CN102459442A - 耐久抗静电添加剂组合物 - Google Patents
耐久抗静电添加剂组合物 Download PDFInfo
- Publication number
- CN102459442A CN102459442A CN2010800266062A CN201080026606A CN102459442A CN 102459442 A CN102459442 A CN 102459442A CN 2010800266062 A CN2010800266062 A CN 2010800266062A CN 201080026606 A CN201080026606 A CN 201080026606A CN 102459442 A CN102459442 A CN 102459442A
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- CN
- China
- Prior art keywords
- butyl
- compsn
- salt
- acid
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 3
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- DBCWENWKZARTGU-UHFFFAOYSA-N n-heptadecyloctadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCCCC=[N+]([O-])CCCCCCCCCCCCCCCCC DBCWENWKZARTGU-UHFFFAOYSA-N 0.000 description 1
- WGCBLWIBXXQTAW-UHFFFAOYSA-N n-hexadecyl-n-octadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCCCCN(O)CCCCCCCCCCCCCCCC WGCBLWIBXXQTAW-UHFFFAOYSA-N 0.000 description 1
- GCDJFNYVSDFWDB-UHFFFAOYSA-N n-hexadecylhexadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCC[N+]([O-])=CCCCCCCCCCCCCCCC GCDJFNYVSDFWDB-UHFFFAOYSA-N 0.000 description 1
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- ZXGDIORKSOYRMQ-UHFFFAOYSA-N n-octadecylheptadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+]([O-])=CCCCCCCCCCCCCCCCC ZXGDIORKSOYRMQ-UHFFFAOYSA-N 0.000 description 1
- MCMMSXFAWOGWQE-UHFFFAOYSA-N n-octadecylhexadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+]([O-])=CCCCCCCCCCCCCCCC MCMMSXFAWOGWQE-UHFFFAOYSA-N 0.000 description 1
- TWHQPVYYDWEGRT-UHFFFAOYSA-N n-octadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCCCCNO TWHQPVYYDWEGRT-UHFFFAOYSA-N 0.000 description 1
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- FEQIKDBPUQIQKY-UHFFFAOYSA-N n-phenyl-n-propan-2-ylaniline Chemical compound C=1C=CC=CC=1N(C(C)C)C1=CC=CC=C1 FEQIKDBPUQIQKY-UHFFFAOYSA-N 0.000 description 1
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- 230000008569 process Effects 0.000 description 1
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- 238000010526 radical polymerization reaction Methods 0.000 description 1
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- 229910052708 sodium Inorganic materials 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- IJRHDFLHUATAOS-DPMBMXLASA-N sodium;(z,12r)-12-hydroxyoctadec-9-enoic acid Chemical compound [Na+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O IJRHDFLHUATAOS-DPMBMXLASA-N 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- 235000021262 sour milk Nutrition 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
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- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
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- 239000012745 toughening agent Substances 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 1
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- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
- 239000002446 δ-tocopherol Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0075—Antistatics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
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Abstract
