CN102603183B - 无碱玻璃及其制造方法 - Google Patents
无碱玻璃及其制造方法 Download PDFInfo
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- CN102603183B CN102603183B CN201210034654.7A CN201210034654A CN102603183B CN 102603183 B CN102603183 B CN 102603183B CN 201210034654 A CN201210034654 A CN 201210034654A CN 102603183 B CN102603183 B CN 102603183B
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- Prior art keywords
- glass
- mol
- alkali
- equal
- mgo
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- 239000011521 glass Substances 0.000 title claims abstract description 238
- 238000000034 method Methods 0.000 title claims description 30
- 238000004519 manufacturing process Methods 0.000 title abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 58
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 36
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 32
- 229910052593 corundum Inorganic materials 0.000 claims description 31
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 31
- 229910052906 cristobalite Inorganic materials 0.000 claims description 29
- 239000000377 silicon dioxide Substances 0.000 claims description 27
- 229910052681 coesite Inorganic materials 0.000 claims description 19
- 229910052682 stishovite Inorganic materials 0.000 claims description 19
- 229910052905 tridymite Inorganic materials 0.000 claims description 19
- 238000003280 down draw process Methods 0.000 claims description 16
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 12
- 229910052785 arsenic Inorganic materials 0.000 claims description 11
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- 238000007499 fusion processing Methods 0.000 claims description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract description 65
- 229910004298 SiO 2 Inorganic materials 0.000 abstract description 26
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 82
- 238000002844 melting Methods 0.000 description 53
- 230000008018 melting Effects 0.000 description 53
- 239000000395 magnesium oxide Substances 0.000 description 41
- 239000000203 mixture Substances 0.000 description 34
- 239000000758 substrate Substances 0.000 description 23
- 239000004973 liquid crystal related substance Substances 0.000 description 19
- 235000012239 silicon dioxide Nutrition 0.000 description 19
- 150000001768 cations Chemical class 0.000 description 14
- 150000002500 ions Chemical class 0.000 description 14
- 239000007789 gas Substances 0.000 description 13
- 230000007423 decrease Effects 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 230000005496 eutectics Effects 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 238000007670 refining Methods 0.000 description 12
- 239000012071 phase Substances 0.000 description 11
- 239000011575 calcium Substances 0.000 description 10
- 239000013078 crystal Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- -1 B 2 O 3 Inorganic materials 0.000 description 9
- 229910006404 SnO 2 Inorganic materials 0.000 description 8
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000010587 phase diagram Methods 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 230000007547 defect Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 6
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 229910052863 mullite Inorganic materials 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 229910052661 anorthite Inorganic materials 0.000 description 5
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 5
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 description 5
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 5
- 230000005684 electric field Effects 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 5
- 230000002411 adverse Effects 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000005352 clarification Methods 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 239000006025 fining agent Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 229910001887 tin oxide Inorganic materials 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 238000004776 molecular orbital Methods 0.000 description 3
- 239000006060 molten glass Substances 0.000 description 3
- 238000007500 overflow downdraw method Methods 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 229910052712 strontium Inorganic materials 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- 229910052882 wollastonite Inorganic materials 0.000 description 3
- 239000010456 wollastonite Substances 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 235000012215 calcium aluminium silicate Nutrition 0.000 description 2
- 239000000404 calcium aluminium silicate Substances 0.000 description 2
- WNCYAPRTYDMSFP-UHFFFAOYSA-N calcium aluminosilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O WNCYAPRTYDMSFP-UHFFFAOYSA-N 0.000 description 2
- 229940078583 calcium aluminosilicate Drugs 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 210000002858 crystal cell Anatomy 0.000 description 2
- 229910002026 crystalline silica Inorganic materials 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000001312 dry etching Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 238000007088 Archimedes method Methods 0.000 description 1
- 101001062093 Homo sapiens RNA-binding protein 15 Proteins 0.000 description 1
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- 102100029244 RNA-binding protein 15 Human genes 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- 238000001237 Raman spectrum Methods 0.000 description 1
