CN102559406A - Compound type cleaning solution - Google Patents
Compound type cleaning solution Download PDFInfo
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- CN102559406A CN102559406A CN2011102248987A CN201110224898A CN102559406A CN 102559406 A CN102559406 A CN 102559406A CN 2011102248987 A CN2011102248987 A CN 2011102248987A CN 201110224898 A CN201110224898 A CN 201110224898A CN 102559406 A CN102559406 A CN 102559406A
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Abstract
The invention relates to a compound type cleaning solution which comprises a component A, a component B and pure water, wherein the component A is composed of at least one amphoteric surfactant with 8 or more carbon atoms, and accounts for 0.1-15% of the cleaning solution by mass; the component B is at least one anionic surfactant, non-ionic surfactant or cationic surfactant with 8 or more carbon atoms, and accounts for 1-30% of the cleaning solution by mass; and the balance is pure water. In the invention, the amphoteric surfactant and other surfactants are compounded to prepare a dish hand-washing detergent which has excellent functions of cleaning, efficacy enhancing, thickening, foaming, foam stabilizing and the like and is very favorable for improving the performance of the product such as detergency, viscosity, storage stability and the like. Moreover, the amphoteric surfactant is generally in a water-soluble liquid state and can be easily mixed in a formula solution, thus the industrialization of the product provided by the invention can be easily realized.
Description
Technical field:
The present invention is a kind of detergent for washing dishware with hand, and particularly a kind of Compositional type washings is the liquid cleaner that is used for artificial cleaning tableware, belongs to domestic chemical products and manufacturing field.
Background technology:
Detergent for washing dishware with hand is commonly called as liquid detergent, and using the liquid detergent cleaning tableware is the daily life custom, in family and restaurant, uses liquid detergent very general, and liquid detergent has become the maximum liquid washing agent of volume of production and marketing.The liquid detergent formula for a product is main with AS basically on the home market, is aided with nonionogenic tenside and carries out composite with other auxiliary agents.Wherein the most frequently used AS is sodium alkyl benzene sulfonate and polyoxyethylenated alcohol sodium sulfate etc., and AS is the main soil-removing action that rises in liquid detergent; Nonionogenic tenside is used coconut fatty acid diethanolamine (6501) or amine oxide etc. usually; Mainly play foam enhancing, surely effect such as bubble and thickening, the auxiliary agent that adds as required in the prescription has pH regulator agent, viscosity modifier (thickening material), sanitas, solubilizing agent, essence and pigment etc. usually.The liquid detergent product is generally understood the good sodium alkyl benzene sulfonate of optional price ratio as the major surfaces promoting agent.Sodium alkyl benzene sulfonate is cheap; Has good detersive power; But it also brings some problems, and for example: its Krafft's point (Krafft Piont, the i.e. Kraft point of tensio-active agent) is higher; Make that the freezing cloud point temperature of product is higher relatively, muddiness will occur when temperature drops to 10 ℃ of left and right sides products.And liquid detergent generally is the transparent type product, turbid phenomenon occurs and can cause that the human consumer produces query to quality product, has influence on the sale and the use of product.For reducing the freezing cloud point temperature of liquid detergent product, common way is to add solubilizing agent, like ethanol, urea or sodium xylene sulfonate etc.But solubilizing agent can reduce the viscosity of product, need increase viscosity modifier (thickening material) or amount of surfactant simultaneously and recover viscosity.And for this key property of product detersive power, solubilizing agent is helpless basically, even has the opposite effect.So in general, using solubilizing agent to solve product low temperature turbid phenomenon is not a kind of method of ideal optimization of C.
Summary of the invention:
A kind of Compositional type washings that the present invention invents in order to solve above-mentioned prior art problem just.
Technical scheme of the present invention is: a kind of Compositional type washings comprises A component, B component and pure water; Said A component is that carbonatoms constitutes at least a amphoterics more than 8 or 8, in washings, occupies mass percent 0.1%-15%, is preferably 0.5%-10%; Said B component is that carbonatoms is at least a AS, nonionogenic tenside or the positive example tensio-active agent more than 8 or 8, in washings, occupies mass percent 1%-30%, is preferably 5%-20%; All the other are pure water.
