658 CN 201210138658 A CN201210138658 A CN 201210138658A CN 102633475 B CN102633475 B CN 102633475B
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parts
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orders
mesh
diatom ooze
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CN102633475A (en
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徐连福
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QINGDAO SPRING GAMAY DIATOM OOZE TECHNOLOGY Co Ltd
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QINGDAO SPRING GAMAY DIATOM OOZE TECHNOLOGY Co Ltd
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Abstract

The invention discloses non-glue diatom ooze building material, which is used for wall decoration, surface dressing of boards and intermediate sandwich of the boards, and comprises the following components in parts by weight: 4-90 parts of kieselguhr below 10000 mesh, 20-60 parts of bentonite below 2000 mesh, 10-40 parts of kaolin below 2000 mesh, 5-30 parts of activated clay below 2000 mesh, 10-60 parts of quartz sand below 200 mesh, 5-40 parts of sepiolite below 800 mesh, 5-40 parts of calcium carbonate below 800 mesh, 5-30 parts of medical stone powder below 800 mesh, 2-20 parts of nanosized titania powder below 20000 mesh, 0.1-3 parts of fiber with the length being 5mm or below, 4.5-40 parts of attapulgite below 800 mesh, 2-20 parts of hydroxypropyl methyl cellulose, and 1-20 parts of pigment. According to the non-glue diatom ooze building material, the kieselguhr and other porous natural materials with adsorption capacity are selected to manufacture interior building materials, the proportion is reasonable, chemical adhesive agents are not needed, and adhesive forming is realized through characteristics of the natural materials, so that porous structures of the natural materials can be maintained, indoor pollution can be eliminated, indoor humidity can be adjusted, odor can be removed, noise can be isolated, and flame retardant is realized.

