CN102321506B - Special soap granule for enzyme-added laundry soap and preparation method thereof - Google Patents
Special soap granule for enzyme-added laundry soap and preparation method thereof Download PDFInfo
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- CN102321506B CN102321506B CN 201110252153 CN201110252153A CN102321506B CN 102321506 B CN102321506 B CN 102321506B CN 201110252153 CN201110252153 CN 201110252153 CN 201110252153 A CN201110252153 A CN 201110252153A CN 102321506 B CN102321506 B CN 102321506B
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Abstract
The invention discloses a special soap granule for enzyme-added laundry soap and a preparation method thereof, relates to the fields of soap granules for laundry soap and production thereof, and solves the problem of unstable addition of enzyme preparations in the development of enzyme-added laundry soap. The special soap granule for enzyme-added laundry soap is prepared by the following raw materials by weight: 10.8-13.2 parts of caustic soda, 66-76 parts of mixed fatty acids, 1-5 parts of glycerin, 1-5 parts of borax, 3-10 parts of sodium silicate, 0.2-1 parts of activated clay, and 0.08-0.15 parts of hydroxyethylidene diphosphonic acid. By selecting appropriate components and ratios thereof and by modifying the preparation method, a special soap granule for enzyme-added laundry soap with a highly-stable enzyme preparation is produced; in practical production and application, the stability of the enzyme preparation in the enzyme-added laundry soap is maintained, and the soap has very good decontamination and washing effect.
Description
Technical field
The present invention relates to a kind of washing soap with neat soap and production field thereof, relate in particular to a kind of Special soap granule for enzyme-added laundry soap and preparation method thereof.
Background technology
Soap is the human articles for washing with the longest history that uses, the so far history in existing thousands of years.Since 18th century, developing rapidly of several centuries passed through in soap industry, and to 20 middle of century, under the pressure of synthetic detergent fast development, soap output glides year by year.The gradually atrophy of market capacity after reaching the highest 1,800,000 tons historical output in 1989 of soap series products, basicly stable level ten thousand tons of 70-80 after 2000.In recent years, along with the growing interest of people to quality product and environmental safety, soap becomes again one of focus of concern.Product with the every other abundant marketization is the same, the soap series products has moved towards specialization, the differentiation epoch of the aspects such as form, function, characteristic, the concept of product and function demand are further segmented, the heavy dirt positions such as the collar of the multiplex washing soap cleaning of human consumer clothes, cuff, protein ingredient is more in the corresponding dirt, yet common washing soap can not thoroughly be cleaned dirt.If in the soap series products, add zymin then can significantly improve clean effect, the demand that product performance is increased day by day to adapt to the human consumer.
At present, zymin is mainly used in detergent industry, often adds in the washing powder with the form of solid preparation, to strengthen its soil removability.Analysis-by-synthesis, several factors that zymin is had the greatest impact comprise pH value, storing temp, moisture content, metal ion, stablizer of product etc., therefore the main points of enzymatic household soap exploitation comprise: with the important core that stabilizes to of zymin, create the pH value environment of best proportion of surfactant, the best, the metal ion that shielding is harmful, useful metal ion and other stablizers are added in screening.For washing soap, because its moisture content is higher, the stability problem of zymin fails to be solved well always, thereby has affected the exploitation of enzymatic household soap.
Summary of the invention
The present invention exists zymin to add unsettled problem for solving in the enzymatic household soap exploitation, and a kind of Special soap granule for enzyme-added laundry soap and preparation method thereof is provided.
For achieving the above object, the present invention is by the following technical solutions:
A kind of Special soap granule for enzyme-added laundry soap, the material that is following row weight part are the raw material preparation:
Caustic soda: 10.8 ~ 13.2
Mixed fatty acid: 66 ~ 76
Glycerine: 1 ~ 5
Borax: 1 ~ 5
Flower bulb alkali: 3 ~ 10
Atlapulgite: 0.2 ~ 1
Hydroxy ethylene diphosphonic acid: 0.08 ~ 0.15.
Further, the preparation method of above-mentioned Special soap granule for enzyme-added laundry soap, may further comprise the steps: it is 30% solution that caustic soda is dissolved as mass concentration, add and transfer in the cylinder pot, add subsequently mixed fatty acid, uniform stirring 10 minutes, finish neutralization reaction, measure mixture pH value and trace adjustment mixed fatty acid add-on, make the pH value of neutralized reaction product 8.8 ~ 9.2, then be sequentially added into flower bulb alkali, atlapulgite, hydroxy ethylene diphosphonic acid adds borax after with deionized water dissolving simultaneously, add at last glycerine and continue to stir after be delivered to the moisture eliminator drying, namely get Special soap granule for enzyme-added laundry soap.
