CN102459284B - 用于环状酯和环状碳酸酯的永活性开环聚合的催化体系 - Google Patents

用于环状酯和环状碳酸酯的永活性开环聚合的催化体系 Download PDF

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CN102459284B
CN102459284B CN201080029208.6A CN201080029208A CN102459284B CN 102459284 B CN102459284 B CN 102459284B CN 201080029208 A CN201080029208 A CN 201080029208A CN 102459284 B CN102459284 B CN 102459284B
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polymerization
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CN102459284A (zh
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J-F.卡彭蒂尔
Y.萨拉金
V.波伊里尔
M.赫洛
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NATIONAL CENTER FOR SCIENTIFIC RESEARCH
Total Petrochemicals Research Feluy SA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/06—Zinc compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02—Aliphatic polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/16—Aliphatic-aromatic or araliphatic polycarbonates
    • C08G64/1608—Aliphatic-aromatic or araliphatic polycarbonates saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/30—General preparatory processes using carbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/38—General preparatory processes using other monomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
CN201080029208.6A 2009-04-30 2010-04-29 用于环状酯和环状碳酸酯的永活性开环聚合的催化体系 Active CN102459284B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09290318.6 2009-04-30
EP09290318A EP2253637A1 (en) 2009-04-30 2009-04-30 Catalytic systems for immortal ring-opening polymerisation of cyclic esters and cyclic carbonates
PCT/EP2010/055794 WO2010125138A1 (en) 2009-04-30 2010-04-29 Catalytic systems for immortal ring-opening polymerisation of cyclic esters and cyclic carbonates.

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CN102459284A CN102459284A (zh) 2012-05-16
CN102459284B true CN102459284B (zh) 2015-11-25

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US (2) US9090636B2 (enExample)
EP (2) EP2253637A1 (enExample)
JP (1) JP6148006B2 (enExample)
KR (1) KR101385076B1 (enExample)
CN (1) CN102459284B (enExample)
WO (1) WO2010125138A1 (enExample)

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JP5589140B2 (ja) 2010-07-15 2014-09-10 トタル リサーチ アンド テクノロジー フエリユイ ポリ（カーボネート−ウレタン）またはポリ（エステル−ウレタン）のイソシアネートフリーな製造方法
WO2012156237A1 (en) 2011-05-19 2012-11-22 Total Research & Technology Feluy Use of multifunctonal initiator to prepare diblock copolymers comprising a monovinylaromatic polymer block.
FI20115504A0 (fi) * 2011-05-23 2011-05-23 Teknologian Tutkimuskeskus Vtt Oy Menetelmä glykolidipolyesterin valmistamiseksi renkaanavauspolymeroinnilla
WO2012160042A1 (en) * 2011-05-23 2012-11-29 Total Research & Technology Feluy Process for the polymerization of cyclic carbonates
ES2641647T3 (es) * 2011-09-02 2017-11-10 Total Research & Technology Feluy Sistemas catalíticos basados en complejos de fenolato para polimerización con apertura de anillo inmortal de ésteres y carbonatos cíclicos
WO2013186313A1 (en) * 2012-06-15 2013-12-19 Total Research & Technology Feluy Method of copolymerizing ethylene carbonate with one or more cyclic esters
US20160068630A1 (en) * 2013-04-29 2016-03-10 Total Research & Technology Feluy Process for Preparing Polycarbonates by Polymerization of Five-Membered-Ring Cyclic Carbonates
FR3019064B1 (fr) * 2014-03-25 2020-02-28 IFP Energies Nouvelles Nouvelle composition catalytique et procede pour l'oligomerisation de l'ethylene en hexene-1
CN108676021B (zh) * 2018-04-17 2019-06-04 浙江大学 一种锌催化剂及其制备方法和在内酯开环聚合中的应用
KR102100611B1 (ko) * 2018-08-17 2020-04-14 충남대학교산학협력단 고리형 카보네이트 제조용 금속 착화합물 촉매 및 이를 이용한 고리형 카보네이트의 제조방법
CN109879801A (zh) * 2019-03-25 2019-06-14 华东理工大学 一种含吡啶环的氨基酚氧基锌络合物及其制备方法和应用
EP3736303A1 (en) * 2019-05-06 2020-11-11 Evonik Operations GmbH Novel catalyzed synthesis of biodegradable polyesters
JP7656398B2 (ja) 2019-06-17 2025-04-03 セイコーエプソン株式会社 放射線硬化型インクジェット組成物及びインクジェット方法
CN111253556B (zh) * 2020-03-20 2022-02-18 南京工业大学 一种功能化可回收高分子均聚物及其制备方法与应用
JP7463795B2 (ja) 2020-03-25 2024-04-09 セイコーエプソン株式会社 放射線硬化型インクジェット組成物及びインクジェット方法
JP7435121B2 (ja) * 2020-03-25 2024-02-21 セイコーエプソン株式会社 放射線硬化型インクジェット組成物及びインクジェット方法
CN111671967A (zh) * 2020-04-18 2020-09-18 山东朱氏药业集团有限公司 基于聚乳酸、聚己内酯共聚物的可降解组织胶制备方法
CN112625054B (zh) * 2020-12-28 2022-10-28 华东理工大学 一种吲哚环取代的氨基酚氧基锌络合物及其制备方法和应用
CN113264901B (zh) * 2021-05-13 2023-02-28 华东理工大学 一种含2-取代噻唑-4-基的氨基酚氧基锌络合物及其制备方法和应用

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EP2096132A1 (en) * 2008-02-26 2009-09-02 Total Petrochemicals Research Feluy Monomers issued from renewable resources and process for polymerising them
CN102105502A (zh) * 2008-07-28 2011-06-22 道达尔石化法国公司 具有单乙烯基芳族聚合物嵌段的二嵌段共聚物的制造方法

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Publication number Publication date
US9133304B2 (en) 2015-09-15
US20150148516A1 (en) 2015-05-28
CN102459284A (zh) 2012-05-16
WO2010125138A1 (en) 2010-11-04
EP2424871A1 (en) 2012-03-07
EP2424871B1 (en) 2014-10-29
KR20120008039A (ko) 2012-01-25
JP2012525357A (ja) 2012-10-22
US20120101233A1 (en) 2012-04-26
EP2253637A1 (en) 2010-11-24
US9090636B2 (en) 2015-07-28
KR101385076B1 (ko) 2014-04-18
JP6148006B2 (ja) 2017-06-14

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