CN105538839A - Paint-free reconstituted decorative veneer - Google Patents

Paint-free reconstituted decorative veneer Download PDF

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Publication number
CN105538839A
CN105538839A CN201610125946.XA CN201610125946A CN105538839A CN 105538839 A CN105538839 A CN 105538839A CN 201610125946 A CN201610125946 A CN 201610125946A CN 105538839 A CN105538839 A CN 105538839A
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China
Prior art keywords
paint
decorative veneer
recombinant decorative
paper
time
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CN201610125946.XA
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Chinese (zh)
Inventor
姚燕萍
卓艳
王文杰
姚思远
黄瑞斌
范丽娜
蔡云杰
孙伟胜
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Dehua TB New Decoration MaterialsCo Ltd
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Dehua TB New Decoration MaterialsCo Ltd
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Priority to CN201610125946.XA priority Critical patent/CN105538839A/en
Publication of CN105538839A publication Critical patent/CN105538839A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/06Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • B27D1/04Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/10Next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/06Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/08Impregnating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B43/00Operations specially adapted for layered products and not otherwise provided for, e.g. repairing; Apparatus therefor
    • B32B43/003Cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/10Interconnection of layers at least one layer having inter-reactive properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B2037/1269Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives multi-component adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0004Cutting, tearing or severing, e.g. bursting; Cutter details

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Forests & Forestry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Finished Plywoods (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention relates to reconstituted decorative veneer, in particular to a reconstituted decorative veneer with a paint-free surface and a manufacturing method of the veneer and belongs to the wood processing industry. The paint-free reconstituted decorative veneer is characterized by comprising a transparent wearing coat film adhesive layer, a reconstituted decorative veneer layer, an adhesive layer and a flexible reinforcing material layer sequentially from top to bottom, wherein the thickness of the reconstituted decorative veneer layer is 0.15-1.00 mm; the thickness of the flexible reinforcing material layer is 0.05-0.15 mm; the transparent wearing coat film adhesive layer is formed by dipping transparent wearing cost paper in an amino formaldehyde resin glue solution containing tourmaline powder and Al2O3; the particle size of the tourmaline anion powder is larger than 500 meshes and the quantity of anions in the Geiger-Muller area is larger than 3,000 ions/cc. Under the dual effects of the wearing coat paper and Al2O3, the surface wearing value of the prepared reconstituted decorative veneer with the paint-free surface is smaller than 50 mg/100 r.

Description

One exempts from paint recombinant decorative veneer
Technical field
The present invention relates to a kind of recombinant decorative veneer, particularly relate to a kind of recombinant decorative veneer and manufacture method thereof of non-painting veneer; Belong to wood working industry.
Background technology
Recombinant decorative veneer is for main raw material(s) with rotary-cut (or slicing) veneer of artificial forest or common tree lumber, the one of the technological means manufactures such as veneer is bleachinged and dyeing, laminated gluing, compression molding is adopted to have the novel wooden decorative panel square bar of natural rare tree timber speciality (texture, decorative pattern, color and luster etc.) or other art patterns, and then through slicing, rotary-cut or the fancy veneer sawing solution.
Recombinant decorative veneer, without natural defect, can reach the decorative effect that high-quality precious timber is desirable, ecological significance and social benefit remarkable.Recombinant decorative veneer is mainly pasted on various artificial board substrate surface for Furniture manufacture, or indoor decorating.In order to protect the surface decoration effect that recombinant decorative veneer is good; 2 (priming paint and finish paint) above paint finishings must be carried out at operation field, also need sanding before each paint, add the volatilization of organic solvent in coating; operating environment is extremely worsened, and workflow is very complicated also.Therefore the recombinant decorative veneer of non-painting veneer improves the best selection of works fine environment.
The thickness of recombinant decorative veneer is generally 0.15-1.00mm, and breadth is large, and soft exoskeletal supporting construction, and cover with paint, lacquer, colour wash, etc. operation continuously on its surface more difficult.Conventional flow process is that fancy veneer is first pasted on wood-base fibre and particle panel material substrate surface, and then carries out the operation such as sanding, covering with paint.
