CN102503667A - Foliage fertilizer and preparation method thereof - Google Patents
Foliage fertilizer and preparation method thereof Download PDFInfo
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- CN102503667A CN102503667A CN2011103224636A CN201110322463A CN102503667A CN 102503667 A CN102503667 A CN 102503667A CN 2011103224636 A CN2011103224636 A CN 2011103224636A CN 201110322463 A CN201110322463 A CN 201110322463A CN 102503667 A CN102503667 A CN 102503667A
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Abstract
The invention provides a foliage fertilizer and a preparation method thereof. The foliage fertilizer comprises the following components in percentage by weight: 1-10% of chitosan, 10-25% of bamboo vinegar, 0.5-3% of surfactant, 5-15% of urea, 2-8% of potassium hydroxide, 5-10% of ammonium monoacid phosphate and the balance of water. The foliage fertilizer is the mixture of bamboo vinegar and chitosan; after being applied to the plant foliage, the foliage fertilizer can directly increase the concentration of sugar in the crop, promote the growth of the crop root system, induce the crop to generate multiple anti-disease substances, and have strong actions on inhibiting, passivating and preventing fungi and bacteria, thereby effectively preventing pests and diseases and enhancing the quality and yield of the crop product.
Description
Technical field
The invention belongs to fertilizer field.Particularly, the present invention relates to a kind of foliage fertilizer and preparation method thereof.
Background technology
Bamboo vinegar liquid is in the process of making charcoal with bamboo wood, collects the gas that bamboo wood produces in pyrolytic decomposition, and this gas is cooled off the liquid substance that obtains at normal temperatures.Bamboo vinegar liquid contains nearly 300 kinds of natural polymer organic cpds, comprises the alkaline components of organic acid, alcohols, ketone, aldehydes, ester class and trace etc.
Bamboo vinegar liquid can be improved the soil, and bamboo vinegar liquid is sprayed at the damping-off that can prevent seed in the soil, also can be used as the sterilizing agent of soil.Use the effective inhibition of bamboo vinegar fluid power in the soil and hinder the breeding of the mikrobe of plant-growth; And can kill insects such as root nodule nematode; Can effectively improve the microbe groups of soil; Promote organism to decompose and utilize, thereby crumb structure, air permeability, the water-permeable of soil are improved, improve fertilizer utilization ratio.Bamboo vinegar liquid or plant-growth regulator, bamboo vinegar liquid can promote agronomic crop seed germination, takes root, grow, and can also promote the growth of plants such as vegetables, fruit tree, flowers, paddy rice, lawn.In addition, bamboo vinegar liquid can also be made fertilizer, suppresses the growth of weeds, reduces pesticide dosage, as the repellent of insect pest etc.Bamboo vinegar liquid has good control effect to plant pest, unites use with agricultural chemicals and also has good synergism, and reduction pesticide dosage, minimizing pesticide residue are had good result.
Chitin extensively be present in the crusts of crustaceans such as shrimp, crab and molluscan organs such as the cell walls of mushrooms such as mushroom and cuttlefish in; Be that 2-ethanamide-2-deoxy-D-glucose is through β-1; 4 glycosides chains connect the straight-chain polysaccharide that forms, and are a kind of new type natural macromolecular materials that emerges in recent years.Be called chitosan behind the chitin deacetylate, this is the most important and most widely used verivate of chitin, and it is nonpoisonous and tasteless, heat-resisting, corrosion-resistant, biodegradable, and unique physiological property causes people's very big concern.At present, its exploitation, research and utilization in various fields such as medicine industry, foodstuffs industry, water treatment, daily cosmetic, agricultural, weaving, printing and dyeing, papermaking, mould material, catalysis and analytical chemistry is just being received the attention of many countries.Chitosan contains free hydroxyl group and amino isopolarity group, has very strong water-absorbent and water-retentivity, can be used for the mechanism of dry seed germination or as seed treatment agent, makes seed be embedded in the infringement that prevents mould in the soil in the paint film; Its hydrolysate also can be used for the foliage-spray of crop, has plant growth regulation.The main effect of chitin on agricultural is propagation soil profitable strain, suppresses harmful bacterium; Inducing plant is opened autoimmune response, improves farm crop and vegetable disease-resistant property, minimizing or without the use of agricultural chemicals; Promote plant-growth, improve farm crop and vegetable crop.