Said washings can also add auxiliary agent, and said auxiliary agent is pH regulator agent, viscosity modifier, sanitas, water-softening chemicals, SYNTHETIC OPTICAL WHITNER, abrasive, solubilizing agent, opalizer, essence or pigment etc.; In washings, occupy mass percent 0%-30%.
Said A component can be betaine type, imidazoline type or amino acid type amphoteric surface active agent and composite form between them.
Particularly; Said A component is alkyl dimethyl trimethyl-glycine, fat-based amido propyl betaine, fat-based amido propyl hydroxy sulfo lycine, alkyl-N; N-hydroxyl tetrahydroglyoxaline acetate, alkyl-N; N-hydroxyl sulfo group tetrahydroglyoxaline acetate, fat-based both sexes acetate and fat-based both sexes propionic salt etc., at least a.
Alkyl benzene sulphonate(ABS) that said B component is a straight or branched and verivates such as salt, AEO and vitriol thereof, phosphoric acid salt, sulphosuccinates and carboxylate salt, alkanol vitriol, secondary alkyl sulfonate, MES, α-Xi Jihuangsuanyan, alkylolamide, APG, sucrose ester, polyethers, amine oxide, soap, oleoyl amino acid salts, oleoyl alkyl tauride, oleyl amine Soxylat A 25-7, alkyl ammonium halide, alkyl Bian Ji ammonium halide, ester based quaternary ammonium salt and alkyl imidazoline quaternary ammonium salt etc., at least a.
Product of the present invention adopts following method production: the pure water of 95% formula ratio is added the batching still, start and stir, press the tensio-active agent adding batching still of formula ratio with B component indication; Be stirred to fully dissolving (but heating for dissolving) as required, press the tensio-active agent of formula ratio adding A component indication then, stir; Add various auxiliary agents by formula ratio; Add remaining pure water at last, stir and adjust each item physical and chemical index of feed liquid, after the assay was approved; Be pumped into material-storage jar and leave standstill froth breaking, wait to be filled.
The present invention prepares detergent for washing dishware with hand with amphoterics and other surfactant compounds, need not add solubilizing agent in addition, just can make product keep as clear as crystal state more than 0 ℃.Simultaneously, amphoterics can alleviate the skin irritation of ASs such as sodium alkyl benzene sulfonate to a great extent, makes product milder safety; Amphoterics also has functions such as good decontamination synergy, thickening, foaming, steady bubble, and is very favourable to the performances such as detersive power, viscosity and package stability that improve product.In addition, amphoterics generally is liquid water-soluble, is easy to be compounded in the formula solution, and therefore product of the present invention is easy to realize industrialization.
Table 1: following table is the accessible technical performance index of product of the present invention:
Experimental result shows, amphoterics and ionic or non-ionics be composite to have positive coopertive effect, can effectively reduce the Krafft's point or the cloud point of compound system.The present invention utilizes the synergy between tensio-active agent; With the composite preparation liquid detergent of ASs such as amphoterics and sodium alkyl benzene sulfonate; Can effectively reduce the freezing cloud point temperature of product, make product all keep as clear as crystal state more than 0 ℃.
Embodiment:
In order further to understand content of the present invention, core of the present invention is further set forth at present.
Embodiment 1:
Referring to table 2; A kind of Compositional type washings is made up of the X 2073 of mass ratio 9%, 4% MES, 2% AEO, 1% APG, 1.2% cocamidopropyl propyl group hydroxy sulfo lycine, 0.1% sanitas, 0.1% water-softening chemicals (sequestrant), 0.2～2.5% thickening material (NaCl), 0～1%pH regulator (Hydrocerol A or NaOH), 0～0.0001% pigment, 0.1% essence and pure water.
All components is added the batching still according to formula ratio, start and stir, be stirred to dissolving fully (but heating for dissolving) as required, adjust each item physical and chemical index of feed liquid, after the assay was approved, be pumped into material-storage jar and leave standstill froth breaking, wait to be filled.