本发明涉及包含聚合物基材、具有特定分子量的聚亚烷基乙氧基化物和盐的抗静电聚合物组合物。其他方面为一种制备抗静电聚合物的方法和该聚亚烷基乙氧基化物在聚合物中作为抗静电剂,优选与盐一起作为抗静电剂的用途。
Description
本发明涉及包含聚合物基材、具有特定分子量的聚亚烷基乙氧基化物(polyalkyleneethoxylate)和盐的抗静电聚合物组合物。其他方面是一种制备抗静电聚合物的方法以及该聚亚烷基乙氧基化物在聚合物中作为抗静电剂,优选与盐一起作为抗静电剂的用途。
聚合物易遭受强静电荷,该静电荷一旦施加则由于低导电性仅能缓慢释放。快速放电例如因安全和美学原因是理想的。静电荷聚集的不利效果包括聚合物表面的污损、对接触聚合物的人的电击、由于膜卷材粘附引起生产中断、电子元件的毁损、聚合物粉末中的团块形成以及火花和随后的着火,这可能导致严重的爆炸。
已知通过加入改善表面导电率的添加剂而限制起静电,但该类物质的缺点是当大气湿度低时在实践中无效。因此更好的是使用在低大气湿度下有效的添加剂,这通常可以通过提高体积导电率而实现。然而,提高体积导电率的已知物质,例如碳黑或金属粉末改变了聚合物的机械性能且不能用于透明聚合物。此外,该抗静电添加剂不应引起该聚合物的任何变色,即使在热应力下。
有关抗静电添加剂和起静电的机理的其他细节例如可参见“PlasticsAdditives Handbook”,编辑R.Gaechter和H.Mueller,Hanser Publishers,第4版,1993,第749-773页。
鉴于赋予聚合物以抗静电性的已知方法的上述局限性,持续需要在低大气湿度下有效的生态上无可非议的抗静电活性添加剂体系,该体系的生产简单,可以容易地掺入聚合物中或与聚合物混合,长时间保持所获得的聚合物抗静电效果并且可以没有任何显著限制地以少量用于所有市售聚合物。惊讶地发现具有特定分子量的聚亚烷基乙氧基化物和盐一起与聚合物高度相容,在热暴露过程中基本无损失,不会不利地影响聚合物制品的颜色且甚至在干燥的大气条件下也导致耐久的抗静电效果。
本发明的一个方面是一种组合物,其包含:
a)热塑性或弹性体聚合物基材,
b)式(I)的分子量至少为400的抗静电聚合物:
Q1-Q2(I)
其中
Q1为C20-C100烷基、C20-C100链烯基或被1-5个C1-C100烷基取代的C5-C12环烷基;
Q2为式(II)的基团:
其中
R1为H或CH3;
n为2-6的数;
t为1-200的数;
*为连接点,和
c)无机或有机盐。
例如,Q1为C20-C100烷基,优选C25-C60烷基。
例如,Q2为式(IIa)的基团:
其中
R1为H或CH3,和
t为1-50的数。
优选t为2-20的数。
式(I)化合物的分子量优选大于500。
例如,式(I)化合物的分子量为400-2000,优选500-1600。
式(I)化合物是已知的且大多可市购,例如由Baker Petrolite Inc.以商品名UnithoxTM Ethoxylate市购。
例如,无机或有机盐选自LiClO4、LiCF3SO3、NaClO4、LiBF4、NaBF4、KBF4、NaCF3SO3、KClO4、KPF6、KCF3SO3、KC4F9SO3、Ca(ClO4)2、Ca(PF6)2、Mg(ClO4)2、Mg(CF3SO3)2、Zn(ClO4)2、Zn(PF6)2、Ca(CF3SO3)2、磷酸的Na或K盐、C1-C18羧酸的Na或K盐、芳族或脂族磺酸的Na或K盐。
作为无机盐优选NaClO4、Zn(ClO4)2和NaBF4。
热塑性或弹性体聚合物的实例如下所列。
1.单烯烃和二烯烃的聚合物,例如聚丙烯、聚异丁烯、聚丁烯-1、聚-4-甲基戊烯-1、聚异戊二烯或聚丁二烯以及环烯烃的聚合物,例如环戊烯或降冰片烯的聚合物;还有聚乙烯(可任选交联),例如高密度聚乙烯(HDPE)、低密度聚乙烯(LDPE)、线性低密度聚乙烯(LLDPE)、支化低密度聚乙烯(BLDPE)。
聚烯烃,即前段中举例提到的单烯烃聚合物,尤其是聚乙烯和聚丙烯,可通过各种方法,尤其是下列方法制备:
a)自由基聚合(通常在高压和高温下);
b)借助催化剂的聚合,所述催化剂通常包含一种或多种周期表第IVb、Vb、VIb或VIII族的金属。这些金属通常具有一个或多个配体,如氧化物、卤化物、醇盐、酯、醚、胺、烷基、链烯基和/或芳基,其可为p-或s-配位的。这些金属配合物可呈游离形式或固定在载体上,例如固定在活化氯化镁、氯化钛(III)、氧化铝或二氧化硅上。这些催化剂可溶于或不溶于聚合介质中。所述催化剂可直接在聚合中呈活性或者可使用其他活化剂,如烷基金属、金属氢化物、烷基金属卤化物、烷基金属氧化物或烷基金属烷(metal alkyloxane),所述金属为周期表第Ia、IIa和/或IIIa族的元素。活化剂例如可用其他酯、醚、胺或甲硅烷基醚基团改性。这些催化剂体系通常已知为Philips、Standard Oil Indiana、Ziegler(-Natta)、TNZ(杜邦)、茂金属或单中心催化剂(SSC)。
2.1)下提及的聚合物的混合物,例如聚丙烯与聚异丁烯的混合物、聚丙烯与聚乙烯的混合物(例如PP/HDPE、PP/LDPE)以及不同类型聚乙烯的混合物(例如LDPE/HDPE)。
3.单烯烃和二烯烃彼此之间或与其他乙烯基单体的共聚物,例如乙烯/丙烯共聚物、线性低密度聚乙烯(LLDPE)及其与低密度聚乙烯(LDPE)的混合物、丙烯/丁烯-1共聚物、丙烯/异丁烯共聚物、乙烯/丁烯-1共聚物、乙烯/己烯共聚物、乙烯/甲基戊烯共聚物、乙烯/庚烯共聚物、乙烯/辛烯共聚物、丙烯/丁二烯共聚物、异丁烯/异戊二烯共聚物、乙烯/丙烯酸烷基酯共聚物、乙烯/甲基丙烯酸烷基酯共聚物、乙烯/乙酸乙烯酯共聚物及其与一氧化碳的共聚物或乙烯/丙烯酸共聚物及其盐(离聚物),还有乙烯与丙烯和二烯如己二烯、二聚环戊二烯或亚乙基降冰片烯的三元共聚物;以及这些共聚物彼此之间的混合物或与在1)下提到的聚合物的混合物,例如聚丙烯-乙烯/丙烯共聚物、LDPE-乙烯/乙酸乙烯酯共聚物、LDPE-乙烯/丙烯酸共聚物、LLDPE-乙烯/乙酸乙烯酯共聚物、LLDPE-乙烯/丙烯酸共聚物和交替或无规结构的聚链烯(polyalkylene)-一氧化碳共聚物及其与其他聚合物如聚酰胺的混合物。
4.烃树脂(例如C5-C9),包括其氢化改性产物(例如增粘剂树脂)及聚链烯和淀粉的混合物。
5.聚苯乙烯、聚对甲基苯乙烯、聚α-甲基苯乙烯。
6.苯乙烯或α-甲基苯乙烯与二烯或丙烯酸系衍生物的共聚物,例如苯乙烯/丁二烯、苯乙烯/丙烯腈、苯乙烯/甲基丙烯酸烷基酯、苯乙烯/丁二烯/丙烯酸烷基酯和甲基丙烯酸烷基酯、苯乙烯/马来酸酐、苯乙烯/丙烯腈/丙烯酸甲酯;由苯乙烯共聚物与另一聚合物如聚丙烯酸酯、二烯聚合物或乙烯/丙烯/二烯三元共聚物构成的高抗冲混合物;以及苯乙烯的嵌段共聚物如苯乙烯/丁二烯/苯乙烯、苯乙烯/异戊二烯/苯乙烯、苯乙烯/乙烯/丁烯/苯乙烯或苯乙烯/乙烯/丙烯/苯乙烯。
7.苯乙烯或α-甲基苯乙烯的接枝共聚物,例如苯乙烯接枝聚丁二烯、苯乙烯接枝聚丁二烯/苯乙烯或聚丁二烯/丙烯腈共聚物;苯乙烯和丙烯腈(或甲基丙烯腈)接枝聚丁二烯;苯乙烯、丙烯腈和甲基丙烯酸甲酯接枝聚丁二烯;苯乙烯和马来酸酐接枝聚丁二烯;苯乙烯、丙烯腈和马来酸酐或马来酰亚胺接枝聚丁二烯;苯乙烯和马来酰亚胺接枝聚丁二烯;苯乙烯和丙烯酸烷基酯或甲基丙烯酸烷基酯接枝聚丁二烯;苯乙烯和丙烯腈接枝乙烯/丙烯/二烯三元共聚物;苯乙烯和丙烯腈接枝聚丙烯酸烷基酯或聚甲基丙烯酸烷基酯;苯乙烯和丙烯腈接枝丙烯酸酯/丁二烯共聚物及其与6)下所提到的共聚物的混合物,例如与已知为所谓的ABS、MBS、ASA或AES聚合物的那些的混合物。