Foliage fertilizer is meant that through crop leaf be the general designation that crop provides the fertilizer of nutritive substance, and it can replenish the deficiency of root fertilising, has rapid extra-nutrition, gives full play to fertilizer efficiency, economical and alleviate the pollution characteristics to soil.But in view of the textural difference of blade face and root, how to solve the fully effective absorption nutritive ingredient in blade face is the important topic of industry research always.
Summary of the invention
The object of the present invention is to provide a kind of novel foliage fertilizer, it can effectively provide bamboo vinegar liquid and chitosan through plant leaf surface simultaneously, and both have synergism for increasing crop yield.
Another object of the present invention provides the preparation method of said foliage fertilizer.
Be used to realize that the technical scheme of above-mentioned purpose is following:
On the one hand, the present invention provides a kind of foliage fertilizer, and by weight percentage, said foliage fertilizer comprises:
Chitosan 1~10%, bamboo vinegar liquid solution 15~25%, tensio-active agent 0.5~3%.
Preferably, said foliage fertilizer also comprises urea 5~15%, Pottasium Hydroxide 2~8%, and Secondary ammonium phosphate 5~10%, surplus is a water.
In described foliage fertilizer, said bamboo vinegar liquid prepares through following steps:
Bamboo wood is crushed to 40~60 orders, and spray adds 10%~20% water of bamboo wood weight, adds 0.5%~1.0% cellulase of bamboo wood weight again; Stack fermentation 12~15 hours, then fermented product is placed distiller, be heated to 100~140 ℃; Pyrolysis 6~9 hours is cooled to 40 ℃ afterwards, will obtain the centrifugal settling of bamboo vinegar liquid crude extract then; Get supernatant, promptly obtain bamboo vinegar liquid.
In addition, the molecular-weight average of the chitosan in the said foliage fertilizer is 5000~6000 dalton; Further preferably, the molecular-weight average of said chitosan is 5500~6000 dalton.
Wherein, said chitosan is through chitin being dissolved in the acetic acid, making with hydrogen peroxide degradation then.
Preferably, said chitosan prepares through following steps:
Calculate by weight; 50~150 parts of chitins are dissolved in the aqueous acetic acid of 700~900 part 0.5~2% (volume ratio), add the aqueous hydrogen peroxide solution of 50~150 part 10~20% (volume ratio) then, be warming up to 40 ℃~70 ℃; Degraded oven dry 1~5 hour.Can know that through the gel liquid chromatographic detection adopting the molecular-weight average of the chitosan of above-mentioned steps preparation is 5000~6000 dalton.
In foliage fertilizer of the present invention, tensio-active agent is X 2073 (being called for short ABS) and/or TX10 (being called for short OP-10); Preferably, said tensio-active agent is OP-10.
On the other hand, the present invention provides the preparation method of above-mentioned foliage fertilizer, and it comprises:
Chitosan, bamboo vinegar liquid and tensio-active agent are added in the entry, be warming up to 30 ℃~60 ℃ then, stirred 1~3 hour, mix and make.
Preferably, said preparation method also comprises: urea, Pottasium Hydroxide and Secondary ammonium phosphate are added in the entry with chitosan, bamboo vinegar liquid, tensio-active agent, be warming up to 30 ℃~60 ℃ then, stirred 1~3 hour, mix.
Wherein, said bamboo vinegar liquid prepares through following steps:
Bamboo wood is crushed to 40~60 orders, and spray adds 10%~20% water of bamboo wood weight, adds 0.5%~1.0% cellulase of bamboo wood weight again; Stack fermentation 12~15 hours, then fermented product is placed distiller, be heated to 100~140 ℃; Pyrolysis 6~9 hours is cooled to 40 ℃ afterwards, will obtain the centrifugal settling of bamboo vinegar liquid crude extract then; Get supernatant, promptly obtain bamboo vinegar liquid.