Embodiment 2-6:
The same embodiment 1 of its course of processing, the proportioning of concrete component is asked for an interview table 2.
Table 2:
Claims (6)
1. a Compositional type washings is characterized in that described washings comprises A component, B component and pure water; Said A component is that carbonatoms constitutes at least a amphoterics more than 8 or 8, in washings, occupies mass percent 0.1%-15%; Said B component is that carbonatoms is at least a AS, nonionogenic tenside or the positive example tensio-active agent more than 8 or 8, in washings, occupies mass percent 1%-30%; All the other are pure water.
2. Compositional type washings according to claim 1; It is characterized in that said washings can also add auxiliary agent, said auxiliary agent is pH regulator agent, viscosity modifier, sanitas, water-softening chemicals, SYNTHETIC OPTICAL WHITNER, abrasive, solubilizing agent, opalizer, essence or pigment; In washings, occupy mass percent 0%-30%.
3. Compositional type washings according to claim 1 is characterized in that said A component is betaine type, imidazoline type or amino acid type amphoteric surface active agent and their composite form, accounts for the mass ratio 0.5%-10% of total mass.
4. Compositional type washings according to claim 3; It is characterized in that said A component is alkyl dimethyl trimethyl-glycine, fat-based amido propyl betaine, fat-based amido propyl hydroxy sulfo lycine, alkyl-N; N-hydroxyl tetrahydroglyoxaline acetate, alkyl-N, N-hydroxyl sulfo group tetrahydroglyoxaline acetate, fat-based both sexes acetate or fat-based both sexes propionic salt are at least a.
5. Compositional type washings according to claim 1; It is characterized in that alkyl benzene sulphonate(ABS) and verivate, alkanol vitriol, secondary alkyl sulfonate, MES, α-Xi Jihuangsuanyan, alkylolamide, APG, sucrose ester, polyethers, amine oxide, soap, oleoyl amino acid salts, oleoyl alkyl tauride, oleyl amine Soxylat A 25-7, alkyl ammonium halide, alkyl Bian Ji ammonium halide, ester based quaternary ammonium salt and alkyl imidazoline quaternary ammonium salts such as salt, AEO and vitriol thereof, phosphoric acid salt, sulphosuccinates and carboxylate salt that said B component is a straight or branched; At least a, account for total mass mass ratio 5%-20%.
6. the ME of a Compositional type washings according to claim 1 or claim 2 is characterized in that described technical process is: a, will fill a prescription in a certain amount of pure water add the batching still, start and stir; Press formula ratio the B component is added the batching still, be stirred to dissolving fully, press formula ratio then and add the A component; Stir, add various auxiliary agents, add remaining pure water at last by formula ratio; Stir and adjust each item physical and chemical index of feed liquid; After the assay was approved, be pumped into material-storage jar and leave standstill froth breaking, wait to be filled.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102248987A CN102559406A (en) | 2011-08-06 | 2011-08-06 | Compound type cleaning solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102248987A CN102559406A (en) | 2011-08-06 | 2011-08-06 | Compound type cleaning solution |
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| CN102559406A true CN102559406A (en) | 2012-07-11 |
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| CN2011102248987A Pending CN102559406A (en) | 2011-08-06 | 2011-08-06 | Compound type cleaning solution |
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Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102872753A (en) * | 2012-10-30 | 2013-01-16 | 大庆浩拓化工有限公司 | Surfactant composition and preparation method thereof |
