CN102978030A - Multifunctional detergent and preparation method thereof - Google Patents

Multifunctional detergent and preparation method thereof Download PDF

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Publication number
CN102978030A
CN102978030A CN2012105235112A CN201210523511A CN102978030A CN 102978030 A CN102978030 A CN 102978030A CN 2012105235112 A CN2012105235112 A CN 2012105235112A CN 201210523511 A CN201210523511 A CN 201210523511A CN 102978030 A CN102978030 A CN 102978030A
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Prior art keywords
sodium sulfate
detergent
multifunctional detergent
multifunctional
detergent according
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CN2012105235112A
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Chinese (zh)
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CN102978030B (en
Inventor
李祖敏
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Zhejiang Yuanmin Science & Technology Co Ltd
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Zhejiang Yuanmin Science & Technology Co Ltd
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Priority to CN201210523511.2A priority Critical patent/CN102978030B/en
Publication of CN102978030A publication Critical patent/CN102978030A/en
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Publication of CN102978030B publication Critical patent/CN102978030B/en
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Abstract

The invention provides a multifunctional detergent and a preparation method thereof. The formula of the multifunctional detergent comprises fatty alcohol ether sodium sulfate, fatty acid methyl ester sulfonate and glycine betaine at a weight ratio of 4-7:2-5:1-3. The formula also can comprise dodecylbenzene sulfonic acid, alpha-alkenyl sulphonate and an addition agent. The detergent provided by the invention has the double advantages of forming by adding water and good washing effect and is comparative to more than 10 times of liquid detergent on the market in terms of effect; and the detergent provided by the invention can be dissolved under any conditions when encountering water, has low simulation and can be degraded, thus the environmental pollution and damage are reduced and the detergent is an environment-friendly product. The preparation method of the detergent is simple, low in cost and suitable for industrial production.

