CN102597019A - 使用负载的后过渡金属催化剂体系制备的聚乙烯 - Google Patents
使用负载的后过渡金属催化剂体系制备的聚乙烯 Download PDFInfo
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- CN102597019A CN102597019A CN2010800490091A CN201080049009A CN102597019A CN 102597019 A CN102597019 A CN 102597019A CN 2010800490091 A CN2010800490091 A CN 2010800490091A CN 201080049009 A CN201080049009 A CN 201080049009A CN 102597019 A CN102597019 A CN 102597019A
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- 239000003054 catalyst Substances 0.000 title claims abstract description 26
- 229910052723 transition metal Inorganic materials 0.000 title claims abstract description 7
- 150000003624 transition metals Chemical class 0.000 title claims abstract description 7
- 239000004698 Polyethylene Substances 0.000 title claims description 12
- -1 Polyethylene Polymers 0.000 title claims description 10
- 229920000573 polyethylene Polymers 0.000 title claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 230000004913 activation Effects 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 238000001542 size-exclusion chromatography Methods 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 239000002516 radical scavenger Substances 0.000 claims description 8
- 229960001866 silicon dioxide Drugs 0.000 claims description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000003446 ligand Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 5
- 239000005977 Ethylene Substances 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229910001848 post-transition metal Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical group C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229910021585 Nickel(II) bromide Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- VPCAAUUIFCAFRZ-UHFFFAOYSA-N butylalumane Chemical compound CCCC[AlH2] VPCAAUUIFCAFRZ-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 238000010516 chain-walking reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
- 229910000071 diazene Inorganic materials 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001595 flow curve Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012821 model calculation Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- IPLJNQFXJUCRNH-UHFFFAOYSA-L nickel(2+);dibromide Chemical compound [Ni+2].[Br-].[Br-] IPLJNQFXJUCRNH-UHFFFAOYSA-L 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000003534 oscillatory effect Effects 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000000974 shear rheometry Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09174498.7 | 2009-10-29 | ||
| EP09174498A EP2316864A1 (en) | 2009-10-29 | 2009-10-29 | Polyethylene prepared with supported late transition metal catalyst system. |
| PCT/EP2010/066320 WO2011051371A1 (en) | 2009-10-29 | 2010-10-28 | Polyethylene prepared with supported late transition metal catalyst systems |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102597019A true CN102597019A (zh) | 2012-07-18 |
Family
ID=41818604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010800490091A Pending CN102597019A (zh) | 2009-10-29 | 2010-10-28 | 使用负载的后过渡金属催化剂体系制备的聚乙烯 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US8822612B2 (enExample) |
| EP (2) | EP2316864A1 (enExample) |
| KR (1) | KR101472643B1 (enExample) |
| CN (1) | CN102597019A (enExample) |
| BR (1) | BR112012010048A2 (enExample) |
| DK (1) | DK2493938T3 (enExample) |
| EA (1) | EA201270593A1 (enExample) |
| ES (1) | ES2715080T3 (enExample) |
| IN (1) | IN2012DN01557A (enExample) |
| MX (1) | MX2012004950A (enExample) |
| WO (1) | WO2011051371A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107118288A (zh) * | 2017-05-25 | 2017-09-01 | 江苏奥克化学有限公司 | 一种负载型后过渡金属催化剂及其制备方法 |
| CN109153750A (zh) * | 2016-05-20 | 2019-01-04 | 切弗朗菲利浦化学公司 | 制备低密度聚乙烯的低压方法 |
| CN116063598A (zh) * | 2018-09-17 | 2023-05-05 | 切弗朗菲利浦化学公司 | 改性负载型铬催化剂和由其生产的基于乙烯的聚合物 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101958015B1 (ko) | 2016-11-08 | 2019-07-04 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020058768A1 (en) * | 1997-03-10 | 2002-05-16 | Mackenzie Peter Borden | Supported group 8-10 transition metal Olefin polymerization catalysts |
| CN1174003C (zh) * | 1998-10-14 | 2004-11-03 | 纳幕尔杜邦公司 | 烯烃聚合 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5700895A (en) * | 1993-08-23 | 1997-12-23 | Sumitomo Chemical Company, Limited | Ethylene-α-olefin copolymer and molded article thereof |
