CN102422468B - 复合氧电极及其制造方法 - Google Patents

复合氧电极及其制造方法 Download PDF

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Publication number
CN102422468B
CN102422468B CN201080018282.8A CN201080018282A CN102422468B CN 102422468 B CN102422468 B CN 102422468B CN 201080018282 A CN201080018282 A CN 201080018282A CN 102422468 B CN102422468 B CN 102422468B
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CN
China
Prior art keywords
phase
nanoparticles
oxygen electrode
particle
oxide
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Expired - Fee Related
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CN201080018282.8A
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English (en)
Chinese (zh)
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CN102422468A (zh
Inventor
M·莫根森
P·贾尔马森
M·万德尔
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Danmarks Tekniske Universitet
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Danmarks Tekniske Universitet
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4207—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells for several batteries or cells simultaneously or sequentially
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H01M10/441—Methods for charging or discharging for several batteries or cells simultaneously or sequentially
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/482—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for several batteries or cells simultaneously or sequentially
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H01M4/8885—Sintering or firing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/1233—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with one of the reactants being liquid, solid or liquid-charged
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
    • H01M8/1253—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides the electrolyte containing zirconium oxide
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
    • H02J7/0013—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries acting upon several batteries simultaneously or sequentially
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8689—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Power Engineering (AREA)
  • Inert Electrodes (AREA)
  • Catalysts (AREA)
CN201080018282.8A 2009-04-24 2010-04-23 复合氧电极及其制造方法 Expired - Fee Related CN102422468B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09005779A EP2244322A1 (en) 2009-04-24 2009-04-24 Composite oxygen electrode and method for preparing same
EP09005779.5 2009-04-24
PCT/EP2010/002521 WO2010121828A1 (en) 2009-04-24 2010-04-23 Composite oxygen electrode and method

Publications (2)

Publication Number Publication Date
CN102422468A CN102422468A (zh) 2012-04-18
CN102422468B true CN102422468B (zh) 2015-07-22

Family

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Family Applications (1)

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CN201080018282.8A Expired - Fee Related CN102422468B (zh) 2009-04-24 2010-04-23 复合氧电极及其制造方法

Country Status (9)

Country Link
US (1) US20120037499A1 (enExample)
EP (2) EP2244322A1 (enExample)
JP (1) JP5571772B2 (enExample)
KR (1) KR20120004471A (enExample)
CN (1) CN102422468B (enExample)
AU (1) AU2010241164B9 (enExample)
CA (1) CA2759157A1 (enExample)
RU (1) RU2537561C2 (enExample)
WO (1) WO2010121828A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120251917A1 (en) * 2011-04-04 2012-10-04 Korea Institute Of Science And Technology Solid oxide fuel cell comprising nanostructure composite cathode and fabrication method thereof
US20130243943A1 (en) * 2012-03-01 2013-09-19 Samir BOULFRAD Porous solid backbone impregnation for electrochemical energy conversion systems
CA2870400A1 (en) * 2012-04-23 2013-10-31 Technical University Of Denmark Sensor employing internal reference electrode
KR101334899B1 (ko) * 2012-08-16 2013-11-29 국립대학법인 울산과학기술대학교 산학협력단 고체 산화물 연료전지용 캐소드와 그 제조 방법 및 이 캐소드를 포함하는 연료전지
US9525179B2 (en) * 2013-03-13 2016-12-20 University Of Maryland, College Park Ceramic anode materials for solid oxide fuel cells
CN106876726A (zh) * 2015-12-12 2017-06-20 中国科学院大连化学物理研究所 一种长期稳定的固体氧化物燃料电池高活性阴极的制备方法
CN106887631A (zh) * 2015-12-12 2017-06-23 中国科学院大连化学物理研究所 一种提高钙钛矿氧化物阴极稳定性的方法
CN112930603A (zh) * 2018-10-31 2021-06-08 德克萨斯大学系统董事会 复合膜及其制备和使用方法
CN111962098B (zh) * 2020-08-17 2022-06-21 广东电网有限责任公司广州供电局 固体氧化物电解池的氧电极浆料及其制备方法、固体氧化物电解池
CN114540833A (zh) * 2022-02-22 2022-05-27 临沂大学 一种CeO2@Co3S4异质多层次纳米结构催化材料及其制备方法与应用
CN118016904B (zh) * 2024-03-25 2024-10-11 成都华盛氢能工程技术中心(有限合伙) 一种固体氧化物燃料电池电极及其制备方法

Citations (2)

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US6017647A (en) * 1995-11-16 2000-01-25 The Dow Chemical Company Electrode structure for solid state electrochemical devices
CN101381880A (zh) * 2007-08-31 2009-03-11 丹麦技术大学 复合电极

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US5993986A (en) * 1995-11-16 1999-11-30 The Dow Chemical Company Solide oxide fuel cell stack with composite electrodes and method for making
WO2003084894A1 (en) * 2002-04-10 2003-10-16 Japan Science And Technology Agency Complex mixed conductor and its preparing method
EP1530814A4 (en) * 2002-06-06 2009-05-27 Univ Pennsylvania CERAMIC ANODES AND PROCESS FOR PRODUCING THESE ANODES
US6958196B2 (en) * 2003-02-21 2005-10-25 Trustees Of The University Of Pennsylvania Porous electrode, solid oxide fuel cell, and method of producing the same
JP4876373B2 (ja) * 2004-04-23 2012-02-15 トヨタ自動車株式会社 燃料電池用カソードおよびその製造方法
JP2006004835A (ja) * 2004-06-18 2006-01-05 Nissan Motor Co Ltd 固体酸化物形燃料電池
JP2006040822A (ja) * 2004-07-29 2006-02-09 Central Res Inst Of Electric Power Ind 多孔質混合伝導体およびその製造方法および固体酸化物形燃料電池の空気極材料
JP2006059703A (ja) * 2004-08-20 2006-03-02 Mitsubishi Materials Corp 電気化学セル
DE602006013786D1 (de) 2005-02-02 2010-06-02 Univ Denmark Tech Dtu Verfahren zur herstellung einer reversiblen festoxidbrennstoffzelle
RU2403655C9 (ru) * 2005-04-21 2011-04-20 Члены Правления Университета Калифорнии Инфильтрация исходного материала и способ покрытия
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Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
US6017647A (en) * 1995-11-16 2000-01-25 The Dow Chemical Company Electrode structure for solid state electrochemical devices
CN101381880A (zh) * 2007-08-31 2009-03-11 丹麦技术大学 复合电极

Also Published As

Publication number Publication date
RU2011147510A (ru) 2013-05-27
US20120037499A1 (en) 2012-02-16
HK1169516A1 (zh) 2013-01-25
EP2422391A1 (en) 2012-02-29
AU2010241164B2 (en) 2014-09-25
AU2010241164B9 (en) 2014-10-02
JP2012524956A (ja) 2012-10-18
WO2010121828A1 (en) 2010-10-28
EP2244322A1 (en) 2010-10-27
AU2010241164A1 (en) 2011-11-10
RU2537561C2 (ru) 2015-01-10
JP5571772B2 (ja) 2014-08-13
CA2759157A1 (en) 2010-10-28
KR20120004471A (ko) 2012-01-12
CN102422468A (zh) 2012-04-18

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