CN102438972B - 通过在含铜非均相催化剂上氢化甘油三脂肪酸酯而制备脂肪醇的方法 - Google Patents

通过在含铜非均相催化剂上氢化甘油三脂肪酸酯而制备脂肪醇的方法 Download PDF

Info

Publication number
CN102438972B
CN102438972B CN201080021975.2A CN201080021975A CN102438972B CN 102438972 B CN102438972 B CN 102438972B CN 201080021975 A CN201080021975 A CN 201080021975A CN 102438972 B CN102438972 B CN 102438972B
Authority
CN
China
Prior art keywords
hydrogenation
carried out
reactor
process according
fatty acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080021975.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN102438972A (zh
Inventor
D·米尔克
R·普罗哈兹卡
J·亨克尔曼
M·赫尔茨勒
D·赫兹博格
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN102438972A publication Critical patent/CN102438972A/zh
Application granted granted Critical
Publication of CN102438972B publication Critical patent/CN102438972B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Catalysts (AREA)
CN201080021975.2A 2009-05-20 2010-05-19 通过在含铜非均相催化剂上氢化甘油三脂肪酸酯而制备脂肪醇的方法 Expired - Fee Related CN102438972B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09160709.3 2009-05-20
EP09160709 2009-05-20
PCT/EP2010/056859 WO2010133619A1 (de) 2009-05-20 2010-05-19 Verfahren zur herstellung von fettalkoholen durch hydrierung von fettsäuretriglyceriden an einem kupferhaltigen heterogenen katalysator

Publications (2)

Publication Number Publication Date
CN102438972A CN102438972A (zh) 2012-05-02
CN102438972B true CN102438972B (zh) 2015-09-09

Family

ID=42313277

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080021975.2A Expired - Fee Related CN102438972B (zh) 2009-05-20 2010-05-19 通过在含铜非均相催化剂上氢化甘油三脂肪酸酯而制备脂肪醇的方法

Country Status (9)

Country Link
US (1) US8946490B2 (cg-RX-API-DMAC10.html)
EP (1) EP2432756B1 (cg-RX-API-DMAC10.html)
JP (1) JP5771192B2 (cg-RX-API-DMAC10.html)
KR (1) KR101742749B1 (cg-RX-API-DMAC10.html)
CN (1) CN102438972B (cg-RX-API-DMAC10.html)
BR (1) BRPI1012167B1 (cg-RX-API-DMAC10.html)
ES (1) ES2619559T3 (cg-RX-API-DMAC10.html)
MY (1) MY156726A (cg-RX-API-DMAC10.html)
WO (1) WO2010133619A1 (cg-RX-API-DMAC10.html)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9605198B2 (en) 2011-09-15 2017-03-28 Chevron U.S.A. Inc. Mixed carbon length synthesis of primary Guerbet alcohols
US20130068457A1 (en) * 2011-09-15 2013-03-21 Chevron U.S.A. Inc. Method of Manufacture of Guerbet Alcohols For Making Surfactants Used In Petroleum Industry Operations
US9422469B2 (en) * 2013-03-15 2016-08-23 Chevron U.S.A. Inc. Mixed carbon length synthesis of primary guerbet alcohols
BR112015021763B1 (pt) 2013-03-07 2021-06-08 Genomatica, Inc método de purificação de um álcool graxo (falc)
EP3101000B1 (en) 2014-01-28 2020-07-29 Nippon Shokubai Co., Ltd. Hydrogenation reaction method
US20160280987A2 (en) * 2014-08-25 2016-09-29 Prochem International BV Non-toxic and biodegradable surfactants
US20180222831A1 (en) * 2015-08-05 2018-08-09 White Dog Labs, Inc. Method for the production of at least one derivate of a carboxylic acid
CN105061140A (zh) * 2015-08-11 2015-11-18 华东师范大学 无氢条件下脂肪酸或脂肪酸酯制备脂肪醇的方法以及应用于该方法的催化剂
EP3541771B1 (en) * 2016-11-16 2021-01-06 Archer Daniels Midland Company Process for producing 1,2-propanediol from glycerol
US10072231B2 (en) * 2016-12-02 2018-09-11 Ag Chem, Llc Process for the conversion of free fatty acids to glycerol esters and production of novel catalyst systems
DE102019131569A1 (de) * 2019-11-22 2021-05-27 Clariant International Ltd Chromfreier wasser- und saeurestabiler katalysator fuer hydrierungen
EP4549622A1 (en) 2023-10-31 2025-05-07 Basf Se Hydrogenation of carbonyl compounds using hydrogen with low deuterium content
CN119857488B (zh) * 2025-01-23 2026-04-17 浙江工业大学 一种大孔径氧化铝负载的铜基催化剂及其制备和应用

