CN102503301A - Safe environment-friendly colored anti-efflorescence ceramic tile gap filler - Google Patents
Safe environment-friendly colored anti-efflorescence ceramic tile gap filler Download PDFInfo
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- CN102503301A CN102503301A CN2011103320402A CN201110332040A CN102503301A CN 102503301 A CN102503301 A CN 102503301A CN 2011103320402 A CN2011103320402 A CN 2011103320402A CN 201110332040 A CN201110332040 A CN 201110332040A CN 102503301 A CN102503301 A CN 102503301A
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Abstract
The invention relates to a safe environment-friendly colored anti-efflorescence ceramic tile gap filler of salts on surface soil, which comprises the following components in percentage by weight: 35.00-50.00% of special-type white cement, 45.00-60.00% of filler, 0.03-0.15% of cellulose ether, 1.00-3.00% of adhesive, 0.05-0.30% of lignin fiber, 0.00-0.10% of chemical fiber, 0.00-0.30% of thixotropic agent, 0.00-0.40% of water reducing agent, 0.20-0.50% of retarder, 0.00-0.4% of mildew inhibitor, 0.00-0.25% of water repellent and 0.00-3.00% of ferric oxide series pigment. The ceramic tile gap filler not only can thoroughly solve the problem of accumulation of salts on the surface soil, but also has the advantages of moderate price, high safety, environment friendliness, wide application range and the like, and is convenient for production, transportation and storage.
Description
Technical field
The present invention relates between the buildings indoor and outdoor ceramic tile slit fills used a kind of safety and environmental protection and does not have accumulation of salt in the surface soil color tile grout.
Background technology
Along with the development of society, ceramic tile has become one of material the most frequently used in the building decoration.For fear of producing hollowing owing to expanding with heat and contract with cold between ceramic tile and the ceramic tile, need between ceramic tile and the ceramic tile to reserve certain slit, this slit need be filled with material of construction.At first, used packing material by ordinary white silicate cement and coarse whiting or other white fillers by a certain percentage field mix form.Because the packing material rigidity that this scene arbitrarily mixes is big, aquation is insufficient, water regain reaches shortcomings such as color dullness greatly; Cracking, dry linting, shortcoming such as not attractive in appearance often appear in packing material; And rainwater is easy to get into the ceramic tile back side, through freeze-thaw cycle cause the ceramic tile hollowing, phenomenon such as come off.To these problems that occur, domestic scholars is also studied.Through analyzing, the main method one that adopts be with the ordinary white silicate cement as inorganic coagulation material, re-dispersible glue powder is as the organic gel gel material, ether of cellulose is as water-holding agent, silica powder is as filler.Though can solve defectives such as cracking that traditional ceramic tile pointing occurs, efflorescence through these methods to a certain extent,, thereby produce the accumulation of salt in the surface soil to a certain degree because the ordinary white silicate cement hydration is produced the calcium hydroxide product in the system.Can reduce the degree of the accumulation of salt in the surface soil through adding some properties-correcting agent, take place but can not fundamentally stop this phenomenon.Method two be with reactive resin as adhesive material, solidifying agent is as initiator, inert material is as filler.Though this material can thoroughly solve accumulation of salt in the surface soil problem, prepare by a certain percentage at the scene of need, causes construction inconvenient, has hidden danger of quality, simultaneously certain smell is arranged also, dangerous environmental protection, and price is high.Method three be with emulsion as the organic gel gel material, inert material is as filler, both mix.Though this material can thoroughly solve accumulation of salt in the surface soil problem, exist and produce, transport and the storage inconvenience, the wavelength width of a slit of being filled and the degree of depth all have certain limitation, and curing speed is slow.
Summary of the invention
In order to solve above-mentioned deficiency of the prior art, the present invention provides a kind of safety and environmental protection not have accumulation of salt in the surface soil color tile grout.Advantages such as this tile grout not only can thoroughly solve the accumulation of salt in the surface soil problem of spackling, and has moderate cost, and safety and environmental protection is produced, transported and stores conveniently, and use range is wide.
