KR20180114717A - Detergent composition comprising a sugar based anionic surfactant - Google Patents

Abstract

The present invention relates to a detergent composition. According to the present invention, the detergent composition uses a sugar based anionic surfactant to provide excellent detergency and air bubble power. Moreover, rinsing ability is improved for the detergent composition to be specifically used for liquid detergent for a kitchen.

Description

[0001] The present invention relates to a detergent composition comprising a sugar anionic surfactant,

The present invention relates to a detergent composition comprising a sugar anionic surfactant.

The most basic and important factors of the kitchen liquid detergent composition are foam power and detergency. Consumers first judge the cleaning ability according to the amount and shape of the bubbles. Even if the cleaning power is excellent, it is judged that the cleaning ability is insufficient when the amount of bubbles is insufficient or the bubble persistence is insufficient. Therefore, conventionally, anionic surfactant is used as a main cleansing component and nitrogen-positive or nonionic surfactant such as amine oxide or cocamidopropyl betaine is mixed with a chelating agent in order to have a favorable abundant amount of foam and detergency. Use a boosted cleaning agent. Among them, amine oxide has a cationic property in a weakly acidic region. Therefore, the amine oxide forms a complex with an anionic surfactant, thereby increasing emulsifying power and foaming power against oil. Therefore, a composition using amine oxide as a foam booster is widely used have.

However, the detergent composition using amine oxide or betaine has a problem that the detergency and bubble power are excellent, but the rinsability is poor.

Recently, kitchen detergents have a main surfactant content of 10 to 17 wt%. Unlike the concentrated kitchen detergents in the past, the detergent is wiped in a sponge without directly diluting the detergent in water and rubbed directly on a tableware. A kitchen detergent containing amine oxide or betaine has the disadvantage of being slippery and less rinse in such use, especially when the amine oxide content is high.

Because of this problem, kitchen cleaners using amine oxide system require more rinse time than unused kitchen cleaners, and thus use more water.

The method of simply reducing the content of amine oxide in order to improve the rinsability has a disadvantage in that the rinsability is improved but the foaming power and cleaning power are also decreased. Therefore, there is a growing demand for liquid cleaning agents for kitchens which have abundant foaming power and excellent cleaning power when used and quickly disappear when the rinse is carried out.

An object of the present invention is to provide a liquid dishwashing liquid composition containing a sugar anion surfactant which improves the rinsability without deteriorating the washing power and the bubble power.

In the present invention, 1 to 30% by weight of a sugar anionic surfactant based on the total weight of the composition; 1 to 20% by weight of a nonionic surfactant; And 1 to 10% by weight of an electrolyte.

The detergent composition according to the present invention is excellent in detergency and foaming power by using a sugar anionic surfactant, and can be used as a liquid detergent for kitchens, particularly, as the detergency improves.

In addition, the filtrate of the fermentation broth of Saccharomyces, which is further contained in the detergent composition, contains a large amount of minerals, vitamins, proteins and the like, so that skin moisturization can be maintained. In addition, the antioxidant activity of vitamins and minerals contained in Saccharomyces can prevent the skin from becoming rough.

Therefore, even if a kitchen detergent is used, the skin is not dried and an excellent skin moisturizing effect can be obtained.

Fig. 1 shows the result of evaluating the moisturizing ability of the composition according to the present invention.

The present invention relates to a composition comprising 1 to 30% by weight, based on the total weight of the composition, of a sugar anionic surfactant; 1 to 20% by weight of a nonionic surfactant; And 1 to 10% by weight of an electrolyte.

Hereinafter, the detergent composition according to the present invention will be described in more detail.

The detergent composition according to the present invention comprises, as described above, a sugar anionic surfactant, a nonionic surfactant and an electrolyte.

In the present invention, the anionic surfactant can impart excellent detergency to the detergent composition. In particular, the present invention can provide a detergent composition having excellent foamability and excellent rinsing performance without deteriorating detergency by using a sugar anionic surfactant.

The kind of the sugar anion surfactant is not particularly limited, and for example, a polyglucoside anionic surfactant can be used. Specifically, alkylpolyglucoside carboxylate and alkylpolyglucoside sulfonate represented by the following formula 1 or 2 ≪ / RTI > may be used.