Description

A kind of no glue diatom ooze building materials
[technical field]
The present invention relates to indoor material of construction, relate in particular to a kind of no glue diatom ooze building materials.
[background technology]
At present, along with improving constantly of Economic development and people's living standard, wall decoration coating has obtained being extensive use of.Because interior decoration comprises that wall decoration coating has used the finishing material that contains numerous chemical substances in a large number, has caused " indoor decoration pollution syndromes ", has had a strong impact on the healthy of people.Therefore a kind of wall decoration coating occurred on the market, this coating is major ingredient with inorganic material shape aggregate, powder and inorganic porous powder, and its advantage is can not damage the healthy of people.
But, above-mentioned these inorganic porous powder coatings for can with the metope mortise, often in prescription, added chemical sizing agent.The chemical sizing agent that adds all blocks the original micropore of these coating, cause coating knot plate to solidify and lose original Filtration Adsorption function, and sizing agent itself goes back objectionable impuritiess such as Diazolidinyl Urea, does not belong to the product of real environment-friendly and green.
[summary of the invention]
It is main component and the indoor building materials that need not add chemical sizing agent with inorganic porous powders such as diatom oozes that the technical problem to be solved in the present invention provides a kind of.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is that a kind of no glue diatom ooze building materials are used for wall decoration, the surface daub on a wall of sheet material and the intermediate course of sheet material, are made up of the following component of counting by ratio of weight and the number of copies:
4~90 parts in the following diatomite of 10000 orders;
20~60 parts of the following wilkinites of 2000 orders;
10~40 parts of the following kaolin of 2000 orders;
5~30 parts of the following atlapulgites of 2000 orders;
10~60 parts of the following quartz sands of 200 orders;
5~40 parts of the following sepiolites of 800 orders;
5~40 parts in the following calcium carbonate of 800 orders;
5~30 parts in the following medical stone powder of 800 orders;
2~20 parts of the following nano titanium dioxide powders of 20000 orders;
Length is 0.1~3 part of 5mm and following fiber;
4.5~40 parts of the following attapulgites of 800 orders;
2~20 parts of Vltra tearss;
1~20 part of pigment.
As further improvement, above-mentioned no glue diatom ooze building materials are made up of the following component of counting by ratio of weight and the number of copies:
20~60 parts in the following diatomite of 10000 orders;
30~50 parts of the following wilkinites of 2000 orders;
20~30 parts of the following kaolin of 2000 orders;
15~20 parts of the following atlapulgites of 2000 orders;
20~40 parts of the following quartz sands of 200 orders;
8~30 parts of the following sepiolites of 800 orders;
10~30 parts in the following calcium carbonate of 800 orders;
10~20 parts in the following medical stone powder of 800 orders;
5~15 parts of the following nano titanium dioxide powders of 20000 orders;
Length is 0.3~3 part of 5mm and following fiber;
8~30 parts of the following attapulgites of 800 orders;
4~15 parts of Vltra tearss;
1~10 part of pigment.
Main raw performance of the present invention is as follows:
1) diatom is a kind of unicellular algae that occurs on earth the earliest, and existence is in seawater or lake water, and body is very small, generally has only several microns to tens microns.Diatom can carry out photosynthesis, the self-control organism.Growth and breeding with surprising rapidity usually.Its remains formation of deposits diatomite.The diatomite main component is silicic acid matter, and there are countless pores on the surface, and is adsorbable, decompose airborne peculiar smell, has damping, deodorization functions.Adopting diatomite is the building materials that raw material is produced, not only have do not fire, dehumidifying, deodorizing and the good characteristics of permeability, but also can purify air, sound insulation, waterproof and heat insulation, and cost is not high yet.
2) wilkinite is the moisture clay pit based on montmorillonite.Montmorillonite has adsorptivity and cation exchange property, can be used for removing purification, the wastewater treatment of toxin, gasoline and the kerosene of edible oil; Owing to good water-swelling property and dispersion and suspension and pulping are arranged, therefore are used for drilling mud, fire-retardant (fire extinguishing suspends); Also filler can be in paper industry, done, the performance of coating such as sticking power, opacifying power, water tolerance, abrasion resistance etc. can be optimized; Because good cohesive force is arranged, the yarn sizing that can replace starch to be used for textile industry had both saved grain, and was phozy again, also do not give off a peculiar smell behind the oar.
3) kaolin: the pure kaolin of matter have whiteness height, soft, the easy dispersion suspension of matter in water, good plasticity-and high cohesiveness, excellent electric insulation performance; Have good antiacid dissolubility, very low cation exchange capacity, physico-chemical property such as resistivity against fire preferably.Therefore kaolin has become tens necessary raw mineral materialss of industry such as papermaking, pottery, rubber, chemical industry, coating, medicine and national defence.
4) atlapulgite: atlapulgite is to be raw material with clay (mainly being wilkinite), through inorganic acidification, and the sorbent material of making through water rinse, drying again, outward appearance is off-white powder, and odorless is tasteless, nontoxic, absorption property is very strong, can be adsorbed with color substance, organic substance.The easy moisture absorption was placed for a long time and can be reduced absorption property in air.
5) sepiolite be a kind of tool layer chain-like structure contain Shuifu County's magnesium silicate clay mineral, sepiolite has performances such as extremely strong absorption, decolouring and dispersion, high thermostability is also arranged, and high thermal resistance can reach 1500-1700 ℃, and formative nature, insulativity, anti-salinity are all very good.
6) quartz sand is a kind of silicate minerals of hard, wear-resisting, stable chemical performance, and its essential mineral composition is SiO2.In the processing of prefabricated, onsite concrete and metope, mix a certain proportion of quartz sand, have energy-saving heat preserving, oxygenation, health-care effect.Higher owing to the quartz sand reflectivity, be the raw material of clarification disinfecting tap water, quartz sand is placed on health care oxygenation effect equally on the metope, again because it has higher thermal conductivity, be used as interior wall or exterior wall raw material, can reach the effect of heat preservation energy-saving.
