CN105773736B - A kind of functional form exempts to paint recombinant decorative veneer - Google Patents
A kind of functional form exempts to paint recombinant decorative veneer Download PDFInfo
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- CN105773736B CN105773736B CN201610125924.3A CN201610125924A CN105773736B CN 105773736 B CN105773736 B CN 105773736B CN 201610125924 A CN201610125924 A CN 201610125924A CN 105773736 B CN105773736 B CN 105773736B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27D—WORKING VENEER OR PLYWOOD
- B27D1/00—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
- B27D1/04—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27D—WORKING VENEER OR PLYWOOD
- B27D1/00—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
- B27D1/04—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
- B27D1/08—Manufacture of shaped articles; Presses specially designed therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B21/06—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/40—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/32—Modified amine-aldehyde condensates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2479/00—Furniture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2601/00—Upholstery
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Forests & Forestry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to the recombinant decorative veneer and its manufacture method of a kind of recombinant decorative veneer, more particularly to a kind of functional form non-painting veneer；Belong to wood working industry.Functional form exempts to paint recombinant decorative veneer, it is characterised in that from top to bottom includes transparent wear top layer glued membrane ply of paper, recombinant decorative ply, adhesive layer and flexible reinforced material layer successively；The thickness of the recombinant decorative ply is 0.15 1.00mm；The thickness of the flexible reinforced material layer is 0.05 0.15mm；The transparent wear top layer glued membrane ply of paper is that transparent wear overlay paper is immersed in comprising tourmaline powder and AL2O3Amino formaldehyde resin glue in the glued membrane ply of paper that is formed；The granularity of tourmaline anion powder is more than 500 mesh, and in Geiger Miller regions, anion count number is more than 3000ions/cc.Paper and AL in wearing coat2O3Double action under, non-painting veneer recombinant decorative veneer surface abrasion value ﹤ 50mg/100r produced by the present invention.
Description
Technical field
The present invention relates to a kind of recombinant decorative veneer, more particularly to a kind of recombinant decorative veneer of non-painting veneer and its manufacture
Method；Belong to wood working industry.
Background technology
Recombinant decorative veneer is the rotary-cut with artificial forest or common tree lumber（Or slicing）Veneer is main raw material(s), is adopted
Bleachinged and dyeing with veneer, one kind that laminated gluing, the technological means such as compression molding are fabricated has natural rare tree timber speciality
（Texture, decorative pattern, color and luster etc.）Or the novel wooden decorative panel square bar of other art patterns, then again through slicing, rotary-cut or sawing
The fancy veneer formed.
Recombinant decorative veneer can reach the preferable decorative effect of high-quality precious timber, ecological significance and society without natural defect
Can remarkable benefit.Recombinant decorative veneer is mainly pasted on various artificial board substrate surfaces and is used for Furniture manufacture, or interior decoration dress
Repair.In order to protect the good surface decoration effect of recombinant decorative veneer, must be carried out 2 times in operation field（Priming paint and finish paint）More than
Paint finishing, sanding is also needed before paint every time, along with the volatilization of organic solvent in coating, operating environment is extremely deteriorated, work
Make flow also very complicated.Therefore the recombinant decorative veneer of non-painting veneer is to improve the best selection of works fine environment.
The thickness of recombinant decorative veneer is usually 0.15-1.00mm, and breadth is big, and soft bone free frame support structure, at it
It is relatively difficult that surface carries out continuous covering with paint operation.Conventional flow is that fancy veneer is first pasted on to wood-base fibre and particle panel material base material table
Face, the operations such as sanding, covering with paint are then carried out again.
CN104631734A（2015-5-20）Disclose a kind of paint free plate, but the feature of environmental protection of the paint free plate and wearability
Still have much room for improvement.
The content of the invention
It is an object of the invention to provide a kind of functional form with high-environmental and high-wearing feature to exempt to paint recombinant decorative veneer.