8.含卤素的聚合物,例如聚氯丁二烯、氯化橡胶、氯化或氯磺化聚乙烯、乙烯和氯化乙烯的共聚物、表氯醇均聚物及共聚物,尤其是含卤素的乙烯基化合物的聚合物,例如聚氯乙烯、聚偏二氯乙烯、聚氟乙烯、聚偏二氟乙烯;及其共聚物如氯乙烯/偏二氯乙烯、氯乙烯/乙酸乙烯酯或偏二氯乙烯/乙酸乙烯酯共聚物。
9.衍生自α,β-不饱和酸及其衍生物的聚合物,例如聚丙烯酸酯和聚甲基丙烯酸酯,或用丙烯酸丁酯进行抗冲击改性的聚甲基丙烯酸甲酯、聚丙烯酰胺和聚丙烯腈。
10.在9.)下所提到的单体彼此之间的共聚物或与其他不饱和单体的共聚物,例如丙烯腈/丁二烯共聚物、丙烯腈/丙烯酸烷基酯共聚物、丙烯腈/丙烯酸烷氧基烷基酯共聚物、丙烯腈/乙烯基卤共聚物或丙烯腈/甲基丙烯酸烷基酯/丁二烯三元共聚物。
11.衍生自不饱和醇和胺或其酰基衍生物或缩醛的聚合物,例如聚乙烯醇、聚乙酸乙烯酯、聚硬脂酸乙烯酯、聚苯甲酸乙烯酯或聚马来酸乙烯酯、聚乙烯醇缩丁醛、聚邻苯二甲酸烯丙基酯、聚烯丙基蜜胺;及其与第1.点中提到的烯烃的共聚物。
12.环醚的均聚物和共聚物,例如聚亚烷基二醇、聚氧化乙烯、聚氧化丙烯或其与二缩水甘油基醚的共聚物。
13.聚缩醛如聚甲醛以及含有共聚单体如氧化乙烯的那些聚甲醛;用热塑性聚氨酯、丙烯酸酯或MBS改性的聚缩醛。
14.聚苯醚和聚苯硫醚及其与苯乙烯聚合物或聚酰胺的混合物。
15.聚氨酯,其一方面衍生自具有羟基端基的聚醚、聚酯和聚丁二烯,另一方面衍生自脂族或芳族多异氰酸酯及其初始产品。
16.衍生自二胺和二羧酸和/或衍生自氨基羧酸或相应内酰胺的聚酰胺和共聚酰胺,例如聚酰胺4、聚酰胺6、聚酰胺6,6、6,10、6,9、6,12、4,6、12,12、聚酰胺11、聚酰胺12、衍生于间二甲苯二胺和己二酸的芳族聚酰胺;由六亚甲基二胺与间苯二甲酸和/或对苯二甲酸和任选的作为改性剂的弹性体制备的聚酰胺,例如聚-2,4,4-三甲基六亚甲基对苯二甲酰胺或聚间亚苯基间苯二甲酰胺。上述聚酰胺与聚烯烃、烯烃共聚物、离聚物或化学键合或接枝的弹性体的嵌段共聚物;或与聚醚,例如与聚乙二醇、聚丙二醇或聚四亚甲基二醇的嵌段共聚物。还有用EPDM或ABS改性的聚酰胺或共聚酰胺;以及在加工过程中缩合的聚酰胺(“RIM聚酰胺体系”)。
17.聚脲、聚酰亚胺、聚酰胺酰亚胺和聚苯并咪唑。
18.聚酯,其衍生自二羧酸和二醇和/或衍生自羟基羧酸或相应的内酯,例如聚对苯二甲酸乙二醇酯、聚对苯二甲酸丁二醇酯、聚-1,4-二羟甲基环己烷对苯二甲酸酯、聚羟基苯甲酸酯以及衍生自具有羟基端基的聚醚的嵌段聚醚酯;还有用聚碳酸酯或MBS改性的聚酯。
19.聚碳酸酯和聚酯碳酸酯。
20.聚砜、聚醚砜和聚醚酮。
21.天然聚合物例如天然橡胶或纤维素的类似聚合物化学改性的衍生物,例如乙酸纤维素、丙酸纤维素和丁酸纤维素,以及纤维素醚,例如甲基纤维素。
22.上述聚合物的混合物(聚合物共混物),例如PP/EPDM、聚酰胺/EPDM或ABS、PVC/EVA、PVC/ABS、PVC/MBS、PC/ABS、PBTP/ABS、PC/ASA、PC/PBT、PVC/CPE、PVC/丙烯酸酯、POM/热塑性PUR、PC/热塑性PUR、POM/丙烯酸酯、POM/MBS、PPO/HIPS、PPO/PA 6,6及共聚物、PA/HDPE、PA/PP、PA/PPO。
优选热塑性或弹性体聚合物基材为聚烯烃、聚苯乙烯、丙烯腈/丁二烯/苯乙烯共聚物(ABS)、α,β-不饱和酸的聚合物、含卤素聚合物、环状醚的均聚物或共聚物、不饱和醇和胺的聚合物、聚缩醛、聚苯醚、聚氨酯、聚酰胺、聚酯、聚脲、聚碳酸酯、聚砜或天然橡胶。
热塑性或弹性体聚合物基材尤其为聚烯烃、聚苯乙烯、丙烯腈/丁二烯/苯乙烯共聚物(ABS)、α,β-不饱和酸的聚合物、含卤素聚合物或环状醚的均聚物或共聚物。
热塑性或弹性体聚合物基材更尤其为聚氯乙烯(PVC)、聚苯乙烯、各种形式的聚乙烯或聚丙烯。
例如,式(I)的抗静电聚合物基于热塑性或弹性体聚合物基材的重量以0.1-30重量%的量存在。
例如,无机或有机盐基于热塑性或弹性体聚合物基材的重量以0.1-10重量%的量存在。
式(I)的抗静电聚合物与无机或有机盐的重量比为200∶1-20∶1。
在具体实施方案中,该组合物额外包含选自UV吸收剂、位阻胺、酚类抗氧化剂、亚磷酸酯或亚膦酸酯以及苯并呋喃酮类或吲哚满酮类的添加剂。
上述添加剂的实例如下给出。
1.抗氧化剂
1.1烷基化单酚,例如2,6-二叔丁基-4-甲基苯酚、2-叔丁基-4,6-二甲基苯酚、2,6-二叔丁基-4-乙基苯酚、2,6-二叔丁基-4-正丁基苯酚、2,6-二叔丁基-4-异丁基苯酚、2,6-二环戊基-4-甲基苯酚、2-(α-甲基环己基)-4,6-二甲基苯酚、2,6-二(十八烷基)-4-甲基苯酚、2,4,6-三环己基苯酚、2,6-二叔丁基-4-甲氧基甲基苯酚,侧链为线性或支化的壬基酚,例如2,6-二壬基-4-甲基苯酚、2,4-二甲基-6-(1′-甲基十一烷-1′-基)苯酚、2,4-二甲基-6-(1′-甲基十七烷-1′-基)苯酚、2,4-二甲基-6-(1′-甲基十三烷-1′-基)苯酚及其混合物。
1.2.烷硫基甲基苯酚,例如2,4-二辛硫基甲基-6-叔丁基苯酚、2,4-二辛硫基甲基-6-甲基苯酚、2,4-二辛硫基甲基-6-乙基苯酚、2,6-二(十二烷硫基)甲基-4-壬基酚。
1.3.氢醌类和烷基化氢醌类,例如2,6-二叔丁基-4-甲氧基苯酚、2,5-二叔丁基氢醌、2,5-二叔戊基氢醌、2,6-二苯基-4-十八烷氧基苯酚、2,6-二叔丁基氢醌、2,5-二叔丁基-4-羟基茴香醚、3,5-二叔丁基-4-羟基茴香醚、硬脂酸3,5-二叔丁基-4-羟基苯酯、己二酸双(3,5-二叔丁基-4-羟基苯基)酯。
1.4.生育酚类,例如α-生育酚、β-生育酚、γ-生育酚、δ-生育酚及其混合物(维生素E)。
1.5.羟基化硫代二苯醚,例如2,2′-硫代双(6-叔丁基-4-甲基苯酚)、2,2′-硫代双(4-辛基苯酚)、4,4′-硫代双(6-叔丁基-3-甲基苯酚)、4,4′-硫代双(6-叔丁基-2-甲基苯酚)、4,4′-硫代双(3,6-仲戊基苯酚)、4,4′-双(2,6-甲基-4-羟基苯基)二硫化物。
1.6.亚烷基双酚,例如2,2′-亚甲基双(6-叔丁基-4-甲基苯酚)、2,2′-亚甲基双(6-叔丁基-4-乙基苯酚)、2,2′-亚甲基双[4-甲基-6-(α-甲基环己基)苯酚]、2,2′-亚甲基双(4-甲基-6-环己基苯酚)、2,2′-亚甲基双(6-壬基-4-甲基苯酚)、2,2′-亚甲基双(4,6-二叔丁基苯酚)、2,2′-亚乙基双(4,6-二叔丁基苯酚)、2,2′-亚乙基双(6-叔丁基-4-异丁基苯酚)、2,2′-亚甲基双[6-(α-甲基苄基)-4-壬基酚]、2,2′-亚甲基双[6-(α,α-二甲基苄基)-4-壬基酚]、4,4′-亚甲基双(2,6-二叔丁基苯酚)、4,4′-亚甲基双(6-叔丁基-2-甲基苯酚)、1,1-双(5-叔丁基-4-羟基-2-甲基苯基)丁烷、2,6-双(3-叔丁基-5-甲基-2-羟基苄基)-4-甲基苯酚、1,1,3-三(5-叔丁基-4-羟基-2-甲基苯基)丁烷、1,1-双(5-叔丁基-4-羟基-2-甲基苯基)-3-正十二烷基巯基丁烷、乙二醇双[3,3-双(3′-叔丁基-4′-羟基苯基)丁酸酯]、双(3-叔丁基-4-羟基-5-甲基苯基)二环戊二烯、双[2-(3′-叔丁基-2′-羟基-5′-甲基苄基)-6-叔丁基-4-甲基苯基]对苯二甲酸酯、1,1-双(3,5-甲基-2-羟基苯基)丁烷、2,2-双-(3,5-二叔丁基-4-羟基苯基)丙烷、2,2-双(5-叔丁基-4-羟基-2-甲基苯基)-4-正十二烷基巯基丁烷、1,1,5,5-四(5-叔丁基-4-羟基-2-甲基苯基)戊烷。
