CN102501547B - Melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process - Google Patents
Melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process Download PDFInfo
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- CN102501547B CN102501547B CN201110354826.4A CN201110354826A CN102501547B CN 102501547 B CN102501547 B CN 102501547B CN 201110354826 A CN201110354826 A CN 201110354826A CN 102501547 B CN102501547 B CN 102501547B
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Abstract
The invention relates to a melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process. The melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process is characterized by comprising the following steps: synthesizing melamine formaldehyde resin; preparing melamine formaldehyde resin thin wood dipping adhesive; manufacturing dipping thin wood; processing patterns; and manufacturing patterned products, wherein in the step of pattern processing, the dipping wood is subjected to pattern processing by using a laser cutting machine according to the design requirement, so that the dipping wood is manufactured to be provided with laser cutting patterns. The melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process has the advantages that the cost is low and the efficiency is high; the product does not have brittleness and has high toughness and laser cutting patterns; the patterns are three-dimensional; and the solid wood has excellent sense of reality and the like.
Description
Technical field
The invention belongs to building and ornament materials manufacture craft, is a kind of melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process.
Background technology
Existing melamine resin dipped article mainly be take dipping decorative paper as main, also there is small part to adopt the goods of dipping decorative paper technique impreg skin, veneer, because the main distinction of veneer and facing paper is the inhomogeneities of its existence, the tensile strength perpendicular to grain of veneer is low, fragile when dipping and veneer operation, veneer rear surface easily produces be full of cracks, and when particularly veneer temperature is high, the defect producing is more obvious.Therefore, the existing technique with melamine resin impregnated paper can not meet the quality and performance requirement of impreg skin, veneer goods; Its goods exist the shortcomings such as fragility is large, poor toughness, and without radium-shine cutting pattern, parquets lacks third dimension, and the solid wood sense of reality is poor.
Summary of the invention
The object of the invention is, a kind of industrialization manufacture that is suitable for is provided, production cost is low, efficiency is high, its goods are without fragility, good toughness, have radium-shine cutting pattern, parquets has third dimension, the melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process that the solid wood sense of reality is good.
The object of the invention is to be realized by following technical scheme: a kind of melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process, it is characterized in that, it comprises, and melamine resin is synthetic, preparation, resin dipping thin wood manufacture, the figure of melamine resin veneer dipping adhesive are processed and parquets goods manufacturing step:
1) melamine resin is synthetic: in reactor, by the rate of charge of formaldehyde and melamine, be that 2.2:1mol/mol adds 37% formalin, under stirring condition, with 30% NaOH solution, adjusting reacting liquid pH value is 9.0～9.2, by mass parts, 100 parts of melamines and 10～12 parts of modifier 1 are joined in reactor, be warming up to 40 ℃, the urea that adds 30 parts, be warming up to 88-92 ℃, after insulation 20min, survey water dilution factor, when water dilution factor reaches 600%～520%, be cooled to 83-87 ℃, add 4～6 parts of modifier 2, reacting liquid pH value 8.0 in reactor, after insulation 60min, survey water dilution factor, when water dilution factor reaches 240%～220%, N with 30%
ait is 8.3～8.7 that OH solution is adjusted reacting liquid pH value, is cooled to 35 ℃ of blowings,
2) preparation of melamine resin veneer maceration extract adhesive: in the synthetic melamine resin of step 1), by mass parts, 100 parts of melamine resins, add 0.4 part of curing agent, 0.1 part of bleeding agent, 0.1 part of releasing agent, preparation melamine resin veneer dipping adhesive stirs;
3) resin dipping thin wood manufacture: the versicolor veneer that the 0.15～0.25mm that has again in advance nonwoven is thick immerses step 2 as ground floor and the thick veneer of the 0.2～0.4mm that has again nonwoven in advance as the second layer) in the melamine resin veneer dipping adhesive of preparation, the pickup of veneer is 135%, it is 10.0%～13.0% that veneer after dipping is dried to volatile content at 120～130 ℃, precuring degree 30%～40%;
4) figure processing: step 3) ground floor resin dipping thin wood is adopted to radium-shine laser cutting machine, carry out figure by designing requirement and be processed into the ground floor resin dipping thin wood with radium-shine cutting pattern;
5) parquets goods are manufactured:
(1) step 4) is there is to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick to and on second layer resin dipping thin wood, make parquets goods;
(2) step 4) is there is to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick on second layer resin dipping thin wood, again first and second layer of resin dipping thin wood adhering to and three ply board are carried out to hot-press gluing, its pressure is 1.2～1.3MPa, 125～130 ℃ of hot pressing temperatures, hot pressing time 1min makes parquets goods.