Wherein, the molecular-weight average of said chitosan is 5000~6000 dalton; Preferably, the molecular-weight average of said chitosan is 5500~6000 dalton.
In above-mentioned preparation method, said chitosan is through chitin being dissolved in the acetic acid, making with hydrogen peroxide degradation then.
Preferably, said chitosan prepares through following steps:
Calculate by weight; 50~150 parts of chitins are dissolved in the aqueous acetic acid of 700~900 part 0.5~2% (volume ratio), add the aqueous hydrogen peroxide solution of 50~150 part 10~20% (volume ratio) then, be warming up to 40 ℃~70 ℃; Degraded oven dry 1~5 hour.
In above-mentioned preparation method, the tensio-active agent of employing is X 2073 (being called for short ABS) and/or TX10 (being called for short OP-10); Preferably, said tensio-active agent is OP-10.
Below be detailed description of the present invention:
The foliage fertilizer of chitosan-containing provided by the present invention and bamboo vinegar liquid can have two types: the first kind is to be added to the water through chitosan, bamboo vinegar liquid, the tensio-active agent that resolves into small molecular weight after degrading by chitin; Be warming up to 30~60 ℃; Stirred 1~3 hour, and mixed and be prepared from; Second type is to be added to the water through chitosan, bamboo vinegar liquid, urea, Pottasium Hydroxide, Secondary ammonium phosphate, the tensio-active agent that resolves into small molecular weight after degrading by chitin, is warming up to 30~60 ℃, stirs 1~3 hour, mixes to be prepared from.The weight percent of each component is: chitosan 1~10%, urea 5~15%, Pottasium Hydroxide 2~8%, Secondary ammonium phosphate 5~10%, tensio-active agent 0.5~3%, bamboo vinegar liquid 15~25%, water 39~61.5%.
In order to solve the nutritive substance that comprises chitosan etc. is provided effectively to crop through the blade face; Thereby replenish the root fertilising deficiency, supplement the nutrients rapidly, give full play to fertilizer efficiency, amount of application seldom, can alleviate advantages such as pollution to soil; Find after deliberation; Crop can effectively absorb through the bamboo vinegar liquid of foliage applying and the mixture of chitosan, the more important thing is that both share and can have synergism for crop yield, thereby gives full play to the effect of foliage fertilizer.
Wherein, chitin is dissolved in the acetum, passes through hydrogen peroxide degradation then, resolve into the small molecules chitosan after chitin is degraded, its molecular-weight average is controlled at about 6000.The mixture that the chitosan of this molecular weight ranges is processed bamboo vinegar liquid and chitosan is beneficial to crop and effectively absorbs very much, and its main effect comprises: the concentration that can directly increase sugar for farm crop promotes the farm crop root growth; Can strengthen the Physiology and biochemistry machine matter of plant, induce and make the multiple disease-resistance substance of deposits yields, fungi, bacterium are had extremely strong inhibition, passivation and prophylactic effect, thus prevention and elimination of disease and pests effectively, the quality and the output of raising crop products.Bamboo vinegar fluid power effectively inhibition hinders the breeding of the mikrobe of plant-growth; And can kill insect such as root nodule nematode, and can effectively improve the microbe groups of soil, promote organism to decompose and utilize; Thereby crumb structure, air permeability, the water-permeable of soil are improved, improve fertilizer utilization ratio.Bamboo vinegar liquid or plant-growth regulator, bamboo vinegar liquid can promote agronomic crop seed germination, takes root, grow, and can also promote the growth of plants such as vegetables, fruit tree, flowers, paddy rice, lawn.
In addition, contain tensio-active agent in the mixture of bamboo vinegar liquid of the present invention and chitosan, it can reduce the surface tension on fertilizer and blade face; Thereby increase the bond area between them; Improve the absorption and the utilization ratio of fertilizer, reduce the usage quantity of fertilizer, reduce the agricultural-food production cost.