1.7.O-、N-和S-苄基化合物,例如3,5,3′,5′-四叔丁基-4,4′-二羟基二苄基醚、4-羟基-3,5-二甲基苄基巯基乙酸十八烷基酯、4-羟基-3,5-二叔丁基苄基巯基乙酸十三烷基酯、三(3,5-二叔丁基-4-羟基苄基)胺、二硫代对苯二甲酸双(4-叔丁基-3-羟基-2,6-二甲基苄基)酯、双(3,5-二叔丁基-4-羟基苄基)硫化物、3,5-二叔丁基-4-羟基苄基巯基乙酸异辛基酯。
1.8.羟基苄基化丙二酸酯,例如2,2-双(3,5-二叔丁基-2-羟基苄基)丙二酸二-十八烷基酯、2-(3-叔丁基-4-羟基-5-甲基苄基)丙二酸二-十八烷基酯、2,2-双(3,5-二叔丁基-4-羟基苄基)丙二酸二-十二烷基巯基乙基酯、2,2-双(3,5-二叔丁基-4-羟基苄基)丙二酸双[4-(1,1,3,3-四甲基丁基)苯基]酯。
1.9.芳族羟基苄基化合物,例如1,3,5-三(3,5-二叔丁基-4-羟基苄基)-2,4,6-三甲基苯、1,4-双(3,5-二叔丁基-4-羟基苄基)-2,3,5,6-四甲基苯、2,4,6-三(3,5-二叔丁基-4-羟基苄基)苯酚。
1.10.三嗪化合物,例如2,4-双(辛基巯基)-6-(3,5-二叔丁基-4-羟基苯胺基)-1,3,5-三嗪、2-辛基巯基-4,6-双(3,5-二叔丁基-4-羟基苯胺基)-1,3,5-三嗪、2-辛基巯基-4,6-双(3,5-二叔丁基-4-羟基苯氧基)-1,3,5-三嗪、2,4,6-三(3,5-二叔丁基-4-羟基苯氧基)-1,2,3-三嗪、1,3,5-三(3,5-二叔丁基-4-羟基苄基)异氰脲酸酯、1,3,5-三(4-叔丁基-3-羟基-2,6-二甲基苄基)异氰脲酸酯、2,4,6-三(3,5-二叔丁基-4-羟基苯基乙基)-1,3,5-三嗪、1,3,5-三(3,5-二叔丁基-4-羟基苯基丙酰基)-六氢-1,3,5-三嗪、1,3,5-三(3,5-二环己基-4-羟基苄基)异氰脲酸酯。
1.11.苄基膦酸酯,例如2,5-二叔丁基-4-羟基苄基膦酸二甲酯、3,5-二叔丁基-4-羟基苄基膦酸二乙酯、3,5-二叔丁基-4-羟基苄基膦酸二(十八烷基)酯、5-叔丁基-4-羟基-3-甲基苄基膦酸二(十八烷基)酯、3,5-二叔丁基-4-羟基苄基膦酸的单乙酯的钙盐。
1.12.酰氨基苯酚类,例如4-羟基月桂酰苯胺、4-羟基硬脂酰苯胺、N-(3,5-二叔丁基-4-羟基苯基)氨基甲酸辛酯。
1.13.β-(3,5-二叔丁基-4-羟基苯基)丙酸与如下一元醇或多元醇的酯:例如与甲醇、乙醇、正辛醇、异辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫二甘醇、二甘醇、三甘醇、季戊四醇、三(羟乙基)异氰脲酸酯、N,N′-双(羟乙基)草酰胺、3-硫杂十一烷醇、3-硫杂十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧杂双环[2.2.2]辛烷的酯。
1.14.β-(5-叔丁基-4-羟基-3-甲基苯基)丙酸与如下一元醇或多元醇的酯:例如与甲醇、乙醇、正辛醇、异辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫二甘醇、二甘醇、三甘醇、季戊四醇、三(羟乙基)异氰脲酸酯、N,N′-双(羟乙基)草酰胺、3-硫杂十一烷醇、3-硫杂十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧杂双环[2.2.2]辛烷、3,9-双[2-{3-(3-叔丁基-4-羟基-5-甲基苯基)丙酰氧基}-1,1-二甲基乙基]-2,4,8,10-四氧杂螺[5.5]十一烷的酯。
1.15.β-(3,5-二环己基-4-羟基苯基)丙酸与如下一元醇或多元醇的酯:例如与甲醇、乙醇、辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫二甘醇、二甘醇、三甘醇、季戊四醇、三(羟乙基)异氰脲酸酯、N,N′-双(羟乙基)草酰胺、3-硫杂十一烷醇、3-硫杂十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧杂双环[2.2.2]辛烷的酯。
1.16.3,5-二叔丁基-4-羟基苯基乙酸与如下一元醇或多元醇的酯:例如与甲醇、乙醇、辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫二甘醇、二甘醇、三甘醇、季戊四醇、三(羟乙基)异氰脲酸酯、N,N′-双(羟乙基)草酰胺、3-硫杂十一烷醇、3-硫杂十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧杂双环[2.2.2]辛烷的酯。
1.17.β-(3,5-二叔丁基-4-羟基苯基)丙酸的酰胺,例如N,N′-双(3,5-二叔丁基-4-羟基苯基丙酰基)六亚甲基二胺、N,N′-双(3,5-二叔丁基-4-羟基苯基丙酰基)三亚甲基二胺、N,N′-双(3,5-二叔丁基-4-羟基苯基丙酰基)肼、N,N′-双[2-(3-[3,5-二叔丁基-4-羟基苯基]丙酰氧基)乙基]草酰胺(XL-1,由Uniroyal提供)。
1.18.抗坏血酸(维生素C)。
1.19.胺类抗氧化剂,例如N,N′-二异丙基对苯二胺、N,N′-二仲丁基对苯二胺、N,N′-双(1,4-二甲基戊基)对苯二胺、N,N′-双(1-乙基-3-甲基戊基)对苯二胺、N,N′-双(1-甲基庚基)对苯二胺、N,N′-二环己基对苯二胺、N,N′-二苯基对苯二胺、N,N′-双(2-萘基)对苯二胺、N-异丙基-N′-苯基对苯二胺、N-(1,3-二甲基丁基)-N′-苯基对苯二胺、N-(1-甲基庚基)-N′-苯基对苯二胺、N-环己基-N′-苯基对苯二胺、4-(对甲苯胺磺酰基)二苯胺、N,N′-二甲基-N,N′-二仲丁基对苯二胺、二苯胺、N-烯丙基二苯胺、4-异丙氧基二苯胺、N-苯基-1-萘基胺、N-(4-叔辛基苯基)-1-萘基胺、N-苯基-2-萘基胺、辛基化二苯胺如p,p′-二叔辛基二苯胺、4-正丁基氨基苯酚、4-丁酰基氨基苯酚、4-壬酰基氨基苯酚、4-十二烷酰基氨基苯酚、4-十八烷酰基氨基苯酚、双(4-甲氧基苯基)胺、2,6-二叔丁基-4-二甲基氨基甲基苯酚、2,4′-二氨基二苯基甲烷、4,4′-二氨基二苯基甲烷、N,N,N′,N′-四甲基-4,4′-二氨基二苯基甲烷、1,2-双[(2-甲基苯基)氨基]乙烷、1,2-双(苯基氨基)丙烷、邻甲苯基双胍、双[4-(1′,3′-二甲基丁基)苯基]胺、叔辛基化N-苯基-1-萘基胺、单-和二-烷基化叔丁基二苯胺/叔辛基二苯胺的混合物、单-和二-烷基化壬基二苯胺的混合物、单-和二-烷基化十二烷基二苯胺的混合物、单-和二-烷基化异丙基二苯胺/异己基二苯胺的混合物、单-和二-烷基化叔丁基二苯胺的混合物、2,3-二氢-3,3-二甲基-4H-1,4-苯并噻嗪、吩噻嗪、单-和二-烷基化叔丁基吩噻嗪/叔辛基吩噻嗪的混合物、单-和二-烷基化叔辛基吩噻嗪的混合物、N-烯丙基吩噻嗪、N,N,N′,N′-四苯基-1,4-二氨基丁-2-烯。