Described modifier 1 is mainly by forming by 70～75 parts of 20～30 parts of the ethylene glycol of mass parts, butanols.
Described modifier 2 is mainly by forming by 10～20 parts of 80～90 parts of the caprolactams of mass parts, para toluene sulfonamide.Described three ply board is glued board, core-board, solid wood board, veneer.
Melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process of the present invention is suitable for industrialization manufacture, veneer is in advance with non-woven fabric compounded, overcome veneer self intensity low, breadth is little, be unfavorable for industrialization quantity-produced disadvantage, veneer is through becoming after the compound veneer of large format with non-woven fabric compounded, can utilize existing impregnated paper production line to complete resin dipping thin wood produces, ground floor resin dipping thin wood adopts radium-shine laser cutting machine to carry out figure processing, there is production cost low, efficiency is high, its goods are without fragility, good toughness, there is radium-shine cutting pattern, parquets has third dimension, the advantages such as the solid wood sense of reality is good.
The specific embodiment
Melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process of the present invention comprises that melamine resin is synthetic, preparation, resin dipping thin wood manufacture, the figure of melamine resin veneer dipping adhesive are processed and parquets goods manufacturing step:
1) melamine resin is synthetic: in reactor, by the rate of charge of formaldehyde and melamine, be that 2.2:1mol/mol adds 37% formalin, under stirring condition, with 30% NaOH solution, adjusting reacting liquid pH value is 9.0～9.2, by mass parts, 100 parts of melamines and 10～12 parts of modifier 1 are joined in reactor, be warming up to 40 ℃, the urea that adds 30 parts, be warming up to 88-92 ℃, after insulation 20min, survey water dilution factor, when water dilution factor reaches 600%～520%, be cooled to 83-87 ℃, add 4～6 parts of modifier 2, reacting liquid pH value 8.0 in reactor, after insulation 60min, survey water dilution factor, when water dilution factor reaches 240%～220%, N with 30%
ait is 8.3～8.7 that OH solution is adjusted reacting liquid pH value, is cooled to 35 ℃ of blowings,
2) preparation of melamine resin veneer maceration extract adhesive: in the synthetic melamine resin of step 1), by mass parts, 100 parts of melamine resins, add 0.4 part of curing agent, 0.1 part of bleeding agent, 0.1 part of releasing agent, preparation melamine resin veneer dipping adhesive stirs;
3) resin dipping thin wood manufacture: the versicolor veneer that the 0.15～0.25mm that has again in advance nonwoven is thick immerses step 2 as ground floor and the thick veneer of the 0.2～0.4mm that has again nonwoven in advance as the second layer) in the melamine resin veneer dipping adhesive of preparation, the pickup of veneer is 135%, it is 10.0%～13.0% that veneer after dipping is dried to volatile content at 120～130 ℃, precuring degree 30%～40%;
4) figure processing: step 3) ground floor resin dipping thin wood is adopted to radium-shine laser cutting machine, carry out figure by designing requirement and be processed into the ground floor resin dipping thin wood with radium-shine cutting pattern;
5) parquets goods are manufactured:
(1) step 4) is there is to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick to and on second layer resin dipping thin wood, make parquets goods;
(2) step 4) is there is to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick on second layer resin dipping thin wood, again first and second layer of resin dipping thin wood and the 3rd layer of glued board, core-board or the solid wood that adhere to are carried out to hot-press gluing, its pressure is 1.2～1.3MPa, 125～130 ℃ of hot pressing temperatures, hot pressing time 1min makes parquets goods.
