CN102497930B - 光潜钛螯合物催化剂 - Google Patents
光潜钛螯合物催化剂 Download PDFInfo
- Publication number
- CN102497930B CN102497930B CN201080041002.5A CN201080041002A CN102497930B CN 102497930 B CN102497930 B CN 102497930B CN 201080041002 A CN201080041002 A CN 201080041002A CN 102497930 B CN102497930 B CN 102497930B
- Authority
- CN
- China
- Prior art keywords
- linear
- alkyl
- hydrogen
- branching
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- ZIEDITZGUQHESI-UJSYLISESA-L CC(C)O[Tl](OC(C)C)(O/C(/c1ccccc1)=C\C(C(C)(C)C)=O)O/C(/c1ccccc1)=C\C(C(C)(C)C)=O Chemical compound CC(C)O[Tl](OC(C)C)(O/C(/c1ccccc1)=C\C(C(C)(C)C)=O)O/C(/c1ccccc1)=C\C(C(C)(C)C)=O ZIEDITZGUQHESI-UJSYLISESA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0214—Aryloxylates, e.g. phenolates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09170294 | 2009-09-15 | ||
| EP09170294.4 | 2009-09-15 | ||
| PCT/EP2010/062779 WO2011032837A1 (en) | 2009-09-15 | 2010-09-01 | Photo-latent titanium-chelate catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102497930A CN102497930A (zh) | 2012-06-13 |
| CN102497930B true CN102497930B (zh) | 2016-03-02 |
Family
ID=41664722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080041002.5A Expired - Fee Related CN102497930B (zh) | 2009-09-15 | 2010-09-01 | 光潜钛螯合物催化剂 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8933138B2 (https=) |
| EP (1) | EP2477738B1 (https=) |
| JP (1) | JP5894919B2 (https=) |
| KR (1) | KR101752517B1 (https=) |
| CN (1) | CN102497930B (https=) |
| BR (1) | BR112012005909A2 (https=) |
| ES (1) | ES2720595T3 (https=) |
| RU (1) | RU2548004C2 (https=) |
| WO (1) | WO2011032837A1 (https=) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112012010051A2 (pt) * | 2009-10-28 | 2016-05-24 | Bayer Materialscience Ag | catalisadores e sua utilização. |
| RU2610090C9 (ru) * | 2011-04-05 | 2018-04-26 | Басф Се | Фотолатентные катализаторы на основе титан-оксо-хелатов |
| TWI426050B (zh) * | 2011-04-19 | 2014-02-11 | China Petrochemical Dev Corp Taipei Taiwan | A method for preparing titanium-silicon molecular sieve and method for producing cyclohexanone oxime using the molecular sieve |
| EP2818525B1 (en) * | 2012-02-21 | 2016-12-28 | Nitto Kasei Co., Ltd. | Electrodeposition coating composition, and catalyst for electrodeposition coating composition |
| JP2015108029A (ja) * | 2012-03-12 | 2015-06-11 | 日東化成株式会社 | 電着塗料組成物、電着塗料組成物用触媒 |
| JP2015512331A (ja) | 2012-03-22 | 2015-04-27 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 硬化塗膜の製造方法及び製造装置 |
| US9339832B2 (en) | 2012-03-22 | 2016-05-17 | Basf Se | Spraygun for producing cured coating films and methods of use thereof |
| US9315636B2 (en) * | 2012-12-07 | 2016-04-19 | Az Electronic Materials (Luxembourg) S.A.R.L. | Stable metal compounds, their compositions and methods |
| US9201305B2 (en) | 2013-06-28 | 2015-12-01 | Az Electronic Materials (Luxembourg) S.A.R.L. | Spin-on compositions of soluble metal oxide carboxylates and methods of their use |
| US9822263B2 (en) * | 2014-04-28 | 2017-11-21 | Nitto Kasei Co., Ltd. | Electrodeposition coating material composition and catalyst for electrodeposition coating material |
| US9499698B2 (en) | 2015-02-11 | 2016-11-22 | Az Electronic Materials (Luxembourg)S.A.R.L. | Metal hardmask composition and processes for forming fine patterns on semiconductor substrates |
| US10053596B2 (en) * | 2016-08-30 | 2018-08-21 | Prc-Desoto International, Inc. | Curable film-forming compositions demonstrating increased wet-edge time |