Utilize Special soap granule for enzyme-added laundry soap described above to prepare the method for enzymatic household soap, may further comprise the steps: according to 100 parts of Special soap granule for enzyme-added laundry soaps, 0.01 ~ 0.03 part of zymin, 0.03 ~ 0.1 part in essence, BHT0.001 ~ 0.002 part, an amount of deionized water and pigment, add successively in the spice post, successively through refining, grinding, shaping, printing, packing gets product at last after stirring.
Further, when the preparation enzymatic household soap, all process steps temperature is between 25-50 ℃.
Described zymin is Sumizyme MP, alkali cellulose enzyme or alkaline lipase.
What pay special attention to is, the effect of the borax among the present invention and the coordinated of glycerine performance zymin stablizer, its mechanism is: borax at first is hydrolyzed into boric acid, then with glycerine generation esterification, generation contains the stable complex of two six-membered cyclic structures, by hydrogen bond and zymin combination, its huge steric hindrance can stabilized enzyme formulations three-dimensional structure, reduce the inactivation of enzyme, thereby greatly increase the stability of zymin, therefore must guarantee that the percentage composition of glycerine and borax can not be excessively low, otherwise can greatly reduce in the enzymatic household soap finished product activity keeping time of zymin.
The present invention does not use the strong metal ion chelation agents of character such as traditional ethylenediamine tetraacetic acid (EDTA) 2 sodium salts, ethylenediamine tetraacetic acid (EDTA) 4 sodium salts, tri-polyphosphate and nitrilotriacetic acid sodium salt, do not use reducing substances and the oxidizing substances such as traditional sodium sulfite salt, rongalite, thiosulfuric acid sodium salt, hydrogen peroxide, percarbonate, persulphate, clorox, can shield efficiently harmful metal ion, useful metal ion and other stablizers are added in screening.
The present invention is by selecting suitable component and proportioning thereof and the preparation method suitably being improved, produce the Special soap granule for enzyme-added laundry soap with high stability zymin, use through actual production, the stability of zymin is kept in the enzymatic household soap, has good decontamination washing effect.
Embodiment
Below in conjunction with specific embodiment, the present invention is done to set forth further.
Embodiment 1
A kind of Special soap granule for enzyme-added laundry soap, the material of following row weight part are the raw material preparation:
Caustic soda 10.8
Mixed fatty acid: 66
Glycerine: 1
Borax: 3
Flower bulb alkali: 3
Atlapulgite: 1
Hydroxy ethylene diphosphonic acid: 0.1.
Utilize above-mentioned raw materials to prepare the preparation method of Special soap granule for enzyme-added laundry soap: it is 30% the aqueous solution that caustic soda is dissolved as mass concentration, add and transfer in the cylinder pot, add subsequently mixed fatty acid, uniform stirring 10 minutes, finish neutralization reaction, measure mixture pH value and trace adjustment mixed fatty acid add-on, so that the pH value of product is 9, then be sequentially added into flower bulb alkali, atlapulgite, hydroxy ethylene diphosphonic acid, simultaneously borax is added after with deionized water dissolving, add at last glycerine and continue to stir after be delivered to the moisture eliminator drying, namely get Special soap granule for enzyme-added laundry soap.
Utilize the above-mentioned Special soap granule for enzyme-added laundry soap that makes to prepare the method for enzymatic household soap:, between 25-35 ℃, with 100 parts of Special soap granule for enzyme-added laundry soaps, 0.01 part of alkaline lipase, 0.05 part in essence, BHT0.002 part, an amount of deionized water and pigment, add successively in the spice post, after stirring, through refining, grinding, shaping, printing, packing gets product at last successively.
Embodiment 2
A kind of Special soap granule for enzyme-added laundry soap, the material of following row weight part are the raw material preparation:
Caustic soda 11.4
Mixed fatty acid: 72
Glycerine: 2
Borax: 4
Flower bulb alkali: 5
Atlapulgite: 0.6
Hydroxy ethylene diphosphonic acid: 0.15.