2.UV吸收剂和光稳定剂
2.1.2-(2′-羟基苯基)苯并三唑类,例如2-(2′-羟基-5′-甲基苯基)苯并三唑、2-(3′,5′-二叔丁基-2′-羟基苯基)苯并三唑、2-(5′-叔丁基-2′-羟基苯基)苯并三唑、2-(2′-羟基-5′-(1,1,3,3-四甲基丁基)苯基)苯并三唑、2-(3′,5′-二叔丁基-2′-羟基苯基)-5-氯苯并三唑、2-(3′-叔丁基-2′-羟基-5′-甲基苯基)-5-氯苯并三唑、2-(3′-仲丁基-5′-叔丁基-2′-羟基苯基)苯并三唑、2-(2′-羟基-4′-辛氧基苯基)苯并三唑、2-(3′,5′-二叔戊基-2′-羟基苯基)苯并三唑、2-(3′,5′-双(α,α-二甲基苄基)-2′-羟基苯基)苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-辛氧基羰基乙基)苯基)-5-氯苯并三唑、2-(3′-叔丁基-5′-[2-(2-乙基己氧基)羰基乙基]-2′-羟基苯基)-5-氯苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-甲氧羰基乙基)苯基)-5-氯苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-甲氧羰基乙基)苯基)苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-辛氧基羰基乙基)苯基)苯并三唑、2-(3′-叔丁基-5′-[2-(2-乙基己氧基)羰基乙基]-2′-羟基苯基)苯并三唑、2-(3′-十二烷基-2′-羟基-5′-甲基苯基)苯并三唑、2-(3′-叔丁基-2′-羟基-5′-(2-异辛氧基羰基乙基)苯基苯并三唑、2,2′-亚甲基双[4-(1,1,3,3-四甲基丁基)-6-苯并三唑-2-基苯酚];2-[3′-叔丁基-5′-(2-甲氧基羰基乙基)-2′-羟基苯基]-2H-苯并三唑与聚乙二醇300的酯交换产物;其中R=3′-叔丁基-4′-羟基-5′-2H-苯并三唑-2-基苯基、2-[2′-羟基-3′-(α,α-二甲基苄基)-5′-(1,1,3,3-四甲基丁基)苯基]苯并三唑;2-[2′-羟基-3′-(1,1,3,3-四甲基丁基)-5′-(α,α-二甲基苄基)苯基]苯并三唑。
2.2.2-羟基二苯甲酮类,例如4-羟基、4-甲氧基、4-辛氧基、4-癸氧基、4-十二烷氧基、4-苄氧基、4,2′,4′-三羟基和2′-羟基-4,4′-二甲氧基衍生物。
2.3.取代和未取代苯甲酸的酯,例如水杨酸4-叔丁基苯酯、水杨酸苯酯、水杨酸辛基苯酯、二苯甲酰间苯二酚、双(4-叔丁基苯甲酰)间苯二酚、苯甲酰间苯二酚、3,5-二叔丁基-4-羟基苯甲酸2,4-二叔丁基苯酯、3,5-二叔丁基-4-羟基苯甲酸十六烷基酯、3,5-二叔丁基-4-羟基苯甲酸十八烷基酯、3,5-二叔丁基-4-羟基苯甲酸2-甲基-4,6-二叔丁基苯酯。
2.4.丙烯酸酯,例如α-氰基-β,β-二苯基丙烯酸乙酯、α-氰基-β,β-二苯基丙烯酸异辛酯、α-甲酯基肉桂酸甲酯、α-氰基-β-甲基对甲氧基肉桂酸甲酯、α-氰基-β-甲基-对甲氧基肉桂酸丁酯、α-甲酯基对甲氧基肉桂酸甲酯、N-(β-甲酯基-β-氰基乙烯基)-2-甲基二氢吲哚、四(α-氰基-β,β-二苯基丙烯酸新戊基酯。
2.5.镍化合物,例如2,2′-硫代双[4-(1,1,3,3-四甲基丁基)苯酚]的镍配合物,例如1∶1或1∶2配合物,其具有或不具有其他配体如正丁胺、三乙醇胺或N-环己基二乙醇胺,二丁基二硫代氨基甲酸镍,4-羟基-3,5-二叔丁基苄基膦酸的单烷基酯如甲酯或乙酯的镍盐,酮肟如2-羟基-4-甲基苯基十一烷基酮肟的镍配合物,1-苯基-4-月桂酰基-5-羟基吡唑的镍配合物,其具有或不具有其他配体。
2.6.位阻胺,例如双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯、双(2,2,6,6-四甲基-4-哌啶基)琥珀酸酯、双(1,2,2,6,6-五甲基-4-哌啶基)癸二酸酯、双(1-辛氧基-2,2,6,6-四甲基-4-哌啶基)癸二酸酯、双(1,2,2,6,6-五甲基-4-哌啶基)正丁基-3,5-二叔丁基-4-羟基苄基丙二酸酯、1-(2-羟乙基)-2,2,6,6-四甲基-4-羟基哌啶与琥珀酸的缩合物、N,N′-双(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺与4-叔辛基氨基-2,6-二氯-1,3,5-三嗪的线性或环状缩合物、三(2,2,6,6-四甲基-4-哌啶基)次氮基三乙酸酯、四(2,2,6,6-四甲基-4-哌啶基)-1,2,3,4-丁烷四甲酸酯、1,1′-(1,2-亚乙基)-双(3,3,5,5-四甲基哌嗪酮)、4-苯甲酰基-2,2,6,6-四甲基哌啶、4-硬脂氧基-2,2,6,6-四甲基哌啶、双(1,2,2,6,6-五甲基哌啶基)-2-正丁基-2-(2-羟基-3,5-二叔丁基苄基)丙二酸酯、3-正辛基-7,7,9,9-四甲基-1,3,8-三氮杂螺[4.5]癸-2,4-二酮、双(1-辛氧基-2,2,6,6-四甲基哌啶基)癸二酸酯、双(1-辛氧基-2,2,6,6-四甲基哌啶基)琥珀酸酯、N,N′-双-(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺与4-吗啉基-2,6-二氯-1,3,5-三嗪的线性或环状缩合物、2-氯-4,6-双(4-正丁基氨基-2,2,6,6-四甲基哌啶基)-1,3,5-三嗪与1,2-双(3-氨基丙基氨基)乙烷的缩合物、2-氯-4,6-二(4-正丁基氨基-1,2,2,6,6-五甲基哌啶基)-1,3,5-三嗪与1,2-双(3-氨基丙基氨基)乙烷的缩合物、8-乙酰基-3-十二烷基-7,7,9,9-四甲基-1,3,8-三氮杂螺[4.5]癸烷-2,4-二酮、3-十二烷基-1-(2,2,6,6-四甲基-4-哌啶基)吡咯烷-2,5-二酮、3-十二烷基-1-(1,2,2,6,6-五甲基-4-哌啶基)吡咯烷-2,5-二酮、4-十六烷氧基-和4-硬脂氧基-2,2,6,6-四甲基哌啶的混合物、N,N′-双(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺与4-环己基氨基-2,6-二氯-1,3,5-三嗪的缩合物、1,2-双(3-氨基丙基氨基)乙烷与2,4,6-三氯-1,3,5-三嗪以及4-丁基氨基-2,2,6,6-四甲基哌啶的缩合物(CAS登记号[136504-96-6]);1,6-己二胺与2,4,6-三氯-1,3,5-三嗪以及N,N-二丁胺与4-丁基氨基-2,2,6,6-四甲基哌啶的缩合物(CAS登记号[192268-64-7]);N-(2,2,6,6-四甲基-4-哌啶基)正十二烷基琥珀酰亚胺、N-(1,2,2,6,6-五甲基-4-哌啶基)正十二烷基琥珀酰亚胺、2-十一烷基-7,7,9,9-四甲基-1-氧杂-3,8-二氮杂-4-氧代螺[4,5]癸烷、7,7,9,9-四甲基-2-环十一烷基-1-氧杂-3,8-二氮杂-4-氧代螺[4,5]癸烷与表氯醇的反应产物、1,1-双(1,2,2,6,6-五甲基-4-哌啶基氧基羰基)-2-(4-甲氧基苯基)乙烯、N,N′-双甲酰基-N,N′-双(2,2,6,