CN102372910B - 树脂组合物和树脂成形体 - Google Patents
树脂组合物和树脂成形体 Download PDFInfo
- Publication number
- CN102372910B CN102372910B CN201110070301.8A CN201110070301A CN102372910B CN 102372910 B CN102372910 B CN 102372910B CN 201110070301 A CN201110070301 A CN 201110070301A CN 102372910 B CN102372910 B CN 102372910B
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- 239000011347 resin Substances 0.000 title claims abstract description 71
- 229920005989 resin Polymers 0.000 title claims abstract description 71
- 239000011342 resin composition Substances 0.000 claims abstract description 83
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 55
- 239000004626 polylactic acid Substances 0.000 claims abstract description 55
- -1 phosphazene compound Chemical class 0.000 claims abstract description 42
- 150000001875 compounds Chemical class 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims description 45
- 239000003063 flame retardant Substances 0.000 claims description 44
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 37
- 229920001971 elastomer Polymers 0.000 claims description 22
- 239000005060 rubber Substances 0.000 claims description 22
- 239000007787 solid Substances 0.000 claims description 18
- 238000002844 melting Methods 0.000 claims description 15
- 230000008018 melting Effects 0.000 claims description 14
- 239000003112 inhibitor Substances 0.000 claims description 11
- 229920000800 acrylic rubber Polymers 0.000 claims description 9
- 229920000058 polyacrylate Polymers 0.000 claims description 9
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 4
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 238000012360 testing method Methods 0.000 abstract description 47
- 229910000831 Steel Inorganic materials 0.000 abstract description 39
- 239000010959 steel Substances 0.000 abstract description 39
- 239000000203 mixture Substances 0.000 abstract description 8
- 230000007423 decrease Effects 0.000 description 13
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000000465 moulding Methods 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 229920002994 synthetic fiber Polymers 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 239000004310 lactic acid Substances 0.000 description 4
- 235000014655 lactic acid Nutrition 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920001432 poly(L-lactide) Polymers 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- BDNKZNFMNDZQMI-UHFFFAOYSA-N 1,3-diisopropylcarbodiimide Chemical compound CC(C)N=C=NC(C)C BDNKZNFMNDZQMI-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 2
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229940022769 d- lactic acid Drugs 0.000 description 2
- BGRWYRAHAFMIBJ-UHFFFAOYSA-N diisopropylcarbodiimide Natural products CC(C)NC(=O)NC(C)C BGRWYRAHAFMIBJ-UHFFFAOYSA-N 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000012796 inorganic flame retardant Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RBMHUYBJIYNRLY-UHFFFAOYSA-N 2-[(1-carboxy-1-hydroxyethyl)-hydroxyphosphoryl]-2-hydroxypropanoic acid Chemical compound OC(=O)C(O)(C)P(O)(=O)C(C)(O)C(O)=O RBMHUYBJIYNRLY-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 101100264195 Caenorhabditis elegans app-1 gene Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 1
- 235000003166 Opuntia robusta Nutrition 0.000 description 1
- 244000218514 Opuntia robusta Species 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 229920006167 biodegradable resin Polymers 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 125000000000 cycloalkoxy group Chemical group 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229910000071 diazene Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- SQEHYBILZVXINP-UHFFFAOYSA-N n'-tert-butyl-n-propan-2-ylmethanediimine Chemical compound CC(C)N=C=NC(C)(C)C SQEHYBILZVXINP-UHFFFAOYSA-N 0.000 description 1
- JEQPWXGHMRFTRF-UHFFFAOYSA-N n,n'-bis(2-methylpropyl)methanediimine Chemical compound CC(C)CN=C=NCC(C)C JEQPWXGHMRFTRF-UHFFFAOYSA-N 0.000 description 1
- NASVTBDJHWPMOO-UHFFFAOYSA-N n,n'-dimethylmethanediimine Chemical compound CN=C=NC NASVTBDJHWPMOO-UHFFFAOYSA-N 0.000 description 1
- ATYQZACNIHLXIS-UHFFFAOYSA-N n,n'-dinaphthalen-2-ylmethanediimine Chemical compound C1=CC=CC2=CC(N=C=NC3=CC4=CC=CC=C4C=C3)=CC=C21 ATYQZACNIHLXIS-UHFFFAOYSA-N 0.000 description 1
- CMESPBFFDMPSIY-UHFFFAOYSA-N n,n'-diphenylmethanediimine Chemical compound C1=CC=CC=C1N=C=NC1=CC=CC=C1 CMESPBFFDMPSIY-UHFFFAOYSA-N 0.000 description 1
