CN102348758A - 填充有官能化的碳纳米管的环氧树脂的改善的机械性能 - Google Patents

填充有官能化的碳纳米管的环氧树脂的改善的机械性能 Download PDF

Info

Publication number
CN102348758A
CN102348758A CN2010800116154A CN201080011615A CN102348758A CN 102348758 A CN102348758 A CN 102348758A CN 2010800116154 A CN2010800116154 A CN 2010800116154A CN 201080011615 A CN201080011615 A CN 201080011615A CN 102348758 A CN102348758 A CN 102348758A
Authority
CN
China
Prior art keywords
carbon nanotubes
epoxy
ozone
material according
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010800116154A
Other languages
English (en)
Chinese (zh)
Inventor
H.迈尔
张忠
张晖
汤龙程
彭珂
刘璐琪
李洪超
S.巴恩米勒
J.希茨布莱克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Publication of CN102348758A publication Critical patent/CN102348758A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5033Amines aromatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/005Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • C08K3/041Carbon nanotubes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Bridges Or Land Bridges (AREA)
  • Reinforced Plastic Materials (AREA)
CN2010800116154A 2009-03-13 2010-02-27 填充有官能化的碳纳米管的环氧树脂的改善的机械性能 Pending CN102348758A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09003652A EP2228406A1 (en) 2009-03-13 2009-03-13 Improved mechanical properties of epoxy filled with functionalized carbon nanotubes
EP09003652.6 2009-03-13
PCT/EP2010/001226 WO2010102732A1 (en) 2009-03-13 2010-02-27 Improved mechanical properties of epoxy filled with functionalized carbon nanotubes

Publications (1)

Publication Number Publication Date
CN102348758A true CN102348758A (zh) 2012-02-08

Family

ID=40677630

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010800116154A Pending CN102348758A (zh) 2009-03-13 2010-02-27 填充有官能化的碳纳米管的环氧树脂的改善的机械性能

Country Status (7)

Country Link
US (1) US20120123020A1 (https=)
EP (2) EP2228406A1 (https=)
JP (1) JP2012520351A (https=)
KR (1) KR20110138349A (https=)
CN (1) CN102348758A (https=)
TW (1) TW201105718A (https=)
WO (1) WO2010102732A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102604129A (zh) * 2012-03-11 2012-07-25 东华大学 一种碳纳米管在环氧树脂中的分散方法
CN103374207A (zh) * 2012-04-18 2013-10-30 国家纳米科学中心 一种环氧复合材料及其制备方法

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9085678B2 (en) 2010-01-08 2015-07-21 King Abdulaziz City For Science And Technology Clean flame retardant compositions with carbon nano tube for enhancing mechanical properties for insulation of wire and cable
EP2479215A1 (de) * 2011-01-25 2012-07-25 Bayer MaterialScience AG Verfahren zur Herstellung eines Verbundmaterials
US10023702B2 (en) 2011-09-02 2018-07-17 Bae Systems Plc Curable monomers
US8871019B2 (en) 2011-11-01 2014-10-28 King Abdulaziz City Science And Technology Composition for construction materials manufacturing and the method of its production
CN103131293A (zh) * 2012-11-13 2013-06-05 高润宝 飞行器用碳纳米管改性耐高温透波涂料的制备方法
CN103059514B (zh) * 2012-12-05 2015-05-20 哈尔滨工业大学 磁化疏液型碳纳米管基纳米通道阻尼片制备方法及阻尼器
KR101481263B1 (ko) * 2013-04-29 2015-01-13 전북대학교산학협력단 강인화 에폭시 수지 조성물, 이의 제조방법 및 강인화 에폭시 수지
WO2019002907A1 (en) * 2017-06-26 2019-01-03 Nano-Tech S.P.A. POLYMERIC COMPOSITIONS CHARGED WITH CARBON NANOTUBES, THEIR PRODUCTION AND THEIR USE
KR102185383B1 (ko) * 2019-01-08 2020-12-01 인하대학교 산학협력단 오존 처리된 단일 벽 탄소나노튜브로 강화된 현무암 섬유 강화 에폭시 복합재료 및 이의 제조방법
CN110256815B (zh) * 2019-06-25 2022-03-25 山东大展纳米材料有限公司 一种增韧导电环氧树脂复合材料及其制备方法
KR102214478B1 (ko) * 2019-09-09 2021-02-09 인하대학교 산학협력단 오존 처리한 카본블랙이 도입된 탄소 섬유 강화 에폭시 복합재료 및 제조 방법
KR102404145B1 (ko) * 2020-07-14 2022-06-02 인하대학교 산학협력단 그래핀 산화물이 도입된 현무암 섬유 강화 에폭시 복합소재 및 이의 제조방법
CN111825952B (zh) * 2020-07-14 2023-02-10 国家纳米科学中心 一种超顺排碳纳米管环氧树脂复合材料及其制备方法和应用
CN115538170B (zh) * 2022-09-06 2023-10-13 长春工业大学 一种改性碳纤维及其制备方法和应用以及改性碳纤维环氧树脂复合材料

