CN102510886B - 成膜聚合物和有机中空粒子用于涂层剂的用途 - Google Patents

成膜聚合物和有机中空粒子用于涂层剂的用途 Download PDF

Info

Publication number
CN102510886B
CN102510886B CN201080042350.4A CN201080042350A CN102510886B CN 102510886 B CN102510886 B CN 102510886B CN 201080042350 A CN201080042350 A CN 201080042350A CN 102510886 B CN102510886 B CN 102510886B
Authority
CN
China
Prior art keywords
acid
weight
purposes
acrylate
minutes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080042350.4A
Other languages
English (en)
Chinese (zh)
Other versions
CN102510886A (zh
Inventor
A·塔奇布雷特
O·瓦格纳
C·提特马什
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN102510886A publication Critical patent/CN102510886A/zh
Application granted granted Critical
Publication of CN102510886B publication Critical patent/CN102510886B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • C08F212/30Sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres
    • C08L2205/20Hollow spheres

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Graft Or Block Polymers (AREA)
CN201080042350.4A 2009-07-22 2010-07-21 成膜聚合物和有机中空粒子用于涂层剂的用途 Expired - Fee Related CN102510886B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09166115 2009-07-22
EP09166115.7 2009-07-22
PCT/EP2010/060512 WO2011009875A1 (de) 2009-07-22 2010-07-21 Verwendung filmbildender polymere und organischer hohlteilchen für beschichtungsmittel

Publications (2)

Publication Number Publication Date
CN102510886A CN102510886A (zh) 2012-06-20
CN102510886B true CN102510886B (zh) 2015-04-29

Family

ID=42831645

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080042350.4A Expired - Fee Related CN102510886B (zh) 2009-07-22 2010-07-21 成膜聚合物和有机中空粒子用于涂层剂的用途

Country Status (9)

