CN102585363A - 一种改性聚丙烯复合材料及其制备方法 - Google Patents
一种改性聚丙烯复合材料及其制备方法 Download PDFInfo
- Publication number
- CN102585363A CN102585363A CN201210018724XA CN201210018724A CN102585363A CN 102585363 A CN102585363 A CN 102585363A CN 201210018724X A CN201210018724X A CN 201210018724XA CN 201210018724 A CN201210018724 A CN 201210018724A CN 102585363 A CN102585363 A CN 102585363A
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- CN
- China
- Prior art keywords
- dioxide
- silicon
- polypropylene
- grafts
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000004743 Polypropylene Substances 0.000 title claims abstract description 31
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 29
- -1 polypropylene Polymers 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 title abstract description 23
- 150000001875 compounds Chemical class 0.000 title abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 23
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 36
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 36
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 24
- 229960001866 silicon dioxide Drugs 0.000 claims description 22
- 235000012239 silicon dioxide Nutrition 0.000 claims description 22
- 238000001035 drying Methods 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 14
- 239000000047 product Substances 0.000 claims description 14
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 10
- 238000010907 mechanical stirring Methods 0.000 claims description 10
- 238000010992 reflux Methods 0.000 claims description 10
- 238000000967 suction filtration Methods 0.000 claims description 10
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 5
- 229920006124 polyolefin elastomer Polymers 0.000 abstract 3
- 238000005452 bending Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 17
- 239000011159 matrix material Substances 0.000 description 11
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 10
- 239000004926 polymethyl methacrylate Substances 0.000 description 10
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 8
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 8
- 238000003825 pressing Methods 0.000 description 8
- 239000000376 reactant Substances 0.000 description 8
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000035939 shock Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Images
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- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210018724.XA CN102585363B (zh) | 2012-01-20 | 2012-01-20 | 一种改性聚丙烯复合材料及其制备方法 |
Applications Claiming Priority (1)
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---|---|---|---|
CN201210018724.XA CN102585363B (zh) | 2012-01-20 | 2012-01-20 | 一种改性聚丙烯复合材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102585363A true CN102585363A (zh) | 2012-07-18 |
CN102585363B CN102585363B (zh) | 2014-02-12 |
Family
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Family Applications (1)
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CN201210018724.XA Expired - Fee Related CN102585363B (zh) | 2012-01-20 | 2012-01-20 | 一种改性聚丙烯复合材料及其制备方法 |
Country Status (1)
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CN (1) | CN102585363B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107365406A (zh) * | 2016-05-13 | 2017-11-21 | 中国石化扬子石油化工有限公司 | 一种改性聚丙烯材料及其制备方法 |
CN113999575A (zh) * | 2021-11-17 | 2022-02-01 | 重庆会通科技有限公司 | 一种再生聚丙烯喷涂材料及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102108160A (zh) * | 2009-12-28 | 2011-06-29 | 上海日之升新技术发展有限公司 | 汽车保险杠用聚丙烯/纳米二氧化硅复合材料及制备方法 |
-
2012
- 2012-01-20 CN CN201210018724.XA patent/CN102585363B/zh not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102108160A (zh) * | 2009-12-28 | 2011-06-29 | 上海日之升新技术发展有限公司 | 汽车保险杠用聚丙烯/纳米二氧化硅复合材料及制备方法 |
Non-Patent Citations (2)
Title |
---|
吴照勇等: "纳米SiO2/PEA复合粒子的制备和表征", 《高分子材料科学与工程》, vol. 24, no. 1, 31 January 2008 (2008-01-31) * |
王平华,严满清: "纳米SiO2粒子对PP结晶行为的影响", 《中国塑料》, vol. 17, no. 3, 31 March 2003 (2003-03-31), pages 21 - 24 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107365406A (zh) * | 2016-05-13 | 2017-11-21 | 中国石化扬子石油化工有限公司 | 一种改性聚丙烯材料及其制备方法 |
CN113999575A (zh) * | 2021-11-17 | 2022-02-01 | 重庆会通科技有限公司 | 一种再生聚丙烯喷涂材料及其制备方法 |
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Publication number | Publication date |
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CN102585363B (zh) | 2014-02-12 |
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Owner name: DALIAN JUXING TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: DALIAN POLYTECHNIC UNIVERSITY Effective date: 20150105 |
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Free format text: CORRECT: ADDRESS; FROM: 116034 DALIAN, LIAONING PROVINCE TO: 116102 DALIAN, LIAONING PROVINCE |
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Effective date of registration: 20150105 Address after: 116102 Liaoning, Dalian, Jinzhou District, the streets of the town of twenty Mile Street Industrial Zone, No. thirteen, No. 27 Patentee after: DALIAN POLYSHINE CO.,LTD. Address before: 116034 Ganjingzi Light Industry Zone, Liaoning, No. 1, No. Patentee before: Dalian Polytechnic University |
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Effective date of registration: 20170106 Address after: Ganjingzi District of Dalian City, Liaoning province 116039 xinzhaizi by industrial zone Patentee after: Dalian poly plastic materials Co.,Ltd. Address before: 116102 Liaoning, Dalian, Jinzhou District, the streets of the town of twenty Mile Street Industrial Zone, No. thirteen, No. 27 Patentee before: DALIAN POLYSHINE CO.,LTD. |
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TR01 | Transfer of patent right |
Effective date of registration: 20180509 Address after: 116102 27 Xingye street, thirteen Li Industrial Zone, Dalian bonded area, Liaoning Patentee after: DALIAN POLYSHINE CO.,LTD. Address before: 116039 Liaoning province Dalian Ganjingzi District Xin Zhai Zi by home industrial area Patentee before: Dalian poly plastic materials Co.,Ltd. |
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