| CZ235197A3 (en) | 1995-01-24 | 1997-12-17 | Du Pont | Alpha olefins, olefin polymers and process for preparing thereof |
| US5880241A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
| JPH08306233A (ja) * | 1995-05-08 | 1996-11-22 | Fujikura Ltd | 電力ケーブル用絶縁体組成物 |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| US5865677A (en) | 1997-01-03 | 1999-02-02 | Tiger Electronics, Ltd. | Hand-held electronic game |
| CA2282415A1 (en) | 1997-02-25 | 1998-08-27 | Christopher Moore Killian | Polymers containing functionalized olefin monomers |
| US6103658A (en) * | 1997-03-10 | 2000-08-15 | Eastman Chemical Company | Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom |
| CA2210131C (en) * | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
| US6255414B1 (en) * | 1998-09-01 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| JP2000080125A (ja) * | 1998-09-08 | 2000-03-21 | Idemitsu Petrochem Co Ltd | エチレン単独重合体及びそれを成形してなる成形体 |
| US6531424B2 (en) * | 1999-12-17 | 2003-03-11 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| CN1246349C (zh) * | 2001-01-12 | 2006-03-22 | 阿托菲纳研究公司 | 茂金属薄膜树脂 |
| EP1674523A1 (en) * | 2004-12-22 | 2006-06-28 | Total Petrochemicals Research Feluy | Caps and closures |
| EP1856164A1 (en) | 2005-03-04 | 2007-11-21 | E.I. Dupont De Nemours And Company | Supported olefin polymerization catalysts |
| JP2007177183A (ja) * | 2005-12-28 | 2007-07-12 | Nippon Polyethylene Kk | 電線・ケーブル被覆用樹脂材料及びそれを用いた被覆電線・ケーブル |
| JP5414971B2 (ja) * | 2005-12-28 | 2014-02-12 | 日本ポリエチレン株式会社 | エチレン系樹脂組成物によるフィルム |
| EP1972642A1 (en) | 2007-03-19 | 2008-09-24 | Total Petrochemicals Research Feluy | Homo-or co-polymers of ethylene with combination of processability and toughness properties |
| WO2009069823A1 (ja) * | 2007-11-30 | 2009-06-04 | Sumitomo Chemical Company, Limited | エチレン－α－オレフィン共重合体および成形体 |
| JP2011099091A (ja) * | 2009-09-30 | 2011-05-19 | Sumitomo Chemical Co Ltd | エチレン系重合体の製造方法 |
-
2009
- 2009-10-29 EP EP09174498A patent/EP2316864A1/en not_active Withdrawn
-
2010
- 2010-10-28 WO PCT/EP2010/066320 patent/WO2011051371A1/en not_active Ceased
- 2010-10-28 MX MX2012004950A patent/MX2012004950A/es not_active Application Discontinuation
- 2010-10-28 ES ES10778604T patent/ES2715080T3/es active Active
- 2010-10-28 US US13/502,158 patent/US8822612B2/en not_active Expired - Fee Related
- 2010-10-28 DK DK10778604.8T patent/DK2493938T3/en active
- 2010-10-28 CN CN2010800490091A patent/CN102597019A/zh active Pending
- 2010-10-28 IN IN1557DEN2012 patent/IN2012DN01557A/en unknown
- 2010-10-28 KR KR1020127009942A patent/KR101472643B1/ko not_active Expired - Fee Related
- 2010-10-28 BR BR112012010048A patent/BR112012010048A2/pt not_active IP Right Cessation
- 2010-10-28 EP EP10778604.8A patent/EP2493938B1/en not_active Not-in-force
- 2010-10-28 EA EA201270593A patent/EA201270593A1/ru unknown
-
2014
- 2014-07-07 US US14/324,402 patent/US9181366B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020058768A1 (en) * | 1997-03-10 | 2002-05-16 | Mackenzie Peter Borden | Supported group 8-10 transition metal Olefin polymerization catalysts |
| CN1174003C (zh) * | 1998-10-14 | 2004-11-03 | 纳幕尔杜邦公司 | 烯烃聚合 |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109153750A (zh) * | 2016-05-20 | 2019-01-04 | 切弗朗菲利浦化学公司 | 制备低密度聚乙烯的低压方法 |
| CN109153750B (zh) * | 2016-05-20 | 2022-04-26 | 切弗朗菲利浦化学公司 | 制备低密度聚乙烯的低压方法 |
| CN107118288A (zh) * | 2017-05-25 | 2017-09-01 | 江苏奥克化学有限公司 | 一种负载型后过渡金属催化剂及其制备方法 |
| CN107118288B (zh) * | 2017-05-25 | 2019-10-18 | 江苏奥克化学有限公司 | 一种负载型后过渡金属催化剂及其制备方法 |
| CN116063598A (zh) * | 2018-09-17 | 2023-05-05 | 切弗朗菲利浦化学公司 | 改性负载型铬催化剂和由其生产的基于乙烯的聚合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| IN2012DN01557A (enExample) | 2015-06-05 |
| ES2715080T3 (es) | 2019-05-31 |
| EP2316864A1 (en) | 2011-05-04 |
| WO2011051371A1 (en) | 2011-05-05 |
| MX2012004950A (es) | 2012-06-12 |
| EA201270593A1 (ru) | 2012-09-28 |
| KR20120068925A (ko) | 2012-06-27 |
| US20140323675A1 (en) | 2014-10-30 |
| US8822612B2 (en) | 2014-09-02 |
| BR112012010048A2 (pt) | 2016-05-24 |
| KR101472643B1 (ko) | 2014-12-15 |
| US9181366B2 (en) | 2015-11-10 |
| US20120277388A1 (en) | 2012-11-01 |
| EP2493938A1 (en) | 2012-09-05 |
| EP2493938B1 (en) | 2018-12-12 |
| DK2493938T3 (en) | 2019-04-01 |
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