CN106495573B - Modified silicon soil property lake mud building materials and preparation method for inner wall decoration - Google Patents
Modified silicon soil property lake mud building materials and preparation method for inner wall decoration Download PDFInfo
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- CN106495573B CN106495573B CN201610934354.2A CN201610934354A CN106495573B CN 106495573 B CN106495573 B CN 106495573B CN 201610934354 A CN201610934354 A CN 201610934354A CN 106495573 B CN106495573 B CN 106495573B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/28—Polysaccharides or derivatives thereof
- C04B26/285—Cellulose or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/04—Heat treatment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
Abstract
The invention discloses the modified silicon soil property lake mud building materials and preparation method for inner wall decoration, belong to building materials technology field.Building materials of the present invention include following components: distilled water, modified silicon soil property lake mud powder, activation conch meal, modified mineral water-holding thickening agent, dichloride in anatase type titanium dioxide, modified kaolin powder, heavy calcium carbonate, calcium lime powder, modified acrylate emulsion, medical stone powder, hydroxyethylmethylcellulose, pigment, nano TiO 2 modified chitosan anti-bacteria mould inhibitor.Building materials of the present invention are formed by the material science compatibility of green, environmental protection, building materials inherently safe, stabilization, nontoxic, non-volatility pernicious gas.It can not only adsorb, the pernicious gases such as purifying formaldehyde, benzene, can also adjust indoor humidity, enhancing coating wall surface skin texture, sound-insulating, eliminate peculiar smell, fire protection flame retarding, and building materials of the present invention also have the characteristics that it is at low cost, do not crack, do not lose powder, antibacterial and mouldproof, easily reparation.
Description
Technical field
The invention belongs to building materials technology fields, more particularly to the modified silicon soil property lake mud building materials and system for inner wall decoration
Preparation Method.
Background technique
As living standard is continuously improved, people are higher and higher to the personalization of decoration and the feature of environmental protection requirement of material, with
The demand that decorations indoor wall has been unable to meet people is decorated toward the collocation for commonly using powder of lacquer putty for use on, emulsion paint, starts wind again in recent years
Diatom ooze coating is wasted, but its fancy price allows many consumers to hope and draw back.The pernicious gases such as formaldehyde releases after house decoration
It lengthens up to several weeks even many decades, has seriously affected the life and health of people.Market is common at present has odorless emulsion paint, except aldehyde cream
The building materials such as shellac varnish, diatom ooze, ordor removing, except aldehyde mainly rely on itself reduce or without using glue containing formaldehyde, physical absorption and
The methods of chemical breakdown.It itself reduces or only can guarantee self-pollution in safe range, and to room without using containing formaldehyde components
The formaldehyde of interior other furniture release is then without substantive catharsis；Physical absorption can not effectively decomposing formaldehyde, and adsorption saturation
After be most likely to produce secondary pollution；Chemical breakdown then passes through consumption autacoid reaction except aldehyde, when effective component runs out of
Quan Hou cannot achieve for a long time except aldehyde effect.
The technical research disclosed in diatom ooze has very much." a kind of nano combined diatom ooze disclosed in CN102060557B
Material and its construction method " in mention by spraying mode of loading for nanometer titanium dioxide titanium solution (light on diatom ooze surface of constructing
Catalyst) it loads in the micropore on diatom ooze surface layer, and by the porosity of diatom ooze by free formaldehyde present in room air
And other pernicious gases are adsorbed onto diatom ooze coating, pass through the decomposition of photocatalyst (nano-titanium dioxide) and negative ion powder
It is broken down into harmless carbon dioxide and water, to achieve the purpose that purify air.But by being sprayed on diatom ooze construction surface
It applies mode of loading to load to nanometer titanium dioxide titanium solution (photocatalyst) in the micropore on diatom ooze surface layer, this mode is easy because applying
Work is improper and runs counter to desire.The amount for spraying photocatalyst excessively then easily blocks adsorption hole and reduces adsorption capacity, sprays photocatalyst
It is too short and ineffective to measure few then protection period, and photocatalyst needs ultraviolet light irradiation just with decomposition, in natural light
Ultraviolet light hardly enter interior, just further limited to the capacity of decomposition of photocatalyst；It is " a kind of disclosed in CN102633475B
No glue diatom ooze building materials " in mention select diatomite, kaolin, bentonite, atlapulgite, medical stone powder, quartz sand, sepiolite
These natural materials porous and with adsorption capacity with Concave-convex clay rod, since chemical adhesive need not be used, entirely with upper
The feature bonding forming for stating natural material, is better able to keep the porous structure of above-mentioned natural material to have absorption, moisture pick-up properties,
Indoor pollution can be eliminated, indoor humidity is adjusted, eliminates peculiar smell, insulating noise, coating surface sense of texture is strong, the effect of fire protection flame retarding
Fruit.Binder is not used suitably due to using above-mentioned many ore pulvis, is easily dehydrated into hardened painting after its drying, weathering
Layer easily loses bond effect with wall, the problems such as coating cracking, fall off, lose powder easily occurs, there are the secondary pollutions such as dust.On and
Stating patent only used diatomite, sepiolite with adsorption function, and the material with catalysis, decomposition function is not used, institute
With after its adsorption saturation, coating becomes potential pollutant.And its fancy price enables many consumers hope and timid
Step, eventually leads to it and fails to popularize always.