| CN102978030A (en) * | 2012-12-04 | 2013-03-20 | 浙江源敏科技有限公司 | Multifunctional detergent and preparation method thereof |
| CN103142422A (en) * | 2013-03-24 | 2013-06-12 | 成都携恩科技有限公司 | Lotion for cleaning and nourishing skin surface |
| CN103396902A (en) * | 2013-08-19 | 2013-11-20 | 王凌 | Powder cleaning agent and preparation method thereof |
| CN103740491A (en) * | 2014-01-26 | 2014-04-23 | 广东景兴卫生用品有限公司 | Antibacterial laundry detergent and preparation process thereof |
| CN103897880A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Daily safe detergent |
| CN104178370A (en) * | 2014-08-29 | 2014-12-03 | 成都顺发消洗科技有限公司 | Bactericidal laundry detergent containing traditional Chinese medicine components and preparation method thereof |
| CN104293512A (en) * | 2014-09-12 | 2015-01-21 | 皖南医学院 | Multifunctional cleaning and sterilizing spray and preparation method thereof |
| CN104877802A (en) * | 2015-04-28 | 2015-09-02 | 威莱(广州)日用品有限公司 | Cleaning agent for silk-wool and/or down feather clothes and preparation method of cleaning agent |
| CN104893846A (en) * | 2014-03-07 | 2015-09-09 | 张�杰 | Public textile (linen) room-temperature neutral detergent and preparation method thereof |
| CN105452434A (en) * | 2013-07-19 | 2016-03-30 | 狮王株式会社 | Wipe-off-type liquid cleaning agent |
| CN105802757A (en) * | 2016-04-11 | 2016-07-27 | 广州立白企业集团有限公司 | Method for enabling detergent composition to have small-range viscosity change in wide temperature range and detergent composition |
| CN106635503A (en) * | 2016-12-16 | 2017-05-10 | 上海和黄白猫有限公司 | Surfactant with pH value buffering agent |
| CN106999618A (en) * | 2014-12-08 | 2017-08-01 | 金诺斯公司 | The compositions of additives and its method sterilized for pigment |
| CN107325898A (en) * | 2017-06-28 | 2017-11-07 | 太仓大唐化纤厂 | A kind of detergent for improving chemical fibre pliability |
| CN107502473A (en) * | 2017-07-27 | 2017-12-22 | 广州市浪奇实业股份有限公司 | A kind of liquid detergent |
| CN107523432A (en) * | 2016-06-17 | 2017-12-29 | 狮王株式会社 | Tableware washes agent composition by liquid |
| CN107922890A (en) * | 2015-08-10 | 2018-04-17 | 狮王株式会社 | Wash up washes agent by liquid |
| CN108264973A (en) * | 2016-12-30 | 2018-07-10 | 北京绿伞化学股份有限公司 | It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof |
| CN108395945A (en) * | 2018-04-11 | 2018-08-14 | 岳圳 | A kind of liquid detergent of complex function and preparation method thereof |
| CN108587813A (en) * | 2018-07-11 | 2018-09-28 | 佛山市陵谐环保科技有限公司 | A kind of fruits and vegetables detergent |
| CN110042013A (en) * | 2019-05-24 | 2019-07-23 | 卓聪（上海）环保科技发展有限公司 | Hydrophilic protection cleaning agents of membrane of hard surface and preparation method thereof |
| CN111718805A (en) * | 2020-06-17 | 2020-09-29 | 南风化工集团股份有限公司 | Tableware detergent with caraway extract as fishy smell removing component and preparation method thereof |
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| CN1214628A (en) * | 1996-01-29 | 1999-04-21 | 庄臣消费者有限公司 | Detergent compositions |
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| CN1214628A (en) * | 1996-01-29 | 1999-04-21 | 庄臣消费者有限公司 | Detergent compositions |
| CN1197633A (en) * | 1997-04-07 | 1998-11-04 | 莱雅公司 | Detergent cosmetic compositions and use thereof |
| CN1276713A (en) * | 1997-09-18 | 2000-12-13 | 科尔加特·帕尔莫利弗公司 | Stabilized hair care products |
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102872753A (en) * | 2012-10-30 | 2013-01-16 | 大庆浩拓化工有限公司 | Surfactant composition and preparation method thereof |
| CN102978030A (en) * | 2012-12-04 | 2013-03-20 | 浙江源敏科技有限公司 | Multifunctional detergent and preparation method thereof |