The present invention above-mentioned technical purpose technical scheme is that：
A kind of functional form exempts to paint recombinant decorative veneer, from top to bottom includes transparent wear top layer glued membrane ply of paper successively, recombinates
Fancy veneer layer, adhesive layer and flexible reinforced material layer；The thickness of the recombinant decorative ply is 0.15-1.00mm；Institute
The thickness for stating flexible reinforced material layer is 0.05-0.15mm；The transparent wear top layer glued membrane ply of paper is transparent wear overlay paper
It is immersed in and includes tourmaline powder and AL2O3Amino formaldehyde resin glue in the glued membrane ply of paper that is formed；The grain of tourmaline anion powder
Degree is more than 500 mesh, and in Geiger Miller regions, anion count number is more than 3000ions/cc；
Adhesive used in the adhesive layer is Lauxite or cyanurotriamide modified urea resin adhesive；
The preparation method of cyanurotriamide modified urea resin adhesive is：
A. 100 parts of formalin that mass concentration of weighing by weight is 36.5-37.4wt%, mass concentration 30-
50wt% alkaline substance solution 0.1-0.5 parts and 0.3-0.6 part Hyperbranched Polymer with Terminal Amido PAMAM, reactor is put into, is opened
Open stirring；
B. 1-4 part hexachlorocyclotriph,sphazenes are added by weight, are warming up to 50-55 DEG C, when being voluntarily warming up to 75-85 DEG C, are added
Add 35-55 part melamines, be continuously heating to 90-95 DEG C, react to obtain preliminary condensation polymer；
C. 40-45 part melamines are added in above-mentioned preliminary condensation polymer, and add 0.6-0.9 part para toluene sulfonamides,
Obtain the second condensation polymer；
20-30 part urea is added when the second condensation polymer D. being cooled into 70-75 DEG C, continues to react 8-12min, is cooled to
Plastic emitting at 30-50 DEG C.
The present invention is modified using para toluene sulfonamide, Hyperbranched Polymer with Terminal Amido PAMAM, adds urine stage by stage by several times
Element, melamine and formaldehyde, repeatedly feed intake, and make the intermediates content maximum of the modification muf resin glue in preparation process, so as to
To improve timber intensity, wearability and service life；Utilize a large amount of active officials of Hyperbranched Polymer with Terminal Amido PAMAM intramoleculars
It can roll into a ball with the highly branched characteristic of its structure to be modified muf resin, make the performance enhancement of resin, stability improves, free formaldehyde
Burst size is effectively controlled；Recombinant Wood burst size of methanal using the modified MUF adhesives processing of the present invention is less than 0.2mg/L,
Reach Japanese F ☆ ☆ ☆ ☆ standards；
Meanwhile the present invention using urea, melamine, formaldehyde as matrix, using in hexachlorocyclotriph,sphazene phosphorus chlorine key it is active
Property, chlorine is easy to be substituted, serial phosphazene compound (see reaction equation one) is made by substitution reaction, nucleophilic such as occurs with urea
Substitution reaction, add and polycondensation reaction is participated in matrix, so as to introduce phosphazenium groups（See reaction equation two）.Phosphazenium groups are hexa-atomic
Ring, quite stable, with P, N alternating double bond arrangement, exist with ring-type or linear structure, due to there is preferable collaboration between phosphorus, nitrogen
Effect, i.e. phosphorus have the heat-absorbing action of similar metaphosphoric acid, and nitrogen has the function that inert gas dilution oxygen, so that the present invention
Modified MUF adhesives have preferable high temperature resistant and flame retardant effect, and smoke and toxic gas are few, have environmentally friendly fire-retardant work
With.
Reaction equation one
Reaction equation two
The tourmaline powder and AL that the present invention passes through specific proportioning2O3 Add in the glue of specific modulation and be prepared into transparent wear
Top layer bond paper, the functional form that high-environmental and high-wearing feature are then prepared into by hot-press methods different twice exempt from paint restructuring
Fancy veneer；The performance that each raw material proportioning when glue is modulated is exempted to paint recombinant decorative veneer with functional form has a significant impact, if ammonia
Base formaldehyde resin solution too high levels and tourmaline powder or AL2O3Content it is too low, then functional form exempt from paint recombinant decorative veneer it is resistance to
Mill property and the feature of environmental protection do not reach requirement；Tourmaline powder or AL if amino formaldehyde resin solution content is too low2O3Too high levels,
Then functional form exempts to paint wearing no resistance for recombinant decorative veneer, and intensity does not reach requirement.