Description

Multifunctional detergent and preparation method thereof
Technical field
The present invention relates to the washing composition technical field, refer to especially a kind of multifunctional detergent and preparation method thereof.
Background technology
On the market washing composition that three kinds of powderies are generally arranged is arranged now, a kind of is pure tensio-active agent powdery monomer, bad as the effect of product application.The second is the civilian industry powdered detergent of everybody more clearly as similar washing powder, and it is take inorganic salt as main, a kind of powdered detergent of tensio-active agent for assisting.Also have part in the prescription of its product, the biological limitation that adds materials is arranged and can't be as being widely used and promoting.The third is to be the tensio-active agent that major ingredient adds sub-fraction again with Mierocrystalline cellulose, thin up becomes the outward appearance denseness of common liquid detergent on the similar market, outward appearance tradition after this product dilution does not more reach cleaning performance in practical application, and the quality guaranteed period of finished product is short apt to deteriorate.
Summary of the invention
The present invention proposes a kind of multifunctional detergent and preparation method thereof, the effect of this washing composition be on the market more than 10 times, and have the moulding of being watered and the good two-fold advantage of washing effect.
Technical scheme of the present invention is achieved in that
A kind of multifunctional detergent, its prescription comprises: fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate and trimethyl-glycine; Its weight ratio is 4-7:2-5:1-3.
As preferred technical scheme, also comprise Witco 1298 Soft Acid, a-alkenyl sulphonate and pH adjusting agent in the described prescription.
As preferred technical scheme, the mass percent of described fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate, trimethyl-glycine, Witco 1298 Soft Acid, a-alkenyl sulphonate, auxiliary agent is
20-35%:10-25%:5-15%:10-25%:5-15%:31-50%。
As preferred technical scheme, also comprise pH adjusting agent in the described prescription.Be used for regulating the pH value of prescription, owing to all be neutral material in this prescription, therefore, generally do not need to add pH adjusting agent.
As preferred technical scheme, described fatty alcohol-ether sodium sulfate is polyoxyethylenated alcohol sodium sulfate.
As preferred technical scheme, described trimethyl-glycine is cocamidopropyl betaine.
As preferred technical scheme, described auxiliary agent is sodium sulfate, or sodium sulfate and Na2EDTA.
As preferred technical scheme, described pH adjusting agent is citric acid.
It is the main powdered detergent that adds the tensio-active agent of sub-fraction that this product does not comprise by Mierocrystalline cellulose.
A kind of preparation method of multifunctional detergent comprises:
Step S1: poly alkyl alcohol ether sodium sulfate, Witco 1298 Soft Acid, α-sodium olefin sulfonate, fatty acid methyl ester sulfonate, trimethyl-glycine and auxiliary agent are mixed;
Step S2 the temperature 80-150 ℃ of moulding of dusting, and get final product the mixed solution behind the above-mentioned adjusting pH.
As preferred technical scheme, the time of the described moulding of dusting is 1-3min.
Beneficial effect:
(1) washing composition of the present invention has the moulding of being watered and the good two-fold advantage of washing effect;
(2) washing composition of the present invention is equivalent on the market effect of liquid washing agent more than 10 times;
(3) product of the present invention can dissolve at any condition chance water, stimulates little, degradable, and environmental contamination reduction and harm are the products of environment-friendly type;
(4) preparation method is simple, and cost is low, is suitable for suitability for industrialized production.
Embodiment
The below will be clearly and completely described the technical scheme in the embodiment of the invention, and obviously, described embodiment only is the present invention's part embodiment, rather than whole embodiment.Based on the embodiment among the present invention, those of ordinary skills belong to the scope of protection of the invention not making the every other embodiment that obtains under the creative work prerequisite.
A kind of multifunctional detergent of the present invention, the material in its prescription is the commercially available material that is easy to get.The present invention is through rationally composite, and through the high temperature moulding of dusting by kinds of surface promoting agent and inorganic additive.According to concrete needs, be watered by a certain percentage the conventional shape outward appearance that can form 5-15 times of effective concentration, have that stronger decontamination is deoiled, the comprehensive multifunctional washing composition of performance gentleness.The prescription of liquid washing agent more than 10 times on the suitable market of this product, existing with our company now with annual 20000 tons productivity, namely be equivalent to the quantity more than 200,000 tons on the market.Greatly reduce and produce institute's some electric energy that produced and thing energy, and the waste gas of a large amount of dischargings that produce at transport point, reducing social energy loss and also improved clean environment simultaneously, social benefit is huge, has very strong market competition advantage.Product of the present invention is met water in any condition and can be dissolved, and stimulates little, degradable, and environmental contamination reduction and harm are the products of environment-friendly type.The product key point be different from some powdered detergents on other market they can not be watered moulding and some can moulding but product that can not corresponding washing effect, this product has just been made the washing composition that has outward appearance and identical function is arranged in conjunction with their two kinds of advantages.It is the main powdered detergent that adds the tensio-active agent of sub-fraction that this product does not comprise by Mierocrystalline cellulose.
Embodiment 1
Multifunctional detergent 1, its prescription comprises: fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate and trimethyl-glycine; Its weight ratio is 4:2:3.
Its preparation comprises:
Step S1: above-mentioned substance is mixed;
Step S2 delivers to cat head with the material that mixes by high-pressure pump, in 80-150 ℃ of moulding of dusting of tower body temperature, and time 1-3min, and get final product.
Embodiment 2
Multifunctional detergent 2, its prescription comprises: the mass percent of fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate, trimethyl-glycine, Witco 1298 Soft Acid, a-alkenyl sulphonate, sodium sulfate is 20:25:9:10:5:31.
Its preparation method comprises:
Step S1: poly alkyl alcohol ether sodium sulfate, Witco 1298 Soft Acid, α-sodium olefin sulfonate, fatty acid methyl ester sulfonate and trimethyl-glycine are mixed, add afterwards sodium sulfate and obtain mixed solution;
Step S2 delivers to cat head with above-mentioned mixed solution by high-pressure pump, and the temperature 80-150 ℃ of moulding of dusting, the time is 3min and get final product.
Embodiment 3
Multifunctional detergent 3, its prescription comprises: the mass percent of fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate, trimethyl-glycine, Witco 1298 Soft Acid, a-alkenyl sulphonate, sodium sulfate is 20:10:5:10:5:50.
Preparation and embodiment 2 are together.
Embodiment 4
Multifunctional detergent 4, its prescription comprises: the mass percent of fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate, trimethyl-glycine, Witco 1298 Soft Acid, a-alkenyl sulphonate, Na2EDTA and sodium sulfate is 25:15:6:12:8:1:33.
Its preparation method comprises:
Step S1: fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate, trimethyl-glycine, Witco 1298 Soft Acid, a-alkenyl sulphonate, Na2EDTA and sodium sulfate are mixed, and adding afterwards such as the lemon acid for adjusting pH is 6.5-7.5;
Step S2 delivers to cat head with above-mentioned mixed solution by high-pressure pump, and in 80-150 ℃ of moulding of dusting of tower body temperature, the time is 1-3min and get final product.
Embodiment 5
Multifunctional detergent 5, its prescription comprises: fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate and trimethyl-glycine; Its weight ratio is 7:3:2.
Product of the present invention can add 5 parts to 15 parts water, and water stirs until added water adds while add, and just can convert into the washing composition of different mass.Product of the present invention has the moulding of being watered and the good two-fold advantage of washing effect.
The above only is preferred embodiment of the present invention, and is in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, is equal to replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (10)