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1154448B (de) 1961-07-18 1963-09-19 Hydrierwerk Rodleben Veb Verfahren zur Herstellung hoehermolekularer ein- und mehrwertiger Alkohole
DE2909671A1 (de) 1979-03-12 1980-10-02 Basf Ag Verfahren zur herstellung von schalenkatalysatoren
NL8101637A (nl) 1981-04-02 1982-11-01 Unilever Nv Werkwijze voor het selectief hydrogeneren van vetzuurderivaten.
US4626604A (en) * 1985-09-11 1986-12-02 Davy Mckee (London) Limited Hydrogenation process
DE3776997D1 (de) 1986-07-23 1992-04-09 Henkel Kgaa Verfahren zur direkthydrierung von glyceridoelen.
DE3708430A1 (de) 1987-03-16 1988-09-29 Henkel Kgaa Verfahren zur direkthydrierung von butterfett
DE3809270A1 (de) * 1988-03-19 1989-09-28 Henkel Kgaa Verfahren zur katalytischen hydrierung von fluessigen fettsaeure-triglyceriden zur gleichzeitigen gewinnung von fettalkoholen und c(pfeil abwaerts)3(pfeil abwaerts)-diolen
US5120885A (en) * 1990-09-21 1992-06-09 Kao Corporation Process for producing alcohol
JPH0699337B2 (ja) * 1990-12-27 1994-12-07 花王株式会社 アルコールの製造方法
MY107920A (en) * 1990-12-27 1996-06-29 Kao Corp Process for producing alcohol
DE4129622A1 (de) 1991-09-06 1993-03-11 Henkel Kgaa Verfahren zur herstellung von ungesaettigten fettalkoholen
JPH0734867B2 (ja) * 1991-10-09 1995-04-19 花王株式会社 水素化用触媒及びその製造方法
DE4242466C2 (de) 1992-12-16 2003-07-03 Cognis Deutschland Gmbh Verfahren zur Herstellung von Fettalkoholen
US5475160A (en) * 1994-11-07 1995-12-12 Shell Oil Company Process for the direct hydrogenation of triglycerides
MY129140A (en) * 1994-11-07 2007-03-30 Shell Int Research Process and a catalyst for the direct hydrogenation of carboxylic esters
DE4442346A1 (de) 1994-11-29 1996-05-30 Basf Ag Verfahren zur Herstellung eines Katalysators, bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Oxidmasse
DE19843798C2 (de) 1998-09-24 2003-01-09 Cognis Deutschland Gmbh Verfahren zur Herstellung von Fettalkoholen
US20040133049A1 (en) * 1998-10-07 2004-07-08 Christian Pelzer Process for the continous fixed-bed hydrogenation of fatty acids and fatty acid esters
DE19960428A1 (de) 1999-12-15 2001-07-05 Cognis Deutschland Gmbh Oxidische Zink-Aluminium-Katalysatoren
DE10313702A1 (de) 2003-03-27 2004-10-07 Basf Ag Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen
DE102004033556A1 (de) 2004-07-09 2006-02-16 Basf Ag Katalysatorformkörper und Verfahren zur Hydrierung von Carbonylverbindungen
EP1993985B1 (en) * 2006-03-03 2017-10-04 Basf Se Process for the preparation of 1,2-propanediol
BRPI0815971B1 (pt) 2007-08-31 2017-10-24 Basf Se Method for preparing 1,2-propanodiol
BRPI0815783A2 (pt) 2007-08-31 2015-02-24 Basf Se Processo para a preparação de 1,2-propanodiol.
CN101855190A (zh) 2007-08-31 2010-10-06 巴斯夫欧洲公司 通过甘油的低压氢化制备1,2-丙二醇的方法
JP5690716B2 (ja) 2008-04-22 2015-03-25 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ エタノールを予備改質する方法
CA2735396C (en) 2008-09-08 2016-09-06 Basf Se Method for the integrated production of cellulose and low-molecular-weight reusable materials
EP2379478B1 (de) 2008-12-17 2016-08-10 Basf Se Kontinuierliches verfahren zur herstellung von substituierten cyclohexylmethanolen
WO2010084058A1 (de) 2009-01-20 2010-07-29 Basf Se Verfahren zur herstellung von polyurethan-hartschaumstoffen
CN102325744B (zh) 2009-01-21 2014-06-18 巴斯夫欧洲公司 生产祛臭的1,2-丙二醇的方法
KR20110137832A (ko) 2009-04-20 2011-12-23 바스프 에스이 전기화학적 환원에 의한 반응성 아연의 제조 방법

Also Published As

Publication number Publication date
US8946490B2 (en) 2015-02-03
BRPI1012167A2 (pt) 2017-10-24
BRPI1012167B1 (pt) 2018-06-19
JP2012527427A (ja) 2012-11-08
EP2432756B1 (de) 2016-12-21
CN102438972A (zh) 2012-05-02
WO2010133619A1 (de) 2010-11-25
KR101742749B1 (ko) 2017-06-01
KR20120017076A (ko) 2012-02-27
US20120083631A1 (en) 2012-04-05
ES2619559T3 (es) 2017-06-26
JP5771192B2 (ja) 2015-08-26
EP2432756A1 (de) 2012-03-28
MY156726A (en) 2016-03-15

Similar Documents

Publication Publication Date Title
CN102438972A (zh) 通过在含铜非均相催化剂上氢化甘油三脂肪酸酯而制备脂肪醇的方法
CN101848884B (zh) 通过在至少三个连续的反应器中将甘油氢化制备1,2-丙二醇的方法
US7790937B2 (en) Process for the preparation of 1,2-propanediol
US8252962B2 (en) Method for producing 1,2-propandiol by hydrogenating glycerine in a two-step reactor cascade
US8273924B2 (en) Method for producing 1,2-propandiol by low-pressure hydrogenation of glycerine
EP2809643B1 (en) Ethyl acetate production
US8735635B2 (en) Process for making 1, 2-propane diol from hydrogenation of glycerol
WO2014002884A1 (ja) イソプロパノールの製造方法
US7524995B1 (en) Continuous process to produce hexafluoroisopropanol
US9586879B2 (en) Process for the selective production of propanols by hydrogenation of glycerol
CN101395113A (zh) 制备1,2-丙二醇的方法
JP7784651B2 (ja) 不飽和アルコールの製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150909

CF01 Termination of patent right due to non-payment of annual fee