| CN103897880A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Daily safe detergent |
| CN103142422A (en) * | 2013-03-24 | 2013-06-12 | 成都携恩科技有限公司 | Lotion for cleaning and nourishing skin surface |
| CN105452434A (en) * | 2013-07-19 | 2016-03-30 | 狮王株式会社 | Wipe-off-type liquid cleaning agent |
| CN105452434B (en) * | 2013-07-19 | 2018-09-28 | 狮王株式会社 | Wiping washes agent by liquid |
| CN103396902A (en) * | 2013-08-19 | 2013-11-20 | 王凌 | Powder cleaning agent and preparation method thereof |
| CN103740491A (en) * | 2014-01-26 | 2014-04-23 | 广东景兴卫生用品有限公司 | Antibacterial laundry detergent and preparation process thereof |
| CN104893846A (en) * | 2014-03-07 | 2015-09-09 | 张�杰 | Public textile (linen) room-temperature neutral detergent and preparation method thereof |
| CN104893846B (en) * | 2014-03-07 | 2017-10-31 | 张�杰 | A kind of public textile（Cloth grass）Normal temperature neutral detergent and preparation method |
| CN104178370A (en) * | 2014-08-29 | 2014-12-03 | 成都顺发消洗科技有限公司 | Bactericidal laundry detergent containing traditional Chinese medicine components and preparation method thereof |
| CN104293512A (en) * | 2014-09-12 | 2015-01-21 | 皖南医学院 | Multifunctional cleaning and sterilizing spray and preparation method thereof |
| CN106999618A (en) * | 2014-12-08 | 2017-08-01 | 金诺斯公司 | The compositions of additives and its method sterilized for pigment |
| CN104877802A (en) * | 2015-04-28 | 2015-09-02 | 威莱(广州)日用品有限公司 | Cleaning agent for silk-wool and/or down feather clothes and preparation method of cleaning agent |
| CN107922890A (en) * | 2015-08-10 | 2018-04-17 | 狮王株式会社 | Wash up washes agent by liquid |
| CN107922890B (en) * | 2015-08-10 | 2021-01-26 | 狮王株式会社 | Liquid detergent for washing tableware |
| CN105802757A (en) * | 2016-04-11 | 2016-07-27 | 广州立白企业集团有限公司 | Method for enabling detergent composition to have small-range viscosity change in wide temperature range and detergent composition |
| CN107523432A (en) * | 2016-06-17 | 2017-12-29 | 狮王株式会社 | Tableware washes agent composition by liquid |
| CN106635503A (en) * | 2016-12-16 | 2017-05-10 | 上海和黄白猫有限公司 | Surfactant with pH value buffering agent |
| CN108264973A (en) * | 2016-12-30 | 2018-07-10 | 北京绿伞化学股份有限公司 | It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof |
| CN107325898A (en) * | 2017-06-28 | 2017-11-07 | 太仓大唐化纤厂 | A kind of detergent for improving chemical fibre pliability |
| CN107502473A (en) * | 2017-07-27 | 2017-12-22 | 广州市浪奇实业股份有限公司 | A kind of liquid detergent |
| CN108395945A (en) * | 2018-04-11 | 2018-08-14 | 岳圳 | A kind of liquid detergent of complex function and preparation method thereof |
| CN108587813A (en) * | 2018-07-11 | 2018-09-28 | 佛山市陵谐环保科技有限公司 | A kind of fruits and vegetables detergent |
| CN110042013A (en) * | 2019-05-24 | 2019-07-23 | 卓聪（上海）环保科技发展有限公司 | Hydrophilic protection cleaning agents of membrane of hard surface and preparation method thereof |
| CN111718805A (en) * | 2020-06-17 | 2020-09-29 | 南风化工集团股份有限公司 | Tableware detergent with caraway extract as fishy smell removing component and preparation method thereof |
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Effective date of registration: 20121106 Address after: Tianhe Road 510900 Guangdong city of Guangzhou province Tianhe District No. 228 building 26 floor Applicant after: Walch (Guangzhou) Daily Articles Co., Ltd. Address before: Tianhe Road 510900 Guangdong city of Guangzhou province Tianhe District No. 228 building 26 floor Applicant before: Walch (Guangzhou) Daily Articles Co., Ltd. Applicant before: Tianjin Mothers' First Choice Healthy Products Co., Ltd. |
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Application publication date: 20120711 |