- IDVWLLCLTVBSCS-UHFFFAOYSA-N n,n'-ditert-butylmethanediimine Chemical compound CC(C)(C)N=C=NC(C)(C)C IDVWLLCLTVBSCS-UHFFFAOYSA-N 0.000 description 1
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical class CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000009512 pharmaceutical packaging Methods 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001434 poly(D-lactide) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010-181556 | 2010-08-16 | ||
| JP2010181556 | 2010-08-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102372910A CN102372910A (zh) | 2012-03-14 |
| CN102372910B true CN102372910B (zh) | 2015-09-23 |
Family
ID=45565294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110070301.8A Active CN102372910B (zh) | 2010-08-16 | 2011-03-18 | 树脂组合物和树脂成形体 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8937124B2 (enExample) |
| JP (1) | JP2012062465A (enExample) |
| KR (1) | KR20120024362A (enExample) |
| CN (1) | CN102372910B (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012179734A (ja) * | 2011-02-28 | 2012-09-20 | Fujifilm Corp | 射出成形方法 |
| CA2902145A1 (en) * | 2013-03-25 | 2014-10-02 | Teijin Limited | Resin composition |
| DE102013223504A1 (de) * | 2013-11-18 | 2015-05-21 | Tesa Se | Flammbeständige, temperaturbeständige und hydrolysebeständige Träger sowie deren Verwendung in Haftklebebändern für Automobilanwendungen |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5973024A (en) * | 1997-07-09 | 1999-10-26 | Nisshinbo Industries, Inc. | Method for control of biodegradation rate of biodegradable plastic |
| US20020128344A1 (en) * | 2000-12-07 | 2002-09-12 | Yuko Fujihira | Biodegradable resin material and method for producing the same |
| JP3984440B2 (ja) | 2001-06-20 | 2007-10-03 | 三菱樹脂株式会社 | 樹脂組成物、フィルム及び廃棄方法 |
| EP1445282A4 (en) * | 2001-08-03 | 2004-11-24 | Toray Industries | RESIN COMPOSITION AND MOLDED ARTICLE, FILM AND FIBER |
| WO2003091344A1 (en) * | 2002-04-24 | 2003-11-06 | Sony Corporation | Biodegradable flame retardant composite composition and process for producing the same |
| US7060744B2 (en) * | 2002-09-13 | 2006-06-13 | Asahi Kasei Chemicals Corporation | Phosphazene composition |
| CA2532456A1 (en) * | 2003-07-18 | 2005-02-17 | Ciba Specialty Chemicals Holding Inc. | Flame retardant polylactic acid |
| US7645823B2 (en) * | 2003-12-02 | 2010-01-12 | Sony Corporation | Resin composition, molded product from resin composition and method for preparing resin composition |
| JP2005248032A (ja) | 2004-03-04 | 2005-09-15 | Sakamoto Yakuhin Kogyo Co Ltd | 難燃性脂肪族ポリエステル樹脂組成物 |
| WO2005123831A1 (ja) * | 2004-06-16 | 2005-12-29 | Unitika Ltd. | ポリ乳酸含有樹脂組成物及びそれより得られる成形体 |
| CN101942182B (zh) * | 2004-09-17 | 2012-05-23 | 东丽株式会社 | 树脂组合物和由其形成的成型品 |
| JP2006262770A (ja) * | 2005-03-24 | 2006-10-05 | Ueda Holdings:Kk | 乳酸、ポリ乳酸及び生分解性プラスチック |
| JP5339670B2 (ja) | 2006-05-22 | 2013-11-13 | 三菱樹脂株式会社 | 樹脂組成物および射出成形体 |
| JP2008094878A (ja) * | 2006-10-06 | 2008-04-24 | Yajima Giken Inc | ポリ乳酸樹脂組成物 |
| JP5517276B2 (ja) | 2007-01-09 | 2014-06-11 | 東レ株式会社 | ポリエステルフィルム |
| KR20100059782A (ko) * | 2007-09-27 | 2010-06-04 | 유니띠까 가부시키가이샤 | 수지 조성물 및 그것을 성형한 성형체 |
| JP5479747B2 (ja) | 2008-04-08 | 2014-04-23 | 花王株式会社 | ポリ乳酸樹脂組成物 |
| CN101990565B (zh) | 2008-04-08 | 2015-08-12 | 日本电气株式会社 | 聚乳酸树脂组合物 |
| JP5140555B2 (ja) | 2008-11-05 | 2013-02-06 | 帝人化成株式会社 | 難燃性ポリ乳酸組成物およびその成形品 |
| RU2485144C2 (ru) | 2008-11-05 | 2013-06-20 | Тейдзин Кемикалз Лтд. | Композиция полимера молочной кислоты и формованное изделие из данной композиции |
| JP2010111739A (ja) | 2008-11-05 | 2010-05-20 | Teijin Chem Ltd | 難燃性ポリ乳酸樹脂組成物 |
| JP5481967B2 (ja) | 2009-06-26 | 2014-04-23 | 富士ゼロックス株式会社 | 樹脂組成物、成形体、および樹脂組成物の製造方法 |
| JP5612329B2 (ja) | 2010-02-09 | 2014-10-22 | 帝人株式会社 | ポリ乳酸樹脂組成物 |
| EP2527400B1 (en) | 2010-01-18 | 2016-03-30 | Teijin Limited | Polylactic acid composition |
-
2011
- 2011-02-16 US US13/028,829 patent/US8937124B2/en not_active Expired - Fee Related
- 2011-03-11 KR KR1020110021724A patent/KR20120024362A/ko not_active Ceased
- 2011-03-18 CN CN201110070301.8A patent/CN102372910B/zh active Active
- 2011-08-11 JP JP2011175956A patent/JP2012062465A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US8937124B2 (en) | 2015-01-20 |
| JP2012062465A (ja) | 2012-03-29 |
| US20120041114A1 (en) | 2012-02-16 |
| KR20120024362A (ko) | 2012-03-14 |
| CN102372910A (zh) | 2012-03-14 |
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Legal Events
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Tokyo Patentee after: Fuji film business innovation Co.,Ltd. Address before: Tokyo Patentee before: Fuji Xerox Co.,Ltd. |