And mixture second type of bamboo vinegar liquid of the present invention and chitosan also contains nutrition such as the required nitrogen of crop, phosphorus, potassium, and can directly spray in the blade face, and is easy to use.
Embodiment
Below in conjunction with embodiment the present invention is further described in detail, the embodiment that provides has been merely and has illustrated the present invention, rather than in order to limit scope of the present invention.
Experimental technique among the following embodiment like no specified otherwise, is ordinary method.Used test materials among the following embodiment like no specified otherwise, is conventional shop and buys and obtain.
Embodiment 1:
Material name weight percent (%) material name weight percent (%)
Chitosan 5 bamboo vinegar liquid 15
Tensio-active agent 2 water 78
The preparation of raw material bamboo vinegar liquid:
100 kilograms of bamboo woods (from Lishui of Zhejiang) are crushed to 50 orders, and spray adds 15 kg of water, adds 0.6 kilogram of cellulase, stacks fermentation 14 hours; Then fermented product being joined in the distiller, is fuel with the bamboo wood tankage, is heated to 120 ℃; Pyrolysis 7 hours is cooled to 40 ℃, obtains the bamboo vinegar liquid crude extract; Supernatant is got in centrifugal settling, obtains 50 kilograms of bamboo vinegar liquid.
The raw materials of chitosan preparation:
100 kilograms of chitins are dissolved in 750 kilograms of 1% aqueous acetic acids, add 60 kilograms of 15% aqueous hydrogen peroxide solutions then, be warming up to 50 ℃, degraded 3 hours, dry for use.
Detect the molecular-weight average of the chitosan make with liquid phase chromatography, testing conditions is following:
Moving phase and stationary phase are chromatographic grade THF and normal hexane; CGX 500 silicagel columns; Granularity is 10 μ m, and the aperture is
adopt degree pump such as a L-7100, it is connected with a L-7400UV detector; Being Hitachi, Ltd produces; The detection wavelength is 260nm, and 7100 type sampling valves, quantity tube are 20 μ L; The length of the pipe connecting between sampling valve and pump is 120mm, and volume is 12 μ L; Data gathering is through D-7000HPLC system interface and software; Flow velocity is 1.0mL/min, and sample quality concentration is 0.5g/L, is controlled at 25 ℃ to temperature with L-7300 post stove.The molecular-weight average that records the chitosan of preparation is 5000~6000 dalton.
The foliage fertilizer preparation:
To join in 780 kg of water according to 15 kilograms of 50 kilograms of chitosans, bamboo vinegar liquid, the tensio-active agent OP-1020 kilogram of method for preparing, heat up 55 ℃, stirred 2 hours, mix, centrifugal.
Embodiment 2:
The preparation of raw material bamboo vinegar liquid:
100 kilograms of bamboo woods are crushed to 50 orders, and spray adds 15 kg of water, adds 0.6 kilogram of cellulase, stacks fermentation 14 hours; Then fermented product being joined in the distiller, is fuel with the bamboo wood tankage, is heated to 120 ℃; Pyrolysis 7 hours is cooled to 40 ℃, obtains the bamboo vinegar liquid crude extract; Supernatant is got in centrifugal settling, obtains 50 kilograms of bamboo vinegar liquid.
The raw materials of chitosan preparation:
80 kilograms of chitins are dissolved in 880 kilograms of 1% aqueous acetic acids, add 70 kilograms of 10% aqueous hydrogen peroxide solutions then, be warming up to 40 ℃, degraded 2.5 hours, dry for use.
Detect the molecular-weight average of the chitosan make with liquid phase chromatography, testing conditions is following:
Moving phase and stationary phase are chromatographic grade THF and normal hexane; CGX 500 silicagel columns; Granularity is 10 μ m, and the aperture is
adopt degree pump such as a L-7100, it is connected with a L-7400UV detector; Being Hitachi, Ltd produces; The detection wavelength is 260nm, and 7100 type sampling valves, quantity tube are 20 μ L; The length of the pipe connecting between sampling valve and pump is 120mm, and volume is 12 μ L; Data gathering is through D-7000HPLC system interface and software; Flow velocity is 1.0mL/min, and sample quality concentration is 0.5g/L, is controlled at 25 ℃ to temperature with L-7300 post stove.The molecular-weight average that records the chitosan of preparation is 5000~6000 dalton.