Amino formaldehyde resin is incorporated in the paper of wearing coat by maceration extract.After hot-press solidifying, on recombinant decorative veneer surface
Hard diaphragm is formed, thus reaches the effect for exempting from paint.No matter making furniture or interior decoration with it, without 2 paint
Cover with paint, lacquer, colour wash, etc., shorten workflow, reduce the environmental pollution of operation field.Non-painting veneer recombinant decorative veneer of the present invention is electric
In the presence of stone negative ion powder, 500/(s.cm of the sustainable generation in surface2) more than negative aeroion, play surface it is degerming,
Eliminate peculiar smell and pernicious gas, the effect to purify the air of a room., can activating human body due to far infrared band caused by its piezoelectricity
Cell, physiological activity is adjusted, therefore there is good health-care efficacy.Paper and AL in wearing coat2O3Double action under, this hair
Bright obtained non-painting veneer recombinant decorative veneer surface abrasion value ﹤ 50mg/100r.
Preferably, after the step D plastic emittings, the modified MUF adhesives in use, add 5-10 part formaldehyde
Agent for capturing and 1-3 part curing agent.
Preferably, the alkaline matter in the preparation method step A of the modified MUF adhesives is sodium hydroxide, hydroxide
Potassium, calcium hydroxide, barium hydroxide or ammoniacal liquor.
It is highly preferred that the quantification of 18-65g/m of the wearing coat bond paper2。
Preferably, the flexible reinforced material is non-woven fabrics or brown paper.
Using specific flexible reinforced material, framework supporting structure is formed, can carry out continuously covering with paint, lacquer, colour wash, etc. operation.
Preferably, the step 2）It is Lauxite or cyanurotriamide modified that first time hot pressing, which posts the adhesive used,
Lauxite.
Preferably, the step 2）First time heat pressing process is：80-120 DEG C of temperature, pressure 0.3-1.0Mpa, time
50-180s。
Preferably, the step 3）Glue is also added with curing agent and releasing agent when modulating.
Preferably, the step 4）The impregnation resin content of first time impregnation and second of impregnation is respectively 100-130%；It is wear-resisting
The quantification of 18-65g/m of top layer bond paper2。
The wearing coat bond paper of certain content and the proportioning of impregnation resin content, functional form can be made to exempt to paint recombinant decorative veneer
Wearability, the feature of environmental protection and intensity have the function that Synergistic.
Preferably, the step 5）Second of heat pressing process be：100-130 DEG C of temperature, pressure 0.7-1.0Mpa, time
5-10min。
Preferably, the step 6）The product overlayed is specifically cut out into burr removing with chopper or specific purpose tool, neatly
Stack；The step 7）Functional form specifically is exempted to paint recombinant decorative on-board check, grades, pack, be put in storage.
In summary, the invention has the advantages that：
1st, amino formaldehyde resin is incorporated in the paper of wearing coat by maceration extract.After hot-press solidifying, in recombinant decorative veneer table
Face forms hard diaphragm, thus reaches the effect for exempting from paint.No matter furniture or interior decoration are made with it, without 2 oil
Paint is covered with paint, lacquer, colour wash, etc., and is shortened workflow, is reduced the environmental pollution of operation field.
2nd, through non-painting veneer recombinant decorative veneer made from the above method, in the presence of tourmaline anion powder, surface
500/(s.cm of sustainable generation2) more than negative aeroion, play that surface is degerming, eliminates peculiar smell and pernicious gas, purification
The effect of room air.Due to far infrared band caused by its piezoelectricity, energy activating human body cells, physiological activity is adjusted, therefore
With good health-care efficacy.
3rd, in wearing coat paper and AL2O3Double action under, through non-painting veneer recombinant decorative veneer made from the above method
Surface abrasion value ﹤ 50mg/100r.
Embodiment
Embodiment 1
A kind of functional form exempts to paint recombinant decorative veneer, and the manufacture method of the veneer comprises the following steps：
A, slicing：Recombinant decorative veneer by recombinant decorative material slicing into thickness for 0.35mm.
B, first time hot pressing：Quantification of 20g/m is posted at the back side of recombinant decorative veneer2Non-woven fabrics.Heat pressing process is：Pressure
Power 0.5Mpa, 110 DEG C of temperature, time 60s.
C, glue is modulated：It is 800 mesh, anion that granularity is added in the cyanurotriamide modified pollopas solution of 100kg
Count number 5000ions/cc tourmaline anion powder 5kg, AL2O30.3kg, appropriate curing agent, releasing agent etc., and stir equal
It is even.