| CN111051570B (zh) | 2017-09-06 | 2022-05-10 | 默克专利股份有限公司 | 具有改善的热稳定性可用作硬掩膜的含旋涂式无机氧化物的组合物和填充材料 |
| EP3762143A1 (en) | 2018-03-09 | 2021-01-13 | PPG Industries Ohio Inc. | Compounds for coordinating with a metal, compositions containing such compounds, and methods of catalyzing reactions |
| US12116447B2 (en) | 2019-04-18 | 2024-10-15 | Dow Global Technologies Llc | Adhesive composition |
| EP4223848A4 (en) | 2020-09-30 | 2024-03-27 | Asahi Kasei Kabushiki Kaisha | POLYURETHANE-BASED HARDENER AND ITS USE |
| TWI811888B (zh) | 2021-12-14 | 2023-08-11 | 國立清華大學 | 新型鈦觸媒之用途以及聚酯樹酯之製備方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884334A (zh) * | 2005-06-22 | 2006-12-27 | 拜尔材料科学股份公司 | 聚氨酯弹性体、其制备方法和其用途 |
| CN101273074A (zh) * | 2005-09-15 | 2008-09-24 | 莫门蒂夫功能性材料公司 | 使用有机铋催化剂制备氨基硅烷封端的聚合物以及使用非锡催化剂由此制备固化的聚合物 |
| WO2009050115A1 (en) * | 2007-10-17 | 2009-04-23 | Basf Se | Photolatent catalysts based on organometallic compounds |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3635906A (en) * | 1968-11-12 | 1972-01-18 | Du Pont | Preparation of polyurethanes using organo-tin catalyst and time-lapse modifier |
| DE2962089D1 (en) | 1978-07-14 | 1982-03-18 | Basf Ag | Light-curable moulding, impregnating and coating compositions and shaped articles prepared therefrom |
| US4292252A (en) | 1978-07-28 | 1981-09-29 | Tenneco Chemicals Inc. | Process for preparing organotin esters |
| US4575330A (en) | 1984-08-08 | 1986-03-11 | Uvp, Inc. | Apparatus for production of three-dimensional objects by stereolithography |
| US4973623A (en) | 1989-05-26 | 1990-11-27 | Dow Corning Corporation | Fast curing oximo-ethoxy functional siloxane sealants |
| SE9200564L (sv) | 1992-02-26 | 1993-03-15 | Perstorp Ab | Dendritisk makromolekyl av polyestertyp, foerfarande foer framstaellning daerav samt anvaendning daerav |
| JP3325307B2 (ja) | 1992-06-05 | 2002-09-17 | 積水化学工業株式会社 | 室温硬化性組成物 |
| DE4228514A1 (de) | 1992-08-27 | 1994-03-03 | Hoechst Ag | Bindemittel für Pulverlacke |
| BE1007373A3 (nl) | 1993-07-30 | 1995-05-30 | Dsm Nv | Stralingsuithardbare bindmiddelsamenstelling voor poederverfformuleringen. |
| US5545600A (en) | 1994-12-21 | 1996-08-13 | Knudsen; George A. | Process for the preparation of dialkyltin dialkoxide |
| CN1063188C (zh) * | 1996-12-17 | 2001-03-14 | 中国科学院化学研究所 | 一种合成间规聚苯乙烯催化剂体系及其制法 |
| CA2292483A1 (en) | 1998-12-17 | 2000-06-17 | Sinzi Hirato | Electrodeposition paint composition |
| DE19935471A1 (de) | 1999-07-28 | 2001-02-08 | Goldschmidt Ag Th | Beschichtung von Oberflächen |
| GB0000569D0 (en) * | 2000-01-12 | 2000-03-01 | Ici Plc | Organometallic compositions |
| US6664323B2 (en) | 2001-02-02 | 2003-12-16 | General Electric Company | Moisture curable sealants |
| JP2002356651A (ja) | 2001-05-30 | 2002-12-13 | Dow Corning Toray Silicone Co Ltd | 撥水コーティング用シリコーン組成物 |
| US6620871B2 (en) | 2001-06-07 | 2003-09-16 | Nike, Inc. | Rubber compositions with increased shelf life and reduced cure temperatures and times |
| US20030118725A1 (en) * | 2001-11-02 | 2003-06-26 | Shipley Company, L.L.C. | Precursor compounds for metal oxide film deposition and methods of film deposition using the same |
| CN1174017C (zh) * | 2002-05-24 | 2004-11-03 | 中国科学院化学研究所 | 用β-二酮钛非茂催化剂制备聚降冰片烯的工艺方法 |
| DE10260299A1 (de) | 2002-12-20 | 2004-07-01 | Bayer Ag | Reaktivsysteme, deren Herstellung und deren Verwendung |
