CN102318629A - Insecticidal composition containing novaluron and flubendiamide - Google Patents
Insecticidal composition containing novaluron and flubendiamide Download PDFInfo
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- CN102318629A CN102318629A CN201110199225A CN201110199225A CN102318629A CN 102318629 A CN102318629 A CN 102318629A CN 201110199225 A CN201110199225 A CN 201110199225A CN 201110199225 A CN201110199225 A CN 201110199225A CN 102318629 A CN102318629 A CN 102318629A
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- fipronil bisamide
- fluorine uride
- uride
- fluorine
- rice
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Abstract
The invention discloses an insecticidal composition containing novaluron and flubendiamide. The weight percentage of the novaluron and the flubendiamide in the composition is 1 percent to 80 percent: 1 percent to 80 percent. The insecticidal composition can prevent different injurious insects, has obvious synergy, can enlarge the insecticidal spectrum, and has high activity on rice fulgorid, rice-stem borer, paddy borer, rice leaf roller, asparagus caterpillar, diamond back moth, peach fruit borer, apple leaf miner and the like; the dosage of the farm chemicals can be reduced, the residue of the farm chemicals on the crops can be reduced, and the environmental pollution can be reduced; and the insecticidal composition is safe to the human beings and the animals and has good environmental compatibility, and the injurious insects are difficult to have drug fastness on the insecticidal composition.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the Pesticidal combination of a kind of fluorine-containing uride and fipronil bisamide.
Background technology
The fluorine uride, English common name (novaluron), molecular formula: C
17H
9ClF
8N
2O
4, chemical name: (±)-N-[[[3-chloro-4-[1,1,2-three fluoro-2-(trifluoromethoxy) ethyoxyls] phenyl] ammonia] carbonyl]-2,6-difluorobenzamide.The fluorine uride belongs to novel benzoyl area kind insect growth regulator, IGR, can organize the chitin in the stage of casting off a skin in the insect growth process synthetic, casts off a skin thereby influence to palm off as, makes insect when casting off a skin, can not form new epidermis, and polypide is deformity and death.Can also regulate growing of insect, suppress molt metamorphosis, suppress the food speed of insect, have very high ovicidal activity.Main through in the insect's food-taking entering insect bodies, also can contact in the entering insect bodies.Destruction through to the growth of expense adult slowly kills off the insect pests, and this process possibly continue about several days time, and is from the not effect of insect in adult stage, comparatively safe to beneficial insect to.
Fipronil bisamide, English common name (flubendiamide), molecular formula: C
23H
22F
7IN
2O
4S, chemical name: 3-iodo-N '-(2-mesyl-1,1-dimethyl ethyl group-N-{4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl) ethyl]-0-tolyl } phthalamide.Fipronil bisamide belongs to novel phthalic amide insecticides, activates calcium release channel in blue Buddhist nun's alkali recipient cell, and the uncontrolled that causes storing calcium ion discharges.It is the compound that acts on blue Buddhist nun's alkali (Ryanodine) acceptor of insect cell at present few in number.Lepidoptera pest there is the spectrum preventive effect, does not have cross resistance with existing insecticide and produce, be suitable for very much the control that existing insecticide produces the insect of resistance.Larva there is very outstanding preventive effect, limited to the adult preventive effect, there is not ovicidal action.Slightly conduct through xylem the back in the infiltration plant body.Resistance of rainwater washing against.
Yet in the real process of agricultural production, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.Important insect such as lepidoptera pest on the agricultural are because its breeding cycle is short, and breeding amount is big, and mobility is little, and the selfing degree is high, is easy to generate resistance especially.
The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor research, find fluorine uride and fipronil bisamide can produce good synergistic effect after composite, and still unexposed about the composite relevant report of fluorine uride and fipronil bisamide.
Summary of the invention
Degradation problem under the resistance generation that the long-term use of fluorine uride list agent possibly bring, the drug effect, the Pesticidal combination that the present invention proposes contains A, two kinds of active components of B, and an amount of surfactant and carrier.
The Pesticidal combination of a kind of fluorine-containing uride and fipronil bisamide is characterized in that: the percentage by weight of fluorine uride and fipronil bisamide is 1～80%: 1～80%.
Described Pesticidal combination is characterized in that: the percentage by weight of fluorine uride and fipronil bisamide is 2～60%: 2～60%.
Described Pesticidal combination is characterized in that: the percentage by weight of fluorine uride and fipronil bisamide is 5～40%: 5～40%;
Described Pesticidal combination is characterized in that: the percentage by weight of fluorine uride and fipronil bisamide is 5～30%: 5～30%.