- 229910002800 Si–O–Al Inorganic materials 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 description 1
- 239000005407 aluminoborosilicate glass Substances 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 238000004630 atomic force microscopy Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000009125 cardiac resynchronization therapy Methods 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009795 derivation Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000006066 glass batch Substances 0.000 description 1
- 238000005816 glass manufacturing process Methods 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Inorganic materials [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052645 tectosilicate Inorganic materials 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/06—Forming glass sheets
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/06—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in pot furnaces
- C03B5/08—Glass-melting pots
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/004—Refining agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69447805P | 2005-06-28 | 2005-06-28 | |
| US60/694,478 | 2005-06-28 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800228806A Division CN101208276B (zh) | 2005-06-28 | 2006-06-28 | 硼硅铝酸盐玻璃的澄清 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102603183A CN102603183A (zh) | 2012-07-25 |
| CN102603183B true CN102603183B (zh) | 2015-04-15 |
Family
ID=36942503
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210034654.7A Active CN102603183B (zh) | 2005-06-28 | 2006-06-28 | 无碱玻璃及其制造方法 |
| CN2006800228806A Active CN101208276B (zh) | 2005-06-28 | 2006-06-28 | 硼硅铝酸盐玻璃的澄清 |
| CN201210034659.XA Active CN102603184B (zh) | 2005-06-28 | 2006-06-28 | 下拉法制造无碱玻璃板的方法 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800228806A Active CN101208276B (zh) | 2005-06-28 | 2006-06-28 | 硼硅铝酸盐玻璃的澄清 |
| CN201210034659.XA Active CN102603184B (zh) | 2005-06-28 | 2006-06-28 | 下拉法制造无碱玻璃板的方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US7851394B2 (enExample) |
| EP (2) | EP3296274B1 (enExample) |
| JP (1) | JP5142996B2 (enExample) |
| KR (1) | KR101346446B1 (enExample) |
| CN (3) | CN102603183B (enExample) |
| TW (1) | TWI387571B (enExample) |
| WO (1) | WO2007002865A1 (enExample) |
Families Citing this family (83)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7260960B2 (en) * | 2003-02-27 | 2007-08-28 | Carty William M | Selective glass batching methods for improving melting efficiency and reducing gross segregation of glass batch components |
| EP1705160A4 (en) * | 2003-12-26 | 2009-05-06 | Asahi Glass Co Ltd | ALKALIFREY GLASS, MANUFACTURING METHOD AND LIQUID CRYSTAL DISPLAY PANEL |
| EP3296274B1 (en) * | 2005-06-28 | 2023-04-26 | Corning Incorporated | Fining of boroalumino silicate glasses |
| KR101399745B1 (ko) | 2006-02-10 | 2014-05-26 | 코닝 인코포레이티드 | 고온 및 화학적 안정성을 갖는 유리 조성물 및 그 제조방법 |
| JP5703535B2 (ja) * | 2006-05-23 | 2015-04-22 | 日本電気硝子株式会社 | 無アルカリガラス基板 |
| JP2013173670A (ja) * | 2006-05-23 | 2013-09-05 | Nippon Electric Glass Co Ltd | 無アルカリガラスおよび無アルカリガラス基板 |
| US7534734B2 (en) * | 2006-11-13 | 2009-05-19 | Corning Incorporated | Alkali-free glasses containing iron and tin as fining agents |
| US9434642B2 (en) | 2007-05-21 | 2016-09-06 | Corning Incorporated | Mechanically flexible and durable substrates |
| JP5435394B2 (ja) * | 2007-06-08 | 2014-03-05 | 日本電気硝子株式会社 | 強化ガラス基板及びその製造方法 |
| US7709406B2 (en) * | 2007-07-31 | 2010-05-04 | Corning Incorporation | Glass compositions compatible with downdraw processing and methods of making and using thereof |
| US8196434B2 (en) | 2007-08-08 | 2012-06-12 | Corning Incorporated | Molten glass delivery apparatus for optical quality glass |
| CN105776849B (zh) | 2007-11-29 | 2020-04-14 | 康宁股份有限公司 | 具有改进的韧性和抗刮性的玻璃 |
| DE102008005857A1 (de) | 2008-01-17 | 2009-07-23 | Schott Ag | Alkalifreies Glas |
| JP5583606B2 (ja) | 2008-02-26 | 2014-09-03 | コーニング インコーポレイテッド | ケイ酸塩ガラス用の清澄剤 |
| WO2009117735A1 (en) * | 2008-03-21 | 2009-09-24 | California Institute Of Technology | Forming of metallic glass by rapid capacitor discharge |
| US8613814B2 (en) | 2008-03-21 | 2013-12-24 | California Institute Of Technology | Forming of metallic glass by rapid capacitor discharge forging |
| US8613816B2 (en) | 2008-03-21 | 2013-12-24 | California Institute Of Technology | Forming of ferromagnetic metallic glass by rapid capacitor discharge |
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Also Published As
| Publication number | Publication date |
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| TW200821273A (en) | 2008-05-16 |
| EP3296274B1 (en) | 2023-04-26 |
| KR101346446B1 (ko) | 2014-01-15 |
| CN102603183A (zh) | 2012-07-25 |
| CN101208276A (zh) | 2008-06-25 |
| US8640498B2 (en) | 2014-02-04 |
| CN102603184B (zh) | 2015-04-15 |
| CN102603184A (zh) | 2012-07-25 |
| US7851394B2 (en) | 2010-12-14 |
| US20110082022A1 (en) | 2011-04-07 |
| KR20080023356A (ko) | 2008-03-13 |
| EP3296274A2 (en) | 2018-03-21 |
| EP3296274A3 (en) | 2018-06-13 |
| CN101208276B (zh) | 2012-04-25 |
| WO2007002865A1 (en) | 2007-01-04 |
| US8642491B2 (en) | 2014-02-04 |
| JP2008544942A (ja) | 2008-12-11 |
| US20110079049A1 (en) | 2011-04-07 |
| US20060293162A1 (en) | 2006-12-28 |
| EP1899275A1 (en) | 2008-03-19 |
| TWI387571B (zh) | 2013-03-01 |
| JP5142996B2 (ja) | 2013-02-13 |
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