[Chemical Formula 1]

(2)

In Formula 1 or 2, R may be an alkyl group having 8 to 18 carbon atoms, an alkyl group having 8 to 16 carbon atoms, an alkyl group having 8 to 14 carbon atoms, or an alkyl group having 10 to 12 carbon atoms. At this time, the alkyl group may be a linear or branched structure. N represents an average degree of polymerization and may be 1 or 2.

In one embodiment, the content of the sugar anion surfactant is not particularly limited and may be in the range of 0.1 to 30 wt%, 0.1 to 15 wt%, 0.5 to 10 wt%, or 1 to 8 wt%, based on the total weight of the detergent composition (100 wt% % ≪ / RTI > In this range, a detergent composition having not only bubble power and cleaning power but also excellent rinsability can be obtained.

In addition to the sugar anion surfactant, the anionic surfactant may be a primary or secondary alcohol sulfuric acid monoester compound having 8 to 18 carbon atoms. As the alcohol, coconut oil fatty alcohol, tallow fatty alcohol, oleyl alcohol or oxo alcohol having 1 to 20 carbon atoms can be used. As the anionic surfactant, alkyl ethoxysulfate may be used. The content of the nonionic surfactant is not particularly limited and may be 10 wt% or less, 1 to 8 wt%, or 2 to 6 wt%, based on the total weight of the detergent composition (100 wt%).

In the present invention, the above-mentioned sugar anionic surfactant can be used in combination with a nonionic surfactant and / or an amphoteric surfactant to impart a synergistic effect to detergency.

In the present invention, the kind of the nonionic surfactant is not particularly limited, and it may be a primary or secondary alcohol type nonionic surfactant containing 1 to 25 moles of ethylene oxide, an alkyl polyglucoside type nonionic surfactant and a fatty acid amide type nonionic surfactant A surfactant (for example, ammonia amide, monoethanol amide, diethanol amide or isopropanol amide) can be used. Specifically, an alkyl polyglucoside-based nonionic surfactant can be used. The alkyl polyglucoside-based nonionic surfactant may have a straight-chain or branched alkyl group having 8 to 22, 8 to 20, or 8 to 16 carbon atoms.

The nonionic surfactant is not particularly limited as long as it can be used in a conventional cosmetic composition, and a lipophilic nonionic surfactant or a hydrophilic nonionic surfactant can be used. For example, a lipophilic nonionic surfactant Sorbitan fatty acid esters such as sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate , Penta-2-ethylhexyl acid diglycerol sorbitan, tetra-2-ethylhexyl acid diglycerol sorbitan and the like); Glycerin polyglycerin fatty acids (monosaccharic fatty acid glycerin, monoelucic acid glycerin, sesquioleic acid glycerin, monostearic acid glycerin,?,? '- oleic acid pyroglutamic acid glycerin, monostearic acid glycerin malic acid, etc.); Propylene glycol fatty acid esters (such as propylene glycol monostearate); Hardened castor oil derivatives; Sorbitan fatty acid esters (POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan fatty acid esters, POE-sorbitan fatty acid esters, Sorbitan tetraoleate, and the like); POE-sorbit fatty acid esters (POE-sorbitol monolaurate, POE-sorbitol monooleate, POE-sorbitol pentaoleate, POE-sorbitol monostearate, and the like); POE-glycerin fatty acid esters (POE-glycerin monostearate, POE-glycerin monoisostearate, POE-glycerin triisostearate, etc.); POE-fatty acid esters (POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic molds (Pluronic and the like); POE / POP-alkyl ethers (POE / POP-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether and the like); Tetra POE tetra POP-ethylenediamine condensation products (such as Tetronic); POE-castor oil-hardened castor oil derivative (POE-castor oil, POE-hardened castor oil, POE-hardened castor oil free monoisostearate, POE-hardened castor oil free triisostearate, POE-hardened castor oil free monopyrroglutamate monoisoprene Stearic acid diester, POE-hardened castor oil free maleic acid); POE beeswax / lanolin derivatives (POE-sorbitol beeswax); Alkanolamides (coconut fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid esters; POE-alkylamines; POE-fatty acid amide; Sucrose fatty acid esters; Alkylethoxydimethylamine oxides; And trioleyl phosphoric acid can be used.