Modifier 1 is mainly by forming by 70～75 parts of 20～30 parts of the ethylene glycol of mass parts, butanols.
Modifier 2 is mainly by forming by 10～20 parts of 80～90 parts of the caprolactams of mass parts, para toluene sulfonamide.
Modifier 1 and 2 makes the modified melamine-formaldehyde resin synthesizing have certain toughness, and along with the increase of modifier 2 consumptions, the performances such as the toughness of melamine resin, muddy time progressively improve.
Curing agent used in the present invention adopts commercially available prod, is a kind of composite curing agent, and its main component is p-methyl benzenesulfonic acid, citric acid and acid-base balance agent.Because of resin dipping thin wood, particularly ring porous wood exists the conduit size difference being distributed in late wood's morning to cause the difference of density, and veneer superficial density is inhomogeneous, and there are the problems such as space part.Use curing agent can guarantee to show when low temperature, low pressure veneer overlay smooth, and the resin on resin dipping thin wood surface has stronger mobility at the hot pressing initial stage, in the hot pressing middle and later periods, can solidify rapidly.Bleeding agent adopts commercially available prod, and the main component of bleeding agent is JFC, polyoxyethylene ether compound.Because of late wood's difference morning that veneer exists, cause veneer different in whole breadth adhesive permeance property.Simultaneously because of veneer difficult discharge of himself contained gas in dipping process, use bleeding agent can make veneer reach as far as possible dipping evenly at whole breadth, and gas is discharged smoothly, and releasing agent adopts commercially available prod, and main component is that silicone compounds is poly-, ethylene glycol.Can make the demoulding smoothly under low temperature, low pressure condition of melamine-impregnated veneer, ensure that the addition of the prerequisite bottom knockout agent of the demoulding is more few better smoothly, releasing agent addition increases the glossiness that can affect plate face.
The melamine resin veneer dipping adhesive of the present invention's preparation is colourless transparent liquid, its solids content (%): 50%～53%, viscosity (25 ℃, mPaS): 18～25, pH value: 8.3～8.7, storage period (20 ℃, d): >=7.
Parquets goods adopt melamine resin dipping because of surface, and product surface is without covering with paint, lacquer, colour wash, etc. processing again, and its surface has the performance such as heat-resisting, wear-resisting preferably.As be further to improve its surface property, when manufacturing parquets goods, can increase the abrasion-proof paper that contains alundum (Al2O3) on ground floor surface and improve its anti-wear performance; Or when dipping ground floor and second layer resin dipping thin wood, in melamine resin, add the functional materials such as antiseptic, anti-wear agent, goods are had antibacterial, wear-resisting etc. functional.
specific embodiment 1～4.
Embodiment 1:1) melamine resin is synthetic, adds 37% formalin 141.6g in reactor, under stirring condition with 30% N
ait is 9.0～9.2 that OH solution is adjusted reacting liquid pH value, adds 10g modifier 1; Be warming up to 40 ℃, add melamine 100g, urea 30g; Be warming up to 88～92 ℃, after insulation 20min, survey water dilution factor, when water dilution factor reaches 600%～520%, be cooled to 83～87 ℃, add 4g modifier 2, the reacting liquid pH value in reactor should be 8.0, lower than 8.0, the NaOH solution with 30% is adjusted reacting liquid pH value 8.0; After insulation 60min, survey water dilution factor, when water dilution factor reaches 240%～220%, use immediately 30% N
ait is 8.3 that OH solution is adjusted reacting liquid pH value, is cooled to 35 ℃ of blowings; Can obtain goods 275～285g;
2) preparation of melamine resin veneer maceration extract adhesive: in synthetic 100g melamine resin, add the curing agent of 0.4g, the releasing agent of the bleeding agent of 0.1g, 0.1g stirs and prepares melamine resin veneer dipping adhesive;
3) resin dipping thin wood manufacture: the versicolor veneer that the 0.15mm that has again in advance nonwoven is thick immerses step 2 as ground floor and the thick veneer of the 0.2mm that has again nonwoven in advance as the second layer) in the melamine resin veneer dipping adhesive of preparation, the pickup of veneer is 135%, it is 10.0%～13.0% that veneer after dipping is dried to volatile content at 120～130 ℃, precuring degree 30%～40%;
4) figure processing: step 3) ground floor resin dipping thin wood is adopted to radium-shine laser cutting machine, carry out figure by designing requirement and be processed into the ground floor resin dipping thin wood with radium-shine cutting pattern;
5) parquets goods are manufactured: step 4) is had to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick to and on second layer resin dipping thin wood, make parquets goods.