CN104631734A(2015-5-20) disclose a kind of paint free plate, but the feature of environmental protection of this paint free plate and wearability still have much room for improvement.
Summary of the invention
The object of this invention is to provide a kind of there is high-environmental and high-wearing feature exempt from paint recombinant decorative veneer.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs:
One exempts from paint recombinant decorative veneer, comprises transparent wear top layer glued membrane ply of paper from top to bottom successively, recombinant decorative ply, adhesive layer and flexible reinforced material layer; The thickness of described recombinant decorative ply is 0.15-1.00mm; The thickness of described flexible reinforced material layer is 0.05-0.15mm; Described transparent wear top layer glued membrane ply of paper is that transparent wear overlay paper is immersed in and comprises tourmaline powder and AL 2o 3amino formaldehyde resin glue in the glued membrane ply of paper that formed; The granularity of tourmaline anion powder is greater than 500 orders, at Geiger. and Miller region anion count number is greater than 3000ions/cc.
Amino formaldehyde resin is incorporated in the paper of wearing coat by maceration extract.After hot-press solidifying, form hard diaphragm on recombinant decorative veneer surface, thus reach the effect exempting to paint.No matter make furniture or interior decoration with it, all need not 2 paint finishings, shorten workflow, decrease the environmental pollution of operation field.Non-painting veneer recombinant decorative veneer of the present invention under the effect of tourmaline anion powder, surperficial sustainable generation 500/(s.cm 2) more than negative aeroion, play surface degerming, eliminate peculiar smell and pernicious gas, the effect purified the air of a room.Due to the far infrared band that its piezoelectricity produces, energy activating human body cells, regulates physiological activity, therefore has good health-care efficacy.At wearing coat paper and AL 2o 3double action under, the non-painting veneer recombinant decorative veneer surface abrasion value ﹤ 50mg/100r that the present invention obtains.
As preferably, described adhesive layer is Lauxite or cyanurotriamide modified urea resin layer.
More preferably, described wearing coat bond paper is quantitatively 18-65g/m 2.
As preferably, described flexible reinforced material is non-woven fabrics or brown paper.
Adopt specific flexible reinforced material, form framework supporting structure, operation can be covered with paint, lacquer, colour wash, etc. continuously.
One exempts from paint recombinant decorative veneer, adopts the following step to be prepared from:
1) slicing: recombinant decorative material slicing become thickness to be the recombinant decorative veneer of 0.15-1.00mm;
2) first time hot pressing: post flexible reinforced material at the back side of recombinant decorative veneer by first time hot pressing, the thickness of described flexible reinforced material is 0.05-0.15mm;
3) glue modulation: add tourmaline anion powder, AL in amino formaldehyde resin solution 2o 3, and stir; Wherein the mass ratio of amino formaldehyde resin solution and tourmaline powder is 100:(5-10), amino formaldehyde resin solution and AL 2o 3mass ratio be 100:(0.2-1);
4) transparent wear top layer glued membrane paper manufacture: by transparent wear overlay paper successively by common glue carry out first time impregnation and by contain tourmaline powder, AL 2o 3amino formaldehyde resin glue carry out second time impregnation, and to dry;
5) second time hot pressing: a recombinant decorative veneer compound wearing coat bond paper and back side being posted flexible reinforced material, and carry out second time hot pressing;
6) cutting edge;
7) post processing.
The present invention is by the tourmaline powder of specific proportioning and AL 2o 3add in the glue of specific modulation and be prepared into transparent wear top layer bond paper, what be then prepared into high-environmental and high-wearing feature by twice different hot-press method exempts from paint recombinant decorative veneer; Each pulp furnish during glue modulation has a significant impact with the performance exempting to paint recombinant decorative veneer, if amino formaldehyde resin solution content too high and tourmaline powder or AL 2o 3content too low, then wearability and the feature of environmental protection of exempting to paint recombinant decorative veneer do not reach requirement; If amino formaldehyde resin solution content too low and tourmaline powder or AL 2o 3too high levels, then exempt to paint the wearing no resistance of recombinant decorative veneer, intensity does not reach requirement.