The foliage fertilizer preparation:
To join in 590 kg of water according to 50 kilograms of 40 kilograms in 100 kilograms in 15 kilograms of 50 kilograms of chitosans, bamboo vinegar liquid, urea, Pottasium Hydroxide, Secondary ammonium phosphates, the tensio-active agent OP-1020 kilogram of method for preparing; Heat up 55 ℃; Stirred 2 hours, and mixed, centrifugal.
Embodiment 3:
The preparation of raw material bamboo vinegar liquid:
100 kilograms of bamboo woods are crushed to 60 orders, and spray adds 20 kg of water, adds 0.8 kilogram of cellulase, stacks fermentation 15 hours; Then fermented product being joined in the distiller, is fuel with the bamboo wood tankage, is heated to 140 ℃; Pyrolysis 9 hours is cooled to 40 ℃, obtains the bamboo vinegar liquid crude extract; Supernatant is got in centrifugal settling, obtains 60 kilograms of bamboo vinegar liquid.
The raw materials of chitosan preparation:
The 120 kg chitin is dissolved in 840 kilograms of 1% aqueous acetic acids, adds 80 kilograms of 20% aqueous hydrogen peroxide solutions then, be warming up to 60 ℃, degraded 3 hours, dry for use.
Detect the molecular-weight average of the chitosan make with liquid phase chromatography, shown in testing conditions such as the embodiment 1.The molecular-weight average that records the chitosan of preparation is 5000~6000 dalton.
The foliage fertilizer preparation:
To join in 495 kg of water for 15 kilograms according to 70 kilograms of 60 kilograms in 18 kilograms of 60 kilograms of chitosans, bamboo vinegar liquid, urea 120 kg, Pottasium Hydroxide, Secondary ammonium phosphates, the surfactant A BS of method for preparing; Heat up 45 ℃; Stirred 2.5 hours, and mixed, centrifugal.
Embodiment 4:
The preparation of raw material bamboo vinegar liquid:
100 kilograms of bamboo woods are crushed to 60 orders, and spray adds 18 kg of water, adds 0.7 kilogram of cellulase, stacks fermentation 12 hours; Then fermented product being joined in the distiller, is fuel with the bamboo wood tankage, is heated to 100 ℃; Pyrolysis 7 hours is cooled to 40 ℃, obtains the bamboo vinegar liquid crude extract; Supernatant is got in centrifugal settling, obtains 40 kilograms of bamboo vinegar liquid.
The raw materials of chitosan preparation:
50 kilograms of chitins are dissolved in 900 kilograms of 1% aqueous acetic acids, add 25 kilograms of 18% aqueous hydrogen peroxide solutions then, be warming up to 60 ℃, degraded 3.5 hours, dry for use.
Detect the molecular-weight average of the chitosan make with liquid phase chromatography, shown in testing conditions such as the embodiment 1.The molecular-weight average that records the chitosan of preparation is about 6000.
The foliage fertilizer preparation:
To join in 40 kg of water for 10 kilograms according to 80 kilograms of 40 kilograms in 130 kilograms in 25 kilograms of 70 kilograms of chitosans, bamboo vinegar liquid, urea, Pottasium Hydroxide, Secondary ammonium phosphates, OP-1020 kilogram, the ABS of method for preparing; Heat up 60 ℃; Stirred 2.5 hours, and mixed, centrifugal.
Embodiment 5: the compliance test result of foliage fertilizer of the present invention
With the cucumber is trial crops, has verified the effect of fertilizer of foliage fertilizer of the present invention.
1, test design and mensuration
Trial crops: cucumber, basic condition see the following form 1.