Embodiment 2:1) melamine resin is synthetic, adds 37% formalin 141.6g in reactor, under stirring condition with 30% N
ait is 9.0～9.2 that OH solution is adjusted reacting liquid pH value, adds 11g modifier 1; Be warming up to 40 ℃, add melamine 100g, urea 30g; Be warming up to 88～92 ℃, after insulation 20min, survey water dilution factor, when water dilution factor reaches 600%～520%, be cooled to 83～87 ℃, add 5g modifier 2, the reacting liquid pH value in reactor should be 8.0, lower than 8.0, the NaOH solution with 30% is adjusted reacting liquid pH value 8.0; After insulation 60min, survey water dilution factor, when water dilution factor reaches 240%～220%, use immediately 30% N
ait is 8.3 that OH solution is adjusted reacting liquid pH value, is cooled to 35 ℃ of blowings; Can obtain goods 276～286g;
2) preparation of melamine resin veneer maceration extract adhesive: in synthetic 100g melamine resin, add the curing agent of 0.4g, the releasing agent of the bleeding agent of 0.1g, 0.1g stirs and prepares melamine resin veneer dipping adhesive;
3) resin dipping thin wood manufacture: the versicolor veneer that the 0.2mm that has again in advance nonwoven is thick immerses step 2 as ground floor and the thick veneer of the 0.3mm that has again nonwoven in advance as the second layer) in the melamine resin veneer dipping adhesive of preparation, the pickup of veneer is 135%, it is 10.0%～13.0% that veneer after dipping is dried to volatile content at 120～130 ℃, precuring degree 30%～40%;
4) figure processing: step 3) ground floor resin dipping thin wood is adopted to radium-shine laser cutting machine, carry out figure by designing requirement and be processed into the ground floor resin dipping thin wood with radium-shine cutting pattern;
5) parquets goods are manufactured: step 4) is had to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick to and on second layer resin dipping thin wood, make parquets goods.
Embodiment 3:1) melamine resin is synthetic, adds 37% formalin 141.6g in reactor, under stirring condition with 30% N
ait is 9.0～9.2 that OH solution is adjusted reacting liquid pH value, adds 12g modifier 1; Be warming up to 40 ℃, add melamine 100g, urea 30g; Be warming up to 88～92 ℃, after insulation 20min, survey water dilution factor, when water dilution factor reaches 600%～520%, be cooled to 83～87 ℃, add 6g modifier 2, the reacting liquid pH value in reactor should be 8.0, lower than 8.0, the NaOH solution with 30% is adjusted reacting liquid pH value 8.0; After insulation 60min, survey water dilution factor, when water dilution factor reaches 240%～220%, use immediately 30% N
ait is 8.3 that OH solution is adjusted reacting liquid pH value, is cooled to 35 ℃ of blowings; Can obtain goods 276～287g;
2) preparation of melamine resin veneer maceration extract adhesive: in synthetic 100g melamine resin, add the curing agent of 0.4g, the releasing agent of the bleeding agent of 0.1g, 0.1g stirs and prepares melamine resin veneer dipping adhesive;
3) resin dipping thin wood manufacture: the versicolor veneer that the 0.25mm that has again in advance nonwoven is thick immerses step 2 as ground floor and the thick veneer of the 0.4mm that has again nonwoven in advance as the second layer) in the melamine resin veneer dipping adhesive of preparation, the pickup of veneer is 135%, it is 10.0%～13.0% that veneer after dipping is dried to volatile content at 120～130 ℃, precuring degree 30%～40%;
4) figure processing: step 3) ground floor resin dipping thin wood is adopted to radium-shine laser cutting machine, carry out figure by designing requirement and be processed into the ground floor resin dipping thin wood with radium-shine cutting pattern;
5) parquets goods are manufactured: step 4) is had to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick to and on second layer resin dipping thin wood, make parquets goods.