As preferably, described step 2) first time hot pressing posts the adhesive of use for Lauxite or cyanurotriamide modified urea resin.
As preferably, described step 2) first time heat pressing process be: temperature 80-120 DEG C, pressure 0.3-1.0Mpa, time 50-180s.
As preferably, during described step 3) glue modulation, be also added with curing agent and releasing agent.
As preferably, the impregnation resin content of described step 4) first time impregnation and second time impregnation is respectively 100-130%; The quantitative of wearing coat bond paper is 18-65g/m 2.
The wearing coat bond paper of certain content and the proportioning of impregnation resin content, can make wearability, the feature of environmental protection and the intensity exempting to paint recombinant decorative veneer reach the effect of Synergistic.
As preferably, described step 5) second time heat pressing process is: temperature 100-130 DEG C, pressure 0.7-1.0Mpa, time 5-10min.
As preferably, described step 6) specifically cuts out burr removing with the product that chopper or specific purpose tool will overlay, and neatly stacks; Described step 7) specifically will be exempted from paint recombinant decorative on-board check, will grade, pack, put in storage.
In sum, the present invention has following beneficial effect:
1, amino formaldehyde resin is incorporated in the paper of wearing coat by maceration extract.After hot-press solidifying, form hard diaphragm on recombinant decorative veneer surface, thus reach the effect exempting to paint.No matter make furniture or interior decoration with it, all need not 2 paint finishings, shorten workflow, decrease the environmental pollution of operation field.
2, through the non-painting veneer recombinant decorative veneer that said method is obtained, under the effect of tourmaline anion powder, surperficial sustainable generation 500/(s.cm 2) more than negative aeroion, play surface degerming, eliminate peculiar smell and pernicious gas, the effect purified the air of a room.Due to the far infrared band that its piezoelectricity produces, energy activating human body cells, regulates physiological activity, therefore has good health-care efficacy.
3, at wearing coat paper and AL 2o 3double action under, through the non-painting veneer recombinant decorative veneer surface abrasion value ﹤ 50mg/100r that said method is obtained.
Detailed description of the invention
Embodiment 1
One exempts from paint recombinant decorative veneer, and the manufacture method of this veneer comprises the following steps:
A, slicing: recombinant decorative material slicing become thickness to be the recombinant decorative veneer of 0.35mm.
B, hot pressing: posting at the back side of recombinant decorative veneer is quantitatively 20g/m 2non-woven fabrics.The adhesive used is cyanurotriamide modified Lauxite.Heat pressing process is: pressure 0.5Mpa, temperature 110 DEG C, time 60s.
C, glue are modulated: in the pollopas solution that 100kg is cyanurotriamide modified, add tourmaline anion powder 5kg, AL that granularity is 800 orders, anion count number 5000ions/cc 2o 30.3kg, suitable curing agent, releasing agent etc., and stir.
D, transparent wear top layer glued membrane paper manufacture: transparent wear overlay paper passes through common glue successively and contains tourmaline powder, AL on special production line 2o 3cyanurotriamide modified urea resin glue, and dry, 2 times impregnation resin content is respectively 110%; The quantitative of wearing coat bond paper is 30g/m 2.
E, to overlay: a wearing coat bond paper and back side post the recombinant decorative veneer compound of non-woven fabrics, and send into hot pressing in hot press.Heat pressing process is: temperature 125 DEG C, pressure 0.8Mpa, time 5min.
F, cutting edge: with chopper, the product overlayed is cut out burr removing, neatly stack.
G, post processing: paint recombinant decorative on-board check will be exempted from by standard, grade, pack, put in storage.