The amount of the nonionic surfactant is not particularly limited and may be 1 to 20% by weight, 2 to 10% by weight or 4 to 6% by weight based on the total weight of the detergent composition (100% by weight). A detergent composition having excellent detergency within the above range can be obtained.

In the present invention, the kind of the amphoteric surfactant is not particularly limited, and it is preferable that the amphoteric surfactant is selected from the group consisting of fatty acid amide based betaines having 8 to 22 carbon atoms or 10 to 16 carbon atoms and alkyl amine oxides having 8 to 22 carbon atoms or 10 to 16 carbon atoms At least one selected can be used.

Further, the amphoteric surfactant is not particularly limited as long as it can be used in a conventional cosmetic composition, and examples thereof include an imidazoline surfactant (2-undecyl-N, N, N- (hydroxyethylcarboxymethyl ) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt and the like); And a betaine surfactant (2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine, sulfobetaine etc.) ≪ / RTI > may be used.

The amount of the amphoteric surfactant is not particularly limited and may be 1 to 20% by weight, 1 to 10% by weight or 2 to 5% by weight based on the total weight of the detergent composition (100% by weight). A detergent composition having excellent detergency within the above range can be obtained.

Also, the detergent composition according to the present invention may comprise an electrolyte. The electrolyte exhibits a viscoelastic effect in a surfactant system and can increase cleaning power and foaming power. In addition, the electrolyte can exhibit an effect of increasing dispersion stability and a function of increasing cleaning power in a surfactant system.

The type of the electrolyte is not particularly limited, and for example, a monovalent or multivalent organic or inorganic acid salt may be used. Specific examples of the salts include salts of citrate, chloride, bromide, iodide, acetate, bicarbonate, phosphate, citrate, sulfate, polyphosphate, pyrophosphate, triphosphate, tetrapyrite, Metal salts may be used. More specifically, at least one selected from the group consisting of citrate salts, chlorides, nitrates, bicarbonates, phosphates, silicates, and carbonates may be used. As the counter cation of the anion of the salt, sodium, calcium, magnesium, zinc, aluminum or iron may be used. In the present invention, sodium citrate may be used as the electrolyte.

The content of the electrolyte is not particularly limited and may be 1 to 10% by weight or 2 to 5% by weight based on the total weight of the detergent composition (100% by weight). A detergent composition having excellent detergency and stability in the above range can be obtained.

In addition, the detergent composition according to the present invention may further comprise a Saccharomyces fermentation filtrate. Saccharomyces is an upper component of galactomiss, which contains various fermenting species. The saccharomyces fermentation filtrate used in the present invention is Saccharomyces sp . Microorganism, and specifically may be Saccharomyces cerevisiae, Schizosaccharomyces pombe, Saccharomyces boulardii, and the like.

The fermented filtrate of saccharomyces can contain a large amount of minerals, vitamins and proteins to maintain skin moisturization, and the skin can be prevented from being roughened through the antioxidative action of the vitamins and minerals. Therefore, even if a kitchen detergent is used, the skin is not dried and an excellent skin moisturizing effect can be obtained.

Such saccharomyces fermented filtrate can be produced by a conventional method. For example, cultured Saccharomyces strains at 15 to 20 ° C for 2 to 3 days are subjected to sterilization and membrane filtration ). ≪ / RTI > The saccharomyces fermentation filtrate can be used at a concentration of 0.001 to 1%.

The content of the saccharomyces fermentation filtrate is not particularly limited and may be 0.001 to 1% by weight, 0.005 to 0.5% by weight or 0.01 to 0.1% by weight based on the total weight of the detergent composition (100% by weight). If it is less than 0.001% by weight, it is difficult to expect a moisturizing and skin protecting effect in the detergent. If it exceeds 1% by weight, the detergency and rinsing power of the detergent may decrease.