Embodiment 4: the step 1) of embodiment 1-3,2), 3) and 4) identical with embodiment 1, just parquets goods manufacture 5) be step 4) to be there is to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick on second layer resin dipping thin wood, again first and second layer of resin dipping thin wood adhering to and three ply board are carried out to hot-press gluing, its pressure is 1.2～1.3MPa, 125～130 ℃ of hot pressing temperatures, and hot pressing time 1min makes parquets goods.Described three ply board is glued board, core-board, solid wood board, veneer or other wood-based plate, and its thickness is 0.5～25mm.
On the basis of embodiment 1～4, with melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process of the present invention, can realize the making of three layers of above parquets goods.
The raw material of melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process of the present invention also obtains, and is commercially available prod.
The specific embodiment of melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process of the present invention is also non exhaustive; the enlightenment that those skilled in the art obtain according to the present invention, copies and improves without creative work any the scope that all belongs to rights protection of the present invention.
Veneer of the present invention is to utilize the natural timber of the graceful changeable wood grain of rare tree etc. or the wood materials of artificial (laminated veneer lumber, integrated timber) texture, is the laminar timber that adopts slicing or half-round cut processing method to produce.Veneer is mainly as ornament materials, and sticker, on base material, improves decorative effect, meets the demand of people to precious timber.
It is described that to have again in advance the versicolor veneer of nonwoven be to form large format flexibility veneer with veneer hot-press gluing again after veneer adopts nonwoven dipping or spraying Lauxite with nonwoven.
Melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process of the present invention proves through the actual production of 6 months, have that production cost is low, efficiency is high, its goods, without fragility, good toughness, have radium-shine cutting pattern, parquets third dimension, the good texts of the solid wood sense of reality.
Claims (1)
1. a melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process, it is characterized in that, it comprises, and melamine resin is synthetic, preparation, resin dipping thin wood manufacture, the figure of melamine resin veneer dipping adhesive are processed and parquets goods manufacturing step:
1) melamine resin is synthetic: in reactor, by the rate of charge of formaldehyde and melamine, be that 2.2:1mol/mol adds 37% formalin, under stirring condition, with 30% NaOH solution, adjusting reacting liquid pH value is 9.0～9.2, by mass parts, 100 parts of melamines and 10～12 parts of modifier 1 are joined in reactor, be warming up to 40 ℃, the urea that adds 30 parts, be warming up to 88-92 ℃, after insulation 20min, survey water dilution factor, when water dilution factor reaches 600%～520%, be cooled to 83-87 ℃, add 4～6 parts of modifier 2, reacting liquid pH value 8.0 in reactor, after insulation 60min, survey water dilution factor, when water dilution factor reaches 240%～220%, N with 30%
ait is 8.3～8.7 that OH solution is adjusted reacting liquid pH value, be cooled to 35 ℃ of blowings, described modifier 1 is mainly by forming by 70～75 parts of 20～30 parts of the ethylene glycol of mass parts, butanols, and described modifier 2 is mainly by forming by 10～20 parts of 80～90 parts of the caprolactams of mass parts, para toluene sulfonamide,
2) preparation of melamine resin veneer maceration extract adhesive: in the synthetic melamine resin of step 1), by mass parts, 100 parts of melamine resins, add 0.4 part of curing agent, 0.1 part of bleeding agent, 0.1 part of releasing agent, preparation melamine resin veneer dipping adhesive stirs;