Summary of the invention
It is an object of the present invention in view of the above shortcomings of the prior art, provide the modified silicon soil property for inner wall decoration
Lake mud building materials and preparation method.Building materials of the present invention by green, environmental protection material science compatibility form, building materials inherently safe, stabilization,
Nontoxic, non-volatility pernicious gas.It can not only adsorb, the pernicious gases such as purifying formaldehyde, benzene, moreover it is possible to adjust indoor humidity, increase
Strong coating wall surface skin texture, sound-insulating eliminate peculiar smell, fire protection flame retarding, and building materials of the present invention also have it is at low cost, do not crack,
It does not lose powder, antibacterial and mouldproof, easy the features such as repairing.
In order to solve the above technical problems, the technical solution adopted by the present invention is that:
For the modified silicon soil property lake mud building materials of inner wall decoration, the component including following parts by weight: distilled water 30-60
Part, 10-35 parts of modified silicon soil property lake mud powder, conch meal 1-15 parts of activation, 2-10 parts of modified mineral water-holding thickening agent, anatase titanium dioxide are received
1-12 parts of titanium dioxide of rice, 1-12 parts of modified kaolin powder, 0.1-5 parts of heavy calcium carbonate, 0.1-5 parts of calcium lime powder, modified third
0.1-5 parts of olefin(e) acid ester lotion, 0.1-4 parts of medical stone powder, 0.5-5 parts of hydroxyethylmethylcellulose, 0.1-3 parts of pigment, nanometer
0.5-3 parts of TiO2 modified chitosan anti-bacteria mould inhibitor.
Further, the above-mentioned modified silicon soil property lake mud building materials for inner wall decoration, the component including following parts by weight:
35-50 parts of distilled water, 20-23 parts of modified silicon soil property lake mud powder, activation conch meal 4-10 parts, modified mineral water-holding thickening agent 5-8
Part, 1-3 parts of calcium lime powder, changes 3-8 parts of dichloride in anatase type titanium dioxide, 3-8 parts of modified kaolin powder, 1-3 parts of heavy calcium carbonate
Property 1.5-2 parts of acrylic acid ester emulsion, 1-2 parts of medical stone powder, 1-2 parts of hydroxyethylmethylcellulose, 0.5-1 parts of pigment, nanometer
1-1.5 parts of TiO2 modified chitosan anti-bacteria mould inhibitor.
Further, the above-mentioned modified silicon soil property lake mud building materials for inner wall decoration, the component including following parts by weight:
Component including following parts by weight: 45 parts of distilled water, 21 parts of modified silicon soil property lake mud powder, activation 7 parts of conch meal, modified mineral
6 parts of water-holding thickening agent, 5 parts of dichloride in anatase type titanium dioxide, 5 parts of modified kaolin powder, 2 parts of heavy calcium carbonate, calcium lime powder 2
Part, 1.8 parts of modified acrylate emulsion, 1.5 parts of medical stone powder, 1.7 parts of hydroxyethylmethylcellulose, pigment 0.8 part, nanometer
1.2 parts of TiO2 modified chitosan anti-bacteria mould inhibitor.
Further, the above-mentioned modified silicon soil property lake mud building materials for inner wall decoration, the modified silicon soil property lake mud powder, work
It is preferred to change conch meal, dichloride in anatase type titanium dioxide, modified kaolin powder, heavy calcium carbonate, calcium lime powder and medical stone powder
100-800 mesh granularity.
Preparation method of the present invention for the modified silicon soil property lake mud building materials of inner wall decoration, comprising the following steps: by tripoli
Matter lake mud is fitted into blender, and 3-5 parts by weight PAS inorganic flocculating agent is added, and 100-200r/min stirs 30-60s, stands 3-
5min, be discharged supernatant after be packed into rotary kiln, through 500 DEG C -550 DEG C of calcinings 6-8 hour, after sintering crushing and mistake 100-800 mesh
Sieve obtains dring silicon soil property lake mud powder；By dring silicon soil property lake mud powder, HK-560 silane coupling agent, PEG-8 dimeticone water
Soluble silicone and injection active carbon powder are by weight 100:(0.7-1): (1.5-2): (0.8-1) is packed into rotary kiln, 450-650
DEG C heat preservation 1-3h, carries out revolution heat modification, modified silicon soil property lake mud powder needed for being made；Kaolin is packed into rotary kiln, is passed through
200-400 DEG C calcining 2-4 hours, after sintering crush and cross 100-800 mesh screen, obtain modified kaolin powder；By above-mentioned weight
Number is high by modified silicon soil property lake mud powder, activation conch meal, modified mineral water-holding thickening agent, dichloride in anatase type titanium dioxide, modification
The modified shell of ridge soil powder, heavy calcium carbonate, calcium lime powder, medical stone powder, hydroxyethylmethylcellulose, pigment, nano TiO 2 is poly-
Sugared antibacterial mildew inhibitor is packed into blender, and 3000-5000r/min stirs 20-30min, is uniformly mixed each its；Above-mentioned weight is added
Number distilled water and modified acrylate emulsion, 15-30r/min stir 3-5h, cross 50-800 mesh screen, have both obtained described for interior
The modified silicon soil property lake mud building materials of wall decoration.
