CN108264973A - It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof - Google Patents
It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof Download PDFInfo
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- CN108264973A CN108264973A CN201611251743.1A CN201611251743A CN108264973A CN 108264973 A CN108264973 A CN 108264973A CN 201611251743 A CN201611251743 A CN 201611251743A CN 108264973 A CN108264973 A CN 108264973A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of using natural plant essential oils as detergent of preservative and preparation method thereof, the raw material for preparing the detergent includes anion surfactant, cationic surfactant, nonionic surfactant, amphoteric surfactant, inorganic salts, auxiliary agent, natural plant essential oils.Wherein, the essential oil includes the mixture of one or more of wormwood essential oil, tree peony peel essential oil, chamomile essential oil, tea tree ethereal oil, sandalwood essential oil, grapefruit essential oil, Luo Wensha leaf essential oils.In detergent of the present invention, natural plants essential oil is made with preservative and lasting agent, and according to《Microbial Challenge, which is tested, evaluates the anti-corrosion effect of cosmetics》The operating method of middle Microbial Challenge experiment has carried out preservative challenge testing, it was demonstrated that has very strong anti-corrosion effect.
Description
Technical field
It is more particularly to a kind of using natural plant essential oils as the detergent of preservative the invention belongs to detergent composition field
And preparation method thereof.
Background technology
It is healthy to own bodies now with the gradual promotion of people's educational level, the level of consumption, environmental protection consciousness
Enhancing, the requirement to product is also higher and higher, not only in the performance of product, more focuses on the safety of product, the feature of environmental protection.
This just promotes manufacturing enterprise, and safety, the feature of environmental protection of product are controlled on source.For daily use chemicals industry, make in the product
Raw material less, raw material it is more natural, then product is safer, more environmentally friendly.All products are all there are one shelf life, whole
To ensure the not raw bacterium of product in a shelf life, it is not corrupt, it is required for adding a certain amount of preservative, preservative meeting as you know
There is certain negative interaction to people, therefore, be badly in need of a kind of natural antiseptic agent at present.
Invention content
In view of the above problems, it is of the invention provide it is a kind of using natural plant essential oils as the detergent of preservative and
Preparation method.In detergent of the present invention, natural plants essential oil is made with preservative and lasting agent, it is used this
A little plants essential oils have antibacterial bacteriostatic, improve immunity, is nonirritant, care family health.
The purpose of the present invention is what is be achieved through the following technical solutions：
A kind of application of natural plant essential oils, the natural plant essential oils are as aseptic applications in cleaning product；The day
Right plants essential oil includes wormwood essential oil, tree peony peel essential oil, chamomile essential oil, tea tree ethereal oil, sandalwood essential oil, grapefruit essential oil, sieve
The mixture of one or more of literary Sha's leaf essential oil.
It is a kind of using natural plant essential oils as the detergent of preservative, prepare the detergent raw material include anionic surface
Activating agent, nonionic surfactant, amphoteric surfactant, inorganic salts, auxiliary agent, natural plant essential oils, the weight of each raw material
Portion rate is：
Anion surfactant 3.0 ~ 30
Nonionic surfactant 8 ~ 25
Amphoteric surfactant 3 ~ 13
Inorganic salts 0.1-3.5
Auxiliary agent 0.5 ~ 5
Natural plant essential oils 0.5 ~ 2.5
Deionized water 21-85.
Further, the raw material further includes cationic surfactant, and ratio of weight and number is：
Cationic surfactant 0.3-2.
Further, the anion surfactant is sodium lauroyl sarcosine.
Further, the cationic surfactant is sub- oleamide ethyl dimethyl ammonium sodium ethylsulfate.
Further, the nonionic surfactant includes alkyl glycosides, fatty alcohol polyoxyethylene ether and aminoglucose
One or more of mixture.
Further, the amphoteric surfactant is dodecanamide propyl dimethyl betaine.
Further, the auxiliary agent is acrylate copolymer.
Further, the inorganic salts are sodium chloride.
Further, the natural plant essential oils include wormwood essential oil, tree peony peel essential oil, chamomile essential oil, tea tree ethereal oil,
The mixture of one or more of sandalwood essential oil, grapefruit essential oil, Luo Wensha leaf essential oils.