| US6969754B2 (en) | 2003-12-11 | 2005-11-29 | Valspar Sourcing, Inc. | Blocked isocyanate crosslinker solution |
| US7671144B2 (en) | 2004-01-30 | 2010-03-02 | Kaneka Corporation | Pressure sensitive adhesive composition |
| EP1786847B1 (en) | 2004-06-16 | 2008-02-27 | E.I.Du pont de nemours and company | Air-activated organotin catalysts for polyurethane synthesis |
| WO2006008251A2 (en) | 2004-07-21 | 2006-01-26 | Ciba Specialty Chemicals Holding Inc. | Process for the photoactivation and use of a catalyst by an inverted two-stage procedure |
| DE102004044085A1 (de) | 2004-09-09 | 2006-03-16 | Tesa Ag | Haftklebemasse mit dualem Vernetzungsmechanismus |
| DE102005029282A1 (de) | 2005-06-23 | 2006-12-28 | Henkel Kgaa | Silanvernetzende Kleb- und Dichtstoffmassen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP4957052B2 (ja) | 2006-04-04 | 2012-06-20 | Nok株式会社 | 加硫接着剤組成物 |
| JP5290165B2 (ja) | 2006-06-22 | 2013-09-18 | チバ ホールディング インコーポレーテッド | 化学線硬化性コーティング組成物 |
| DE102006047738A1 (de) | 2006-10-06 | 2008-04-10 | Tesa Ag | Hitzeaktivierbares Klebeband insbesondere für die Verklebung von elektronischen Bauteilen und Leiterbahnen |
| WO2008045395A2 (en) | 2006-10-10 | 2008-04-17 | Dow Corning Corporation | Process for making organopolysiloxane compositions |
| GB2444255A (en) | 2006-11-30 | 2008-06-04 | Formerol Ltd | Mouldable one-part RTV silicone elastomer |
| JP5285892B2 (ja) | 2007-10-25 | 2013-09-11 | 東レ・ダウコーニング株式会社 | 室温硬化性オルガノポリシロキサン組成物 |
-
2010
- 2010-09-01 BR BR112012005909-2A patent/BR112012005909A2/pt not_active Application Discontinuation
- 2010-09-01 US US13/395,464 patent/US8933138B2/en not_active Expired - Fee Related
- 2010-09-01 KR KR1020127009504A patent/KR101752517B1/ko not_active Expired - Fee Related
- 2010-09-01 JP JP2012529201A patent/JP5894919B2/ja not_active Expired - Fee Related
- 2010-09-01 EP EP10747638.4A patent/EP2477738B1/en not_active Not-in-force
- 2010-09-01 WO PCT/EP2010/062779 patent/WO2011032837A1/en not_active Ceased
- 2010-09-01 RU RU2012114678/04A patent/RU2548004C2/ru not_active IP Right Cessation
- 2010-09-01 CN CN201080041002.5A patent/CN102497930B/zh not_active Expired - Fee Related
- 2010-09-01 ES ES10747638T patent/ES2720595T3/es active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884334A (zh) * | 2005-06-22 | 2006-12-27 | 拜尔材料科学股份公司 | 聚氨酯弹性体、其制备方法和其用途 |
| CN101273074A (zh) * | 2005-09-15 | 2008-09-24 | 莫门蒂夫功能性材料公司 | 使用有机铋催化剂制备氨基硅烷封端的聚合物以及使用非锡催化剂由此制备固化的聚合物 |
| WO2009050115A1 (en) * | 2007-10-17 | 2009-04-23 | Basf Se | Photolatent catalysts based on organometallic compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2477738A1 (en) | 2012-07-25 |
| RU2012114678A (ru) | 2013-10-27 |
| WO2011032837A1 (en) | 2011-03-24 |
| EP2477738B1 (en) | 2019-01-23 |
| KR20120103765A (ko) | 2012-09-19 |
| JP5894919B2 (ja) | 2016-03-30 |
| US8933138B2 (en) | 2015-01-13 |
| US20120259033A1 (en) | 2012-10-11 |
| JP2013504671A (ja) | 2013-02-07 |
| ES2720595T3 (es) | 2019-07-23 |
| CN102497930A (zh) | 2012-06-13 |
| RU2548004C2 (ru) | 2015-04-10 |
| BR112012005909A2 (pt) | 2020-08-25 |
| KR101752517B1 (ko) | 2017-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102497930B (zh) | 光潜钛螯合物催化剂 | |
| KR101528648B1 (ko) | 유기금속 화합물을 기재로 하는 광잠재성 촉매 | |
| CN102497931B (zh) | 光潜钛催化剂 | |
| CN103596684B (zh) | 光潜钛-氧-螯合物催化剂 | |
| KR20090025357A (ko) | 화학선-경화성 피복 조성물 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160302 Termination date: 20200901 |