The above for inner wall decoration modified silicon soil property lake mud building materials needed for component can by market purchase or now
There is technology realization, and main component be described as follows:
Modified silicon soil property lake mud powder: referring to the tripoli matter mud formed in lake sediment by the effect of joining, be dehydrated,
Tripoli matter lake mud powder is made in low temperature calcination, pulverizing process, and molecular structure has larger hole, has similar structure with diatomite
It makes, equally there is preferable absorption, catharsis to room air pollution.With HK-560 silane coupling agent, PEG-8 dimeticone
Water-soluble siloxanes and injection active carbon powder are turned round heat modification, and modified irony lake mud powder is made, modified not only to make its system
Finished product has elasticity, changes its inherent shortcoming for drying after-hardening, cracking, become fragile, losing powder, and increase coat inside hole
Gap enhances its adsorption capacity, and the constriction coefficient of coating can be effectively reduced, and reduces the risk of cracking.
Activate conch meal: conch meal is by grinding shells into powder, wherein 95% main component is calcium carbonate, there are also few
Measure amino acid and polysaccharide material.Conch meal is widely used in production whitening product, animal and fowl fodder, food calcium source additive, high-grade dress
Decoration paint, high-end interior wall coating, desiccant etc..Activation conch meal is made in conch meal after the processing of vacuum life activating technology, most
The big active factors remained in shell, instead of the effect of traditional photocatalyst.Its purify air performance and diatom ooze there are few
Difference similarly has the function of elimination peculiar smell, fire protection flame retarding, adjusting air humidity, absorbing sound and lowering noise, antistatic, antibacterial bacteriostatic,
And it compares diatom ooze and also has more the soft and smooth visual effect of texture.
Modified mineral water-holding thickening agent: it is made of natural minerals by modified, compounding, essential mineral has bentonite, height
The mineral such as ridge soil pass through couplant modification, enhance water-keeping thickening effect, can not only be used for filler material, and it is plastic to enhance its
Property, caking property and water-retaining property, be of great significance to crack resistence, anti-picking.
Dichloride in anatase type titanium dioxide: English name Anatase Titanium Dioxide, it is known that nano-titanium dioxide
Also known as titanium dioxide, mainly there is two kinds of crystal habits of anatase titanium dioxide and rutile-type, and the photocatalytic activity of dichloride in anatase type titanium dioxide
It is higher than rutile type nano titanium dioxide.The maximum purposes of titanium dioxide is coating industry, the coating manufactured with titanium dioxide, and color is fresh
Gorgeous, covering power is high, and strong coloring force is low-consuming, wide in variety, can play a protective role to the stability of medium, and there are also enhance paint film
Mechanical strength, adhesive force, prevent crackle, prevent ultraviolet light, moisture penetrate, extend the paint film service life the characteristics of.Under light action,
Continuous redox reaction can occur for dichloride in anatase type titanium dioxide, have photochemical activity, be the organic compounds object light such as formaldehyde
Quick reducing catalyst.
Modified kaolin powder: kaolin is also known as porcelain stone, be multi mineral composition hydrosilicate aggregate, mainly at
It is divided into kaolinite, is a kind of hydrous alumino silicates.Modified kaolin powder is made in kaolin after calcining, grinding.By calcining
Kaolin the hydroxyl in its structure can be made to take off, the amount of dissolution of silicon and aluminium is maximum at this time, with very high activity.Addition is forged
Kaolin powder after burning can not only reduce cost, moreover it is possible to the viscosity and adsorption activity of enhancing building materials of the present invention.
Heavy calcium carbonate: English name Heavy Calcium Carbonate, abbreviation coarse whiting are by natural magnesium salt mine
Object such as calcite, marble, lime stone are ground.Common powdery inorganic filler, have chemical purity is high, inertia is big,
It is not easy to chemically react, thermal stability is good, will not decompose at 400 DEG C or less, whiteness is high, oil absorbency is low, index of refraction is low, matter is soft, dry
It is dry, without the crystallization water, the advantages that low wearing valve of hardness is small, nontoxic, tasteless, odorless, good dispersion.In tripoli matter lake mud of the present invention
Heavy calcium carbonate is added in building materials, its toughness and hygroscopicity can be improved, and is of great significance to crack resistence, anti-picking.
Modified acrylate emulsion: with acrylic acid or esters of acrylic acid for main Material synthesis, stablize with excellent light
Property and weatherability, good water-fast, alkaline-resisting, chemical resistance and adhesive property, thus be widely used as adhesive, building materials at
Film and daily-use chemical industry, electrochmical power source, functional membrane, medical high polymer, nano material and water process etc..By organic
Acrylate emulsion modified with organosiloxane the advantages of both can integrating, improves propylene acid esters lotion " heat sticks cold short ", weather-proof, water-fast etc.
Performance greatly improves tripoli matter lake mud building materials of the present invention to avoid influence of the variation because of amblent air temperature to bond effect
Stability.
Medical stone powder: English name maifanstone is a kind of natural silicate mineral, is a kind of half igneous of neutral alkali
Rock, close to volcanic rock, microscopic structure be it is spongy porous, have extremely strong adsorption capacity, it is net to can be used for water quality
Change, sewage treatment, and there is very strong suction-operated to bacterium, the function such as the absorption, purification, degerming of building materials of the present invention can be improved
Can, have with modified silicon soil property lake mud powder, dichloride in anatase type titanium dioxide and nano TiO 2 modified chitosan anti-bacteria mould inhibitor and cooperates with
Effect.