D, glued membrane paper in transparent wear top layer manufactures：Transparent wear overlay paper passes sequentially through common glue on special production line
With contain tourmaline powder, AL2O3Cyanurotriamide modified urea resin glue, and dry, 2 times impregnation resin content is respectively 110%；It is wear-resisting
The quantification of 30g/m of top layer bond paper2。
E, second of hot pressing overlays：One wearing coat bond paper and a back side post the recombinant decorative veneer of non-woven fabrics
It is compound, and it is sent into hot pressing in hot press.Heat pressing process is：125 DEG C, pressure 0.8Mpa, time 5min of temperature.
F, cutting edge：The product overlayed is cut out into burr removing with chopper, it is neat to stack.
G, post-process：Functional form is exempted to paint recombinant decorative on-board check by standard, grades, pack, be put in storage.
Adhesive used in the adhesive layer that first time hot pressing uses when posting is cyanurotriamide modified urea resin adhesive；
The preparation method of modified MUF adhesives is：
A. parts by weight are weighed the alkali that 100 parts of formalin that mass concentration is 36.5wt%, mass concentration be 30wt%
Property 0.1 part and 0.3 part Hyperbranched Polymer with Terminal Amido PAMAM of substance solution, put into reactor, open stirring；Alkaline matter is
Sodium hydroxide, potassium hydroxide, calcium hydroxide, barium hydroxide or ammoniacal liquor；
B. 1 part of hexachlorocyclotriph,sphazene is added, is warming up to 50 DEG C, when being voluntarily warming up to 75 DEG C, adds 35 parts of melamines, after
It is continuous to be warming up to 90 DEG C, react to obtain preliminary condensation polymer；
C. 40 parts of melamines are added in above-mentioned preliminary condensation polymer, and adds 0.6 part of para toluene sulfonamide, obtain second
Condensation polymer；
20 parts of urea are added when the second condensation polymer D. being cooled into 70 DEG C, continue to react 8min, plastic emitting when being cooled to 30 DEG C.
Embodiment 2
A kind of functional form exempts to paint recombinant decorative veneer, and the manufacture method of the veneer comprises the following steps：
A, slicing：Recombinant decorative veneer by recombinant decorative material slicing into certain thickness for 0.5mm.
B, first time hot pressing：Quantification of 35g/m is posted at the back side of recombinant decorative veneer2Brown paper.Heat pressing process is：Pressure
Power 0.8Mpa, 105 DEG C of temperature, time 100s.
C, glue is modulated：It is 1100 mesh, anion that granularity is added in the cyanurotriamide modified urea-formaldehyde resin solutions of 100kg
Count number 3000ions/cc tourmaline anion powder 8kg, AL2O30.5kg, appropriate curing agent, releasing agent etc., and stir equal
It is even.
D, glued membrane paper in transparent wear top layer manufactures：Transparent wear overlay paper passes sequentially through common glue on special production line
With contain tourmaline powder, AL2O3Lauxite glue, and dry, 2 times impregnation resin content is respectively 100%；Wearing coat bond paper
Quantification of 35g/m2。
E, first time hot pressing overlays：One wearing coat bond paper and a back side post the recombinant decorative veneer of brown paper
It is compound, and it is sent into hot pressing in hot press.Heat pressing process is：110 DEG C, pressure 0.9Mpa, time 8min of temperature.
F, cutting edge：The product overlayed is cut out into burr removing with chopper, it is neat to stack.
G, post-process：Functional form is exempted to paint recombinant decorative on-board check by standard, grades, pack, be put in storage.
Adhesive used in the adhesive layer that first time hot pressing uses when posting is cyanurotriamide modified urea resin adhesive；
The preparation method of modified MUF adhesives is：
A. parts by weight are weighed the alkali that 100 parts of formalin that mass concentration is 37.4wt%, mass concentration be 50wt%
Property 0.5 part and 0.6 part Hyperbranched Polymer with Terminal Amido PAMAM of substance solution, put into reactor, open stirring；Alkaline matter is
Sodium hydroxide, potassium hydroxide, calcium hydroxide, barium hydroxide or ammoniacal liquor；
B. 1 part of hexachlorocyclotriph,sphazene is added, is warming up to 55 DEG C, when being voluntarily warming up to 85 DEG C, adds 55 parts of melamines, after
It is continuous to be warming up to 95 DEG C, react to obtain preliminary condensation polymer；
C. 45 parts of melamines are added in above-mentioned preliminary condensation polymer, and adds 0.9 part of para toluene sulfonamide, obtain second
Condensation polymer；
30 parts of urea are added when the second condensation polymer D. being cooled into 75 DEG C, continues to react 12min, goes out when being cooled to 50 DEG C
Glue.