The detergent composition of the present invention may contain a solubilizing agent, an organic solvent, an odor, a dye, a pH adjusting agent, a metal chelating agent, an enzyme or water within the range not hindering the object of the present invention in addition to the above- May be suitably selected and adjusted by one of ordinary skill in the art. In this case, it is preferable to use purified water, and it may be a liquid phase or a solvent dissolved in a liquid solvent at room temperature and having a function other than a function of a simple filler. As such a solvent, a solubilizing agent or an organic solvent may be used.

Examples of the solubilizing agent include polyethylene glycol having a weight average molecular weight of 100 to 2,000, glycerin, propylene glycol, an alkanol having 1 to 4 carbon atoms, an alkylaryl sulfonate, a carboxylic acid sulfate or a sulfonate salt, a urea, a hydrocarboxylate, And a heterocyclic group may be used. Examples of the alkanol having 1 to 4 carbon atoms include methanol, ethanol, propanol, isopropanol, linear or branched butanol, and the like. The solubilizing agent is used in an amount of 0.1 to 5% by weight or 1 to 3% by weight based on the total composition. If the solubilizing agent is less than 0.1% by weight, the solubilizing effect is not sufficiently exhibited. There is a risk of separation.

As the organic solvent, a mono- or polyhydric alcohol may be used. Specifically, methanol, ethanol, propanol, isopropanol, butanol, glycerin, or a mixture thereof having a carbon number of about 1 to 4 can be used.

As the fragrance, aromatic compounds conventionally used may be used, and those which are chemically synthesized or extracted from natural materials and known in the art may be used.

The preservative may be ethanol, phenoxyethanol, formaldehyde solution, pentene diol, paraben or sodium benzoate.

The pH adjusting agent is used to maintain a pH of 6.0 to 10.5, and a low molecular weight inorganic or organic compound may be used. Examples of the alkali regulator include caustic soda, caustic soda, diethanolamine or triethanolamine. As the acidic regulator, citric acid, malic acid, salicylic acid, tartaric acid, lactic acid, acetic acid, sorbic acid or benzoic acid can be used.

The metal ion sulfonating agent is used for increasing the formulation and phase stability of the liquid composition of the present invention and may be selected from citric acid, lactic acid, succinic acid, tartaric acid, malic acid, EDTA, EDTA-2Na, EDTA-4Na, DTA, NTPA, At least one selected from the group consisting of polyacrylic acid, gluconic acid, sorbates and sodium bicarbonate can be used.

The liquid detergent composition of the present invention can be produced by any method conventionally used in this field. To prepare a particularly homogeneous liquid or gel type dishwashing detergent composition, it may be prepared by mixing together the required optional ingredients in the usual manner using suitable agitation.

The liquid detergent composition of the present invention can be used for cleaning kitchen tools.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the following embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

Example

Examples 1 to 8

A liquid detergent composition was prepared with the composition and contents (wt%, wt%) as shown in Table 1 below.

An alkylpolysaccharide having 12 to 14 carbon atoms as an anionic surfactant, an alkylethoxy sulfate having 12 to 14 carbon atoms as an anionic surfactant, an alkylamine oxide having 12 to 14 carbon atoms as an amphoteric surfactant, an alkylpolyglucoside carboxylate having a carbon number of 12 Alkylpolyglucoside sulfonate having a carbon number of 12 was used, alkylpolyglucoside having a carbon number of 8 to 14 was used as a nonionic surfactant, sodium citrate was used as an electrolyte, and citric acid was used as a pH regulator.

Each of the raw materials was sequentially added to the composition so as to be a homogeneous liquid phase, and then mixed by stirring.

Example ingredient One 2 3 4 5 6 7 8 Alkyl ethoxy sulfate 6 4 2 0 6 4 2 0 Alkyl amine oxide 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 Alkylpolyglucoside
Carboxylate 1.2 3.2 5.2 7.2 - - - - Alkylpolyglucoside
Sulfonate - - - - 1.2 3.2 5.2 7.2 Alkylpolyglucoside 4.6 4.6 4.6 4.6 4.6 4.6 4.6 4.6 Sodium citrate 2 2 2 2 2 2 2 2 pH adjusting agent q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100

Examples 9 to 20

A liquid detergent composition was prepared with the composition and contents (wt%, wt%) as shown in Table 2 below.