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101189373A (zh) * 2004-10-22 2008-05-28 海珀里昂催化国际有限公司 改进的碳纳米管臭氧分解

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1469930A (en) 1974-10-11 1977-04-06 Atomic Energy Authority Uk Carbon filaments
CA1175616A (en) 1981-01-05 1984-10-09 Exxon Research And Engineering Company Production of iron monoxide and carbon filaments therefrom
US4663230A (en) 1984-12-06 1987-05-05 Hyperion Catalysis International, Inc. Carbon fibrils, method for producing same and compositions containing same
US7588699B2 (en) 2001-11-02 2009-09-15 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Electrically conductive, optically transparent polymer/carbon nanotube composites and process for preparation thereof
EP2258763A1 (en) 2002-11-27 2010-12-08 William Marsh Rice University Functionalized carbon nanotube-polymer composites and interactions with radiation
CA2532190C (en) 2003-06-16 2012-08-21 William Marsh Rice University Sidewall functionalization of carbon nanotubes with hydroxyl-terminated moieties
US20070259994A1 (en) 2003-06-23 2007-11-08 William Marsh Rice University Elastomers Reinforced with Carbon Nanotubes
EP1789477A2 (en) 2004-08-02 2007-05-30 University Of Houston Carbon nanotube reinforced polymer nanocomposites
DE102004054959A1 (de) 2004-11-13 2006-05-18 Bayer Technology Services Gmbh Katalysator zur Herstellung von Kohlenstoffnanoröhrchen durch Zersetzung von gas-förmigen Kohlenverbindungen an einem heterogenen Katalysator
DE102006007147A1 (de) 2006-02-16 2007-08-23 Bayer Technology Services Gmbh Verfahren zur kontinuierlichen Herstellung von Katalysatoren
US20070276077A1 (en) 2006-04-05 2007-11-29 Nano-Proprietary, Inc. Composites
JP2009532531A (ja) 2006-03-31 2009-09-10 アプライド・ナノテック・ホールディングス・インコーポレーテッド カーボンナノチューブ強化ナノコンポジット
US20080090951A1 (en) 2006-03-31 2008-04-17 Nano-Proprietary, Inc. Dispersion by Microfluidic Process
WO2008034939A1 (en) 2006-09-04 2008-03-27 Natucell Ay Functionalized cellulose - carbon nanotube nanocomposites and hybride materials
US20100130646A1 (en) 2006-10-31 2010-05-27 Korea Research Institute Of Chemical Technology Method for manufacturing epoxy nanocomposite material containing vapor-grown carbon nanofibers and its products thereby

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101189373A (zh) * 2004-10-22 2008-05-28 海珀里昂催化国际有限公司 改进的碳纳米管臭氧分解