Embodiment three
Functional form is exempted from paint recombinant decorative veneer and is prepared using the following steps：
1）Slicing：Recombinant decorative veneer by recombinant decorative material slicing into thickness for 1.00mm；
2）First time hot pressing：Flexible reinforced material is posted by first time hot pressing at the back side of recombinant decorative veneer；It is flexible
The thickness of reinforcing material is 0.15mm；First time heat pressing process is：120 DEG C, pressure 1.0Mpa, time 50s of temperature；
3）Glue is modulated：Tourmaline anion powder, AL are added in amino formaldehyde resin solution2O3, curing agent and the demoulding
Agent, and stir；Wherein the mass ratio of amino formaldehyde resin solution and tourmaline powder is 100：10, amino formaldehyde resin solution
With AL2O3Mass ratio be 100：1；
4）The glued membrane paper manufacture of transparent wear top layer：Transparent wear overlay paper is passed sequentially through into common glue and carries out first time leaching
Glue and by containing tourmaline powder, AL2O3Amino formaldehyde resin glue carry out second of impregnation, and dry；First time impregnation and
The impregnation resin content of second of impregnation is respectively 130%；The quantification of 65g/m of wearing coat bond paper2；
5）Second of hot pressing：One wearing coat bond paper and a back side are posted to the re-assemble of flexible reinforcing material
It is compound to adorn veneer, and carries out second of hot pressing；Second of heat pressing process be：130 DEG C, pressure 1.0Mpa, time 5min of temperature；
6）Cutting edge：The product overlayed is cut out into burr removing with chopper or specific purpose tool, it is neat to stack；
7）Post processing：Functional form is exempted to paint recombinant decorative on-board check, grades, pack, be put in storage.
The functional form being finally made exempts from paint recombinant decorative veneer from top to bottom includes transparent wear top layer glued membrane ply of paper successively,
Recombinant decorative ply, adhesive layer and flexible reinforced material layer；The granularity of tourmaline anion powder is more than 500 mesh, in Geiger
Miller region anion count number is more than 3000ions/cc.
Adhesive used in the adhesive layer that first time hot pressing uses when posting is cyanurotriamide modified urea resin adhesive；
The preparation method of modified MUF adhesives is：
A. parts by weight are weighed the alkali that 100 parts of formalin that mass concentration is 36.9wt%, mass concentration be 40wt%
Property 0.4 part and 0.5 part Hyperbranched Polymer with Terminal Amido PAMAM of substance solution, put into reactor, open stirring；Alkaline matter is
Sodium hydroxide, potassium hydroxide, calcium hydroxide, barium hydroxide or ammoniacal liquor；
B. 3 parts of hexachlorocyclotriph,sphazenes are added, are warming up to 53 DEG C, when being voluntarily warming up to 80 DEG C, add 45 parts of melamines, after
It is continuous to be warming up to 92 DEG C, react to obtain preliminary condensation polymer；
C. 43 parts of melamines are added in above-mentioned preliminary condensation polymer, and adds 0.8 part of para toluene sulfonamide, obtain second
Condensation polymer；
20-30 part urea is added when the second condensation polymer D. being cooled into 72 DEG C, continues to react 9min, goes out when being cooled to 40 DEG C
Glue.
Example IV
With embodiment one, the difference is that after step D plastic emittings, modified MUF adhesives in use, add 5 parts of formaldehyde
Agent for capturing and 1 part of curing agent；
The preparation method of formaldehyde catching agent is：10 parts of urea are crushed, add 5 melamines, 8 parts of p-methyl benzenesulfonic acid
Two hydrazides, 6 parts of sulfanilic acids, 1 part of nano silicon, stir；
The preparation method of curing agent is：100 parts of water are added in reactor, open stirring, are warming up to 40 DEG C, addition 20
Part aluminum sulfate, 15 parts of p-methyl benzenesulfonic acid, dissolving is complete, is down to room temperature discharging.