6-四甲基-4-哌啶基)六亚甲基二胺、4-甲氧基亚甲基丙二酸与1,2,2,6,6-五甲基-4-羟基哌啶的二酯、聚[甲基丙基-3-氧基-4-(2,2,6,6-四甲基-4-哌啶基)]硅氧烷、马来酸酐-α-烯烃共聚物与2,2,6,6-四甲基-4-氨基哌啶或1,2,2,6,6-五甲基-4-氨基哌啶的反应产物、2,4-双[N-(1-环己氧基-2,2,6,6-四甲基哌啶-4-基)-N-丁基氨基]-6-(2-羟乙基)氨基-1,3,5-三嗪、1-(2-羟基-2-甲基丙氧基)-4-十八碳酰氧基-2,2,6,6-四甲基哌啶、5-(2-乙基己酰基)氧基甲基-3,3,5-三甲基-2-吗啉酮、Sanduvor(Clariant;CAS登记号[106917-31-1])、5-(2-乙基己酰基)氧基甲基-3,3,5-三甲基-2-吗啉酮、2,4-双[(1-环己氧基-2,2,6,6-哌啶-4-基)丁基氨基]-6-氯-s-三嗪与N,N′-双(3-氨基丙基)乙二胺)的反应产物、1,3,5-三(N-环己基-N-(2,2,6,6-四甲基哌嗪-3-酮-4-基)氨基)-s-三嗪、1,3,5-三(N-环己基-N-(1,2,2,6,6-五甲基哌嗪-3-酮-4-基)氨基)-s-三嗪。
2.7.草酰胺类,例如4,4′-二辛氧基草酰替苯胺、2,2′-二乙氧基草酰替苯胺、2,2′-二辛氧基-5,5′-二叔丁基草酰替苯胺、2,2′-二(十二烷氧基)-5,5′-二叔丁基草酰替苯胺、2-乙氧基-2′-乙基草酰替苯胺、N,N′-双(3-二甲基氨基丙基)草酰胺、2-乙氧基-5-叔丁基-2′-乙基草酰替苯胺及其与2-乙氧基-2′-乙基-5,4′-二叔丁基草酰替苯胺的混合物、邻-和对-甲氧基二取代草酰替苯胺的混合物以及邻-和对-乙氧基二取代草酰替苯胺的混合物。
2.8.2-(2-羟基苯基)-1,3,5-三嗪类,例如2,4,6-三(2-羟基-4-辛氧基苯基)-1,3,5-三嗪、2-(2-羟基-4-辛氧基苯基)-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-(2,4-二羟基苯基)-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2,4-双(2-羟基-4-丙氧基苯基)-6-(2,4-二甲基苯基)-1,3,5-三嗪、2-(2-羟基-4-辛氧基苯基)-4,6-双(4-甲基苯基)-1,3,5-三嗪、2-(2-羟基-4-十二烷氧基苯基)-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-(2-羟基-4-十三烷氧基苯基)-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-[2-羟基-4-(2-羟基-3-丁氧基丙氧基)苯基]-4,6-双(2,4-二甲基)-1,3,5-三嗪、2-[2-羟基-4-(2-羟基-3-辛氧基丙氧基)苯基]-4,6-双(2,4-二甲基)-1,3,5-三嗪、2-[4-(十二烷氧基/十三烷氧基-2-羟基丙氧基)-2-羟基苯基]-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-[2-羟基-4-(2-羟基-3-十二烷氧基丙氧基)苯基]-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2-(2-羟基-4-己氧基)苯基-4,6-二苯基-1,3,5-三嗪、2-(2-羟基-4-甲氧基苯基)-4,6-二苯基-1,3,5-三嗪、2,4,6-三[2-羟基-4-(3-丁氧基-2-羟基丙氧基)苯基]-1,3,5-三嗪、2-(2-羟基苯基)-4-(4-甲氧基苯基)-6-苯基-1,3,5-三嗪、2-{2-羟基-4-[3-(2-乙基己基-1-氧基)-2-羟基丙氧基]苯基}-4,6-双(2,4-二甲基苯基)-1,3,5-三嗪、2,4-双(4-[2-乙基己氧基]-2-羟基苯基)-6-(4-甲氧基苯基)-1,3,5-三嗪。
3.金属去活化剂,例如N,N′-二苯基草酰胺、N-水杨醛-N′-水杨酰肼、N,N′-双(水杨酰)肼、N,N′-双(3,5-二叔丁基-4-羟基苯基丙酰)肼、3-水杨酰氨基-1,2,4-三唑、双(亚苄基)草酰二肼、草酰替苯胺、间苯二甲酰二肼、癸二酰双苯基肼、N,N′-二乙酰己二酰二肼、N,N′-双(水杨酰)草酰二肼、N,N′-双(水杨酰)硫代丙酰二肼。
4.亚磷酸酯和亚膦酸酯,例如亚磷酸三苯酯、亚磷酸二苯基烷基酯、亚磷酸苯基二烷基酯、亚磷酸三(壬基苯基)酯、亚磷酸三月桂基酯、亚磷酸三(十八烷基)酯、二硬脂基季戊四醇二亚磷酸酯、亚磷酸三(2,4-二叔丁基苯基)酯、二异癸基季戊四醇二亚磷酸酯、双(2,4-二叔丁基苯基)季戊四醇二亚磷酸酯、双(2,4-二枯基苯基)季戊四醇二亚磷酸酯、双(2,6-二叔丁基-4-甲基苯基)季戊四醇二亚磷酸酯、二异癸氧基季戊四醇二亚磷酸酯、双(2,4-二叔丁基-6-甲基苯基)季戊四醇二亚磷酸酯、双(2,4,6-三(叔丁基苯基)季戊四醇二亚磷酸酯、三硬脂基山梨糖醇三亚磷酸酯、4,4′-亚联苯基二亚膦酸四(2,4-二叔丁基苯基)酯、6-异辛氧基-2,4,8,10-四叔丁基-12H-二苯并[d,g]-1,3,2-二氧杂磷杂八环、亚磷酸双(2,4-二叔丁基-6-甲基苯基)甲酯、亚磷酸双(2,4-二叔丁基-6-甲基苯基)乙酯、6-氟-2,4,8,10-四叔丁基-12-甲基二苯并[d,g]-1,3,2-二氧杂磷杂八环、2,2′,2″-次氮基[三乙基三(3,3′,5,5′-四叔丁基-1,1′-联苯-2,2′-二基)亚磷酸酯]、(3,3′,5,5′-四叔丁基-1,1′-联苯-2,2′-二基)亚磷酸2-乙基己酯、5-丁基-5-乙基-2-(2,4,6-三叔丁基苯氧基)-1,3,2-二氧杂磷杂环丙烷(dioxaphosphirane)。尤其优选如下亚磷酸酯:
5.羟胺,例如N,N-二苄基羟胺、N,N-二乙基羟胺、N,N-二辛基羟胺、N,N-二月桂基羟胺、N,N-二(十四烷基)羟胺、N,N-二(十六烷基)羟胺、N,N-二(十八烷基)羟胺、N-十六烷基-N-十八烷基羟胺、N-十七烷基-N-十八烷基羟胺、衍生自氢化牛油脂肪胺的N,N-二烷基羟胺。
6.硝酮,例如N-苄基-α-苯基硝酮、N-乙基-α-甲基硝酮、N-辛基-α-庚基硝酮、N-月桂基-α-十一烷基硝酮、N-十四烷基-α-十三烷基硝酮、N-十六烷基-α-十五烷基硝酮、N-十八烷基-α-十七烷基硝酮、N-十六烷基-α-十七烷基硝酮、N-十八烷基-α-十五烷基硝酮、N-十七烷基-α-十七烷基硝酮、N-十八烷基-α-十六烷基硝酮、衍生自N,N-二烷基羟胺(衍生自氢化牛油脂肪胺)的硝酮。
7.硫代协合剂,例如硫代二丙酸二月桂基酯、硫代二丙酸二肉豆蔻基酯、硫代二丙酸二硬脂基酯或二硬脂基二硫化物。
8.过氧化物清除剂,例如β-硫代二丙酸的酯,例如月桂基酯、硬脂基酯、肉豆蔻基酯或十三烷基酯、巯基苯并咪唑或2-巯基苯并咪唑的锌盐、二丁基二硫代氨基甲酸锌、二(十八烷基)二硫化物、季戊四醇四(β-十二烷基巯基)丙酸酯。
9.聚酰胺稳定剂,例如与碘和/或磷化合物组合的铜盐和二价锰盐。
10.碱性助稳定剂,例如三聚氰胺、聚乙烯吡咯烷酮、双氰胺、氰脲酸三烯丙基酯、脲衍生物、肼衍生物、胺、聚酰胺、聚氨酯、高级脂肪酸的碱金属盐和碱土金属盐,例如硬脂酸钙、硬脂酸锌、山萮酸镁、硬脂酸镁、蓖麻醇酸钠和棕榈酸钾、焦儿茶酸锑或焦儿茶酸锌。
