CN112080353A - Mild and efficient surfactant composition for cleaning - Google Patents
Mild and efficient surfactant composition for cleaning Download PDFInfo
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- CN112080353A CN112080353A CN202010907497.0A CN202010907497A CN112080353A CN 112080353 A CN112080353 A CN 112080353A CN 202010907497 A CN202010907497 A CN 202010907497A CN 112080353 A CN112080353 A CN 112080353A
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- mild
- surfactant composition
- cleaning
- highly effective
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- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 27
- 238000004140 cleaning Methods 0.000 title claims abstract description 15
- 239000003463 adsorbent Substances 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 241001122767 Theaceae Species 0.000 claims abstract description 10
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 10
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 10
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims abstract description 10
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 108700004121 sarkosyl Proteins 0.000 claims abstract description 8
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims abstract description 8
- 230000002378 acidificating effect Effects 0.000 claims abstract description 7
- 239000004088 foaming agent Substances 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 5
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 claims abstract description 5
- 239000012747 synergistic agent Substances 0.000 claims abstract description 4
- 150000001768 cations Chemical class 0.000 claims abstract description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000003093 cationic surfactant Substances 0.000 claims description 9
- -1 C1-C18 alkyl quaternary ammonium salts Chemical class 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 6
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 3
- KOPMZTKUZCNGFY-UHFFFAOYSA-N 1,1,1-triethoxybutane Chemical compound CCCC(OCC)(OCC)OCC KOPMZTKUZCNGFY-UHFFFAOYSA-N 0.000 claims description 2
- 229960000411 camphor oil Drugs 0.000 claims description 2
- 239000010624 camphor oil Substances 0.000 claims description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- QXLPXWSKPNOQLE-UHFFFAOYSA-N methylpentynol Chemical compound CCC(C)(O)C#C QXLPXWSKPNOQLE-UHFFFAOYSA-N 0.000 claims 1
- 239000008233 hard water Substances 0.000 abstract description 4
- 238000003756 stirring Methods 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- QNVRIHYSUZMSGM-UHFFFAOYSA-N hexan-2-ol Chemical compound CCCCC(C)O QNVRIHYSUZMSGM-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 230000000840 anti-viral effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a mild and efficient surfactant composition for cleaning, which comprises the following components in parts by weight: 50-70 parts of dodecyl dimethyl betaine, 1-5 parts of an acidic additive, 20-30 parts of sodium lauroyl sarcosinate, 20-30 parts of a cation surface activity synergistic agent, 1-3 parts of a foaming agent, 1-3 parts of a compound auxiliary adsorbent and 1-3 parts of tea polyphenol. The surfactant composition for cleaning is weak in acidity as a whole, mild in system, free of damage to skin, still strong in detergency in hard water and good in detergency effect.
Description
Technical Field
The invention relates to the technical field of surfactants, in particular to a mild and efficient surfactant composition for cleaning.
Background
The surfactant is an important fine chemical product and plays an important role in the daily life of people. On one hand, the variety of surfactants is large, and on the other hand, the functional requirements of people on the surfactants are more and more complex, and the surfactants with different functions are generally required to be compounded for use so as to meet different requirements.
In a scene with a lot of dirt such as indoor floor and toilet, a cleaning agent containing hydrochloric acid is generally used for effectively removing the dirt, but hydrochloric acid is volatile, generates a pungent smell, is strong in acidity and is easy to damage human skin.
Disclosure of Invention
Aiming at the problems, the invention provides a mild and efficient surfactant composition for cleaning, which is weakly acidic as a whole, mild in system, free of damage to skin, still has strong detergency in hard water and good detergency effect.
In order to achieve the purpose, the invention is solved by the following technical scheme:
a mild and efficient surfactant composition for cleaning comprises the following components in parts by weight: 50-70 parts of dodecyl dimethyl betaine, 1-5 parts of an acidic additive, 20-30 parts of sodium lauroyl sarcosinate, 20-30 parts of a cation surface activity synergistic agent, 1-3 parts of a foaming agent, 1-3 parts of a compound auxiliary adsorbent and 1-3 parts of tea polyphenol.
Specifically, the acidic additive is one selected from citric acid and acetic acid.
Specifically, the cationic surfactant synergistic agent is a quaternary ammonium salt cationic surfactant.
Specifically, the quaternary ammonium salt cationic surfactant is one or more than two selected from C1-C18 alkyl quaternary ammonium salts.
Specifically, the foaming agent is selected from one of alpha-terpene alcohol, camphor oil, methanol, triethoxy butane, methyl amyl alcohol and pyridine.