After modified MUF adhesive preparation methods are additionally included in the addition formaldehyde catching agent, then addition first is compound successively
11 parts of 6 parts of conditioning agent and the second composite regulator；
First composite regulator is by mass ratio 1：3：Tricaprylmethyl ammonium bromide, the glycerine and poly- four of 2 proportionings
PVF forms；
Second composite regulator is by mass ratio 1：2：Diphenylamines, 2,6- di-t-butyls and the nitrogen of benzo three of 3 proportionings
Azoles forms.
Embodiment five
With embodiment two, the difference is that after step D plastic emittings, modified MUF adhesives in use, add 5 parts of formaldehyde
Agent for capturing and 3 parts of curing agent；
The preparation method of formaldehyde catching agent is：20 parts of urea are crushed, add 10 melamines, 12 parts to toluene
Sulphur acid dihydrazide, 7 parts of sulfanilic acids, 2 parts of nano silicons, stir；
The preparation method of curing agent is：100 parts of water are added in reactor, open stirring, are warming up to 50 DEG C, addition 30
Part aluminum sulfate, 10 parts of p-methyl benzenesulfonic acid, dissolving is complete, is down to room temperature discharging.
After modified MUF adhesive preparation methods are additionally included in the addition formaldehyde catching agent, then addition first is compound successively
11 parts of 9 parts of conditioning agent and the second composite regulator；
First composite regulator is by mass ratio 1：4：Tricaprylmethyl ammonium bromide, the glycerine and poly- four of 1 proportioning
PVF forms；
Second composite regulator is by mass ratio 1：4：Diphenylamines, 2,6- di-t-butyls and the nitrogen of benzo three of 1 proportioning
Azoles forms.
Embodiment six
With embodiment three, the difference is that after step D plastic emittings, modified MUF adhesives in use, add 6 parts of formaldehyde
Agent for capturing and 2 parts of curing agent；
The preparation method of formaldehyde catching agent is：15 parts of urea are crushed, add 8 melamines, 11 parts to toluene sulphur
Acid dihydrazide, 6.5 parts of sulfanilic acids, 1.2 parts of nano silicons, stir；
The preparation method of curing agent is：100 parts of water are added in reactor, open stirring, are warming up to 45 DEG C, addition 25
Part aluminum sulfate, 12 parts of p-methyl benzenesulfonic acid, dissolving is complete, is down to room temperature discharging.
After modified MUF adhesive preparation methods are additionally included in the addition formaldehyde catching agent, then addition first is compound successively
7 parts of 8 parts of conditioning agent and the second composite regulator；
First composite regulator is by mass ratio 1：3.4：1.2 proportioning tricaprylmethyl ammonium bromides, glycerine and
Polytetrafluoroethylene (PTFE) forms；
Second composite regulator is by mass ratio 1：2.4：Diphenylamines, 2,6- di-t-butyls and the benzo of 1.3 proportionings
Triazole forms.
Embodiment seven
Functional form is exempted from paint recombinant decorative veneer and is prepared using the following steps：
1）Slicing：Recombinant decorative veneer by recombinant decorative material slicing into thickness for 0.15mm；
2）First time hot pressing：Flexible reinforced material is posted by first time hot pressing at the back side of recombinant decorative veneer, first
The adhesive layer that secondary hot pressing uses when posting is Lauxite；The thickness of flexible reinforced material is 0.05mm；First time hot pressing work
Skill is：80 DEG C, pressure 0.3Mpa, time 180s of temperature；
3）Glue is modulated：Tourmaline anion powder, AL are added in amino formaldehyde resin solution2O3, curing agent and the demoulding
Agent, and stir；Wherein the mass ratio of amino formaldehyde resin solution and tourmaline powder is 100：5, amino formaldehyde resin solution
With AL2O3Mass ratio be 100：0.2；The granularity of tourmaline anion powder is more than 500 mesh, and in Geiger Miller regions, anion counts
Amount is more than 3000ions/cc；
4）The glued membrane paper manufacture of transparent wear top layer：Transparent wear overlay paper is passed sequentially through into common glue and carries out first time leaching
Glue and by containing tourmaline powder, AL2O3Amino formaldehyde resin glue carry out second of impregnation, and dry；First time impregnation and
The impregnation resin content of second of impregnation is respectively 100%；The quantification of 18g/m of wearing coat bond paper2；
5）Second of hot pressing：One wearing coat bond paper and a back side are posted to the re-assemble of flexible reinforcing material
It is compound to adorn veneer, and carries out second of hot pressing；Second of heat pressing process be：100 DEG C, pressure 0.7Mpa, time 10min of temperature；
6）Cutting edge：The product overlayed is cut out into burr removing with chopper or specific purpose tool, it is neat to stack；
7）Post processing：Functional form is exempted to paint recombinant decorative on-board check, grades, pack, be put in storage.