Wherein the nonionic surfactant is selected from the group consisting of cocoamidopropyl betaine and alkylpolyglucoside having 8 to 14 carbon atoms, an amphoteric surfactant having an alkylamine oxide having 12 to 14 carbon atoms, a sugar alkyl anionic surfactant having 12 carbon atoms Polyglucoside carboxylate was used, sodium citrate was used as an electrolyte, and citric acid was used as a pH regulator.

Each of the raw materials was sequentially added to the composition so as to be a homogeneous liquid phase, and then mixed by stirring.

Example ingredient 9 10 11 12 13 14 15 16 17 18 19 20 Cocoamidopropyl betaine 7.2 7.2 7.2 7.2 5.8 4.3 2.9 1.4 7.2 7.2 7.2 7.2 Alkyl amine oxide 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 Alkyl polyglucoside carboxylate 2.3 4.6 6.9 9.2 1.4 2.9 4.3 5.8 9.2 9.2 9.2 9.2 Alkylpolyglucoside 9.3 7.0 4.7 2.4 11.6 11.6 11.6 11.6 2.4 2.4 2.4 2.4 Sodium citrate 2 2 2 2 2 2 2 2 2 2 2 2 Saccharomyces fermentation filtrate 0.001 0.01 0.1 One pH adjusting agent q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100

Comparative Examples 1 to 4

Liquid detergent compositions were prepared with the compositions and contents (wt%, wt%) as shown in Table 3 below.

The liquid detergent composition was prepared in the same manner as in Example.

ingredient Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Alkyl ethoxy sulfate 7.2 7.2 4 4 Alkyl amine oxide 3.2 - 3.2 3.2 Alkyl polyglucoside carboxylate - - - - Alkylpolyglucoside sulfonate - - 3.2 7.8 Alkylpolyglucoside 4.6 7.8 4.6 - Sodium citrate 2 2 - - pH adjusting agent q.s. q.s. q.s. q.s. Purified water To 100 To 100 To 100 To 100

Comparative Examples 5 to 8

Liquid detergent compositions were prepared with the compositions and contents (wt%, wt%) as shown in Table 4 below.

The liquid detergent composition was prepared in the same manner as in Example.

ingredient Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Cocoamidopropyl betaine 7.2 10.4 7.2 7.2 Alkyl amine oxide 3.2 - 3.2 3.2 Alkyl polyglucoside carboxylate - - - 11.6 Alkylpolyglucoside 11.6 11.6 11.6 - Sodium citrate 2 2 - - Saccharomyces fermentation filtrate pH adjusting agent q.s. q.s. q.s. q.s. Purified water To 100 To 100 To 100 To 100

EXPERIMENTAL EXAMPLE 1 Evaluation of Foam Force and Dishwashing Force

Using the liquid detergent compositions prepared by the above-described Examples and Comparative Examples, foam generation and dish washing power against animal oil and vegetable oil contamination at 25 캜 were evaluated.

Specifically, the evaluation of the bubble strength was carried out as follows.

Using a 600 ml cylinder, 1.5 g of a cleaning agent (cleaning agent composition of Examples and Comparative Examples) and 3 g of oil contamination were added to 100 ml of soft water, and after 100 revolutions at 60 rpm, the height at which the bubbles were generated was measured. The evaluation was carried out at 25 캜.

In addition, the plate test method was evaluated as follows.

1 g / sheet of contamination was applied to a watch plate having a diameter of 100 mm, and then a sponge without water was placed, and a certain amount of water and a cleaning agent (cleaning composition of the examples and comparative examples) were administered. And the number of dishes washed was measured. Evaluation criteria of dish washing power are shown in Table 5 below.

Criteria for evaluating dish washing power Number of dishes washed Evaluation standard sign Less than 1 Inadequate × 2 to 3 usually △ 4 to 6 Great ○ 7 or more very best ◎

In this experiment, organic / inorganic residues such as sebum, mud, dead residue, plant residue, protein, starch, fat or oil were used. In this experiment, emulsified contaminants were used. The contaminant composition for the detergency evaluation is shown in Table 6 below.