1. multifunctional detergent, its prescription comprises: fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate and trimethyl-glycine; Its weight ratio is 4-7:2-5:1-3.
2. a kind of multifunctional detergent according to claim 1 is characterized in that, also comprises Witco 1298 Soft Acid, a-alkenyl sulphonate and auxiliary agent in the described prescription.
3. a kind of multifunctional detergent according to claim 2 is characterized in that, the mass percent of described fatty alcohol-ether sodium sulfate, fatty acid methyl ester sulfonate, trimethyl-glycine, Witco 1298 Soft Acid, a-alkenyl sulphonate, auxiliary agent is
20-35%:10-25%:5-15%:10-25%:5-15%:31-50%。
4. a kind of multifunctional detergent according to claim 2 is characterized in that, also comprises pH adjusting agent in the described prescription.
5. a kind of multifunctional detergent according to claim 1 and 2 is characterized in that, described fatty alcohol-ether sodium sulfate is polyoxyethylenated alcohol sodium sulfate.
6. a kind of multifunctional detergent according to claim 1 and 2 is characterized in that, described trimethyl-glycine is cocamidopropyl betaine.
7. a kind of multifunctional detergent according to claim 2 is characterized in that, described auxiliary agent is sodium sulfate, or sodium sulfate and Na2EDTA.
8. a kind of multifunctional detergent according to claim 4 is characterized in that, described pH adjusting agent is citric acid.
9. the preparation method of a multifunctional detergent comprises:
Step S 1: poly alkyl alcohol ether sodium sulfate, Witco 1298 Soft Acid, α-sodium olefin sulfonate, fatty acid methyl ester sulfonate, trimethyl-glycine and auxiliary agent are mixed; Its mass percent is
20-35%:10-25%:5-15%:10-25%:5-15%:31-50%;
Step S2 the temperature 80-150 ℃ of moulding of dusting, and get final product the mixed solution behind the above-mentioned adjusting pH.
10. the preparation method of a kind of multifunctional detergent according to claim 9 is characterized in that, the time of the described moulding of dusting is 1-3min.
CN201210523511.2A 2012-12-04 2012-12-04 Multifunctional detergent and preparation method thereof Expired - Fee Related CN102978030B (en)

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Application Number Priority Date Filing Date Title
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CN102978030A true CN102978030A (en) 2013-03-20
CN102978030B CN102978030B (en) 2014-04-16

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111793529A (en) * 2020-08-10 2020-10-20 訾孟州 Natural composite detergent of high-purity pineapple enzyme and preparation method thereof
CN112251299A (en) * 2020-10-21 2021-01-22 沈阳脱普生活用品服务有限公司上海分公司 High-concentration detergent and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102051278A (en) * 2011-01-24 2011-05-11 北京洛娃日化有限公司 All-purpose cleaning agent
CN102559406A (en) * 2011-08-06 2012-07-11 威莱(广州)日用品有限公司 Compound type cleaning solution

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102051278A (en) * 2011-01-24 2011-05-11 北京洛娃日化有限公司 All-purpose cleaning agent
CN102559406A (en) * 2011-08-06 2012-07-11 威莱(广州)日用品有限公司 Compound type cleaning solution

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111793529A (en) * 2020-08-10 2020-10-20 訾孟州 Natural composite detergent of high-purity pineapple enzyme and preparation method thereof
CN112251299A (en) * 2020-10-21 2021-01-22 沈阳脱普生活用品服务有限公司上海分公司 High-concentration detergent and preparation method thereof

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Denomination of invention: Multifunctional detergent and preparation method thereof

Effective date of registration: 20171227

Granted publication date: 20140416

Pledgee: Zhejiang Cangnan rural commercial bank Limited by Share Ltd.

Pledgor: ZHEJIANG YUANMIN SCIENCE & TECHNOLOGY Co.,Ltd.

Registration number: 2017330000332

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PC01 Cancellation of the registration of the contract for pledge of patent right

Date of cancellation: 20210312

Granted publication date: 20140416

Pledgee: Zhejiang Cangnan rural commercial bank Limited by Share Ltd.

Pledgor: ZHEJIANG YUANMIN SCIENCE & TECHNOLOGY Co.,Ltd.

Registration number: 2017330000332

CF01 Termination of patent right due to non-payment of annual fee
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Termination date: 20211204