The functional form being finally made exempts from paint recombinant decorative veneer from top to bottom includes transparent wear top layer glued membrane ply of paper successively,
Recombinant decorative ply, adhesive layer and flexible reinforced material layer.
Embodiment eight
Functional form is exempted from paint recombinant decorative veneer and is prepared using the following steps：
1）Slicing：Recombinant decorative veneer by recombinant decorative material slicing into thickness for 0.8mm；
2）First time hot pressing：Flexible reinforced material is posted by first time hot pressing at the back side of recombinant decorative veneer, first
The adhesive layer that secondary hot pressing uses when posting is Lauxite；The thickness of flexible reinforced material is 0.1mm；First time heat pressing process
For：90 DEG C, pressure 0.8Mpa, time 90s of temperature；
3）Glue is modulated：Tourmaline anion powder, AL are added in amino formaldehyde resin solution2O3, curing agent and the demoulding
Agent, and stir；Wherein the mass ratio of amino formaldehyde resin solution and tourmaline powder is 100：8, amino formaldehyde resin solution
With AL2O3Mass ratio be 100：0.6；Curing agent is ammonium chloride, ammonium sulfate, oxalic acid etc. or its mixture；Releasing agent is silicones
Metlyl branching silicone oil；
4）The glued membrane paper manufacture of transparent wear top layer：Transparent wear overlay paper is passed sequentially through into common glue and carries out first time leaching
Glue and by containing tourmaline powder, AL2O3Amino formaldehyde resin glue carry out second of impregnation, and dry；First time impregnation and
The impregnation resin content of second of impregnation is respectively 110%；The quantification of 45g/m of wearing coat bond paper2；
5）Second of hot pressing：One wearing coat bond paper and a back side are posted to the re-assemble of flexible reinforcing material
It is compound to adorn veneer, and carries out second of hot pressing；Second of heat pressing process be：110 DEG C, pressure 0.9Mpa, time 8min of temperature；
6）Cutting edge：The product overlayed is cut out into burr removing with chopper or specific purpose tool, it is neat to stack；
7）Post processing：Functional form is exempted to paint recombinant decorative on-board check, grades, pack, be put in storage.
The functional form being finally made exempts from paint recombinant decorative veneer from top to bottom includes transparent wear top layer glued membrane ply of paper successively,
Recombinant decorative ply, adhesive layer and flexible reinforced material layer；The granularity of tourmaline anion powder is more than 500 mesh, in Geiger
Miller region anion count number is more than 3000ions/cc.
After testing, 500/(s.cm of the sustainable generation in non-painting veneer recombinant decorative veneer surface of the present invention2) more than sky
Gas anion, surface abrasion value ﹤ 50mg/100r.
This specific embodiment is only explanation of the invention, and it is not limitation of the present invention, people in the art
Member can make the modification of no creative contribution to the present embodiment as needed after this specification is read, but as long as at this
All protected in the right of invention by Patent Law.