Grapefruit essential oil：Grapefruit essential oil contains the vitamin C of high concentration, Flavanones compound, thus to immune
The highly beneficial value of system, can improve immunity, play the role of antibacterial bacteriostatic；
Main component 4- terpinols in tea tree ethereal oil have effects that very strong sterilization, disinfection, antibacterial, antibacterial, anti-corrosion；
Tree peony peel essential oil：Paeonol in moutan bark is the main component of antibacterial, has experimental study tree peony peel essential oil to golden yellow
Staphylococcus, Candida albicans, Pseudomonas aeruginosa, bacillus anthracis, proteus, alpha streptococcus, beta streptococcus have very well
Bacteriostasis；
Sandalwood essential oil：Sandalwood essential oil has effects that anti-inflammatory, antibacterial.
It is described using natural plant essential oils as the preparation method of the detergent of preservative, the preparation method includes following step
Suddenly：
1）Natural plant essential oils with nonionic surfactant by equal proportion are emulsified in advance, obtain mixture A；
2）50 DEG C~60 DEG C of deionized water of addition 40% ~ 50% in a kettle sequentially adds anionic surface work in order
Property agent, remaining nonionic surfactant, amphoteric surfactant and auxiliary agent, stir while adding, be uniformly mixed i.e. obtain
Mixture B；
3）When temperature is dropped to below 40 DEG C, mixture A, cationic surfactant and remaining deionized water are added in and mixed
It in object B, stirs evenly, filters, stand to get to the detergent using natural plant essential oils as preservative.
It is of the present invention using natural plant essential oils as detergent the having the beneficial effect that compared with prior art of preservative：
1st, present invention firstly discloses being used natural plant essential oils as preservative, it is added in cleaning product, instead of mesh
The preceding chemical preservative used for consumer, avoids the infringement of chemical preservative, protects health, production is looked forward to
Cost, environmental protection, while natural plant essential oils can be reduced for industry with lasting effect, while elimination peculiar smell can be played
Effect, and leave light fragrant；
2nd, it is of the present invention using natural plant essential oils as the detergent of preservative, used natural plant essential oils wormwood essence
Oil, tree peony peel essential oil, chamomile essential oil, tea tree ethereal oil, sandalwood essential oil, grapefruit essential oil, Luo Wensha leaf essential oils, these plants essence
Oil has antibacterial bacteriostatic, improves immunity, care family health.
Specific embodiment
Embodiment 1
A kind of detergent using natural plant essential oils as preservative is present embodiments provided, the parts by weight of each raw material used are such as
Under：
Anion surfactant 3.0 ~ 30
Nonionic surfactant 8 ~ 25
Amphoteric surfactant 3 ~ 13
Inorganic salts 0.1-3.5
Auxiliary agent 0.5 ~ 5
Natural plant essential oils 0.5 ~ 2.5
Deionized water 21-85.
Further, the raw material further includes cationic surfactant, and ratio of weight and number is：
Cationic surfactant 0.3-2.
Further, the natural plant essential oils include wormwood essential oil, tree peony peel essential oil, chamomile essential oil, tea tree ethereal oil,
The mixture of one or more of sandalwood essential oil, grapefruit essential oil, Luo Wensha leaf essential oils.
It is described using natural plant essential oils as the preparation method of the detergent of preservative, the preparation method includes following step
Suddenly：
1）Natural plant essential oils with nonionic surfactant by equal proportion are emulsified in advance, obtain mixture A；
2）In a kettle addition 40% 50 DEG C~60 DEG C of deionized water, sequentially add in order anion surfactant,
Remaining nonionic surfactant, amphoteric surfactant and auxiliary agent, stir while adding, and are uniformly mixed and obtain mixture
B；
3）When temperature is dropped to below 40 DEG C, mixture A, cationic surfactant and remaining deionized water are added in and mixed
It in object B, stirs evenly, filters, stand to get to the detergent using natural plant essential oils as preservative.
Unit of weight used in the present embodiment is kilogram, or gram；
Each raw material described in the present embodiment is technical grade；
Each raw material described in the present embodiment is the conventional products sold in the market；
In the present embodiment, each raw material can in the ratio range provided flexible combination, do not enumerate one by one herein.
Embodiment 2
The present embodiment is the preferred embodiment on the basis of embodiment 1, and raw materials used quality is same as Example 1, each original used
The ratio of weight and number of material is as follows：
Sodium lauroyl sarcosine 8
Alkyl glycosides 12
Sub- oleamide ethyl dimethyl ammonium sodium ethylsulfate 0.5
Dodecanamide propyl dimethyl betaine 9
Acrylate copolymer 1
Grapefruit essential oil 0.8
Sodium chloride 3.5
Deionized water 65.2.