Country Link
US (1) US20120129965A1 (enExample)
EP (1) EP2456837A1 (enExample)
JP (1) JP2012533667A (enExample)
KR (1) KR20120089246A (enExample)
CN (1) CN102510886B (enExample)
AU (1) AU2010275263A1 (enExample)
BR (1) BR112012001381A2 (enExample)
CA (1) CA2767620A1 (enExample)
WO (1) WO2011009875A1 (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2754692B1 (en) * 2011-08-31 2018-02-21 Sekisui Plastics Co., Ltd. Resin particle aggregate, method for manufacturing same and application of same
US9303182B2 (en) 2012-06-05 2016-04-05 Dow Global Technologies Llc Aqueous coating composition with improved stability
DE102012213978A1 (de) * 2012-08-07 2014-02-13 Evonik Degussa Gmbh Unterkritisch formulierte Beschichtungen
JP2014070078A (ja) * 2012-09-27 2014-04-21 Nippon Zeon Co Ltd 中空重合体粒子、水性分散液、塗被組成物、および塗被紙
AU2012392106B2 (en) 2012-10-12 2017-03-30 Dow Global Technologies Llc Aqueous coating composition with improved viscosity stability
CN104277649B (zh) * 2013-07-08 2019-09-27 罗门哈斯公司 双峰吸附胶乳
CA2921876C (en) * 2013-08-22 2022-12-13 Basf Se Method for producing emulsion polymerisates
RU2717795C2 (ru) * 2013-08-22 2020-03-25 Басф Се Способ получения эмульсионных полимеров
JPWO2015080132A1 (ja) * 2013-11-28 2017-03-16 日本ゼオン株式会社 顔料分散液、塗被紙用組成物および塗被紙
CN104231173B (zh) * 2014-09-17 2018-08-14 珠海金鸡化工有限公司 羧基丁苯胶乳制备系统及其制备方法
CN104211858B (zh) * 2014-09-17 2015-12-30 珠海金鸡化工有限公司 羧基丁苯胶乳及其制备方法
RU2675564C1 (ru) * 2015-01-21 2018-12-19 БАСФ Коатингс ГмбХ Водные дисперсии, включающие полимеры, изготовляемые многостадийным способом, и композиции покрывающих агентов, включающие их
CN105175614B (zh) * 2015-08-17 2017-11-17 清华大学 彩色中空聚合物乳液及其制备方法
CN109196005B (zh) * 2016-05-04 2021-03-09 巴斯夫欧洲公司 水性聚合物乳胶的制备方法
WO2017206162A1 (en) * 2016-06-03 2017-12-07 Dow Global Technologies Llc Aqueous polymer dispersion and aqueous coating composition comprising the same
PL3523382T3 (pl) * 2016-10-07 2021-05-31 Basf Se Sposób wytwarzania wodnych dyspersji
CN106583884B (zh) * 2016-11-18 2020-02-04 中车齐齐哈尔车辆有限公司 补焊方法
CN110872367B (zh) * 2018-09-04 2023-10-03 罗门哈斯公司 多级聚合物颗粒的水分散体
US20230203317A1 (en) * 2020-05-25 2023-06-29 Dow Global Technologies Llc Aqueous coating composition and process for preparing the same
CN115521407A (zh) * 2022-09-27 2022-12-27 佛山罗斯夫科技有限公司 一种提高耐擦洗的聚丙烯酸铵盐分散剂的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001068753A1 (en) * 2000-03-16 2001-09-20 Ppg Industries Ohio, Inc. Impregnated glass fiber strands and products including the same
CN1477134A (zh) * 2002-08-21 2004-02-25 Jsr株式会社 中空聚合物颗粒及制法,纸涂布组合物、涂布纸及制法
CN1896110A (zh) * 2006-06-27 2007-01-17 上海东升新材料有限公司 一种中空聚合物乳胶粒及其制备方法
CN101223202A (zh) * 2005-07-14 2008-07-16 巴斯福股份公司 生产乳液聚合物的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2501123C2 (de) 1975-01-14 1984-02-09 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Suspensions-Copolymerisaten
JPS60223873A (ja) 1984-04-20 1985-11-08 Dainippon Ink & Chem Inc 水性塗料組成物
US4733005A (en) 1986-04-21 1988-03-22 The Dow Chemical Company Phosphinyl-containing ethylenically unsaturated compounds
CA2140035C (en) 1992-08-19 2003-07-08 Do I. Lee Hollow polymer latex particles
DE19648744A1 (de) 1996-11-25 1998-05-28 Basf Ag Verfahren zur Herstellung einer Polymerdispersion durch radikalische wäßrige Emulsionspolymerisation mit einer kontinuierlich hergestellten wäßrigen Monomerenemulsion
DE19750618A1 (de) 1997-11-14 1999-05-20 Basf Ag Pigmenthaltige Zubereitungen auf der Basis wässriger Polymerisatdispersionen
US6624272B2 (en) * 1999-12-20 2003-09-23 Jsr Corporation Hollow crosslinked cationic polymer particles, method of producing said particles, and paint composition, cationic electrodeposition paint composition, resin composition, filled paper, paper coating composition, and coated paper
JP2008223188A (ja) * 2007-03-14 2008-09-25 Jsr Corp 塗工用組成物、及び塗工体

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001068753A1 (en) * 2000-03-16 2001-09-20 Ppg Industries Ohio, Inc. Impregnated glass fiber strands and products including the same
CN1477134A (zh) * 2002-08-21 2004-02-25 Jsr株式会社 中空聚合物颗粒及制法,纸涂布组合物、涂布纸及制法
CN101223202A (zh) * 2005-07-14 2008-07-16 巴斯福股份公司 生产乳液聚合物的方法
CN1896110A (zh) * 2006-06-27 2007-01-17 上海东升新材料有限公司 一种中空聚合物乳胶粒及其制备方法

Also Published As

Publication number Publication date
KR20120089246A (ko) 2012-08-09
CA2767620A1 (en) 2011-01-27
EP2456837A1 (de) 2012-05-30
BR112012001381A2 (pt) 2016-04-05
WO2011009875A1 (de) 2011-01-27
AU2010275263A1 (en) 2012-02-16
CN102510886A (zh) 2012-06-20
JP2012533667A (ja) 2012-12-27
US20120129965A1 (en) 2012-05-24

Similar Documents

Publication Publication Date Title
CN102510886B (zh) 成膜聚合物和有机中空粒子用于涂层剂的用途
JP2012533667A5 (enExample)
RU2717795C2 (ru) Способ получения эмульсионных полимеров
CN104487509B (zh) 水性粘合剂组合物
KR102270311B1 (ko) 에멀젼 중합체의 제조 방법
RU2754822C2 (ru) Способ получения водных дисперсий
CN120648312A (zh) 具有改善的粘附性的涂料
NZ716868B2 (en) Method for producing emulsion polymerisates

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150429

Termination date: 20190721

CF01 Termination of patent right due to non-payment of annual fee