The present invention provides a kind of safety and environmental protection not have accumulation of salt in the surface soil color tile grout, and it comprises following component by weight percentage:
Extraordinary white cement 35.00%-50.00%;
Filler 45.00%-60.00%;
Ether of cellulose 0.03%-0.15%;
Tackiness agent 1.00%-3.00%;
Lignin fibre 0.05%-0.30%;
Man-made fiber 0.00%-0.10%;
Thixotropic agent 0.00%-0.30%;
Water reducer 0.00%-0.40%;
Retardant 0.20%-0.50%;
Mould inhibitor 0.00%-0.4%;
Hydrophober 0.00%-0.25%;
Pigment 0.00%-3.00%.
Said extraordinary white cement is No. 42.5 white quick hardening sulphoaluminate cements, said filler be in 40 orders～80 order silica sands, 80 orders～120 order silica sands or the 300 orders～400 order coarse whitings one or more.
Described ether of cellulose is hydroxyethylmethyl-cellulose ether or hydroxypropyl methyl cellulose ether, and viscosity is between 10000mPa.s～40000mPa.s.
Described tackiness agent is one or more in vinyl acetate and ethylene copolymer rubber powder, ethene and vinylchlorid and month silicic acid vinyl acetate terpolymer rubber powder, vinyl acetate and ethene and higher fatty acid vinyl acetate terpolymer rubber powder, vinyl acetate and higher fatty acid vinyl acetate copolymerization rubber powder, vinyl acetate and propenoate and higher fatty acid vinyl acetate terpolymer rubber powder or the vinylformic acid homopolymerization rubber powder.
Described lignin fibre is a wood fibre, and length is at 300 μ m～600 μ m.
Described man-made fiber is one or more in polypropylene fibre, polyacrylonitrile fibre, trevira, wynene or the vinylon, and length is between 1mm～5mm.
Said thixotropic agent is a kind of in calcium-base bentonite thixotropic agent or the sodium bentonite thixotropic agent or two kinds, and said water reducer is a kind of in melamine high-efficiency water-reducing agent or the polycarboxylate water-reducer or two kinds.
Described retardant is one or more in glucono-, Sunmorl N 60S, calglucon, Hydrocerol A, Trisodium Citrate, tartrate or the sodium tartrate.
Described mould inhibitor is that N-(fluorine dichloromethane sulfenyl) phthalic imidine, 2-xenol, copper 8-quinolinolate, methylsulfonyl tetrachloro are given a tongue-lashing pyridine, 2-(thiazole-4-yl) benzoglyoxaline, 2-benzimidazole carbamate, 4-chloro-3, one or more in 5-xylenol or 1-(< Chloro-O-Phenyl>diphenyl methyl) imidazoles.
Said hydrophober is organosilicon series hydrophober, and said pigment is red stone series pigment.
Adopt safety and environmental protection provided by the invention not have the accumulation of salt in the surface soil problem that accumulation of salt in the surface soil color tile grout not only can thoroughly solve spackling, and have moderate cost, safety and environmental protection, advantages such as producing, transport and storage makes things convenient for, and use range is wide.
Embodiment
For further setting forth the present invention, provide embodiment below and explain.
In the present invention; Said extraordinary white cement is that Zhengzhou Wang Lou Cement industry ltd provides white quick hardening sulphoaluminate cement No. 42.5, and said filler is that Lingshou stone dam generation hall mining industry source mill provides 300 orders～400 order coarse whitings, 40 orders～80 order silica sands and 80 orders～120 order silica sands.
Said ether of cellulose is hydroxypropyl methyl cellulose ether and the hydroxyethylmethyl-cellulose ether that Beijing Long Hu Science and Technology Ltd. provides, and viscosity is respectively at 35000mPa.s～45000Pa.s and 10000mPa.s～20000Pa.s.
Described tackiness agent is ethene and vinylchlorid and month silicic acid vinyl acetate terpolymer rubber powder, Vinyl Acetate Copolymer-ethylene copolymer rubber powder and vinyl acetate and ethene and the higher fatty acid vinyl acetate terpolymer rubber powder that Beijing Long Hu Science and Technology Ltd. provides.