Contaminant composition weight (%) Vegetable pollution Animal pollution milk 20 - egg 20 - Starch 15 - margarine 10 - cooking oil 10 30 Uji - 30 Lard - 40 water Up to 100% by weight -

The results of the evaluation of the foam force and the dish detergency measured by the above-described method are shown in Tables 7 and 8 below.

Comparative Example Example One 2 3 4 One 2 3 4 5 6 7 8 Bubble power 100 50 65 85 100 100 95 90 100 100 90 85 Dish washing power ○ △ △ △ ○ ○ ○ ○ ○ ○ ○ ○

Comparative Example Example 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Bubble power: Animal oil 200 130 175 190 200 205 210 240 200 200 190 180 240 240 240 220 Bubble power: Vegetable oil 400 230 300 340 500 505 520 540 470 420 400 300 540 540 540 520 Dish washing power: animal oil △ △ △ △ ○ ○ ○ ○ △ △ △ △ ○ ○ ○ ○ Dish washing power: vegetable oil ◎ △ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ ○ ◎ ◎ ◎ ◎

As shown in Table 7, the detergent compositions of the Examples were excellent in bubble power and dish washing power, and had particularly excellent foam power and detergency of the compositions of Examples 1, 2, 5 and 6.

It was found that Examples 4 and 8 using alkylpolyglucoside carboxylate or alkylpolyglucoside sulfonate without using alkylethoxysulfate showed a slight decrease in bubbles.

In comparison of Examples 3, 7, 4 and 8, the alkylpolyglucoside carboxylate had slightly lower foaming power than the alkylpolyglucoside sulfonate, but the washing power was not different.

Further, when the amphoteric surfactant alkylamine oxide was used in the comparison of Comparative Examples 1 and 2, bubble power and detergency were better, and when the electrolyte was used in Example 6 and Comparative Example 3, foaming power and detergency were further increased And it was found. It was also found that the alkylpolyglucoside sulfonates were slightly superior to the alkylpolyglucosides in the foaming power and the washing power in the comparison of Comparative Examples 3 and 4.

In the case of Comparative Example 1, although it had excellent bubble power and dish washing power, the rinseability was poor and it was difficult to use as a cleaning agent composition (see Experimental Example 2).

Further, as shown in Table 8, the detergent compositions of Examples (Examples 9 to 12, 17 to 20) were excellent in bubble strength and detergency. However, it was confirmed that when the amphoteric surfactant was not used (Comparative Example 6) or when the sodium citrate electrolyte was not used (Comparative Examples 7 and 8), the foamability and cleaning power of the detergent composition were reduced.

In comparison of Comparative Examples 5 and 6, when the amphoteric surfactant alkylamine oxide was used, bubble power and detergency were better, and when alkyl polyglucoside carboxylate was used in comparison with alkyl polyglucoside in Comparative Examples 7 and 8, And washing power.

However, when the alkylpolyglucoside carboxylate was compared with the alkylpolyglucoside alone in the comparison of Comparative Example 5 and Examples 9 to 12, it was found that the alkylpolyglucoside carboxylate was more excellent in the foaming power and cleaning power.

The cocoamidopropyl betaine used as the nonionic surfactant in Examples 13 to 16 was found to have excellent foamability and detergency when it was used in an amount of 5.8% by weight or more.

In Examples 16 to 20, which contained the fermentation filtrate of Saccharomyces, the bubble power and the washing power were not reduced to 0.1 wt% of the fermentation filtrate content of the saccharomyces but the bubble power and the washing power were slightly decreased at 1 wt%.

Experimental Example 2. Evaluation of rinsability

Thirty sheets of the dish were coated with the contamination shown in Table 4, and a certain amount of water, a cleaning agent (cleaning agent composition of Examples and Comparative Examples) was applied to the wringer to bubble out, and then 30 dishes were rubbed with the same number of times. The rinse water and the rinse time were measured at a constant flow rate. The rinse end point was evaluated as a point where the bubbles disappeared visually, and the feel when rubbed by hand at the rinse end point was evaluated. The results are shown in Table 9.