Claims (3)
1. a kind of functional form exempts to paint recombinant decorative veneer, it is characterised in that from top to bottom includes transparent wear top layer bond paper successively
Layer, recombinant decorative ply, adhesive layer and flexible reinforced material layer；The thickness of the recombinant decorative ply is 0.15-
1.00mm；The transparent wear top layer glued membrane ply of paper is that transparent wear overlay paper is immersed in comprising tourmaline anion powder and AL2O3
Amino formaldehyde resin glue in the glued membrane ply of paper that is formed；The granularity of tourmaline anion powder is more than 500 mesh, in Geiger Millers
Area's anion count number is more than 3000ions/cc；
Adhesive used in the adhesive layer is cyanurotriamide modified urea resin adhesive；
The preparation method of cyanurotriamide modified urea resin adhesive is：
100 parts of the formalin that mass concentration of weighing by weight is 36.5-37.4wt%, mass concentration are 30-50wt%'s
Alkaline substance solution 0.1-0.5 parts and 0.3-0.6 part Hyperbranched Polymer with Terminal Amido PAMAM, reactor is put into, open stirring；
1-4 part hexachlorocyclotriph,sphazenes are added by weight, are warming up to 50-55 DEG C, when being voluntarily warming up to 75-85 DEG C, add 35-55
Part melamine, is continuously heating to 90-95 DEG C, reacts to obtain preliminary condensation polymer；
40-45 part melamines are added in above-mentioned preliminary condensation polymer, and add 0.6-0.9 part para toluene sulfonamides, obtain the
Two condensation polymers；
20-30 part urea is added when second condensation polymer is cooled into 70-75 DEG C, continues to react 8-12min, is cooled to 30-50 DEG C
When plastic emitting；
After plastic emitting, the cyanurotriamide modified urea resin adhesive in use, addition 5-10 parts formaldehyde catching agent and
1-3 part curing agent；
Functional form is exempted from paint recombinant decorative veneer and is prepared using the following steps：
1）Slicing：Recombinant decorative veneer by recombinant decorative material slicing into thickness for 0.15-1.00mm；
2）First time hot pressing：Flexible reinforced material, the flexibility are posted by first time hot pressing at the back side of recombinant decorative veneer
The thickness of reinforcing material is 0.05-0.15mm；
3）Glue is modulated：Tourmaline anion powder, AL are added in amino formaldehyde resin solution2O3, and stir；Wherein ammonia
The mass ratio of base formaldehyde resin solution and tourmaline anion powder is 100：（5-10）, amino formaldehyde resin solution and AL2O3Matter
Amount is than being 100：（0.2-1）；
4）The glued membrane paper manufacture of transparent wear top layer：By transparent wear overlay paper pass sequentially through common glue carry out first time impregnation and
By containing tourmaline anion powder, AL2O3Amino formaldehyde resin glue carry out second of impregnation, and dry；
5）Second of hot pressing：One wearing coat bond paper and a back side are posted to the recombinant decorative of flexible reinforcing material
Veneer is compound, and carries out second of hot pressing；
6）Cutting edge；
7）Post processing；
The step 2）First time heat pressing process is：80-120 DEG C of temperature, pressure 0.3-1.0MPa, time 50-180s；
The step 3）Glue is also added with curing agent and releasing agent when modulating；
The step 4）The impregnation resin content of first time impregnation and second of impregnation is respectively 100-130%；Wearing coat bond paper is determined
Measure as 18-65g/m2；
The step 5）Second of heat pressing process be：100-130 DEG C of temperature, pressure 0.7-1.0MPa, time 5-10min.
2. a kind of functional form according to claim 1 exempts to paint recombinant decorative veneer, it is characterised in that the flexible reinforced material
Expect for non-woven fabrics or brown paper.
3. a kind of functional form according to right wants 1 exempts to paint recombinant decorative veneer, it is characterised in that the step 6）Specifically
The product overlayed is cut out into burr removing with chopper or specific purpose tool, it is neat to stack；The step 7）Specifically functional form is exempted to paint
Recombinant decorative on-board check, grade, pack, being put in storage.
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| CN106182217A (en) * | 2016-08-23 | 2016-12-07 | 浙江升华云峰新材股份有限公司 | A kind of oxygen wearable environment protection type ecological board and production technology thereof of living |
| CN107234684A (en) * | 2017-07-25 | 2017-10-10 | 德华兔宝宝装饰新材股份有限公司 | Anion function health paint-free ecological plate and its manufacture method |
| CN107447575A (en) * | 2017-08-10 | 2017-12-08 | 浙江宜佳新材料股份有限公司 | A kind of production technology of negative ion furniture paper |
| CN107513892A (en) * | 2017-08-10 | 2017-12-26 | 浙江宜佳新材料股份有限公司 | A kind of production technology of Photocatalyst anion furniture paper |
| CN109049173A (en) * | 2018-07-13 | 2018-12-21 | 云南新泽兴人造板有限公司 | Negative oxygen ion Surface decorated woodbased panels with paper impregnated thermosetting resins and production technology |
| CN109719809A (en) * | 2019-01-15 | 2019-05-07 | 临沂大瑞木业有限公司 | A kind of compound veneer of solid wood paint-free |
| CN113618867A (en) * | 2021-07-22 | 2021-11-09 | 左众文 | Manufacturing method of environment-friendly heavy-duty decorative plate |
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