Described lignin fibre is the wood fibre that Beijing Long Hu Science and Technology Ltd. provides, and length is at 500 μ m.
Described man-made fiber is built polypropylene fibre and the polyacrylonitrile fibre that Science and Technology Ltd. provides for Beijing sieve, and length is respectively 5mm and 3mm.
Said thixotropic agent is the calcium-base bentonite that Beijing Long Hu Science and Technology Ltd. provides, and said water reducer is the melamine high-efficiency water-reducing agent that Beijing Long Hu Science and Technology Ltd. provides.
Described retardant is Sunmorl N 60S, Trisodium Citrate and the tartrate that sea, Beijing lapidary's trade ltd provides.
Described mould inhibitor is N-(fluorine dichloromethane sulfenyl) phthalic imidine, 2-(thiazole-4-yl) benzoglyoxaline and the 2-benzimidazole carbamate that three rich biochemical technology ltds provide.
Said hydrophober is the organosilicon moisture repellent that the chemical ltd of national starch provides, and said pigment is Shanghai Yipin Pigments Co., Ltd.'s black iron oxide pigment.
Based on above-mentioned scope, the present invention provides first embodiment, and the concrete weight proportion of each component is (unit K g, down together) as follows:
42.5 number white quick hardening sulphoaluminate cement 450.0;
300 orders～400 order coarse whitings 522.0;
Hydroxypropyl methyl cellulose ether 0.5;
Ethene and vinylchlorid and month silicic acid vinyl acetate rubber powder 15.0;
Lignin fibre 1.5;
Polypropylene fibre 0.5;
Thixotropic agent 1.0;
Water reducer 2.0;
Sunmorl N 60S 4.0;
N-(fluorine dichloromethane sulfenyl) phthalic imidine 1.5;
Hydrophober 2.0;
Pigment 0.00.
Based on above-mentioned scope, the present invention provides second embodiment, and the concrete weight proportion of each component is following:
42.5 number white quick hardening sulphoaluminate cement 350.0;
40 orders～80 order silica sands 400.0;
80 orders～120 order silica sands 200.0;
Hydroxyethylmethyl-cellulose ether 1.5;
Ethene and vinylchlorid and month silicic acid vinyl acetate rubber powder 10.0;
Lignin fibre 0.5;
Polyacrylonitrile fibre 0.2;
Thixotropic agent 2.0;
Water reducer 4.0;
Trisodium Citrate 2.0;
2-(thiazole-4-yl) benzoglyoxaline 1.0;
Hydrophober 2.5;
Pigment 26.3.
Based on above-mentioned scope, the present invention provides the 3rd embodiment, and the concrete weight proportion of each component is following:
42.5 number white quick hardening sulphoaluminate cement 400.0;
80 orders～120 order silica sands 200.0;
300 orders～400 order coarse whitings 350.0;
Hydroxypropyl methyl cellulose ether 0.3;
Vinyl Acetate Copolymer-ethylene copolymer rubber powder 20.0;
Lignin fibre 3.0;
Polypropylene fibre 0.0;
Thixotropic agent 0.0;
Water reducer 4.0;
Trisodium Citrate 3.0;
2-(thiazole-4-yl) benzoglyoxaline 1.5;
2-benzimidazole carbamate 1.5;
Hydrophober 1.0;
Pigment 15.70.
Based on above-mentioned scope, the present invention provides the 4th embodiment, and the concrete weight proportion of each component is following:
42.5 number white quick hardening sulphoaluminate cement 500.0;
300 orders～400 order coarse whitings 450.0;
Hydroxyethylmethyl-cellulose ether 1.0;
Vinyl Acetate Copolymer-ethylene copolymer rubber powder 30.0;
Lignin fibre 2.0;
Polypropylene fibre 1.0;
Thixotropic agent 3.0;
Water reducer 0.0;
Sunmorl N 60S 5.0;
N-(fluorine dichloromethane sulfenyl) phthalic imidine 4.0;
Hydrophober 0.0;
Pigment 4.0.