Embodiment 3
The present embodiment is the preferred embodiment on the basis of embodiment 1, and raw materials used quality is same as Example 1, each original used
The ratio of weight and number of material is as follows：
Sodium lauroyl sarcosine 10
Alkyl glycosides 6
Fatty alcohol polyoxyethylene ether 5
Sub- oleamide ethyl dimethyl ammonium ethylsulfate 1.5
Dodecanamide propyl dimethyl betaine 12
Acrylate copolymer 1.0
Wormwood essential oil 0.5
Tree peony peel essential oil 0.5
Sodium chloride 2.0
Deionized water 61.5.
Embodiment 4
The present embodiment is the preferred embodiment on the basis of embodiment 1, and raw materials used quality is same as Example 1, each original used
The ratio of weight and number of material is as follows：
Sodium lauroyl sarcosine 15
Alkyl glycosides 5
Fatty alcohol polyoxyethylene ether 4
Sub- oleamide ethyl dimethyl ammonium ethylsulfate 2
Dodecanamide propyl dimethyl betaine 8
Acrylate copolymer 3
Tea tree ethereal oil 0.8
Sodium chloride 2.5
Deionized water 59.7.
Embodiment 5
The present embodiment is the preferred embodiment on the basis of embodiment 1, and raw materials used quality is same as Example 1, each original used
The ratio of weight and number of material is as follows：
Sodium lauroyl sarcosine 9
Alkyl glycosides 6
Fatty alcohol polyoxyethylene ether 5
Dodecanamide propyl dimethyl betaine 8
Grape amine 6
Grapefruit essential oil 0.8
Sodium chloride 3.0
Deionized water 62.2.
Embodiment 6
The present embodiment is the preferred embodiment on the basis of embodiment 1, and raw materials used quality is same as Example 1, each original used
The ratio of weight and number of material is as follows：
Sodium lauroyl sarcosine 10
Alkyl glycosides 4
Fatty alcohol polyoxyethylene ether 5
Dodecanamide propyl dimethyl betaine 6
Aminoglucose 8
Tree peony peel essential oil 0.8
Tea tree ethereal oil 0.3
Sodium chloride 1.8
Deionized water 64.1.
Embodiment 7
The present embodiment is the preferred embodiment on the basis of embodiment 1, and raw materials used quality is same as Example 1, each original used
The ratio of weight and number of material is as follows：
Sodium lauroyl sarcosine 30
Alkyl glycosides 22
Dodecanamide propyl dimethyl betaine 10
Aminoglucose 8
Chamomile essential oil 0.8
Grapefruit essential oil 0.3
Sodium chloride 2.2
Deionized water 26.7.
Embodiment 8
The present embodiment is the preferred embodiment on the basis of embodiment 1, and raw materials used quality is same as Example 1, each original used
The ratio of weight and number of material is as follows：
Sodium lauroyl sarcosine 25
Alkyl glycosides 20
Dodecanamide propyl dimethyl betaine 18
Aminoglucose 8
Tree peony peel essential oil 0.8
Wormwood essential oil 0.3
Sodium chloride 1.5
Deionized water 26.4.
For the antiseptic property using natural plant essential oils as the detergent of preservative that is provided of detection above-described embodiment, to
The experiment side that upper specific embodiment evaluates the anti-corrosion effect of daily chemical products according to disinfection technology standard and Microbial Challenge experiment
Method has carried out microorganism testing.
Experimental result is as follows：
To above example according to《Microbial Challenge, which is tested, evaluates the anti-corrosion effect of cosmetics》Middle Microbial Challenge experiment
Operating method has carried out preservative challenge testing.
This experimental method is according to repetition plus bacterium, is then cultivated after 7d, and altogether plus 3 bacterium, each plus bacterium amount are 1~5
×106.Above example is in the result such as following table cultivated three times plus after bacterium 7d.
Pass through more than experimental result, it is known that, it is cultivated three times plus after bacterium 7d, clump count is both less than 10, according to《Microorganism
The anti-corrosion effect of cosmetics is evaluated in challenge experiment》In evaluation from the point of view of, have very strong anti-corrosion effect.
Claims (10)
1. a kind of application of natural plant essential oils, which is characterized in that the natural plant essential oils are as aseptic applications in washing
In product；The natural plant essential oils include wormwood essential oil, tree peony peel essential oil, chamomile essential oil, tea tree ethereal oil, sandalwood essential oil,
The mixture of one or more of grapefruit essential oil, Luo Wensha leaf essential oils.