Utilize above-mentioned raw materials to prepare the preparation method of Special soap granule for enzyme-added laundry soap: it is 30% the aqueous solution that caustic soda is dissolved as mass concentration, add and transfer in the cylinder pot, add subsequently mixed fatty acid, uniform stirring 10 minutes, finish neutralization reaction, measure mixture pH value and trace adjustment mixed fatty acid add-on, so that the pH value of product is 8.8, then be sequentially added into flower bulb alkali, atlapulgite, hydroxy ethylene diphosphonic acid, simultaneously borax is added after with deionized water dissolving, add at last glycerine and continue to stir after be delivered to the moisture eliminator drying, namely get Special soap granule for enzyme-added laundry soap.
Utilize the above-mentioned Special soap granule for enzyme-added laundry soap that makes to prepare the method for enzymatic household soap:, between 35-50 ℃, with 100 parts of Special soap granule for enzyme-added laundry soaps, 0.03 part of alkaline lipase, 0.03 part in essence, BHT0.01 part, an amount of deionized water and pigment, add successively in the spice post, after stirring, through refining, grinding, shaping, printing, packing gets product at last successively.
Embodiment 3
A kind of Special soap granule for enzyme-added laundry soap, the material of following row weight part are the raw material preparation:
Caustic soda 12
Mixed fatty acid: 76
Glycerine: 3
Borax: 1
Flower bulb alkali: 10
Atlapulgite: 0.8
Hydroxy ethylene diphosphonic acid: 0.08.
Utilize above-mentioned raw materials to prepare the preparation method of Special soap granule for enzyme-added laundry soap: it is 30% the aqueous solution that caustic soda is dissolved as mass concentration, add and transfer in the cylinder pot, add subsequently mixed fatty acid, uniform stirring 10 minutes, finish neutralization reaction, measure mixture pH value and trace adjustment mixed fatty acid add-on, so that the pH value of product is 9.2, then be sequentially added into flower bulb alkali, atlapulgite, hydroxy ethylene diphosphonic acid, simultaneously borax is added after with deionized water dissolving, add at last glycerine and continue to stir after be delivered to the moisture eliminator drying, namely get Special soap granule for enzyme-added laundry soap.
Utilize the above-mentioned Special soap granule for enzyme-added laundry soap that makes to prepare the method for enzymatic household soap:, between 35-50 ℃, with 100 parts of Special soap granule for enzyme-added laundry soaps, 0.02 part of alkali cellulose enzyme, 0.08 part in essence, BHT0.01 part, an amount of deionized water and pigment, add successively in the spice post, after stirring, through refining, grinding, shaping, printing, packing gets product at last successively.
Embodiment 4
A kind of Special soap granule for enzyme-added laundry soap, the material of following row weight part are the raw material preparation:
Caustic soda 12.6
Mixed fatty acid: 68
Glycerine: 4
Borax: 5
Flower bulb alkali: 7
Atlapulgite: 0.2
Hydroxy ethylene diphosphonic acid: 0.12.
Utilize above-mentioned raw materials to prepare the preparation method of Special soap granule for enzyme-added laundry soap: it is 30% the aqueous solution that caustic soda is dissolved as mass concentration, add and transfer in the cylinder pot, add subsequently mixed fatty acid, uniform stirring 10 minutes, finish neutralization reaction, measure mixture pH value and trace adjustment mixed fatty acid add-on, so that the pH value of product is 9, then be sequentially added into flower bulb alkali, atlapulgite, hydroxy ethylene diphosphonic acid, simultaneously borax is added after with deionized water dissolving, add at last glycerine and continue to stir after be delivered to the moisture eliminator drying, namely get Special soap granule for enzyme-added laundry soap.
Utilize the above-mentioned Special soap granule for enzyme-added laundry soap that makes to prepare the method for enzymatic household soap:, between 30-40 ℃, with 100 parts of Special soap granule for enzyme-added laundry soaps, 0.02 part of alkali cellulose enzyme, 0.05 part in essence, BHT0.01 part, an amount of deionized water and pigment, add successively in the spice post, after stirring, through refining, grinding, shaping, printing, packing gets product at last successively.
Embodiment 5
A kind of Special soap granule for enzyme-added laundry soap, the material of following row weight part are the raw material preparation:
Caustic soda 13.2
Mixed fatty acid: 70
Glycerine: 5
Borax: 2
Flower bulb alkali: 9
Atlapulgite: 0.4
Hydroxy ethylene diphosphonic acid: 0.13.