Usually active weight percentage is 0.5～90% of a gross weight in the composition, and preferable is 5%～85%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1～70% active substance by weight, preferably is 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, preferably is 10～80%.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5～30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The surfactant that Pesticidal combination of the present invention is selected for use is known in those skilled in the art: can be selected from dispersant, wetting agent, binding agent or the antifoaming agent one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze etc. in the preparation.
Described dispersant is selected from alkylnaphthalene sulfonate; Two (alkyl) naphthalenesulfonate formaldehyde condensation compound; Naphthalene sulfonic acid-formaldehyde condensation product; Aryl phenol polyoxyethylene succinate sulfonate; Octylphenol polyethylene oxyethylene group ether sulfate; Polycarboxylate; Lignosulfonates; The phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy; Alkyl benzene sulfonate calcium salt; The naphthalene sulfonic acid-formaldehyde condensation product sodium salt; Alkylphenol-polyethenoxy is phonetic; Aliphatic amine polyoxyethylene is phonetic; Polyoxyethylene carboxylate; During the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, the aluminium chloride.
Described binding agent is selected from: one or more in gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, PVPP, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the polyethylene glycol.
Described antifoaming agent is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (like capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by the preparation of common processing method, is about to active substance and after liquid flux or solid carrier mix, and adds in surfactant such as dispersant, stabilizing agent, wetting agent, adhesive, the antifoaming agent etc. one or more again.
Pesticidal combination of the present invention can be processed into acceptable forms on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent.
Comprise following constituent content when composition is processed wetting powder: fluorine uride 1～40%, fipronil bisamide 1～40%, dispersant 5～10%, wetting agent 2～10%, filler add to 100%.
Active component fluorine uride, fipronil bisamide, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the wetting powder product of the present composition.
Comprise following constituent content when composition is processed water dispersible granules: active component fluorine uride 1～80%, fipronil bisamide 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler add to 100%.
Active component fluorine uride, fipronil bisamide, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that article are quantitatively sent the fluidized bed granulation dryer to, makes the water dispersible granules product of the present composition.
Comprise following constituent content when composition is processed suspending agent: active component fluorine uride 1～25%, fipronil bisamide 1～25%, dispersant 2～10%, wetting agent 2～10%, antifoaming agent 0.1～1%, binding agent 0.1～2%, antifreeze 0.1～8%, deionized water add to 100%.
Dispersant, wetting agent, antifoaming agent, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear; Add active component fluorine uride, fipronil bisamide; Ball milling is 2～3 hours in ball mill; Make diameter of particle all below 5 μ m, make the suspending agent product of the present composition.
The invention has the advantages that: after (1) fluorine uride and fipronil bisamide are composite, have notable synergistic and lasting effect; (2) enlarged insecticidal spectrum, rice fulgorid, rice-stem borer, paddy stem borer, rice leaf roller, beet armyworm, diamond-back moth, peach fruit borer, apple leaf miner have been had greater activity; (3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
The present invention is explained further that the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Application implementation example one
Instance 1 48% fluorine uride fipronil bisamide wetting powder
Fluorine uride 8%, fipronil bisamide 40%, lignosulfonates 7%, soapberry powder 6%, bentonite add to 100%, and mixture carries out comminution by gas stream, make 48% fluorine uride fipronil bisamide wetting powder.
Instance 2 50% fluorine uride fipronil bisamide wetting powders
Fluorine uride 25%, fipronil bisamide 25%, alkyl benzene sulfonate calcium salt 8%, wetting and penetrating agent F 6%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 50% fluorine uride fipronil bisamide wetting powder.
Instance 3 40% fluorine uride fipronil bisamide water dispersible granules
Fluorine uride 10%, fipronil bisamide 30%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, spaonin powder 4%, urea 2%, kaolin add to 100%, the mixed 40% fluorine uride fipronil bisamide water dispersible granules that gets.
Instance 4 60% fluorine uride fipronil bisamide water dispersible granules
Fluorine uride 20%, fipronil bisamide 40%, alkylphenol-polyethenoxy are phonetic 8%, lauryl sodium sulfate 7%, sodium carbonate 1.8%, attapulgite add to 100%, mixed 60% fluorine uride fipronil bisamide water dispersible granules.