Based on above-mentioned scope, the present invention provides the 5th embodiment, and the concrete weight proportion of each component is following:
42.5 number white quick hardening sulphoaluminate cement 425.0;
40 orders～80 order silica sands 250.0;
80 orders～120 order silica sands 150.0;
300 orders～400 order coarse whitings 117.5;
Hydroxypropyl methyl cellulose ether 0.5;
Ethene and higher fatty acid vinyl acetate terpolymer rubber powder 20.0;
Lignin fibre 2.0;
Polypropylene fibre 0.0;
Thixotropic agent 1.0;
Water reducer 1.0;
Tartrate 2.0;
2-(thiazole-4-yl) benzoglyoxaline 0.0;
Hydrophober 1.0;
Pigment 30.0.
The above-mentioned color tile grout that the present invention provides, performance satisfy industry standard JC/T1004-2006 ceramic wall and floor tile gap filler fully " middle CG1 type index request, the specific examples detected result is following:
Table 1 (instance one, two, three, four, five detected results)
Claims (10)
1. a safety and environmental protection does not have accumulation of salt in the surface soil color tile grout, it is characterized in that: comprise following component by weight percentage:
Extraordinary white cement 35.00%-50.00%;
Filler 40.00%-60.00%;
Ether of cellulose 0.03%-0.15%;
Tackiness agent 1.00%-3.00%;
Lignin fibre 0.05%-0.30%;
Man-made fiber 0.00%-0.10%;
Thixotropic agent 0.00%-0.30%;
Water reducer 0.00%-0.40%;
Retardant 0.20%-0.50%;
Mould inhibitor 0.00%-0.4%;
Hydrophober 0.00%-0.25%;
Pigment 0.00%-3.00%.
2. a kind of safety and environmental protection according to claim 1 does not have accumulation of salt in the surface soil color tile grout; It is characterized in that: said extraordinary white cement is No. 42.5 white quick hardening sulphoaluminate cements, said filler be in 40 orders～80 order silica sands, 80 orders～120 order silica sands or the 300 orders～400 order coarse whitings one or more.
3. a kind of safety and environmental protection according to claim 1 does not have accumulation of salt in the surface soil color tile grout, it is characterized in that: described ether of cellulose is hydroxyethylmethyl-cellulose ether or hydroxypropyl methyl cellulose ether, and viscosity is between 10000mPa.s～40000mPa.s.
4. a kind of safety and environmental protection according to claim 1 does not have accumulation of salt in the surface soil color tile grout, it is characterized in that: described tackiness agent is one or more in vinyl acetate and ethylene copolymer rubber powder, ethene and vinylchlorid and month silicic acid vinyl acetate terpolymer rubber powder, vinyl acetate and ethene and higher fatty acid vinyl acetate terpolymer rubber powder, vinyl acetate and higher fatty acid vinyl acetate copolymerization rubber powder, vinyl acetate and propenoate and higher fatty acid vinyl acetate terpolymer rubber powder or the vinylformic acid homopolymerization rubber powder.
5. a kind of safety and environmental protection according to claim 1 does not have accumulation of salt in the surface soil color tile grout, it is characterized in that: described lignin fibre is a wood fibre, and length is at 300 μ m～600 μ m.
6. a kind of safety and environmental protection according to claim 1 does not have accumulation of salt in the surface soil color tile grout; It is characterized in that: described man-made fiber is one or more in polypropylene fibre, polyacrylonitrile fibre, trevira, wynene or the vinylon, and length is between 1mm～5mm.
7. a kind of safety and environmental protection according to claim 1 does not have accumulation of salt in the surface soil color tile grout; It is characterized in that: said thixotropic agent is a kind of in calcium-base bentonite thixotropic agent or the sodium bentonite thixotropic agent or two kinds, and said water reducer is a kind of in melamine high-efficiency water-reducing agent or the polycarboxylate water-reducer or two kinds.
8. a kind of safety and environmental protection according to claim 1 does not have accumulation of salt in the surface soil color tile grout, it is characterized in that: described retardant is one or more in glucono-, Sunmorl N 60S, calglucon, Hydrocerol A, Trisodium Citrate, tartrate or the sodium tartrate.