Hydroxyethylmethylcellulose: English name methyl 2-hydroxyethyl cellulose, is in methylcellulose
(MC) it introduces ethylene oxide substituent group (MS0.3 ~ 0.4) in be made, salt tolerance is better than unmodified polymer, the gel temperature of HEMC
Degree is also compared with MC high.Cellulose described above has very high stability, and there is no pollutions for itself.It can be introduced after addition through stirring
A large amount of micro-bubbles, these bubbles can be improved the workability of construction in later period and improve internal structure gas porosity, and clayey can be improved
Lake mud enhances viscosity, toughness and the water-retaining property of building materials of the present invention to the adsorption capacity and adjusting air humidity of pernicious gas, to anti-
Cracking, anti-picking are of great significance.
Nano TiO 2 modified chitosan anti-bacteria mould inhibitor: wherein nano TiO 2 as a kind of photo-catalytic sterilization, except the reason of aldehyde
Think material, is widely used in cosmetics, antibacterial except fields such as aldehyde coating.Chitosan belongs to the natural antibacterial agent having no toxic side effect, tool
There are good biocompatibility, degradability, reproducibility.The novel antibacterial of preparation is modified to chitosan with nano TiO 2
Nano TiO 2 modified chitosan anti-bacteria mould inhibitor not only improves the antimildew and antibacterial ability of building materials of the present invention, but also under light illumination also
With photocatalytic activity, there is synergistic effect with modified kaolin powder.
In conclusion due to the adoption of the above technical scheme, the present invention is used for the modified silicon soil property lake mud building materials of inner wall decoration
Beneficial effect be:
1. using modified silicon soil property lake mud building materials make wall decorative paint, can not only alleviate lake mud deposition, water storage reduce,
The environmental problems such as the miscellaneous life of water plant, water hypoxia also can be reduced the exploitation of the mineral products such as diatomite, mitigate the destruction of ecology.By low
Temperature calcining tripoli matter lake mud can effectively drive away the fugitive constituent of mineral and combine water, and activatable structural enhances the suction of molecular surface hole
Attached ability.Added by the revolution with HK-560 silane coupling agent, PEG-8 dimeticone water solubility siloxanes and injection active carbon powder
Heat modification makes its manufactured goods have elasticity, changes its inherent shortcoming for drying after-hardening, cracking, become fragile, losing powder, and increase
Coat inside hole enhances its adsorption capacity, the constriction coefficient of coating can be effectively reduced, reduces the risk of cracking.Conch meal
After the processing of vacuum life activating technology, the maximum active factors remained in shell, not only absorption property and diatom ooze are several
Indifference, and the alternative effect of traditional photocatalyst of its degrading activity factor, further increase absorption, decomposability.Add
Dichloride in anatase type titanium dioxide, modified kaolin powder, medical stone powder and the nano TiO 2 modified chitosan anti-bacteria mould inhibitor added, can promote
Decomposition, detergent power into the pernicious gases such as tripoli matter lake mud powder and activation conch meal PARA FORMALDEHYDE PRILLS(91,95), benzene, thoroughly solve adsorption saturation
The problem of.Kaolin of the addition by calcining, because the hydroxyl in its structure is taken off, the amount of dissolution of silicon and aluminium is maximum at this time, has
Very high activity can enhance the viscosity and adsorption activity of building materials of the present invention.Add modified mineral water-holding thickening agent, powdered whiting
Powder, calcium lime powder, modified acrylate emulsion and hydroxyethylmethylcellulose act not only as filler material and reduce cost, and
And caking property, water-retaining property specific to each component, stability obtain synergistic effect, thoroughly solve crack, lose powder, falling off
The problem of.Nano TiO 2 modified chitosan anti-bacteria mould inhibitor not only remains the function of nano TiO 2 decomposing formaldehyde, also has shell
The effect of glycan antibacterial and mouldproof, enhances antiseptic and mildew resistant ability under the synergy of medical stone powder and calcium lime powder.
2. the present invention for inner wall decoration modified silicon soil property lake mud building materials by green, environmental protection material science compatibility and
At building materials inherently safe, stabilization, nontoxic, non-volatility pernicious gas.It can not only adsorb, harmful gas such as purifying formaldehyde, benzene
Body, moreover it is possible to adjust indoor humidity, enhancing coating wall surface skin texture, sound-insulating, eliminate peculiar smell, fire protection flame retarding, and the present invention is built
Material also have the characteristics that it is at low cost, do not crack, do not lose powder, antibacterial and mouldproof, easily repair.
Specific embodiment
The present invention is further described combined with specific embodiments below.
Embodiment 1
For the modified silicon soil property lake mud building materials of inner wall decoration, the component including following parts by weight: 30 parts of distilled water changes
Property 35 parts of tripoli matter lake mud powder, 1 part of conch meal of activation, 10 parts of modified mineral water-holding thickening agent, 1 part of dichloride in anatase type titanium dioxide,
12 parts of modified kaolin powder, 0.1 part of heavy calcium carbonate, 5 parts of calcium lime powder, 0.1 part of modified acrylate emulsion, medical stone powder
4 parts, 0.5 part of hydroxyethylmethylcellulose, 3 parts of pigment, 0.5 part of nano TiO 2 modified chitosan anti-bacteria mould inhibitor.