7) attapulgite clay refers to the attapulgite to be a kind of clay mineral of main ingredient.Attapulgite is earthy, compact mass originates in sedimentogeneous rock and the weathering crust, and color is white in color, canescence, Steel Gray, greyish-green or weak satin luster.The soil property exquisiteness has oily soapy, and light weight, property are crisp, and fracture is conchoidal or irregular shape, and water-absorbent is strong.Tool viscosity and plasticity-when wet, dry post shrinkage is little, not quite shows crackle, and the water logging bubble collapses diffusing.Attapulgite clay is as weighting agent, flow agent, thickening material and the stablizer of coating, and its performance is good, and cost is low, can replace traditional fine particle calcium carbonate.Filming of attapulgite coating observed in Electronic Speculum, and its crystal is netted arrangement, is evenly distributed in the organic binder bond, so the washable wiping of filming.Especially recessed soil is good dispersity under external force stirs, form the stable suspension that is not destroyed by ionogen, coating is not precipitated, not stratified, compare with 106 traditional coating, have multiple superiority: the brushing performance is good, sagging not, save the consumption of titanium dioxide, the filler that can do to paint also, the filler of wall board material, produce the top ceiling wall slab, be characterized in: moisture content is accepted, emission behavior is strong, and it is indeformable not expand, and adhesive property is good, light weight toughness is big, has heat-insulation warm keeping, the effect of sound absorption can be prevented damaging by worms, and anti-sag is strong, can adapt to the variation of air themperature, and indeformable.
The invention has the beneficial effects as follows:
Select diatomite for use, kaolin, wilkinite, atlapulgite, the medical stone powder, quartz sand, these porous of sepiolite and attapulgite clay and the natural materials with adsorptive power, conduct is decorated with coating or is made sheet material after reasonable proportioning, owing to need not use chemical sizing agent, feature bonding with above-mentioned natural materials is shaped entirely, can keep the vesicular structure of above-mentioned natural materials to have absorption more, hygroscopic property, but decontamination chamber internal contamination, regulate indoor humidity, eliminate peculiar smell, insulating noise, the coating surface sense of texture is strong, fire protection flame retarding, the green structural material of a kind of update of can yet be regarded as.
[embodiment]
Embodiment 1:
Present embodiment is a kind of no glue diatom ooze building materials as wall decoration coating, is made up of the following component of counting by ratio of weight and the number of copies:
90 parts in the following diatomite of 10000 orders;
60 parts of the following wilkinites of 2000 orders;
10 parts of the following kaolin of 2000 orders;
5 parts of the following atlapulgites of 2000 orders;
60 parts of the following quartz sands of 200 orders;
5 parts in the following calcium carbonate of 800 orders;
30 parts of the following sepiolites of 800 orders;
10 parts in the following medical stone powder of 800 orders;
7 parts of the following nano titanium dioxide powders of 20000 orders;
Length is 0.3 part of 5mm and following fiber;
30 parts of the following attapulgites of 800 orders;
2 parts of Vltra tearss;
20 parts of pigment.
Process for preparing raw material: clay mineral such as kaolin, diatomite, attapulgite, sepiolite all adopt wet processes.Ore gets 400 orders~2000 order products through fragmentation, washup, pulp, desanding, classification, screening, bleaching, filtration finally by spraying drying.
The finished product working method: all material adds stirring in the conical agitator in proportion in will filling a prescription, and after mixing repeatedly, packs in 5 kilograms of plastics bags, and packing is dispatched from the factory.
Constructional method: all material of adorning in the finished bag is added in the plastic tank of containing 20 liters, add the clear water of 1: 1 ratio, with electric blender material in the bucket is stirred into thick shape.Be coated with mud plate cutter and scrape on metope that putty polishes flat, glass, plank, treat that sixty percent makes various skin texture with special tool when doing, also can make the plane stamp.4 hours surfaces of mud face behind the blade coating are namely dry, can parch after 24 hours.
The present embodiment prescription is based on diatomite, wilkinite, and adsorptivity and cohesive force tool are good, need not to add chemical sizing agent, environmental protection, and wall on the no glue has adsorption effect and metope sense of texture preferably.
Embodiment 2:
Present embodiment is a kind of no glue diatom ooze building materials as wall decoration coating, is made up of the following component of counting by ratio of weight and the number of copies:
50 parts in the following diatomite of 10000 orders;
30 parts of the following wilkinites of 2000 orders;
40 parts of the following kaolin of 2000 orders;
30 parts of the following atlapulgites of 2000 orders;
40 parts of the following quartz sands of 200 orders;
30 parts in the following calcium carbonate of 800 orders;
40 parts of the following sepiolites of 800 orders;
20 parts in the following medical stone powder of 800 orders;
20 parts of the following nano titanium dioxide powders of 20000 orders;
Length is 1 part of 5mm and following fiber;
8 parts of the following attapulgites of 800 orders;
15 parts of Vltra tearss;
10 parts of pigment.
Raw material and finished product working method: identical with embodiment 1.
Constructional method: identical with embodiment 1.
The present embodiment prescription need not to add chemical sizing agent based on diatomite, kaolin, atlapulgite and quartz sand, wall on the no glue, and environmental protection has adsorptivity, water absorbability and insulation oxygenation effect preferably.
Embodiment 3:
A kind of no glue diatom ooze building materials as plate surface covering with paint and making sheet material middle layer, formed by the following component of counting by ratio of weight and the number of copies:
4 parts in the following diatomite of 10000 orders;
40 parts of the following wilkinites of 2000 orders;
20 parts of the following kaolin of 2000 orders;
20 parts of the following atlapulgites of 2000 orders;
10 parts of the following quartz sands of 200 orders;
40 parts in the following calcium carbonate of 800 orders;
8 parts of the following sepiolites of 800 orders;
5 parts in the following medical stone powder of 800 orders;
2 parts of the following nano titanium dioxide powders of 20000 orders;
Length is 3 parts of 5mm and following fibers;
4.5 parts of the following attapulgites of 800 orders;
20 parts of Vltra tearss;
1 part of pigment.
Raw material and finished product working method: identical with embodiment 1.
Constructional method: identical with embodiment 1.
The collocation of present embodiment prescription does not rationally use chemical glue as binding agent, and it is strong to have cohesive force, and takes into account adsorption effect and insulation oxygenation effect, the sheet material environmental protection of making simultaneously.
Embodiment 4:
A kind of no glue diatom ooze building materials as wall decoration, formed by the following component of counting by ratio of weight and the number of copies:
20 parts in the following diatomite of 10000 orders;
50 parts of the following wilkinites of 2000 orders;
30 parts of the following kaolin of 2000 orders;
15 parts of the following atlapulgites of 2000 orders;
20 parts of the following quartz sands of 200 orders;
10 parts in the following calcium carbonate of 800 orders;
20 parts of the following sepiolites of 800 orders;
30 parts in the following medical stone powder of 800 orders;
15 parts of the following nano titanium dioxide powders of 20000 orders;
Length is 0.8 part of 5mm and following fiber;
10 parts of the following attapulgites of 800 orders;
4 parts of Vltra tearss;
8 parts of pigment.
Raw material and finished product working method: identical with embodiment 1.
Constructional method: identical with embodiment 1.
Above-mentioned prescription is taken into account each side, does not add chemical sizing agent, environmental protection, and net effect is good.