9. a kind of safety and environmental protection according to claim 1 does not have accumulation of salt in the surface soil color tile grout; It is characterized in that: described mould inhibitor is that N-(fluorine dichloromethane sulfenyl) phthalic imidine, 2-xenol, copper 8-quinolinolate, methylsulfonyl tetrachloro are given a tongue-lashing pyridine, 2-(thiazole-4-yl) benzoglyoxaline, 2-benzimidazole carbamate, 4-chloro-3, one or more in 5-xylenol or 1-(< Chloro-O-Phenyl>diphenyl methyl) imidazoles.
10. a kind of safety and environmental protection according to claim 1 does not have accumulation of salt in the surface soil color tile grout, it is characterized in that: said hydrophober is organosilicon series hydrophober, and said pigment is red stone series pigment.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103159447A (en) * | 2013-03-13 | 2013-06-19 | 厦门路桥翔通建材科技有限公司 | Composition and its preparation method and use |
| CN103896538A (en) * | 2013-11-11 | 2014-07-02 | 东南大学 | Cement-based ultraviolet-proof tile joint mixture |
| CN104724982A (en) * | 2013-12-23 | 2015-06-24 | 久筑节能科技（天津）有限公司 | Gray ceramic tile adhesive 905 |
| CN104724981A (en) * | 2013-12-23 | 2015-06-24 | 久筑节能科技（天津）有限公司 | White ceramic tile adhesive 907 |
| CN104876501A (en) * | 2015-04-21 | 2015-09-02 | 济宁跃峰建材科技有限公司 | Crack sealer for building exterior wall tile, and preparation method and construction process thereof |
| CN105174805A (en) * | 2015-09-19 | 2015-12-23 | 孙军 | Waterproof accelerant of toilet ground gap filling agent and preparation method |
| CN105330249A (en) * | 2015-11-26 | 2016-02-17 | 上海域金澜优电子商务有限公司 | Production formula of seam beautifying agent with silver ions |
| CN105503072A (en) * | 2015-12-10 | 2016-04-20 | 华砂砂浆有限责任公司 | Tile grout composition and preparation method and application thereof |
| CN105645863A (en) * | 2015-12-31 | 2016-06-08 | 贵州中建建筑科研设计院有限公司 | Ultrafine powdery crack-resistant connection paste for connection of lightweight partition wall panel |
| CN105884286A (en) * | 2016-04-10 | 2016-08-24 | 欧振云 | Ceramic tile crack beautifying agent |
| CN107311595A (en) * | 2017-08-02 | 2017-11-03 | 合肥广民建材有限公司 | A kind of waterproof high viscosity tile grout and preparation method thereof |
| CN107365125A (en) * | 2017-09-08 | 2017-11-21 | 常州市奥普泰科光电有限公司 | A kind of preparation method of high-strength waterproof gap filler |
| CN107417200A (en) * | 2017-06-20 | 2017-12-01 | 合肥市淑芹美装饰工程有限公司 | A kind of ceramic wall and floor tile gap filler and preparation method thereof |
| CN107739172A (en) * | 2017-11-01 | 2018-02-27 | 贵州省独山县顺峰装潢建材厂 | A kind of gap filler of construction and decoration |
| CN108558305A (en) * | 2018-01-30 | 2018-09-21 | 富思特新材料科技发展股份有限公司 | The inorganic tile gap filler and preparation method thereof of squeezing and coating construction |
| CN110526656A (en) * | 2018-05-23 | 2019-12-03 | 佛山市科顺建筑材料有限公司 | A kind of fast high flexibility cement base gap filler and preparation method thereof firmly |
| CN114804753A (en) * | 2022-01-24 | 2022-07-29 | 东方雨虹砂粉科技集团有限公司 | Tile glue for pasting and joint filling and preparation method thereof |
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| CN102180646A (en) * | 2011-01-31 | 2011-09-14 | 北京东方雨虹防水技术股份有限公司 | Non-base-return color ceramic tile joint mixture |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102180646A (en) * | 2011-01-31 | 2011-09-14 | 北京东方雨虹防水技术股份有限公司 | Non-base-return color ceramic tile joint mixture |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103159447A (en) * | 2013-03-13 | 2013-06-19 | 厦门路桥翔通建材科技有限公司 | Composition and its preparation method and use |