11.成核剂,例如无机物质如滑石,金属氧化物如二氧化钛或氧化镁,优选碱土金属的磷酸盐、碳酸盐或硫酸盐;有机化合物如单-或聚羧酸及其盐,例如4-叔丁基苯甲酸、己二酸、二苯基乙酸、琥珀酸钠或苯甲酸钠;聚合化合物如离子共聚物(离聚物)。尤其优选为1,3:2,4-双(3′,4′-二甲基亚苄基)山梨糖醇、1,3:2,4-二(对甲基二亚苄基)山梨糖醇和1,3:2,4-二(亚苄基)山梨糖醇。
12.填料和增强剂,例如碳酸钙、硅酸盐、玻璃纤维、玻璃珠、石棉、滑石、高岭土、云母、硫酸钡、金属氧化物和氢氧化物、炭黑、石墨、木粉和其他天然产物的粉或纤维、合成纤维。
13.其他添加剂,例如增塑剂、润滑剂、乳化剂、颜料、流变添加剂、催化剂、流动调节剂、荧光增白剂、阻燃剂、抗静电剂和发泡剂。
14.苯并呋喃酮类和吲哚满酮类,例如US4,325,863、US4,338,244、US5,175,312、U S5,216,052、US5,252,643、DE-A-4316611、DE-A-4316622、DE-A-4316876、EP-A-0589839、EP-A-0591102、EP-A-1291384中所公开的那些,或3-[4-(2-乙酰氧基乙氧基)苯基]-5,7-二叔丁基苯并呋喃-2-酮、5,7-二叔丁基-3-[4-(2-硬脂酰氧基乙氧基)苯基]苯并呋喃-2-酮、3,3’-双[5,7-二叔丁基-3-(4-[2-羟基乙氧基]苯基)苯并呋喃-2-酮]、5,7-二叔丁基-3-(4-乙氧基苯基)苯并呋喃-2-酮、3-(4-乙酰氧基-3,5-二甲基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(3,5-二甲基-4-新戊酰氧基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(3,4-二甲基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(2,3-二甲基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(2-乙酰基-5-异辛基苯基)-5-异辛基苯并呋喃-2-酮。
这些其他添加剂通常基于热塑性或弹性体聚合物基材的重量以0.1-5重量%的量加入。
本发明的另一方面是一种制备抗静电热塑性或弹性体聚合物制品的方法,包括将如上所述的组合物掺入热塑性或弹性体聚合物基材中。
该制备可以以本身已知的方式通过使用本身已知的装置如压延机、混合机、捏合机、挤出机等将所述组分和需要的话其他添加剂与聚合物混合而进行。添加剂可以单独或相互混合加入。还可以使用所谓的母料。
本发明的抗静电热塑性聚合物可以以已知方式制成所需形式。该类方法例如包括研磨、压延、挤出、注塑、熔结、压缩/熔结或纺丝,还有挤出吹塑或根据塑料溶胶方法的加工。该抗静电热塑性聚合物还可以加工形成发泡材料。
式(I)的分子量至少为400的聚合物作为热塑性或弹性体聚合物的抗静电添加剂的用途也在本发明范围内:
Q1-Q2(I)
其中
Q1为C20-C100烷基、C20-C100链烯基或被1-5个C1-C100烷基取代的C5-C12环烷基;
Q2为式(II)的基团:
其中
R1为H或CH3;
n为2-6的数;
t为1-200的数;以及
*为连接点。
优选额外使用有机或无机盐。
上面所给定义和优选情形同样适合本发明的所有方面。
本发明可以有利地用于包装中的防尘应用。目的是对硬质包装个人护理产品(护发、沐浴和淋浴、皮肤护理、Deo)和家用护理产品(洗涤剂、家用清洁剂)或硬质包装奶制品(牛奶、奶油、人造黄油、酸奶等)实现最小化的粉尘吸引、长时间的视觉外观。适合这些应用的基材聚合物是HDPE、PP、PS。典型的加工步骤例如为挤出吹塑(瓶)、注射(deo)、压片(奶制品的热成型)。包装结构可以是单层或多层。
还令人感兴趣的是电子器件包装和运输、工业包装或ESD*(静电放电)保护的区域设备的抗静电应用。目的是保护电荷敏感性器件以防止发生ESD事件(电子器件)、使可燃物品的爆炸或着火风险最小化、提高长期性能和可靠性。典型的基材聚合物是PP和PS。
下列实施例说明本发明。
所用材料:Unithox 350(化合物101)、Unithox 420(化合物102)、Unithox520(化合物103)、Unithox 550(化合物104)、Unithox 720(化合物105)和Unithox 750(化合物106)。
盐:NaTS为甲苯磺酸钠,NaMes为甲磺酸钠,AcOK为乙酸钾。
聚苯乙烯(PS),来自Dow Inc.的Styron 484天然聚苯乙烯
聚丙烯(PP),来自Borealis Inc.的HC 115MO
高密度聚乙烯(HDPE),来自Borealis Inc.的BL 2571
低密度聚乙烯(LDPE),来自Polimeri Europe Inc.的Riblene FF 29
测量
接触角:
使用固着液滴法和作为测量液的水由Dataphysics OCA 30接触角装置测量所生产带材的接触角。
表面电阻率:
表面电阻率值SR[Ohms/sq]使用弹舌电极(sprung-tongue electrode)类似于DIN 53482在500V的电压下在22℃和限定的空气相对湿度(RH)下测量。
实施例1:PS挤出带材的加工
为了评价其在PS中的加工性和表面性能,根据下列程序将式I化合物掺入聚苯乙烯挤出带材中:
将聚苯乙烯粉末Styron 484天然聚苯乙烯和式I化合物在真空烘箱中分别于80℃和40℃下干燥8小时。将适量的式I化合物加入干燥的聚苯乙烯粉末中,得到含有至多20重量%化合物的配制剂。将各配制剂在汽轮式混合器中混合并在装有扁平口模的双螺杆挤出机(来自Thermo ElectronCorporation的MiniLab挤出机)中挤出。以此方式生产宽度为5mm且厚度为约0.5mm的聚苯乙烯带材。加工温度为约200℃。结果总结于下表1中。
实施例1a为对比例。实施例1b-1m为描述包括三种组分(a)、(b)和(c)的配制剂的本发明实施例。它们表明了各种盐的益处且在大多数情况下显示出良好的加工性和式I化合物的视觉相容性。
表1:PS挤出带材的结果
实施例2:PP挤出带材的加工
为了评价其在PP中的加工性和表面性能,根据下列程序将式I化合物掺入聚丙烯挤出带材中:
将聚丙烯粉末HC115MO和式I化合物在真空烘箱中分别于80℃和40℃下干燥8小时。将适量的式I化合物加入干燥的聚丙烯粉末中,得到含有至多20重量%化合物的配制剂。将各配制剂在汽轮式混合器中混合并在装有扁平口模的双螺杆挤出机(来自Thermo Electron Corporation的MiniLab挤出机)中挤出。以此方式生产宽度为5mm且厚度为约0.5mm的聚丙烯带材。加工温度为约200℃。结果总结于下表2中。
实施例2a为对比例。实施例2b-2m为描述包括三种组分(a)、(b)和(c)的配制剂的本发明实施例。
表2:PP挤出带材的结果
实施例3:HDPE挤出带材的加工
为了评价其在HDPE中的加工性和表面性能,根据下列程序将式I化合物掺入聚乙烯挤出带材中:
将高密度聚乙烯粉末BL2571和式I化合物在真空烘箱中分别于80℃和40℃下干燥8小时。将适量的式I化合物加入干燥的聚乙烯粉末中,得到含有至多20重量%化合物的配制剂。将各配制剂在汽轮式混合器中混合并在装有扁平口模的双螺杆挤出机(来自Thermo Electron Corporation的MiniLab挤出机)中挤出。以此方式生产宽度为5mm且厚度为约0.5mm的聚乙烯带材。加工温度为约200℃。结果总结于下表3中。