Claims (1)

1. no glue diatom ooze building materials are used as wall decoration coating, are made up of the following component of counting by ratio of weight and the number of copies:
90 parts in the following diatomite of 10000 orders;
60 parts of the following wilkinites of 2000 orders;
10 parts of the following kaolin of 2000 orders;
5 parts of the following atlapulgites of 2000 orders;
60 parts of the following quartz sands of 200 orders;
5 parts in the following calcium carbonate of 800 orders;
30 parts of the following sepiolites of 800 orders;
10 parts in the following medical stone powder of 800 orders;
7 parts of the following nano titanium dioxide powders of 20000 orders;
Length is 0.3 part of the following fiber of 5mm;
30 parts of the following attapulgites of 800 orders;
2 parts of Vltra tearss;
20 parts of pigment;
It is characterized in that:
In the process for preparing raw material, clay mineral adopts wet processes, ore is through fragmentation, washup, pulp, desanding, classification, screening, bleaching, filtration, get 400 orders~2000 order products finally by spraying drying, in the finished product working method, all material adds stirring in the conical agitator in proportion in will filling a prescription, after mixing repeatedly, pack in 5 kilograms of plastics bags, packing is dispatched from the factory.
CN 201210138658 2012-04-27 2012-04-27 Non-glue diatom ooze building material Active CN102633475B (en)

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Address after: Laoshan District, Qingdao three road 266000 Shandong city of Qingdao province No. 8 poly center 10 layer 1109

Patentee after: Qingdao Spring Gamay Diatom Ooze Technology Co., Ltd.

Address before: 1305 room 182-6, Haier Road, Laoshan District, Shandong, Qingdao, 266000

Patentee before: Qingdao Spring Gamay Diatom Ooze Technology Co., Ltd.

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