Instance 5 10% fluorine uride fipronil bisamide suspension agents
Fluorine uride 5%, fipronil bisamide 5%, aryl phenol polyoxyethylene succinate sulfonate 7%, soapberry powder 5%, silicone compound 0.1%, polyvinylpyrrolidone 1.5%, propane diols 1.8%, deionized water add to 100%, the mixed 10% fluorine uride fipronil bisamide suspension agent that gets.
Instance 6 30% fluorine uride fipronil bisamide suspension agents
The phonetic formaldehyde condensation products sulphate of fluorine uride 20%, fipronil bisamide 10%, alkylphenol-polyethenoxy 8%, Nekal BX 6%, C
10～20Saturated fat acids 0.2%, gum Arabic 1.2%, triethylene glycol 1.6%, deionized water add to 100%, the mixed 30% fluorine uride fipronil bisamide suspension agent that gets.
Embodiment 7 30% fluorine uride fipronil bisamide suspension emulsions
Fluorine uride 10%, fipronil bisamide 20%, polycarboxylate 5.6%, OP series 3.7%, silicone compound 2.5%, polyethylene glycol 1.5%, ethylene glycol 2.1%, deionized water add to 100%, the mixed 30% fluorine uride fipronil bisamide suspension emulsion that gets.
Embodiment 8 38% fluorine uride fipronil bisamide suspension emulsions
Fluorine uride 8%, fipronil bisamide 30%, aryl phenol polyoxyethylene succinate sulfonate 6.4%, tea are withered 3.6%, polyvinylpyrrolidone 1.8%, agricultural newborn 1600#4.2%, glycerine 1.8%, C
8～10Aliphatic alcohols 0.8%, deionized water add to 100%, through the mixed 38% fluorine uride fipronil bisamide suspension emulsion that gets.
Instance 9 45% fluorine uride fipronil bisamide aqueous emulsions
Fluorine uride 40%, fipronil bisamide 5%, 3-methyl cyclohexanol ketenes 4%, OP series 7%, propyl alcohol 3%, ethylene glycol 2.8%, CMC 1.3%, C
8～10Aliphatic alcohols 0.2%, water is mended to 100%, makes 45% fluorine uride fipronil bisamide aqueous emulsion.
Instance 10 10% fluorine uride fipronil bisamide aqueous emulsions
Fluorine uride 7%, fipronil bisamide 3%, N-pyrrolidones 5%, EGME 3%, agricultural newborn 33#8%, glycerine 2.5%, Magnesiumaluminumsilicate 1.2%, silicone compound 0.3%, water is mended to 100%, makes 10% fluorine uride fipronil bisamide aqueous emulsion.
Instance 11 20% fluorine uride fipronil bisamide microemulsions
Fluorine uride 18%, fipronil bisamide 2%, cyclohexanone 6%, toluene 4%, 600# phosphate 6%, polyethylene glycol 1.9%, water supplies 100%, makes 20% fluorine uride fipronil bisamide microemulsion.
Instance 12 45% fluorine uride fipronil bisamide microemulsions
Fluorine uride 40%, fipronil bisamide 5%, acetone 4%, N-octylpyrrolidone 5%, styrene polyoxyethylene ether ammonium sulfate salt 6%, silicone oil 0.4%, xanthans 1.1%, glycerine 3%, water supplies 100%, makes 45% fluorine uride fipronil bisamide microemulsion.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of fluorine uride, each mixed agent of fipronil bisamide is diluted to five series concentration during test, places beaker subsequent use respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament is soaked taking-up behind the 5s, dries naturally in the soup that configures, put into insect box; Connect then and supply examination 3 instar larvaes, under 25 ℃ of conditions, raise, every processing repeats for 3 times; Every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h; Calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is regarded as invalid test greater than 10%.
Computing formula is following:
The insect corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula is (with the fluorine uride is the standard medicament, and its toxicity index is 100) as follows:
TI * the P of theoretical toxicity index (TTI)=fluorine uride of M
The fluorine urideTI * the P of+fipronil bisamide
Fipronil bisamide
In the formula: M is the mixture of different proportionings
P
Fipronil bisamideBe fipronil bisamide shared ratio in composition
P
The fluorine urideBe fluorine uride shared ratio in composition
A is selected from the fluorine uride;
B is selected from fipronil bisamide.
Application implementation example two:
Supply the examination insect: the wild cabbage beet armyworm.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective lethal concentration scope of confirming fluorine uride, the former medicine of fipronil bisamide and the two different proportioning mixture through preliminary experiment.