Embodiment 2
One exempts from paint recombinant decorative veneer, and the manufacture method of this veneer comprises the following steps:
A, slicing: recombinant decorative material slicing become certain thickness to be the recombinant decorative veneer of 0.5mm.
B, hot pressing: posting at the back side of recombinant decorative veneer is quantitatively 35g/m 2brown paper.The adhesive used is Lauxite.Heat pressing process is: pressure 0.8Mpa, temperature 105 DEG C, time 100s.
C, glue are modulated: in the urea-formaldehyde resin solution that 100kg is cyanurotriamide modified, add tourmaline anion powder 8kg, AL that granularity is 1100 orders, anion count number 3000ions/cc 2o 30.5kg, suitable curing agent, releasing agent etc., and stir.
D, transparent wear top layer glued membrane paper manufacture: transparent wear overlay paper passes through common glue successively and contains tourmaline powder, AL on special production line 2o 3lauxite glue, and dry, 2 times impregnation resin content is respectively 100%; The quantitative of wearing coat bond paper is 35g/m 2.
E, to overlay: a wearing coat bond paper and back side post the recombinant decorative veneer compound of brown paper, and send into hot pressing in hot press.Heat pressing process is: temperature 110 DEG C, pressure 0.9Mpa, time 8min.
F, cutting edge: with chopper, the product overlayed is cut out burr removing, neatly stack.
G, post processing: paint recombinant decorative on-board check will be exempted from by standard, grade, pack, put in storage.
Embodiment three
Exempting from paint recombinant decorative veneer adopts the following step to be prepared from:
1) slicing: recombinant decorative material slicing become thickness to be the recombinant decorative veneer of 1.00mm;
2) first time hot pressing: post flexible reinforced material by first time hot pressing at the back side of recombinant decorative veneer, the adhesive layer used when first time hot pressing posts is Lauxite or cyanurotriamide modified urea resin layer; The thickness of flexible reinforced material is 0.15mm; Heat pressing process is for the first time: temperature 120 DEG C, pressure 1.0Mpa, time 50s;
3) glue modulation: add tourmaline anion powder, AL in amino formaldehyde resin solution 2o 3, curing agent and releasing agent, and to stir; Wherein the mass ratio of amino formaldehyde resin solution and tourmaline powder is 100:10, amino formaldehyde resin solution and AL 2o 3mass ratio be 100:1;
4) transparent wear top layer glued membrane paper manufacture: by transparent wear overlay paper successively by common glue carry out first time impregnation and by contain tourmaline powder, AL 2o 3amino formaldehyde resin glue carry out second time impregnation, and to dry; The impregnation resin content of impregnation and second time impregnation is respectively 130% for the first time; The quantitative of wearing coat bond paper is 65g/m 2;
5) second time hot pressing: a recombinant decorative veneer compound wearing coat bond paper and back side being posted flexible reinforced material, and carry out second time hot pressing; Second time heat pressing process is: temperature 130 DEG C, pressure 1.0Mpa, time 5min;
6) cutting edge: with chopper or specific purpose tool, the product overlayed is cut out burr removing, neatly stack;
7) post processing: paint recombinant decorative on-board check will be exempted from, grade, pack, put in storage.
The paint recombinant decorative veneer of exempting from finally made comprises transparent wear top layer glued membrane ply of paper from top to bottom, recombinant decorative ply, adhesive layer and flexible reinforced material layer successively; The granularity of tourmaline anion powder is greater than 500 orders, at Geiger. and Miller region anion count number is greater than 3000ions/cc.