| CN103159447B (en) * | 2013-03-13 | 2014-11-05 | 厦门路桥翔通建材科技有限公司 | Composition and its preparation method and use |
| CN103896538A (en) * | 2013-11-11 | 2014-07-02 | 东南大学 | Cement-based ultraviolet-proof tile joint mixture |
| CN104724982A (en) * | 2013-12-23 | 2015-06-24 | 久筑节能科技（天津）有限公司 | Gray ceramic tile adhesive 905 |
| CN104724981A (en) * | 2013-12-23 | 2015-06-24 | 久筑节能科技（天津）有限公司 | White ceramic tile adhesive 907 |
| CN104876501A (en) * | 2015-04-21 | 2015-09-02 | 济宁跃峰建材科技有限公司 | Crack sealer for building exterior wall tile, and preparation method and construction process thereof |
| CN105174805A (en) * | 2015-09-19 | 2015-12-23 | 孙军 | Waterproof accelerant of toilet ground gap filling agent and preparation method |
| CN105330249A (en) * | 2015-11-26 | 2016-02-17 | 上海域金澜优电子商务有限公司 | Production formula of seam beautifying agent with silver ions |
| CN105503072A (en) * | 2015-12-10 | 2016-04-20 | 华砂砂浆有限责任公司 | Tile grout composition and preparation method and application thereof |
| CN105645863A (en) * | 2015-12-31 | 2016-06-08 | 贵州中建建筑科研设计院有限公司 | Ultrafine powdery crack-resistant connection paste for connection of lightweight partition wall panel |
| CN105884286A (en) * | 2016-04-10 | 2016-08-24 | 欧振云 | Ceramic tile crack beautifying agent |
| CN107417200A (en) * | 2017-06-20 | 2017-12-01 | 合肥市淑芹美装饰工程有限公司 | A kind of ceramic wall and floor tile gap filler and preparation method thereof |
| CN107311595A (en) * | 2017-08-02 | 2017-11-03 | 合肥广民建材有限公司 | A kind of waterproof high viscosity tile grout and preparation method thereof |
| CN107365125A (en) * | 2017-09-08 | 2017-11-21 | 常州市奥普泰科光电有限公司 | A kind of preparation method of high-strength waterproof gap filler |
| CN107739172A (en) * | 2017-11-01 | 2018-02-27 | 贵州省独山县顺峰装潢建材厂 | A kind of gap filler of construction and decoration |
| CN108558305A (en) * | 2018-01-30 | 2018-09-21 | 富思特新材料科技发展股份有限公司 | The inorganic tile gap filler and preparation method thereof of squeezing and coating construction |
| CN110526656A (en) * | 2018-05-23 | 2019-12-03 | 佛山市科顺建筑材料有限公司 | A kind of fast high flexibility cement base gap filler and preparation method thereof firmly |
| CN114804753A (en) * | 2022-01-24 | 2022-07-29 | 东方雨虹砂粉科技集团有限公司 | Tile glue for pasting and joint filling and preparation method thereof |
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Free format text: CORRECT: INVENTOR; FROM: HAN CHAOHUI XIONG WEIFENG TO: HAN CHAOHUI XIONG WEIFENG REN PING |
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Effective date of registration: 20121206 Address after: 100025, Beijing, Chaoyang District Gaobeidian Kang homes District No. 4 Building Applicant after: Beijing Oriental Yuhong Waterproof Technology Co., Ltd. Applicant after: Xuzhou Woniushan New Waterproof Material Co., Ltd. Applicant after: Shanghai Oriental Yuhong Waterproof Technology Co., Ltd. Address before: 100025, Beijing, Chaoyang District Gaobeidian Kang homes District No. 4 Building Applicant before: Beijing Oriental Yuhong Waterproof Technology Co., Ltd. |
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Application publication date: 20120620 |