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
YOUNG-KUK CHOI ET AL.: "Processing and characterization of epoxy nanocomposites reinforced by cup-stacked carbon nanotubes", 《POLYMER》, vol. 46, 25 October 2005 (2005-10-25) *
刘明贤等: "环氧树脂/碳纳米管纳米复合材料的制备与性能研究进展", 《塑料工业》, vol. 35, no. 8, 31 August 2007 (2007-08-31) *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102604129A (zh) * 2012-03-11 2012-07-25 东华大学 一种碳纳米管在环氧树脂中的分散方法
CN103374207A (zh) * 2012-04-18 2013-10-30 国家纳米科学中心 一种环氧复合材料及其制备方法

Also Published As

Publication number Publication date
WO2010102732A1 (en) 2010-09-16
EP2406317A1 (en) 2012-01-18
TW201105718A (en) 2011-02-16
EP2228406A1 (en) 2010-09-15
US20120123020A1 (en) 2012-05-17
KR20110138349A (ko) 2011-12-27
JP2012520351A (ja) 2012-09-06

Similar Documents

Publication Publication Date Title
CN102348758A (zh) 填充有官能化的碳纳米管的环氧树脂的改善的机械性能
Zhang et al. Dispersion stability of functionalized MWCNT in the epoxy–amine system and its effects on mechanical and interfacial properties of carbon fiber composites
Nadiv et al. Graphene nanoribbon–polymer composites: the critical role of edge functionalization
Ma et al. Development of polymer composites using modified, high-structural integrity graphene platelets
Wan et al. Grafting of epoxy chains onto graphene oxide for epoxy composites with improved mechanical and thermal properties
Huang et al. Chemically modified graphene/polyimide composite films based on utilization of covalent bonding and oriented distribution
Kang et al. Thermal, impact and toughness behaviors of expanded graphite/graphite oxide-filled epoxy composites
JP6490580B2 (ja) 非常に低含有量の炭素系ナノフィラーを有する複合材料、これらの調製方法およびこれらの使用
Tjong Polymer composites with carbonaceous nanofillers: properties and applications
Wu et al. Synthesis, characterization, and electrical properties of polypyrrole/multiwalled carbon nanotube composites
JP5477702B2 (ja) 窒化ホウ素ナノチューブ誘導体、その分散液、及び該窒化ホウ素ナノチューブ誘導体の製造方法
Jiang et al. Plasma functionalization of bucky paper and its composite with phenylethynyl-terminated polyimide
KR20110131203A (ko) 탄소 나노튜브의 수증기 조력 오존분해
Roy et al. Triggering compatibility and dispersion by selective plasma functionalized carbon nanotubes to fabricate tough and enhanced Nylon 12 composites
Wu et al. One step fabrication of multi-walled carbon nanotubes/graphene nanoplatelets hybrid materials with excellent mechanical property
Zhang et al. Tenon effects at drilled multi-walled carbon nanotubes to strongly enhance mechanical and luminescent properties of epoxy resin composites
Wang et al. An effective and green H2O2/H2O/O3 oxidation method for carbon nanotube to reinforce epoxy resin
Kleinschmidt et al. Functionalized-carbon nanotubes with physisorbed ionic liquid as filler for epoxy nanocomposites
Gonzalez-Dominguez et al. Wrapping of SWCNTs in polyethylenoxide-based amphiphilic diblock copolymers: an approach to purification, debundling, and integration into the epoxy matrix
González-Domínguez et al. Reactive fillers based on SWCNTs functionalized with matrix-based moieties for the production of epoxy composites with superior and tunable properties
Pillai et al. Epoxy-based carbon nanotubes reinforced composites
Fu et al. Composite fibers from poly (vinyl alcohol) and poly (vinyl alcohol)‐functionalized multiwalled carbon nanotubes
Yang et al. Realizing the full nanofiller enhancement in melt-spun fibers of poly (vinylidene fluoride)/carbon nanotube composites
Suri et al. A simple chemical treatment for easy dispersion of carbon nanotubes in epoxy matrix for improving mechanical properties
John et al. Plasma functionalized CNT/Cyanate ester nanocomposites for aerospace structural applications

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20120208