The preparation method of modified silicon soil property lake mud building materials for inner wall decoration, comprising the following steps: by tripoli matter lake mud
It is fitted into blender, 5 parts by weight PAS inorganic flocculating agents is added, 100r/min stirs 60s, 40min is stood, after supernatant is discharged
It is packed into rotary kiln, is calcined 6 hours through 550 DEG C, 800 mesh screens are crushed and crossed after sintering, obtain dring silicon soil property lake mud powder；It will do
Dry tripoli matter lake mud powder, HK-560 silane coupling agent, PEG-8 dimeticone water solubility siloxanes and injection active carbon powder are by weight
It is packed into rotary kiln than 100:0.7:2:0.8,450 DEG C of heat preservation 3h carry out revolution heat modification, modified silicon soil property lake needed for being made
Mud powder；Kaolin is packed into rotary kiln, is calcined 2 hours through 400 DEG C, 800 mesh screens are crushed and crossed after sintering, obtains modified kaolinite
Native powder；Modified silicon soil property lake mud powder, activation conch meal, modified mineral water-holding thickening agent, anatase titanium dioxide are received by above-mentioned parts by weight
Rice titanium dioxide, heavy calcium carbonate, calcium lime powder, medical stone powder, hydroxyethylmethylcellulose, pigment, is received modified kaolin powder
Rice TiO2 modified chitosan anti-bacteria mould inhibitor is packed into blender, and 50r/min stirs 30min, is uniformly mixed each its；It is added above-mentioned
Parts by weight distilled water and modified acrylate emulsion, 15r/min stir 5h, cross 800 mesh screens, both obtain the interior wall that is used for and fill
The modified silicon soil property lake mud building materials of decorations.
Embodiment 2
For the modified silicon soil property lake mud building materials of inner wall decoration, the component including following parts by weight: 60 parts of distilled water changes
Property 10 parts of tripoli matter lake mud powder, 15 parts of conch meal of activation, 2 parts of modified mineral water-holding thickening agent, 12 parts of dichloride in anatase type titanium dioxide,
1 part of modified kaolin powder, 5 parts of heavy calcium carbonate, 0.1 part of calcium lime powder, 5 parts of modified acrylate emulsion, medical stone powder 0.1
Part, 5 parts of hydroxyethylmethylcellulose, 0.1 part of pigment, 3 parts of nano TiO 2 modified chitosan anti-bacteria mould inhibitor.
The preparation method of modified silicon soil property lake mud building materials for inner wall decoration, comprising the following steps: by tripoli matter lake mud
It is fitted into blender, 3 parts by weight PAS inorganic flocculating agents is added, 200r/min stirs 30s, 60min is stood, after supernatant is discharged
It is packed into rotary kiln, is calcined 8 hours through 500 DEG C, net is crushed and sieved with 100 mesh sieve after sintering, obtains dring silicon soil property lake mud powder；It will do
Dry tripoli matter lake mud powder, HK-560 silane coupling agent, PEG-8 dimeticone water solubility siloxanes and injection active carbon powder are by weight
It is packed into rotary kiln than 100:1:1.5:1,650 DEG C of heat preservation 1h carry out revolution heat modification, modified silicon soil property lake needed for being made
Mud powder；Kaolin is packed into rotary kiln, is calcined 4 hours through 200 DEG C, net is crushed and sieved with 100 mesh sieve after sintering, obtains modified kaolinite
Native powder；Modified silicon soil property lake mud powder, activation conch meal, modified mineral water-holding thickening agent, anatase titanium dioxide are received by above-mentioned parts by weight
Rice titanium dioxide, heavy calcium carbonate, calcium lime powder, medical stone powder, hydroxyethylmethylcellulose, pigment, is received modified kaolin powder
Rice TiO2 modified chitosan anti-bacteria mould inhibitor is packed into blender, and 80r/min stirs 20min, is uniformly mixed each its；In addition
Parts by weight distilled water and modified acrylate emulsion are stated, 30r/min stirs 3h, crosses 50 mesh screens, both obtains described for interior wall
The modified silicon soil property lake mud building materials of decoration.
Embodiment 3
For the modified silicon soil property lake mud building materials of inner wall decoration, the component including following parts by weight: 35 parts of distilled water changes
Property 23 parts of tripoli matter lake mud powder, 4 parts of conch meal of activation, 8 parts of modified mineral water-holding thickening agent, 3 parts of dichloride in anatase type titanium dioxide, change
8 parts of property kaolin powder, 1 part of heavy calcium carbonate, 3 parts of calcium lime powder, 1.5 parts of modified acrylate emulsion, 2 parts of medical stone powder,
1 part of hydroxyethylmethylcellulose, 1 part of pigment, 1 part of nano TiO 2 modified chitosan anti-bacteria mould inhibitor.