It is 2. a kind of using natural plant essential oils as the detergent of preservative, which is characterized in that the raw material for preparing the detergent includes
Anion surfactant, nonionic surfactant, amphoteric surfactant, inorganic salts, auxiliary agent, natural plant essential oils, respectively
The ratio of weight and number of raw material is：
Anion surfactant 3.0 ~ 30
Nonionic surfactant 8 ~ 25
Amphoteric surfactant 3 ~ 13
Inorganic salts 0.1-3.5
Auxiliary agent 0.5 ~ 5
Natural plant essential oils 0.5 ~ 2.5
Deionized water 21-85.
It is 3. according to claim 2 using natural plant essential oils as the detergent of preservative, which is characterized in that the raw material is also
Including cationic surfactant, ratio of weight and number is：
Cationic surfactant 0.3-2.
It is 4. according to claim 2 using natural plant essential oils as the detergent of preservative, which is characterized in that it is described it is cloudy from
Sub- surfactant is sodium lauroyl sarcosine.
It is 5. according to claim 3 using natural plant essential oils as the detergent of preservative, which is characterized in that the cation
Surfactant is sub- oleamide ethyl dimethyl ammonium sodium ethylsulfate.
It is 6. according to claim 2 using natural plant essential oils as the detergent of preservative, which is characterized in that it is described it is non-from
Sub- surfactant includes the mixture of one or more of alkyl glycosides, fatty alcohol polyoxyethylene ether and aminoglucose.
It is 7. according to claim 2 using natural plant essential oils as the detergent of preservative, which is characterized in that the both sexes
Surfactant is dodecanamide propyl dimethyl betaine.
It is 8. according to claim 2 using natural plant essential oils as the detergent of preservative, which is characterized in that the auxiliary agent
For acrylate copolymer.
It is 9. according to claim 2 using natural plant essential oils as the detergent of preservative, which is characterized in that the natural plant
Object essential oil includes wormwood essential oil, tree peony peel essential oil, chamomile essential oil, tea tree ethereal oil, sandalwood essential oil, grapefruit essential oil, Luo Wensha
The mixture of one or more of leaf essential oil.
10. it is a kind of as described in claim 2-9 using natural plant essential oils as the preparation method of the detergent of preservative, feature
It is, the preparation method includes the following steps：
1）Natural plant essential oils with nonionic surfactant by equal proportion are emulsified in advance, obtain mixture A；
2）50 DEG C~60 DEG C of deionized water of addition 40% ~ 50% in a kettle sequentially adds anionic surface work in order
Property agent, remaining nonionic surfactant, amphoteric surfactant and auxiliary agent, stir while adding, be uniformly mixed i.e. obtain
Mixture B；
3）When temperature is dropped to below 40 DEG C, mixture A, cationic surfactant and remaining deionized water are added in and mixed
It in object B, stirs evenly, filters, stand to get to the detergent using natural plant essential oils as preservative.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611251743.1A CN108264973A (en) | 2016-12-30 | 2016-12-30 | It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611251743.1A CN108264973A (en) | 2016-12-30 | 2016-12-30 | It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof |
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| CN201611251743.1A Pending CN108264973A (en) | 2016-12-30 | 2016-12-30 | It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof |
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| CN110742827A (en) * | 2019-09-27 | 2020-02-04 | 华南师范大学 | Anticorrosive composition and application thereof |
| CN111718805A (en) * | 2020-06-17 | 2020-09-29 | 南风化工集团股份有限公司 | Tableware detergent with caraway extract as fishy smell removing component and preparation method thereof |
| CN112080353A (en) * | 2020-09-02 | 2020-12-15 | 广东丽臣奥威实业有限公司 | Mild and efficient surfactant composition for cleaning |
| CN112136837A (en) * | 2020-09-25 | 2020-12-29 | 上海和黄白猫有限公司 | Antibacterial mite-killing composition, antibacterial mite-killing laundry detergent and preparation method thereof |
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| CN110742827A (en) * | 2019-09-27 | 2020-02-04 | 华南师范大学 | Anticorrosive composition and application thereof |
| CN111718805A (en) * | 2020-06-17 | 2020-09-29 | 南风化工集团股份有限公司 | Tableware detergent with caraway extract as fishy smell removing component and preparation method thereof |
| CN112080353A (en) * | 2020-09-02 | 2020-12-15 | 广东丽臣奥威实业有限公司 | Mild and efficient surfactant composition for cleaning |
| CN112136837A (en) * | 2020-09-25 | 2020-12-29 | 上海和黄白猫有限公司 | Antibacterial mite-killing composition, antibacterial mite-killing laundry detergent and preparation method thereof |
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