The different proportionings with fipronil bisamide of table 1 fluorine uride are to the toxicity test of wild cabbage beet armyworm
Can know by table 1; The proportioning of the composite control wild cabbage of fluorine uride and fipronil bisamide beet armyworm is at 40: 1 to 1: 40 o'clock, and co-toxicity coefficient is all greater than 120, explains that both were mixed in the scope at 40: 1 to 1: 40 all to show synergistic effect; Especially when fluorine uride and fipronil bisamide get proportioning at 5: 1 to 1: 5; Synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when fluorine uride and fipronil bisamide weight ratio are 1: 1 wherein, and synergistic effect is the most obvious.Application implementation example trifluoro uride and the fipronil bisamide and the composite control wild cabbage diamond-back moth test of pesticide effectiveness thereof
This EE is the Bozhou City Mengcheng County in Anhui Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 10% fluorine uride missible oil (commercial), 20% fipronil bisamide water dispersible granules (commercial).
Investigation wild cabbage diamond-back moth insect pest index in the their early stage dispenser, was investigated the insect pest indexes in 24 hours, 72 hours after the dispenser and is calculated preventive effect before the medicine.Experimental result is as follows:
Table 3 fluorine uride, fipronil bisamide and the composite control wild cabbage diamond-back moth test of pesticide effectiveness thereof
Can find out that by table 3 can effectively prevent and treat the wild cabbage diamond-back moth after fluorine uride and fipronil bisamide are composite, control efficiency all is superior to the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example tetrafluoro uride and the fipronil bisamide and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
This EE is in Binyang County, Guangxi province Nanning City, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 10% fluorine uride missible oil (commercial), 20% fipronil bisamide water dispersible granules (commercial).
Investigation rice hoppers insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 24 hours, 72 hours after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 4 fluorine uride, fipronil bisamide and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
Can find out that by table 4 can effectively prevent and treat rice hoppers after fluorine uride and fipronil bisamide are composite, control efficiency all is superior to the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects, and rice-stem borer, paddy stem borer, rice leaf roller are had favorable effect.
Claims (6)
1. the Pesticidal combination of fluorine-containing uride and fipronil bisamide, it is characterized in that: the percentage by weight of fluorine uride and fipronil bisamide is 1～80%: 1～80%.
2. Pesticidal combination according to claim 1 is characterized in that: the percentage by weight of A, two kinds of active components of B is 2～60%: 2～60%.
3. Pesticidal combination according to claim 2 is characterized in that: the percentage by weight of fluorine uride and fipronil bisamide is 5～40%: 5～40%.
4. Pesticidal combination according to claim 1 is characterized in that: composition is processed wetting powder, water dispersible granules, suspending agent.
5. Pesticidal combination according to claim 1 is used to prevent and treat the application of the insect on cereal class, vegetables, ornamental plants, the fruit tree.
6. application according to claim 5 is characterized in that: Pesticidal combination is used to prevent and treat rice fulgorid, rice-stem borer, paddy stem borer, rice leaf roller, beet armyworm, diamond-back moth, peach fruit borer, apple leaf miner.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110199225A CN102318629A (en) | 2011-07-15 | 2011-07-15 | Insecticidal composition containing novaluron and flubendiamide |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110199225A CN102318629A (en) | 2011-07-15 | 2011-07-15 | Insecticidal composition containing novaluron and flubendiamide |
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| Publication Number | Publication Date |
|---|---|
| CN102318629A true CN102318629A (en) | 2012-01-18 |
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| CN201110199225A Pending CN102318629A (en) | 2011-07-15 | 2011-07-15 | Insecticidal composition containing novaluron and flubendiamide |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2258194A2 (en) * | 2004-11-04 | 2010-12-08 | Makhteshim Chemical Works Limited | Pesticidal composition |
| CN102057933A (en) * | 2010-12-21 | 2011-05-18 | 威海韩孚生化药业有限公司 | Suspending agent containing chlorantraniliprole and novaluron and preparation method thereof |
| CN102379282A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing benzoylurea insecticide |
-
2011
- 2011-07-15 CN CN201110199225A patent/CN102318629A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2258194A2 (en) * | 2004-11-04 | 2010-12-08 | Makhteshim Chemical Works Limited | Pesticidal composition |
| CN102057933A (en) * | 2010-12-21 | 2011-05-18 | 威海韩孚生化药业有限公司 | Suspending agent containing chlorantraniliprole and novaluron and preparation method thereof |
| CN102379282A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing benzoylurea insecticide |
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Application publication date: 20120118 |