Embodiment four
Exempting from paint recombinant decorative veneer adopts the following step to be prepared from:
1) slicing: recombinant decorative material slicing become thickness to be the recombinant decorative veneer of 0.15mm;
2) first time hot pressing: post flexible reinforced material by first time hot pressing at the back side of recombinant decorative veneer, the adhesive layer used when first time hot pressing posts is Lauxite or cyanurotriamide modified urea resin layer; The thickness of flexible reinforced material is 0.05mm; Heat pressing process is for the first time: temperature 80 DEG C, pressure 0.3Mpa, time 180s;
3) glue modulation: add tourmaline anion powder, AL in amino formaldehyde resin solution 2o 3, curing agent and releasing agent, and to stir; Wherein the mass ratio of amino formaldehyde resin solution and tourmaline powder is 100:5, amino formaldehyde resin solution and AL 2o 3mass ratio be 100:0.2; The granularity of tourmaline anion powder is greater than 500 orders, at Geiger. and Miller region anion count number is greater than 3000ions/cc;
4) transparent wear top layer glued membrane paper manufacture: by transparent wear overlay paper successively by common glue carry out first time impregnation and by contain tourmaline powder, AL 2o 3amino formaldehyde resin glue carry out second time impregnation, and to dry; The impregnation resin content of impregnation and second time impregnation is respectively 100% for the first time; The quantitative of wearing coat bond paper is 18g/m 2;
5) second time hot pressing: a recombinant decorative veneer compound wearing coat bond paper and back side being posted flexible reinforced material, and carry out second time hot pressing; Second time heat pressing process is: temperature 100 DEG C, pressure 0.7Mpa, time 10min;
6) cutting edge: with chopper or specific purpose tool, the product overlayed is cut out burr removing, neatly stack;
7) post processing: paint recombinant decorative on-board check will be exempted from, grade, pack, put in storage.
The paint recombinant decorative veneer of exempting from finally made comprises transparent wear top layer glued membrane ply of paper from top to bottom, recombinant decorative ply, adhesive layer and flexible reinforced material layer successively.
Embodiment five
Exempting from paint recombinant decorative veneer adopts the following step to be prepared from:
1) slicing: recombinant decorative material slicing become thickness to be the recombinant decorative veneer of 0.8mm;
2) first time hot pressing: post flexible reinforced material by first time hot pressing at the back side of recombinant decorative veneer, the adhesive layer used when first time hot pressing posts is Lauxite or cyanurotriamide modified urea resin layer; The thickness of flexible reinforced material is 0.1mm; Heat pressing process is for the first time: temperature 90 DEG C, pressure 0.8Mpa, time 90s;
3) glue modulation: add tourmaline anion powder, AL in amino formaldehyde resin solution 2o 3, curing agent and releasing agent, and to stir; Wherein the mass ratio of amino formaldehyde resin solution and tourmaline powder is 100:8, amino formaldehyde resin solution and AL 2o 3mass ratio be 100:0.6; Curing agent is ammonium chloride, ammonium sulfate, oxalic acid etc. or its mixture; Releasing agent is silicones metlyl branching silicone oil;
4) transparent wear top layer glued membrane paper manufacture: by transparent wear overlay paper successively by common glue carry out first time impregnation and by contain tourmaline powder, AL 2o 3amino formaldehyde resin glue carry out second time impregnation, and to dry; The impregnation resin content of impregnation and second time impregnation is respectively 110% for the first time; The quantitative of wearing coat bond paper is 45g/m 2;
5) second time hot pressing: a recombinant decorative veneer compound wearing coat bond paper and back side being posted flexible reinforced material, and carry out second time hot pressing; Second time heat pressing process is: temperature 110 DEG C, pressure 0.9Mpa, time 8min;
6) cutting edge: with chopper or specific purpose tool, the product overlayed is cut out burr removing, neatly stack;
7) post processing: paint recombinant decorative on-board check will be exempted from, grade, pack, put in storage.
The paint recombinant decorative veneer of exempting from finally made comprises transparent wear top layer glued membrane ply of paper from top to bottom, recombinant decorative ply, adhesive layer and flexible reinforced material layer successively; The granularity of tourmaline anion powder is greater than 500 orders, at Geiger. and Miller region anion count number is greater than 3000ions/cc.
After testing, the non-painting veneer recombinant decorative veneer sustainable generation in surface of the present invention 500/(s.cm 2) more than negative aeroion, surface abrasion value ﹤ 50mg/100r.