3) resin dipping thin wood manufacture: the versicolor veneer that the 0.15～0.25mm that has again in advance nonwoven is thick immerses step 2 as ground floor and the thick veneer of the 0.2～0.4mm that has again nonwoven in advance as the second layer) in the melamine resin veneer dipping adhesive of preparation, the pickup of veneer is 135%, it is 10.0%～13.0% that veneer after dipping is dried to volatile content at 120～130 ℃, precuring degree 30%～40%;
4) figure processing: step 3) ground floor resin dipping thin wood is adopted to radium-shine laser cutting machine, carry out figure by designing requirement and be processed into the ground floor resin dipping thin wood with radium-shine cutting pattern;
5) parquets goods are manufactured:
(1) step 4) is there is to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick to and on second layer resin dipping thin wood, make parquets goods;
(2) step 4) is there is to the ground floor resin dipping thin wood of radium-shine cutting pattern, by designing requirement, stick on second layer resin dipping thin wood, again first and second layer of resin dipping thin wood adhering to and three ply board are carried out to hot-press gluing, its pressure is 1.2～1.3MPa, 125～130 ℃ of hot pressing temperatures, hot pressing time 1min makes parquets goods.
2. melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process according to claim 1, is characterized in that: described three ply board is glued board, core-board, solid wood board, veneer.
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| CN201110354826.4A CN102501547B (en) | 2011-11-10 | 2011-11-10 | Melamine formaldehyde resin dipping thin wood laser cutting laminate patterned product process |
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| CN104611988A (en) * | 2015-01-13 | 2015-05-13 | 浙江帝龙新材料股份有限公司 | Environment-friendly surface glue film dry-pressing resin and application method thereof |
| CN104708681B (en) * | 2015-02-06 | 2016-08-24 | 林勇 | A kind of production technology of bamboo walling paper |
| CN104816574B (en) * | 2015-05-15 | 2017-05-17 | 北华大学 | Manufacturing method of veneer parquet mural |
| CN109266198A (en) * | 2018-09-20 | 2019-01-25 | 德华兔宝宝装饰新材股份有限公司 | A kind of manufacturing method of automatically cleaning decorative veneer |
| CN113072334A (en) * | 2020-01-06 | 2021-07-06 | 北华大学 | Method for manufacturing anti-freezing resin concrete ultrathin well cover |
| CN114892451A (en) * | 2022-06-02 | 2022-08-12 | 山东东宇鸿翔装饰材料有限公司 | Copper-nitrogen doped TiO 2 Antibacterial paper, antibacterial board and preparation method thereof |
| CN115256582A (en) * | 2022-08-22 | 2022-11-01 | 荣森(北京)科技有限公司 | Water-based melamine resin wood board |
| CN115256581A (en) * | 2022-08-22 | 2022-11-01 | 荣森(北京)科技有限公司 | Water-based melamine resin veneer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104328A (en) * | 2007-01-25 | 2008-01-16 | 庄启程 | Method for manufacturing wood skin decorative high-pressure laminates sheets based on thermosetting resins |
| CN101444924A (en) * | 2008-12-29 | 2009-06-03 | 张友全 | A panel decorated by synchronous relief melamine and the method of producing the same |
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| US20060057923A1 (en) * | 2004-09-10 | 2006-03-16 | Jaffee Alan M | Laminate products and methods of making the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104328A (en) * | 2007-01-25 | 2008-01-16 | 庄启程 | Method for manufacturing wood skin decorative high-pressure laminates sheets based on thermosetting resins |
| CN101444924A (en) * | 2008-12-29 | 2009-06-03 | 张友全 | A panel decorated by synchronous relief melamine and the method of producing the same |
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