Specifically, the compound auxiliary adsorbent is a mixture of sodium fluosilicate and ammonium sulfate according to the mass ratio of 3: 1.
The invention has the beneficial effects that:
firstly, the surfactant composition provided by the invention is added with dodecyl dimethyl betaine, has strong decontamination capability under acidic and alkaline conditions, has strong hard water resistance, does not need to be added with a chelating agent to soften hard water, and can be used as a bactericide to kill various bacteria including tubercle bacillus;
secondly, sodium lauroyl sarcosinate, a cationic surfactant and a foaming agent and a compound auxiliary adsorbent are added, when the surfactant composition is mixed with water and then applied to floor cleaning, the sodium lauroyl sarcosinate and the cationic surfactant can be attached to the surface of dirt on a bottom plate through the synergistic effect of the sodium lauroyl sarcosinate and the cationic surfactant, the dirt is floated through bubbles generated in the cleaning process, the foaming agent is used for reducing the interfacial tension of mixed liquid, air is promoted to form more small bubbles in the mixed liquid, the bubbles can be prevented from merging, the stability of the bubbles is improved, more dirt is removed, and the compound auxiliary adsorbent is also added, so that the dirt is more easily attached and floated through changing the chemical composition of the surface of the dirt;
and thirdly, tea polyphenol is added, and has excellent antioxidant, antiviral and antibacterial capabilities, and the peculiar smell of the floor can be removed.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments in order to provide a further understanding of the nature and technical means of the invention, as well as the specific objects and functions attained by the invention.
Example 1
A mild and efficient surfactant composition for cleaning comprises the following components in parts by weight: 60 parts of dodecyl dimethyl betaine, 1-5 parts of citric acid, 25 parts of sodium lauroyl sarcosine, 20 parts of C12 alkyl quaternary ammonium salt, 2 parts of methanol, 3 parts of a compound auxiliary adsorbent and 3 parts of tea polyphenol.
Preferably, the compound auxiliary adsorbent is a mixture of sodium fluosilicate and ammonium sulfate according to the mass ratio of 3: 1.
The preparation process comprises the following steps: weighing the components for later use, adding tea polyphenol into a beaker, adding methanol and continuously stirring to completely dissolve the tea polyphenol, then adding dodecyl dimethyl betaine, sodium lauroyl sarcosinate, C12 alkyl quaternary ammonium salt, sodium fluosilicate and ammonium sulfate, mixing for 20min under the stirring condition, and finally slowly adding a small amount of citric acid while stirring until the pH value of the surfactant composition is adjusted to 6.0-6.5.
Example 2
A mild and efficient surfactant composition for cleaning comprises the following components in parts by weight: 55 parts of dodecyl dimethyl betaine, 1-5 parts of citric acid, 25 parts of sodium lauroyl sarcosine, 25 parts of C18 alkyl quaternary ammonium salt, 2 parts of methanol, 3 parts of a compound auxiliary adsorbent and 3 parts of tea polyphenol.
Preferably, the compound auxiliary adsorbent is a mixture of sodium fluosilicate and ammonium sulfate according to the mass ratio of 3: 1.
The preparation process comprises the following steps: weighing the components for later use, adding tea polyphenol into a beaker, adding methanol and continuously stirring to completely dissolve the tea polyphenol, then adding dodecyl dimethyl betaine, sodium lauroyl sarcosinate, C18 alkyl quaternary ammonium salt, sodium fluosilicate and ammonium sulfate, mixing for 20min under the stirring condition, and finally slowly adding a small amount of citric acid while stirring until the pH value of the surfactant composition is adjusted to 6.0-6.5.
And (3) testing: the detergency of the surfactant compositions prepared in examples 1 to 2 was measured by a test method of "measurement of detergency and circulating detergency of detergents for clothing and clothes for GB/T13174-2008", and the record is as follows in table 1.
TABLE 1 test results
| Example 1 | Example 2 | |
| Stain removal value | 1.9 | 2.0 |
From the test results in table 1 above, it is seen that the detersive values of the surfactant compositions of examples 1-2 are greater than 1.5 in both examples, and the detersive value of the conventional laundry detergent is about 1.5, which indicates that the surfactant composition of the present invention has strong detersive power.
The above examples only show 2 embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (6)
1. The mild and efficient surfactant composition for cleaning is characterized by comprising the following components in parts by weight: 50-70 parts of dodecyl dimethyl betaine, 1-5 parts of an acidic additive, 20-30 parts of sodium lauroyl sarcosinate, 20-30 parts of a cation surface activity synergistic agent, 1-3 parts of a foaming agent, 1-3 parts of a compound auxiliary adsorbent and 1-3 parts of tea polyphenol.