The preparation method of modified silicon soil property lake mud building materials for inner wall decoration, comprising the following steps: by tripoli matter lake mud
It is fitted into blender, 3.5 parts by weight PAS inorganic flocculating agents is added, 180r/min stirs 40s, stands 55min, and supernatant is discharged
After be packed into rotary kiln, through 515 DEG C calcine 7.5 hours, after sintering crush and cross 600 mesh screens, obtain dring silicon soil property lake mud powder；
Dring silicon soil property lake mud powder, HK-560 silane coupling agent, PEG-8 dimeticone water solubility siloxanes and injection active carbon powder are pressed
Weight ratio 100:0.8:1.9:0.85 is packed into rotary kiln, and 500 DEG C of heat preservation 2.5h carry out revolution heat modification, modified needed for being made
Tripoli matter lake mud powder；Kaolin is packed into rotary kiln, is calcined 2.5 hours through 350 DEG C, 600 mesh screens are crushed and crossed after sintering, are obtained
To modified kaolin powder；Modified silicon soil property lake mud powder, activation conch meal, modified mineral water conservation are thickened by above-mentioned parts by weight
Agent, dichloride in anatase type titanium dioxide, modified kaolin powder, heavy calcium carbonate, calcium lime powder, medical stone powder, hydroxyethyl methyl are fine
It ties up element, pigment, nano TiO 2 modified chitosan anti-bacteria mould inhibitor and is packed into blender, 70r/min stirs 23min, makes its each mixing
Uniformly；Above-mentioned parts by weight distilled water and modified acrylate emulsion is added, 25r/min stirs 3h, 600 mesh screens are crossed, both
The modified silicon soil property lake mud building materials for inner wall decoration.
Embodiment 4
For the modified silicon soil property lake mud building materials of inner wall decoration, the component including following parts by weight: 50 parts of distilled water changes
Property 20 parts of tripoli matter lake mud powder, 10 parts of conch meal of activation, 5 parts of modified mineral water-holding thickening agent, 8 parts of dichloride in anatase type titanium dioxide,
3 parts of modified kaolin powder, 3 parts of heavy calcium carbonate, 1 part of calcium lime powder, 2 parts of modified acrylate emulsion, 1 part of medical stone powder,
2 parts of hydroxyethylmethylcellulose, 0.5 part of pigment, 1.5 parts of nano TiO 2 modified chitosan anti-bacteria mould inhibitor.
The preparation method of modified silicon soil property lake mud building materials for inner wall decoration, comprising the following steps: by tripoli matter lake mud
It is fitted into blender, 4.5 parts by weight PAS inorganic flocculating agents is added, 130r/min stirs 50s, stands 45min, and supernatant is discharged
After be packed into rotary kiln, through 535 DEG C calcine 6.5 hours, after sintering crush and cross 200 mesh screens, obtain dring silicon soil property lake mud powder；
Dring silicon soil property lake mud powder, HK-560 silane coupling agent, PEG-8 dimeticone water solubility siloxanes and injection active carbon powder are pressed
Weight ratio 100:0.9:1.6:0.95 is packed into rotary kiln, and 600 DEG C of heat preservation 1.5h carry out revolution heat modification, modified needed for being made
Tripoli matter lake mud powder；Kaolin is packed into rotary kiln, is calcined 3.5 hours through 250 DEG C, 200 mesh screens are crushed and crossed after sintering, are obtained
To modified kaolin powder；Modified silicon soil property lake mud powder, activation conch meal, modified mineral water conservation are thickened by above-mentioned parts by weight
Agent, dichloride in anatase type titanium dioxide, modified kaolin powder, heavy calcium carbonate, calcium lime powder, medical stone powder, hydroxyethyl methyl are fine
It ties up element, pigment, nano TiO 2 modified chitosan anti-bacteria mould inhibitor and is packed into blender, 60r/min stirs 27min, makes its each mixing
Uniformly；Above-mentioned parts by weight distilled water and modified acrylate emulsion is added, 20r/min stirs 5h, 200 mesh screens are crossed, both
The modified silicon soil property lake mud building materials for inner wall decoration.
Embodiment 5
Modified silicon soil property lake mud building materials for inner wall decoration, it is characterised in that: the component including following parts by weight: it steams
45 parts of distilled water, 21 parts of modified silicon soil property lake mud powder, activation 7 parts of conch meal, 6 parts of modified mineral water-holding thickening agent, dichloride in anatase type
5 parts of titanium dioxide, 5 parts of modified kaolin powder, 2 parts of heavy calcium carbonate, 2 parts of calcium lime powder, 1.8 parts of modified acrylate emulsion,
1.5 parts of medical stone powder, 1.7 parts of hydroxyethylmethylcellulose, 0.8 part of pigment, nano TiO 2 modified chitosan anti-bacteria mould inhibitor 1.2
Part.
The preparation method of modified silicon soil property lake mud building materials for inner wall decoration, comprising the following steps: by tripoli matter lake mud
It is fitted into blender, 4 parts by weight PAS inorganic flocculating agents is added, 150r/min stirs 45s, 50min is stood, after supernatant is discharged
It is packed into rotary kiln, is calcined 7 hours through 525 DEG C, 400 mesh screens are crushed and crossed after sintering, obtain dring silicon soil property lake mud powder；It will do
Dry tripoli matter lake mud powder, HK-560 silane coupling agent, PEG-8 dimeticone water solubility siloxanes and injection active carbon powder are by weight
It is packed into rotary kiln than 100:0.85:1.8:0.9,550 DEG C of heat preservation 2h carry out revolution heat modification, modified silicon soil property needed for being made
Lake mud powder；Kaolin is packed into rotary kiln, is calcined 3 hours through 300 DEG C, 400 mesh screens are crushed and crossed after sintering, obtains modified height
Ridge soil powder；By above-mentioned parts by weight by modified silicon soil property lake mud powder, activation conch meal, modified mineral water-holding thickening agent, anatase titanium dioxide
Nanometer titanium dioxide, modified kaolin powder, heavy calcium carbonate, calcium lime powder, medical stone powder, hydroxyethylmethylcellulose, pigment,
Nano TiO 2 modified chitosan anti-bacteria mould inhibitor is packed into blender, and 65r/min stirs 25min, is uniformly mixed each its；In addition
Parts by weight distilled water and modified acrylate emulsion are stated, 20r/min stirs 4h, crosses 400 mesh screens, both obtains described for interior wall
The modified silicon soil property lake mud building materials of decoration.