实施例3a为对比例。实施例3b-3e为描述包括三种组分(a)、(b)和(c)的配制剂的本发明实施例。最好的实施例为3b和3c。
表3:HDPE挤出带材的结果
实施例4:PS注塑板的加工
为了评价其在PS中的加工性和表面性能,根据下列程序将新的式I化合物掺入聚苯乙烯注塑板中:
将聚苯乙烯粉末Styron 484天然聚苯乙烯和式I化合物在真空烘箱中分别于80℃和40℃下干燥8小时。将适量的式I化合物加入干燥的聚苯乙烯粉末中,得到含有至多20重量%化合物的配制剂。将各配制剂在汽轮式混合器中混合并在双螺杆挤出机(来自Thermo Electron Corp.的MiniLab或Polylab)中配混成粒料,使用注塑机(Arbug 320S)进一步注塑成宽85mm、长90mm和厚2mm的较大板。加工温度为约200℃。结果总结于下表4中。
实施例4a和4d为对比例。实施例4b和4c为描述包括三种组分(a)、(b)和(c)的配制剂的本发明实施例。
表4:PS注塑大块板的结果
实施例5:PP注塑板的加工
为了评价其在PP中的加工性和表面性能,根据下列程序将式I化合物掺入聚丙烯注塑板中:
将聚丙烯粉末HC115MO和式I化合物在真空烘箱中分别于80℃和40℃下干燥8小时。将适量的式I化合物加入干燥的聚丙烯粉末中,得到含有至多20重量%化合物的配制剂。将各配制剂在汽轮式混合器中混合并在双螺杆挤出机(来自Thermo Electron Corp.的MiniLab或Polylab)中配混成粒料,使用微注塑机(来自CronoPlast的BabyPlast)进一步注塑成宽30mm、长40mm和厚2mm的板或使用注塑机(Arbug 320S)进一步注塑成宽85mm、长90mm和厚2mm的较大板。加工温度为约220℃。结果总结于下表5a和5b中。
实施例5a为对比例。实施例5b、5c、5d为描述包括三种组分(a)、(b)和(c)的配制剂的本发明实施例。
表5(a):PP注塑小板的结果
表5(b):PP注塑大板的结果
实施例6:HDPE注塑板的加工
为了评价其在HDPE中的加工性和表面性能,根据下列程序将式I化合物掺入高密度聚乙烯注塑板中:
将高密度聚乙烯粉末BL2571和式I化合物在真空烘箱中分别于80℃和40℃下干燥8小时。将适量的式I化合物加入干燥的聚乙烯粉末中,得到含有至多20重量%化合物的配制剂。将各配制剂在汽轮式混合器中混合并在双螺杆挤出机(来自Thermo Electron Corp.的MiniLab或Polylab)中配混成粒料,使用微注塑机(来自CronoPlast的BabyPlast)进一步注塑成宽30mm、长40mm和厚2mm的板。加工温度为约220℃。结果总结于下表6中。
实施例6a为对比例。实施例6b-6e为描述包括三种组分(a)、(b)和(c)的配制剂的本发明实施例。
表6:HDPE注塑小板的结果
实施例7:PP吹塑瓶的加工
为了评价它们在PP中的加工性能和表面性能,根据下列程序将式I化合物掺入聚丙烯吹塑瓶中:
将聚丙烯粉末HC115MO和式I化合物在真空烘箱中分别于80℃和40℃下干燥8小时。将适量的式I化合物加入干燥的聚丙烯粉末中,得到含有至多20重量%化合物的配制剂。将各配制剂在汽轮式混合器中混合并在双螺杆挤出机(来自Thermo Electron Corp.的MiniLab或Polylab)中配混成粒料,进一步吹塑成50-100mL的瓶(使用均来自Labtech的LE25-30挤出机和LBM-125注塑机)。加工温度为约220℃。结果总结于下表7中。
实施例7a为对比例。实施例7b-7g为说明包括三种组分(a)、(b)和(c)的配制剂的本发明实施例。最好的实施例是描述表面电阻率降低且具有良好加工性和视觉相容性的7b-7e。
表7:PP吹塑瓶的结果
实施例8:用于评价表面效果耐久性的程序
使用下列程序评价表面电阻率的耐久性。在限定的温度和时间下将样品浸入蒸馏水中。将其在环境空气中静置干燥24小时或更短时间并立即在无调节下在50%相对湿度的空气中测量,然后在50%相对湿度的空气中长时间调节之后再次测量。表10总结了表面效果的耐久性。样品为根据实施例5的说明得到的大尺寸PP注塑版。
实施例8a不含抗静电添加剂。实施例8b-8e为本发明实施例。
结果表明在加工之后和在水萃取处理之后的初始值之间几乎观察不到变化,因此表明所研究添加剂的耐久性。
表10:在聚丙烯中得到的表面效果的耐久性
I在室温下将样品浸于水中60分钟并在环境空气中干燥(i)24小时或(ii)15分钟(无调节)之后
II在随后于50%相对湿度下调节3天之后
III在室温下将相同样品浸于水中额外24小时并在环境空气中干燥(i)24小时或(ii)15分钟(无调节)之后
IV在随后于50%相对湿度下调节3天之后
Claims (14)
2.根据权利要求1的组合物,其中Q1为C20-C100烷基。
4.根据前述权利要求中任一项的组合物,其中所述无机或有机盐选自LiClO4、LiCF3SO3、NaClO4、LiBF4、NaBF4、KBF4、NaCF3SO3、KClO4、KPF6、KCF3SO3、KC4F9SO3、Ca(ClO4)2、Ca(PF6)2、Mg(ClO4)2、Mg(CF3SO3)2、Zn(ClO4)2、Zn(PF6)2、Ca(CF3SO3)2、磷酸的Na或K盐、C1-C18羧酸的Na或K盐、芳族或脂族磺酸的Na或K盐。
6.根据权利要求1的组合物,其中所述热塑性或弹性体聚合物基材为聚烯烃、聚苯乙烯、丙烯腈/丁二烯/苯乙烯共聚物(ABS)、α,β-不饱和酸的聚合物、含卤素聚合物、环状醚的均聚物或共聚物、不饱和醇和胺的聚合物、聚缩醛、聚苯醚、聚氨酯、聚酰胺、聚酯、聚脲、聚碳酸酯、聚砜或天然橡胶。
7.根据权利要求6的组合物,其中所述热塑性或弹性体聚合物基材为聚烯烃、聚苯乙烯、丙烯腈/丁二烯/苯乙烯共聚物(ABS)、α,β-不饱和酸的聚合物、含卤素聚合物或环状醚的均聚物或共聚物。
8.根据权利要求7的组合物,其中所述热塑性或弹性体聚合物基材为聚氯乙烯(PVC)、聚乙烯、聚苯乙烯或聚丙烯。
9.根据前述权利要求中任一项的组合物,其中所述式(I)的抗静电聚合物基于所述热塑性或弹性体聚合物基材的重量以0.1-30重量%的量存在。
10.根据前述权利要求中任一项的组合物,其中所述无机或有机盐基于所述热塑性或弹性体聚合物基材的重量以0.1-10重量%的量存在。
11.根据前述权利要求中任一项的组合物,额外包含选自UV吸收剂、位阻胺、酚类抗氧化剂、亚磷酸酯或亚膦酸酯以及苯并呋喃酮类或吲哚满酮类的添加剂。
12.一种制备抗静电热塑性或弹性体聚合物制品的方法,包括将根据权利要求1的组合物掺入热塑性或弹性体聚合物基材中。
13.式(I)的分子量至少为400的聚合物作为热塑性或弹性体聚合物的抗静电添加剂的用途:
Q1-Q2(I)
其中
Q1为C20-C100烷基、C20-C100链烯基或被1-5个C1-C100烷基取代的C5-C12环烷基;
Q2为式(II)的基团:
其中
R1为H或CH3;
n为2-6的数;
t为1-200的数;以及
*为连接点。
14.根据权利要求13的用途,其中额外使用有机或无机盐。
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