This specific embodiment is only explanation of the invention; it is not limitation of the present invention; those skilled in the art can make to the present embodiment the amendment not having creative contribution as required after reading this description, as long as but be all subject to the protection of Patent Law in right of the present invention.

Claims (10)

1. exempt from a paint recombinant decorative veneer, it is characterized in that comprising transparent wear top layer glued membrane ply of paper from top to bottom successively, recombinant decorative ply, adhesive layer and flexible reinforced material layer; The thickness of described recombinant decorative ply is 0.15-1.00mm; The thickness of described flexible reinforced material layer is 0.05-0.15mm; Described transparent wear top layer glued membrane ply of paper is that transparent wear overlay paper is immersed in and comprises tourmaline powder and AL 2o 3amino formaldehyde resin glue in the glued membrane ply of paper that formed; The granularity of tourmaline anion powder is greater than 500 orders, at Geiger. and Miller region anion count number is greater than 3000ions/cc.
2. one according to claim 1 exempts from paint recombinant decorative veneer, it is characterized in that described adhesive layer is Lauxite or cyanurotriamide modified urea resin layer.
3. one according to claim 2 exempts from paint recombinant decorative veneer, and that it is characterized in that described wearing coat bond paper is quantitatively 18-65g/m 2.
4. one according to claim 3 exempts from paint recombinant decorative veneer, it is characterized in that described flexible reinforced material is non-woven fabrics or brown paper.
5. the one according to any one of claim 1-4 exempts from paint recombinant decorative veneer, it is characterized in that adopting the following step to be prepared from:
1) slicing: recombinant decorative material slicing become thickness to be the recombinant decorative veneer of 0.15-1.00mm;
2) first time hot pressing: post flexible reinforced material at the back side of recombinant decorative veneer by first time hot pressing, the thickness of described flexible reinforced material is 0.05-0.15mm;
3) glue modulation: add tourmaline anion powder, AL in amino formaldehyde resin solution 2o 3, and stir; Wherein the mass ratio of amino formaldehyde resin solution and tourmaline powder is 100:(5-10), amino formaldehyde resin solution and AL 2o 3mass ratio be 100:(0.2-1);
4) transparent wear top layer glued membrane paper manufacture: by transparent wear overlay paper successively by common glue carry out first time impregnation and by contain tourmaline powder, AL 2o 3amino formaldehyde resin glue carry out second time impregnation, and to dry;
5) second time hot pressing: a recombinant decorative veneer compound wearing coat bond paper and back side being posted flexible reinforced material, and carry out second time hot pressing;
6) cutting edge;
7) post processing.
6. one according to claim 5 exempts from paint recombinant decorative veneer, it is characterized in that described step 2) first time heat pressing process be: temperature 80-120 DEG C, pressure 0.3-1.0Mpa, time 50-180s.
7. one according to claim 6 exempts from paint recombinant decorative veneer, is also added with curing agent and releasing agent when it is characterized in that described step 3) glue is modulated.
8. one according to claim 7 exempts from paint recombinant decorative veneer, it is characterized in that the impregnation resin content of described step 4) first time impregnation and second time impregnation is respectively 100-130%; The quantitative of wearing coat bond paper is 18-65g/m 2.
9. one according to claim 8 exempts from paint recombinant decorative veneer, it is characterized in that described step 5) second time heat pressing process is: temperature 100-130 DEG C, pressure 0.7-1.0Mpa, time 5-10min.
10. one according to claim 9 exempts from paint recombinant decorative veneer, it is characterized in that the product overlayed specifically is cut out burr removing with chopper or specific purpose tool by described step 6), neatly stacks; Described step 7) specifically will be exempted from paint recombinant decorative on-board check, will grade, pack, put in storage.
CN201610125946.XA 2016-03-07 2016-03-07 Paint-free reconstituted decorative veneer Pending CN105538839A (en)

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