Table 1 trial crops basic condition
The test soil regime: soil basis nutrient is seen table 2.
Table 2 test soil basis nutrient
4 processing are established in test, handle 1 (test fertilizer) area 0.22hm
2, handle 2 (patented claim CN201110278299.3 embodiment 1 foliage fertilizer) area 0.22hm
2, handle 3 (bamboo vinegar liquid of patent CN1401779A embodiment 1) area 0.22hm
2, handle 4 (contrast) area 0.12hm
2
Handle 1---spray the foliage fertilizer of clear water+embodiment of the invention 2 preparations.Wherein with foliage fertilizer with 675ml/hm
2Consumption, dilute 700 times, begin foliage-spray after 7 days 4 times from the cucumber field planting, each 15 days at interval.
Handle 2---spray clear water+foliage fertilizer (according to patented claim CN201110278299.3 embodiment 1 preparation; Wherein containing molecular weight is 5000~6000 daltonian chitosan 5 weight %; Urea 10 weight %, Pottasium Hydroxide 4 weight %, Secondary ammonium phosphate 5 weight %; Tensio-active agent 2 weight %, water 74 weight %).Wherein with foliage fertilizer with 675ml/hm
2Consumption, dilute 700 times, begin foliage-spray after 7 days 4 times from the cucumber field planting, each 15 days at interval.
Handle 3---spray clear water+bamboo vinegar liquid (according to patented claim CN1401779A embodiment 1 preparation).Wherein with foliage fertilizer with 675ml/hm
2Consumption, dilute 700 times, begin foliage-spray after 7 days 4 times from the cucumber field planting, each 15 days at interval.
Handle 4---spray clear water+conventional fertilizer application (urea 8.1g/hm
2, Pottasium Hydroxide 4.1g/hm
2, Secondary ammonium phosphate 4.7g/hm
2), dilute 700 times, begin foliage-spray after 7 days 4 times from the cucumber field planting, each 15 days at interval.
Heavy to the single melon of cucumber, the cucumber melon long, 3 aspects of cucumber yield compare, wherein measuring method is:
Heavy, the long measuring method of cucumber melon of the single melon of cucumber: multidraw, avoid the limit row, adopt the diagonal lines sampling method, choose 5 of representative sampling points, each sampling point is got 10 cucumber, measures calculating mean value respectively.
The cucumber yield measuring method: the test plot gathers in the crops separately, meter produces separately, converts out a hectare output.
2, test-results and analysis
Different treatment to the single melon of cucumber influence heavy, that the cucumber melon is long see table 3.
The single melon of the cucumber of table 3 different treatment is heavy, melon is long
Can know from The above results; Handling 1 (spraying clear water+test fertilizer), processing 2 (patented claim CN201110278299.3 embodiment 1 foliage fertilizers), processing 3 (bamboo vinegar liquid of patent CN1401779A embodiment 1) and processing 4 (spraying clear water+conventional fertilizer application) compares; The single melon of cucumber increases by 13 grams, 8.7 grams, 3.1 grams heavily respectively, and increment rate is respectively 13.9%, 9.3%, 3.3%; The cucumber melon is long to increase 1.5cm, 0.7cm, 0.4cm respectively, and increment rate is respectively 5.8%, 2.7%, 15.6%.
Different treatment is seen table 4 to the influence of cucumber yield.
The cucumber yield of table 4 different treatment
Handle | Output (kg/hm 3) | Raising the output (kg/hm 3) | Stimulation ratio (%) |
1 | 47671 | 4528 | 10.5 |
2 | 47185.8 | 4042.9 | 9.4 |
3 | 44653 | 1510 | 3.5 |
4 | 43142.9 |
Can know that from The above results processing 1, processing 2, processing 3 and processing 4 are compared, cucumber yield increases 4528kg/hm respectively
2, 4042.9kg/hm
2, 1510kg/hm
2, stimulation ratio is respectively 10.5%, 9.4%, 3.5%.