The modified silicon soil property lake mud building materials of inner wall decoration will be used for made of above-mentioned 5 kinds of embodiments separately below, are removed
The comparative test of aldehyde and purification and cracking and picking, is tested as follows:
One, absorption and decomposing formaldehyde comparative test:
Buying certain preferable brand of two sales volume from the large-scale building materials market in Nanning has the diatom ooze for removing aldehyde ordor removing function
Building materials, respectively as the control group 1,2 of this comparative test.Embodiment group is corresponding to be used for using made from above-described embodiment 1-5
The modified silicon soil property lake mud building materials of inner wall decoration.7 pieces of 45 × 45cm glass plates are taken, by respective construction technology respectively by above-mentioned 7 kinds
Building materials are applied on two faces of plasterboard, dry rear for 24 hours spare under identical environment.By 7 same model methylene oxide detecting instruments with
Machine is put into closed glass container of 7 50 × 50 × 50cm with lid and air inlet, is respectively put into the glass plate of adhering coating
And seal, it is passed through formaldehyde gas, methylene oxide detecting instrument display density is made to reach preset value 1.0mg/m3, and it is in identical natural lighting
Under, each period formaldehyde numerical value is counted, repetition daily is passed through formaldehyde and reaches preset value, after record 20d is passed through formaldehyde gas for 24 hours
Final numerical value, as a result as shown in table 1 below.
1 present invention of table is for the absorption of the modified silicon soil property lake mud building materials and control group of inner wall decoration and the examination of decomposing formaldehyde
Test data (unit mg/m3)
It was found from the data of table 1: the gap of each stage and embodiment group is not in for 24 hours for control group 1 and control group 2
Greatly, it was demonstrated that all there is good absorption using two groups of control groups of diatom ooze and five groups of embodiment group PARA FORMALDEHYDE PRILLS(91,95)s of building materials of the present invention
Effect；It is respectively 0.267 mg/m after accumulative test 20d3With 0.282 mg/m3, and the data of five groups of embodiment groups are respectively
0.071 mg/m3、0.068 mg/m3、0.067 mg/m3、0.065 mg/m3、0.061 mg/m3, below control group, Er Qiewu
The average value of group example group is only 0.066mg/m3, it is far below two groups of control groups, it was demonstrated that the present invention is used for the modified silicon of inner wall decoration
Soil property lake mud building materials are better than the decomposition of formaldehyde, detergent power the control group using diatom ooze.
Two, cracking and picking comparative test:
7 pieces of 50 × 50cm drying plaster boards are taken, every piece of weight is recorded, by respective construction technology respectively by above-mentioned 7 kinds of building materials
It is applied on a face of plasterboard, it is dry rear for 24 hours spare under identical environment.The plasterboard of 7 pieces of adhering coatings is placed in 60 DEG C
15d in vacuum drying box, cooled to room temperature after taking-up weigh the cated plasterboard weight of attachment, subtract former plasterboard
Weight both obtains coating weight.Coating surface cracking length is recorded, and is made in parallel with 10kg pressure in coating surface with bulb wooden stick
5 30cm long scratches are made, the weight for the building materials that fall off is collected and weigh, the weight ratio shared by building materials that falls off is calculated, it is as a result as follows
Shown in table 2.
2 present invention of table is for the modified silicon soil property lake mud building materials of inner wall decoration and the cracking of control group and picking test number
According to
It was found from the data of table 2: using the control group 1 and control group 2 of diatom ooze building materials, the length that cracks is respectively
8.5cm, 6.9cm, the accounting that falls off are respectively 7.46%, 5.83%, and the cracking length of five groups of embodiment groups and the accounting that falls off is flat
Mean value is respectively 0.06cm, 0.03%, and control group is with embodiment group numerical difference away from larger, it was demonstrated that the present invention is for inner wall decoration
Modified silicon soil property lake mud building materials compare diatom ooze, the performance with better crack resistence, anti-picking.