≪ Ripperability evaluation standard &

×: Poor

△: Normal

○: Excellent

◎: Best

Comparative Example Example One 2 3 4 One 2 3 4 5 6 7 8 Bubble power 100 50 65 85 100 100 95 90 100 100 90 85 Dish washing power ○ △ △ △ ○ ○ ○ ○ ○ ○ ○ ○ Rinseability X X △ ○ ○ ○ ◎ ◎ ○ ○ ◎ ◎

As shown in Table 9, it was confirmed that the rinseability was improved as the amounts of alkyl glucoside carboxylate and alkyl glucoside sulfonate used were increased in Examples 1 to 8. However, Comparative Example 2, which did not use an alkylamine oxide, reduced the slip by the alkylamine oxide, but did not rinse out quickly due to insufficient cleaning power, and Comparative Example 3 was similarly rinsed quickly when not containing the electrolyte .

Example 2 and Example 6 were most suitable for a kitchen detergent composition having excellent rinsing properties without lowering the foaming power and detergency.

Experimental Example 3. Evaluation of moisturizing ability

A moisturizing property evaluation was carried out by comparing a detergent composition (Example 19) containing saccharomyces filtrate with a conventional detergent composition (Example 12) containing no saccharomyces filtrate.

Specifically, the wettability was measured using wash-off corneometry after washing the wash composition for 10 days with the detergent composition once a day for 7 days, and shown in FIG.

As shown in Fig. 1, the cleaning composition of the example containing saccharomyces filtrate was superior to that of Example 12 in improving the moisture retention.

Experimental Example 4. Determination of the content of saccharomyces filtrate

In order to determine the content of the saccharomyces filtrate, evaluation was made by the sensory evaluation method for Examples 17 to 20. For the experimental method, ten specimens were used three times daily for each detergent, and five types of detergents were compared and evaluated based on Table 10.

As a comparative example, the contents of surfactant, regulator and other additives were controlled in the same manner and no saccharomyces fermentation filtrate was contained.

The evaluation criteria of the moisture-absorbing ability are shown in Table 10 below, and the measurement results are shown in Table 11.

Moisture / skin protection evaluation criteria Evaluator score average Evaluation standard sign 3.0 or less Inadequate × 3.0 to 3.5 usually △ 3.5 ~ 4.0 Great ○ 4.0 or higher very best ◎

division Example 12 Example 17 18 19 20 Moisturizing / Skin Protection ○ ○ ◎ ◎ ◎

In the case of Example 17, there was no increase in the moisturizing effect as compared with Example 12 which did not contain saccharomyces. In Example 20, as shown in Table 8, the washing power and the rinsing power were higher than those of Examples 12, 17, 18 and 19 The content of saccharomyces is 0.01 to 0.1% by weight.

Claims (9)

0.1 to 30% by weight of a sugar-based anionic surfactant based on the total weight of the composition; 1 to 20% by weight of a nonionic surfactant; And 1 to 10% by weight of an electrolyte.
The method according to claim 1,
Wherein the sugar anionic surfactant is a polyglucoside anionic surfactant.
3. The method of claim 2,
Wherein the polyglucoside anionic surfactant comprises at least one selected from the group consisting of alkyl polyglucoside carboxylate and alkyl polyglucoside sulfonate.
The method according to claim 1,
Wherein the nonionic surfactant comprises at least one selected from the group consisting of primary or secondary alcohol-based, alkylpolyglucoside-based, and fatty acid amide-based nonionic surfactants containing 1 to 25 moles of ethylene oxide.
The method according to claim 1,
The electrolyte may be selected from the group consisting of citrate salts, chlorides, bromides, iodides, acetates, bicarbonates, phosphates, citrates, sulfates, polyphosphates, pyrophosphates, triphosphates, tetrapolines, silicates, metasilicates, polysilicates, carbonates, ≪ / RTI > wherein the detergent composition comprises at least one detergent composition.
The method according to claim 1,
At least one amphoteric surfactant selected from the group consisting of fatty acid amide based betaines having 8 to 22 carbon atoms and amine based alkyl amine oxides having 8 to 22 carbon atoms.
The method according to claim 1,
0.001 to 1% by weight of a saccharomyces fermentation filtrate.
8. The method of claim 7,
Wherein the saccharomyces fermentation filtrate is 0.01 to 0.1% by weight.
The method according to claim 1,
A detergent composition for use in the cleaning of kitchen tools.

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