Claims (11)
1. a foliage fertilizer is characterized in that, by weight percentage, said foliage fertilizer comprises: chitosan 1~10%, bamboo vinegar liquid 10~25%, tensio-active agent 0.5~3%.
2. foliage fertilizer according to claim 1 is characterized in that, said foliage fertilizer also comprises: urea 5~15%, and Pottasium Hydroxide 2~8%, Secondary ammonium phosphate 5~10%, surplus is a water.
3. foliage fertilizer according to claim 1 and 2 is characterized in that, the bamboo vinegar liquid in the said foliage fertilizer prepares through following steps:
Bamboo wood is crushed to 40~60 orders, and spray adds 10%~20% water of bamboo wood weight, adds 0.5%~1.0% cellulase of bamboo wood weight again; Stack fermentation 12~15 hours, then fermented product is placed distiller, be heated to 100~140 ℃; Pyrolysis 6~9 hours; Be cooled to 40 ℃ afterwards, will obtain the centrifugal settling of bamboo vinegar liquid crude extract then, get supernatant.
4. according to each described foliage fertilizer in the claim 1 to 3, it is characterized in that the molecular-weight average of said chitosan is 5000~6000 dalton;
Preferably, the molecular-weight average of said chitosan is 5500~6000 dalton.
5. according to each described foliage fertilizer in the claim 1 to 4, it is characterized in that said chitosan is through chitin being dissolved in the acetic acid, making with hydrogen peroxide degradation then;
Preferably, said chitosan prepares through following steps:
Calculate by weight; 50~150 parts of chitins are dissolved in the aqueous acetic acid of 700~900 part 0.5~2% (volume ratio), add the aqueous hydrogen peroxide solution of 50~150 part 10~20% (volume ratio) then, be warming up to 40 ℃~70 ℃; Degraded oven dry 1~5 hour.
6. according to each described foliage fertilizer in the claim 1 to 5, it is characterized in that said tensio-active agent is TX10 and/or X 2073;
Preferably, said tensio-active agent is a TX10.
7. according to the preparation method of each described foliage fertilizer in the claim 1 to 6, it is characterized in that said preparation method comprises:
Chitosan, bamboo vinegar liquid, tensio-active agent are added in the entry, be warming up to 30 ℃~60 ℃ then, stirred 1~3 hour, mix;
Preferably, said preparation method also comprises:
Urea, Pottasium Hydroxide and Secondary ammonium phosphate are added in the entry with chitosan, bamboo vinegar liquid, tensio-active agent, be warming up to 30 ℃~60 ℃ then, stirred 1~3 hour, mix.
8. preparation method according to claim 7 is characterized in that, said bamboo vinegar liquid prepares through following steps:
Bamboo wood is crushed to 40~60 orders, and spray adds 10%~20% water of bamboo wood weight, adds 0.5%~1.0% cellulase of bamboo wood weight; Stack fermentation 12~15 hours, then fermented product is placed distiller, be heated to 100~140 ℃; Pyrolysis 6~9 hours; Be cooled to 40 ℃ afterwards, will obtain the centrifugal settling of bamboo vinegar liquid crude extract then, get supernatant.
9. according to claim 7 or 8 described preparing methods, it is characterized in that the molecular-weight average of said chitosan is 5000~6000 dalton;
Preferably, the molecular-weight average of said chitosan is 5500~6000 dalton.
10. according to each described preparation method in the claim 7 to 9, said chitosan makes with hydrogen peroxide degradation through chitin is dissolved in the acetic acid then;
Preferably, said chitosan prepares through following steps:
Calculate by weight; 50~150 parts of chitins are dissolved in the aqueous acetic acid of 700~900 part 0.5~2% (volume ratio), add the aqueous hydrogen peroxide solution of 50~150 part 10~20% (volume ratio) then, be warming up to 40 ℃~70 ℃; Degraded oven dry 1~5 hour.
11., it is characterized in that said tensio-active agent is TX10 and/or X 2073 according to each described preparation method in the claim 7 to 10;
Preferably, said tensio-active agent is a TX10.
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