2. A mild and highly effective cleansing surfactant composition according to claim 1 wherein said acidic additive is selected from the group consisting of citric acid and acetic acid.
3. The mild and highly effective cleaning surfactant composition according to claim 1, wherein said cationic surfactant synergist is a quaternary ammonium salt type cationic surfactant.
4. The mild and highly effective surfactant composition for cleaning according to claim 3, wherein said quaternary ammonium salt type cationic surfactant is one or more selected from the group consisting of C1-C18 alkyl quaternary ammonium salts.
5. The mild and highly effective detergent surfactant composition according to claim 1, wherein said foaming agent is selected from the group consisting of a-terpene alcohols, camphor oil, methanol, triethoxybutane, methylpentanol, and pyridine.
6. The mild and efficient surfactant composition for cleaning according to claim 1, wherein the compound co-adsorbent is a mixture of sodium fluorosilicate and ammonium sulfate in a mass ratio of 3: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010907497.0A CN112080353A (en) | 2020-09-02 | 2020-09-02 | Mild and efficient surfactant composition for cleaning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010907497.0A CN112080353A (en) | 2020-09-02 | 2020-09-02 | Mild and efficient surfactant composition for cleaning |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112080353A true CN112080353A (en) | 2020-12-15 |
Family
ID=73733058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010907497.0A Pending CN112080353A (en) | 2020-09-02 | 2020-09-02 | Mild and efficient surfactant composition for cleaning |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112080353A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1257350A1 (en) * | 1999-09-17 | 2002-11-20 | Stepan Company | Ternary surfactant blends comprising cationic, anionic, and bridging surfactants and methods of preparing same |
| US7582599B1 (en) * | 2008-10-23 | 2009-09-01 | Kracie Home Products, Ltd. | Detergent composition comprising a mixture of two anionic, a nonionic, and an amphoteric surfactant |
| US9018150B1 (en) * | 2013-12-09 | 2015-04-28 | L'oreal | Cleansing composition with cationic surfactants |
| WO2015086608A1 (en) * | 2013-12-09 | 2015-06-18 | L'oreal | Viscoelastic cleansing gel |
| CN105796375A (en) * | 2014-12-31 | 2016-07-27 | 罗允俊 | Portable cleaning product |
| CN106190642A (en) * | 2016-08-08 | 2016-12-07 | 安徽炎胜新材料科技有限公司 | A kind of Bactericidal tableware detergent and preparation method thereof |
| CN106244353A (en) * | 2016-08-30 | 2016-12-21 | 四川达文西科技有限公司 | A kind of woodenware detergent additive |
| CN108130222A (en) * | 2018-01-29 | 2018-06-08 | 深圳市芭格美生物科技有限公司 | A kind of glasses cleaning agent and preparation method thereof |
| CN108264973A (en) * | 2016-12-30 | 2018-07-10 | 北京绿伞化学股份有限公司 | It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof |
-
2020
- 2020-09-02 CN CN202010907497.0A patent/CN112080353A/en active Pending
Patent Citations (9)
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|---|---|---|---|---|
| EP1257350A1 (en) * | 1999-09-17 | 2002-11-20 | Stepan Company | Ternary surfactant blends comprising cationic, anionic, and bridging surfactants and methods of preparing same |
| US7582599B1 (en) * | 2008-10-23 | 2009-09-01 | Kracie Home Products, Ltd. | Detergent composition comprising a mixture of two anionic, a nonionic, and an amphoteric surfactant |
| US9018150B1 (en) * | 2013-12-09 | 2015-04-28 | L'oreal | Cleansing composition with cationic surfactants |
| WO2015086608A1 (en) * | 2013-12-09 | 2015-06-18 | L'oreal | Viscoelastic cleansing gel |
| CN105796375A (en) * | 2014-12-31 | 2016-07-27 | 罗允俊 | Portable cleaning product |
| CN106190642A (en) * | 2016-08-08 | 2016-12-07 | 安徽炎胜新材料科技有限公司 | A kind of Bactericidal tableware detergent and preparation method thereof |
| CN106244353A (en) * | 2016-08-30 | 2016-12-21 | 四川达文西科技有限公司 | A kind of woodenware detergent additive |
| CN108264973A (en) * | 2016-12-30 | 2018-07-10 | 北京绿伞化学股份有限公司 | It is a kind of using natural plant essential oils as detergent of preservative and preparation method thereof |
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| Title |
|---|
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| 慕红梅: "<<浮游分选技术>>", 31 January 2015 * |
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