Utilize above-mentioned raw materials to prepare the preparation method of Special soap granule for enzyme-added laundry soap: it is 30% the aqueous solution that caustic soda is dissolved as mass concentration, add and transfer in the cylinder pot, add subsequently mixed fatty acid, uniform stirring 10 minutes, finish neutralization reaction, measure mixture pH value and trace adjustment mixed fatty acid add-on, so that the pH value of product is 9, then be sequentially added into flower bulb alkali, atlapulgite, hydroxy ethylene diphosphonic acid, simultaneously borax is added after with deionized water dissolving, add at last glycerine and continue to stir after be delivered to the moisture eliminator drying, namely get Special soap granule for enzyme-added laundry soap.
Utilize the above-mentioned Special soap granule for enzyme-added laundry soap that makes to prepare the method for enzymatic household soap:, between 35-50 ℃, with 100 parts of Special soap granule for enzyme-added laundry soaps, 0.03 part of Sumizyme MP, 0.07 part in essence, BHT0.02 part, an amount of deionized water and pigment, add successively in the spice post, after stirring, through refining, grinding, shaping, printing, packing gets product at last successively.
Claims (2)
1. Special soap granule for enzyme-added laundry soap, the material that it is characterized in that following row weight part are the raw material preparation:
Caustic soda: 10.8 ~ 13.2
Mixed fatty acid: 66 ~ 76
Glycerine: 1 ~ 5
Borax: 1 ~ 5
Flower bulb alkali: 3 ~ 10
Atlapulgite: 0.2 ~ 1
Hydroxy ethylene diphosphonic acid: 0.08 ~ 0.15;
During preparation, may further comprise the steps: it is 30% solution that caustic soda is dissolved as mass concentration, add and transfer in the cylinder pot, add subsequently mixed fatty acid, uniform stirring 10 minutes, finish neutralization reaction, measure mixture pH value and trace adjustment mixed fatty acid add-on, make the pH value of neutralized reaction product 8.8 ~ 9.2, then be sequentially added into flower bulb alkali, atlapulgite, hydroxy ethylene diphosphonic acid, simultaneously borax is added after with deionized water dissolving, add at last glycerine and continue to stir after be delivered to the moisture eliminator drying, namely get Special soap granule for enzyme-added laundry soap.
2. utilize Special soap granule for enzyme-added laundry soap claimed in claim 1 to prepare the method for enzymatic household soap, it is characterized in that may further comprise the steps: according to 100 parts of Special soap granule for enzyme-added laundry soaps, 0.01 ~ 0.03 part of zymin, 0.03 ~ 0.1 part in essence, BHT0.001 ~ 0.002 part, an amount of deionized water and pigment, add successively in the spice post, successively through refining, grinding, shaping, printing, packing gets product at last after stirring;
Wherein all process steps temperature is between 25-50 ℃;
Described zymin is Sumizyme MP, alkali cellulose enzyme or alkaline lipase.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201110252153 CN102321506B (en) | 2011-08-30 | 2011-08-30 | Special soap granule for enzyme-added laundry soap and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201110252153 CN102321506B (en) | 2011-08-30 | 2011-08-30 | Special soap granule for enzyme-added laundry soap and preparation method thereof |
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| CN102321506A CN102321506A (en) | 2012-01-18 |
| CN102321506B true CN102321506B (en) | 2013-01-30 |
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| CN107201282A (en) * | 2017-05-11 | 2017-09-26 | 跨越生物科技（滁州）有限公司 | A kind of environment friendly laundry soap |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101319173A (en) * | 2008-07-21 | 2008-12-10 | 广州立白企业集团有限公司 | Enzymatic household soap and method of preparing the same |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101319173A (en) * | 2008-07-21 | 2008-12-10 | 广州立白企业集团有限公司 | Enzymatic household soap and method of preparing the same |
Non-Patent Citations (1)
| Title |
|---|
| 西北农学院《农用化学基础知识》编写组.肥皂和合成洗涤剂.《农用化学基础知识》.陕西人民出版社,1977, * |
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Effective date of registration: 20190131 Address after: No. 376 Hongqi East Street, Yuncheng City, Shanxi Province Patentee after: Shanxi Coking Coal Yuncheng Salinization Group Co., Ltd. Address before: 044000 No. 294 Jiefang Road, Yuncheng, Shanxi Province Patentee before: Nanfeng Chemical Group Co., Ltd. |
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