Claims (4)
1. being used for the modified silicon soil property lake mud building materials of inner wall decoration, it is characterised in that: the component including following parts by weight: distillation
30-60 parts of water, 10-35 parts of modified silicon soil property lake mud powder, activation conch meal 1-15 parts, 2-10 parts of modified mineral water-holding thickening agent,
1-12 parts of dichloride in anatase type titanium dioxide, 1-12 parts of modified kaolin powder, 0.1-5 parts of heavy calcium carbonate, calcium lime powder 0.1-5
Part, 0.1-5 parts of modified acrylate emulsion, 0.1-4 parts of medical stone powder, 0.5-5 parts of hydroxyethylmethylcellulose, pigment 0.1-3
Part, nano-TiO20.5-3 parts of modified chitosan anti-bacteria mould inhibitor；
The preparation method of the modified silicon soil property lake mud building materials for inner wall decoration, comprising the following steps: by tripoli matter lake mud
It being fitted into blender, 3-5 parts by weight PAS inorganic flocculating agent is added, 100- 200r/min stirs 30-60s, 40-60min is stood,
Discharge supernatant after be packed into rotary kiln, through 500-550 DEG C calcining 6-8 hour, after sintering crushing and mistake 100-800 mesh screen, obtain
To dring silicon soil property lake mud powder；By dring silicon soil property lake mud powder, HK-560 silane coupling agent, PEG-8 dimeticone water-soluble silicon
Oxygen alkane and injection active carbon powder are by weight 100:(0.7-1): (1.5- 2): (0.8-1) is packed into rotary kiln, 450-650 DEG C of guarantor
Warm 1-3h carries out revolution heat modification, modified silicon soil property lake mud powder needed for being made；Kaolin is packed into rotary kiln, through 200-
400 DEG C calcining 2-4 hours, after sintering crush and cross 100-800 mesh screen, obtain modified kaolin powder；By above-mentioned parts by weight
By modified silicon soil property lake mud powder, activation conch meal, modified mineral water-holding thickening agent, dichloride in anatase type titanium dioxide, modified kaolin
Powder, heavy calcium carbonate, calcium lime powder, medical stone powder, hydroxyethylmethylcellulose, pigment, nano-TiO2Modification of chitosan is anti-
Bacterium mould inhibitor is packed into blender, and 50-80r/min stirs 20-30min, is uniformly mixed it；Above-mentioned parts by weight distilled water is added
And modified acrylate emulsion, 15-30r/min stir 3-5h, crosses 800 mesh screen of 50- to get described for inner wall decoration
Modified silicon soil property lake mud building materials.
2. being used for the modified silicon soil property lake mud building materials of inner wall decoration according to claim 1, it is characterised in that: including following heavy
Measure the component of number: 35-50 parts of distilled water, 20-23 parts of modified silicon soil property lake mud powder, activation conch meal 4-10 parts, modified mineral
5-8 parts of water-holding thickening agent, 3-8 parts of dichloride in anatase type titanium dioxide, 3-8 parts of modified kaolin powder, 1-3 parts of heavy calcium carbonate, life
1-3 parts of pulverized limestone, 1.5-2 parts of modified acrylate emulsion, 1-2 parts of medical stone powder, 1-2 parts of hydroxyethylmethylcellulose, pigment
0.5-1 parts, nano-TiO21-1.5 parts of modified chitosan anti-bacteria mould inhibitor.
3. being used for the modified silicon soil property lake mud building materials of inner wall decoration according to claim 1, it is characterised in that: including following heavy
Measure the component of number: 45 parts of distilled water, 21 parts of modified silicon soil property lake mud powder, activation 7 parts of conch meal, modified mineral water-holding thickening agent
6 parts, 5 parts of dichloride in anatase type titanium dioxide, 5 parts of modified kaolin powder, 2 parts of heavy calcium carbonate, 2 parts of calcium lime powder, modified propylene
1.8 parts of acid esters lotion, 1.5 parts of medical stone powder, 1.7 parts of hydroxyethylmethylcellulose, 0.8 part of pigment, nano-TiO2Modified shell is poly-
1.2 parts of sugared antibacterial mildew inhibitor.
4. the according to claim 1 or 2 or 3 modified silicon soil property lake mud building materials for being used for inner wall decoration, it is characterised in that: described
Modified silicon soil property lake mud powder, activation conch meal, dichloride in anatase type titanium dioxide, modified kaolin powder, heavy calcium carbonate, quick lime
Powder and medical stone powder are 100-800 mesh granularity.
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| CN109206954A (en) * | 2018-04-23 | 2019-01-15 | 泉州市德丽佳环保制品有限公司 | A kind of shell magma and preparation method thereof that can remove formaldehyde |
| CN116730691A (en) * | 2023-05-25 | 2023-09-12 | 东莞市欧丽亚环保材料有限公司 | Ceramic tile adhesive and preparation method thereof |
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| CN103880350A (en) * | 2014-02-14 | 2014-06-25 | 华北有色工程勘察院有限公司 | Lake mud grout mix for mine water shutoff curtain and preparation method thereof |
| CN104291740A (en) * | 2013-07-20 | 2015-01-21 | 吕孟龙 | Waterproof alkali activated inorganic polymer coating |
| CN104387104A (en) * | 2014-10-20 | 2015-03-04 | 中建三局第二建设工程有限责任公司 | Method for preparing novel energy-saving sintering wall material by utilizing lake silt |
| CN105837170A (en) * | 2016-03-21 | 2016-08-10 | 东南大学 | Revetment sintered brick with lacustrine silt and shale as raw materials and preparing method thereof |
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|---|---|---|---|---|
| CN104291740A (en) * | 2013-07-20 | 2015-01-21 | 吕孟龙 | Waterproof alkali activated inorganic polymer coating |
| CN103880350A (en) * | 2014-02-14 | 2014-06-25 | 华北有色工程勘察院有限公司 | Lake mud grout mix for mine water shutoff curtain and preparation method thereof |
| CN104387104A (en) * | 2014-10-20 | 2015-03-04 | 中建三局第二建设工程有限责任公司 | Method for preparing novel energy-saving sintering wall material by utilizing lake silt |
| CN105837170A (en) * | 2016-03-21 | 2016-08-10 | 东南大学 | Revetment sintered brick with lacustrine silt and shale as raw materials and preparing method thereof |
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